CN103704256A - Sterilization insecticidal combination containing iprodione - Google Patents
Sterilization insecticidal combination containing iprodione Download PDFInfo
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- CN103704256A CN103704256A CN201310745943.2A CN201310745943A CN103704256A CN 103704256 A CN103704256 A CN 103704256A CN 201310745943 A CN201310745943 A CN 201310745943A CN 103704256 A CN103704256 A CN 103704256A
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Abstract
The invention relates to a sterilization insecticidal combination containing iprodione. Imicyafos and the abietic acid ketone which serve as effective components are mixed; the weight ratio of the two effective components is (1-50):(1-50), and preferably the weight ratio is (3-25):(5-25). The sterilization insecticidal combination comprises 1-80 percent of the effective components by weight, preferably 5-35 percent of the effective components, and the balance being pesticidally available and acceptable auxiliary components. Wettable powder, a suspending agent, a microemulsion, an emulsion in water and a water dispersible granule can be prepared by a known method. The sterilization insecticidal combination containing the iprodione is mainly used for preventing and treating pest diseases of crops such as grains, cottons, oil, fruits, vegetables and flowers.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, be specifically related to a kind ofly contain agricultural chemicals Imicyafos and different bacteruria is two yuan of composite insecticidal and bactericidal compositions of active ingredient.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
Iprodione is that dicarboximide class is efficient, wide spectrum, contact killing type bactericide, has certain therapeutic action simultaneously, also can play systemic action by root absorption.By Profilin kinases, control the thin intracellular signal of many cell functions, comprise that carbohydrate is in conjunction with the interference effect that enters fungal cell's component.Therefore, it gets final product sprouting and the generation of Antifungi spore, also can suppress mycelial growth.Be applicable to the various vegetables such as melon, tomato, capsicum, eggplant, landscape flower, lawn and ornamental plants etc.The disease of main controlling object for being caused by botrytis, corn marigold, Alternariaspp, sclerotinite etc.As gray mold, early blight, black spot, stalk break etc.Can effectively prevent and treat the fungi that benzimidazole systemic fungicide is had to resistance.
Long-term use single insecticide or bactericide, insect or germ are easy to develop immunity to drugs, and pesticide dosage is increased, and cause large, residual many, the adverse consequences such as drug effect is poor of high poison, consumption, and effect field are more single.The different mechanisms of action and without the insecticide of cross resistance and bactericide rational mixture by a certain percentage, can improve crop disease prevention effect, reduce dosage, residual few, minimizing environmental pollution, effectively reduces the pesticide resistance of crop.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Fungicidal insecticidal composition that contains different bacteruria, said composition contains A, two kinds of effective active components of B, and component A selects novel pesticide Imicyafos; B is selected from different bacteruria; it is wide that the present composition has effect field, can desinsection again can sterilization, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention a kind ofly be take novel pesticide Imicyafos and different bacteruria and is carried out two yuan of insecticidal and bactericidal composition preparations that are mixed as active ingredient, wherein in insecticidal and bactericidal composition of the present invention, the ratio of weight and number of active ingredient novel pesticide Imicyafos and different bacteruria is 1～50: 50～1, on the basis of test recipe screening targetedly, the ratio of weight and number of active ingredient novel pesticide Imicyafos and different bacteruria can be preferably to 3～25: 25～5.
Agricultural insecticide bactericidal composition of the present invention is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules by the formulations of pesticide that the preparation method in pesticidal preparations field can be prepared into, in preparation, to account for the portion rate of gross weight in preparation be 1%～80% to active ingredient gross weight, on the basis of test recipe screening targetedly, in preparation, to account for the portion rate of gross weight in preparation be 3%～35% to active ingredient gross weight, and all the other are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, different bacteruria are dissolved completely with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula, active principle A and active principle B and dispersant, wetting agent and filler are mixed, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first mixing other auxiliary agents, through high speed shear, mix, add active principle A and active principle B, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: by above-mentioned formula, active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, pulls open powder copper rosinate X., wetting and penetrating agent F, at least one in alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10at least one in aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, the multiple fungal diseases of vegetables, flowers all has favorable effect, especially to the diseases such as leaf spot, powdery mildew, rust, downy mildew, epidemic disease, anthracnose and rice blast are had to excellent preventive effect.For example prevent and treat stinking smut, head blight; Rice blast, banded sclerotial blight; Sclerotinia rot of colza; Cotton disease; Sweet potato black rot; Cucurbits powdery mildew, anthracnose, gray mold; Kidney bean gray mold; Powdery mildew of pea, brown spot; Floral crops diseases, the diseases such as downy mildew of garpe, wheat rust, melon anthracnose and downy mildew have excellent preventive effect.Insecticidal and bactericidal composition of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, thrips insect, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Semiptera insect, damp insects, centipede insects, thousand-legger class.Especially to destroy the insect of agriculture horticultural crop and trees etc., the insect of destroying the seed of agriculture horticultural crop and trees in soil, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, Semiptera insect preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.In addition the insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thrips are all had to favorable effect.
In addition, insecticidal and bactericidal composition of the present invention is compared similar medicament also a lot of other obvious advantages, the first, compare single dose sphere of action wider, can desinsection again can diseases prevention; The second, greatly delayed the drug-fast generation of crop, reduced agricultural chemicals Reusability number of times, reduced agricultural chemicals usage amount, reduce agricultural cost; The 3rd, the residual quantity of this insecticidal and bactericidal composition is lower, more friendly to environment; Finally in the application of this insecticidal and bactericidal composition, crops are had to general fresh-keeping production-increasing function, the increasing both production and income of agricultural region is significant.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio of below mentioning (comprising percentage) is all ratio of weight and number.
Embodiment 1: by imicyafos15 part, 10 parts of different bacterurias, 8 parts of lignosulfonates, 12 parts of lauryl sodium sulfate and 55 parts of mixing of diatomite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 2: by imicyafos4 part, 26 parts of different bacterurias, 12 parts of alkylphenol polyoxyethylene, 8 parts of oxygen ethene triphenylethylene phosphenylic acid salt and 50 parts of mixing of bentonite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 3: by imicyafos22 part, 8 parts of different bacterurias, 8 parts of dispersants, 12 parts of wetting agents and 50 parts of mixing of filler, uniform stirring in stirred tank is mixing after airslide disintegrating mill, makes the wetting powder of Pesticidal combination of the present invention.
Embodiment 4: by 8 parts of alkylphenol polyoxyethylene, 2 parts of glycerine, 4 parts of CMCs, 2 parts of silicone oil, 58 parts of mixing of water, through high speed shear, mix, add successively 10 parts of imicyafos18 part, different bacterurias, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 5: by 12 parts of dispersants, 2 parts of antifreezing agents, 5 parts of thickeners, 1 part of defoamer, 57 parts of mixing of water, through high speed shear, mix, add successively 8 parts of imicyafos15 part, different bacterurias, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 6: by 10 parts of dispersants, 2 parts of antifreezing agents, 4 parts of thickeners, 1 part of defoamer, 53 parts of mixing of water, through high speed shear, mix, add successively 18 parts of imicyafos12 part, different bacterurias, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 7: 4 parts of imicyafos25 parts, 5 parts of different bacterurias, 14 parts, turpentine oil, 6 parts of castor oil polyoxyethylene ethers, resorcinol are mixed, be dissolved into uniform oil phase; 1 part, part water, 2 parts of propane diols, silicone compound is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 5 parts of polyvinyl alcohol, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, and shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 8: 8 parts of imicyafos5 parts, 25 parts of different bacterurias, 15 parts of solvents, 10 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 9: 9 parts of imicyafos12 parts, 16 parts of different bacterurias, 17 parts of solvents, 8 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 10: 51 parts of imicyafos18 part, 10 parts of different bacterurias, 8 parts of aliphatic amine polyoxyethylene ethers, 8 parts of alkylnaphthalene sulfonates, 5 parts, aluminium chloride and bentonites are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 11: 48 parts of imicyafos18 part, 12 parts of different bacterurias, 8 parts of dispersants, 10 parts of wetting agents, 4 parts of disintegrants and fillers are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 12: 48 parts of imicyafos11 part, 18 parts of different bacterurias, 8 parts of dispersants, 12 parts of wetting agents, 3 parts of disintegrants and fillers are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 13: 22 parts of former medicine imicyafos10 parts, different bacteruria are dissolved completely with cosolvent, add again other compositions such as 8 parts of aliphatic acid polyethenoxy base esters, 2 parts of ethylene glycol, 4 parts of sodium citrates, 4 parts of resorcinols, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Embodiment 14: 16 parts of former medicine imicyafos12 parts, different bacteruria are dissolved completely with cosolvent, then add other compositions such as 9 parts of emulsifier, 2 parts of antifreezing agents, 7 parts of stabilizing agents, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Embodiment 15: 8 parts of former medicine imicyafos18 parts, different bacteruria are dissolved completely with cosolvent, then add other compositions such as 9 parts of emulsifier, 2 parts of antifreezing agents, 10 parts of stabilizing agents, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Field experiment: the control to Cucumber Pests And Diseases
(1) investigation method
Experimental field be located at Shouguang, Shandong, select the medium cucumber field of occurring degree for experimental field, soil fertility is medium, and irrigation and drainage are convenient.Adopt bilinear sampling method, 5 points are got in every community, look into 5 caves at every, and during investigation, 2 blades in the fixing middle part of every strain fix a point to check.
According to gray mold of cucumber grade scale, carry out classification, record total strain number, diseased plant number, severity, calculate diseased plant rate, disease index and preventive effect.Gray mold of cucumber grade scale is:
0 grade: without scab;
1 grade: lesion area accounts for below 5% of whole leaf area;
3 grades: lesion area accounts for 6%～10% of whole leaf area;
5 grades: lesion area accounts for 11%～25% of whole leaf area;
7 grades: lesion area accounts for 26%～50% of whole leaf area;
9 grades: lesion area accounts for the more than 50% of whole leaf area.
(2) control time and number of times
Test is investigated 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 10 days after the 1st medicine, 10 days and preventive effect investigation in 20 days after 2 medicines.
(3) drug effect computational methods
The total number of sheets * 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets * relative level numerical value at different levels)/(investigating the total number of sheets * 9) * 100
Control efficiency (%)=(disease index after the front disease index * treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index * treatment region medicine after blank district medicine)) * 100.
(4) poisoning investigation method
After dispenser, whether 7d range estimation medicament has poisoning to crop continuously.
(5) experimental result and analysis
Table 1 is respectively organized the test effect that test medicine is processed control gray mold of cucumber
As can be seen from Table 1, the effect of the combination control gray mold of cucumber that is mixed that the ratio of weight and number of 30%imicyafos iprodione is 8: 22 is very remarkable, and effect is significantly better than single dose, and its quick-acting and lasting effect are all relatively good, especially outstanding with lasting effect.Complex preparation control efficiency under the consumption of high concentration is significantly better than the effect under low concentration consumption.After after the 1st, 2 medicines, the best control efficiency of 10 days reaches respectively 85.21% and 87.57%, the 2 medicine, 20 days best preventive effects reach 99.78%.And 20 days best preventive effects are 79.42% after the 2nd medicine of single dose 50% iprodione WP, the effect of complex preparation is significantly better than single dose.According to field range estimation, with the cucumber of 30%imicyafos iprodione, substantially there is no insect pest, and growth fraction is more vigorous, and the cucumber of 50% iprodione WP single dose occurs that insect pest is more, than much approximately 15% left and right of insect pest plant with complex preparation.
Within the scope of test dose, plant growth is normal in addition, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.
Claims (5)
1. a Fungicidal insecticidal composition that contains different bacteruria, is characterized in that: this Fungicidal insecticidal composition is to take A novel pesticide Imicyafos and the different bacteruria of B as two yuan of composite composite preparations of active ingredient, and all the other components are usual auxiliaries in agricultural chemicals,
A novel agrochemical Imicyafos,
In this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 1～50: 50～1.
2. a kind of Fungicidal insecticidal composition that contains different bacteruria according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 3～25: 25～5.
3. a kind of Fungicidal insecticidal composition that contains different bacteruria according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, to account for the portion rate of gross weight in preparation be 1%～80% for effective constituents A and B gross weight.
4. a kind of Fungicidal insecticidal composition that contains different bacteruria according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, effective constituents A and B gross weight account for the portion rate of gross weight in preparation and be preferably 5%～35%.
5. a kind of Fungicidal insecticidal composition that contains different bacteruria according to claim 1, is characterized in that: the preparation formulation that insecticidal and bactericidal composition of the present invention can be mixed with is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310745943.2A CN103704256A (en) | 2013-12-30 | 2013-12-30 | Sterilization insecticidal combination containing iprodione |
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| CN201310745943.2A CN103704256A (en) | 2013-12-30 | 2013-12-30 | Sterilization insecticidal combination containing iprodione |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058407A (en) * | 1990-07-06 | 1992-02-05 | 安哥洛商株式会社 | Desinsection, mite and nematode agent that organo phosphorous compounds and preparation method thereof is relevant |
| CN1909781A (en) * | 2004-01-23 | 2007-02-07 | 石原产业株式会社 | Noxious organism controlling composition and method for controlling the noxious organism |
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2013
- 2013-12-30 CN CN201310745943.2A patent/CN103704256A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058407A (en) * | 1990-07-06 | 1992-02-05 | 安哥洛商株式会社 | Desinsection, mite and nematode agent that organo phosphorous compounds and preparation method thereof is relevant |
| CN1909781A (en) * | 2004-01-23 | 2007-02-07 | 石原产业株式会社 | Noxious organism controlling composition and method for controlling the noxious organism |
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Application publication date: 20140409 |