CN103190421A - Cyflufenamid-containing sterilizing composite - Google Patents
Cyflufenamid-containing sterilizing composite Download PDFInfo
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- CN103190421A CN103190421A CN2013101166832A CN201310116683A CN103190421A CN 103190421 A CN103190421 A CN 103190421A CN 2013101166832 A CN2013101166832 A CN 2013101166832A CN 201310116683 A CN201310116683 A CN 201310116683A CN 103190421 A CN103190421 A CN 103190421A
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- cyflufenamid
- sterilization component
- sterilization
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Links
- 239000005755 Cyflufenamid Substances 0.000 title claims abstract description 83
- ACMXQHFNODYQAT-UHFFFAOYSA-N cyflufenamid Chemical compound FC1=CC=C(C(F)(F)F)C(C(NOCC2CC2)=NC(=O)CC=2C=CC=CC=2)=C1F ACMXQHFNODYQAT-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 39
- 239000002131 composite material Substances 0.000 title abstract description 11
- 150000003851 azoles Chemical class 0.000 claims abstract description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000000035 biogenic effect Effects 0.000 claims abstract description 5
- 150000002460 imidazoles Chemical class 0.000 claims abstract description 5
- 150000002916 oxazoles Chemical class 0.000 claims abstract description 5
- 239000011593 sulfur Substances 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 110
- 238000004659 sterilization and disinfection Methods 0.000 claims description 37
- 241000221785 Erysiphales Species 0.000 claims description 22
- 201000010099 disease Diseases 0.000 claims description 22
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 22
- 241000233679 Peronosporaceae Species 0.000 claims description 15
- 206010039509 Scab Diseases 0.000 claims description 15
- 241000894006 Bacteria Species 0.000 claims description 14
- 241000196324 Embryophyta Species 0.000 claims description 14
- 230000000844 anti-bacterial effect Effects 0.000 claims description 13
- 241000209140 Triticum Species 0.000 claims description 12
- 235000021307 Triticum Nutrition 0.000 claims description 12
- -1 fluorine ring azoles Chemical class 0.000 claims description 12
- 240000008067 Cucumis sativus Species 0.000 claims description 11
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 11
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 10
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 claims description 10
- 239000005869 Pyraclostrobin Substances 0.000 claims description 8
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 8
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 8
- OICGFSUWXCJLCO-UHFFFAOYSA-N 1-ethylsulfonylsulfanylethane Chemical compound CCSS(=O)(=O)CC OICGFSUWXCJLCO-UHFFFAOYSA-N 0.000 claims description 7
- SOUGWDPPRBKJEX-UHFFFAOYSA-N 3,5-dichloro-N-(1-chloro-3-methyl-2-oxopentan-3-yl)-4-methylbenzamide Chemical compound ClCC(=O)C(C)(CC)NC(=O)C1=CC(Cl)=C(C)C(Cl)=C1 SOUGWDPPRBKJEX-UHFFFAOYSA-N 0.000 claims description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 7
- 229930182764 Polyoxin Natural products 0.000 claims description 7
- 239000005863 Zoxamide Substances 0.000 claims description 7
- 239000011737 fluorine Substances 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 7
- 150000002576 ketones Chemical class 0.000 claims description 7
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 claims description 7
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 6
- 239000005774 Fenamidone Substances 0.000 claims description 6
- 239000005839 Tebuconazole Substances 0.000 claims description 6
- FROZIYRKKUFAOC-UHFFFAOYSA-N amobam Chemical compound N.N.SC(=S)NCCNC(S)=S FROZIYRKKUFAOC-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- LMVPQMGRYSRMIW-KRWDZBQOSA-N fenamidone Chemical compound O=C([C@@](C)(N=C1SC)C=2C=CC=CC=2)N1NC1=CC=CC=C1 LMVPQMGRYSRMIW-KRWDZBQOSA-N 0.000 claims description 6
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 claims description 6
- AMNAZJFEONUVTD-KEWDHRJRSA-N (2s,3s,4s,5r,6r)-6-(4-amino-2-oxopyrimidin-1-yl)-4,5-dihydroxy-3-[[(2s)-3-hydroxy-2-[[2-(methylamino)acetyl]amino]propanoyl]amino]oxane-2-carboxamide Chemical compound O1[C@H](C(N)=O)[C@@H](NC(=O)[C@H](CO)NC(=O)CNC)[C@H](O)[C@@H](O)[C@@H]1N1C(=O)N=C(N)C=C1 AMNAZJFEONUVTD-KEWDHRJRSA-N 0.000 claims description 5
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 claims description 5
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 claims description 5
- 239000005745 Captan Substances 0.000 claims description 5
- 239000005761 Dimethomorph Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- FEACDOXQOYCHKU-UHFFFAOYSA-N Gougerotin Natural products CNCC(=O)NC1=NC(=O)N(C=C1)C2OC(C(O)C(NC(=O)C(N)CO)C2O)C(=O)N FEACDOXQOYCHKU-UHFFFAOYSA-N 0.000 claims description 5
- 239000005805 Mepanipyrim Substances 0.000 claims description 5
- 239000005807 Metalaxyl Substances 0.000 claims description 5
- 239000005868 Metconazole Substances 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000005822 Propiconazole Substances 0.000 claims description 5
- 239000005864 Sulphur Substances 0.000 claims description 5
- 239000005846 Triadimenol Substances 0.000 claims description 5
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 5
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 5
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 5
- 229940117949 captan Drugs 0.000 claims description 5
- CIFWZNRJIBNXRE-UHFFFAOYSA-N mepanipyrim Chemical compound CC#CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 CIFWZNRJIBNXRE-UHFFFAOYSA-N 0.000 claims description 5
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 claims description 5
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 claims description 5
- UWVQIROCRJWDKL-UHFFFAOYSA-N oxadixyl Chemical compound CC=1C=CC=C(C)C=1N(C(=O)COC)N1CCOC1=O UWVQIROCRJWDKL-UHFFFAOYSA-N 0.000 claims description 5
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims description 5
- 229960005322 streptomycin Drugs 0.000 claims description 5
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 claims description 5
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical group C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 239000005740 Boscalid Substances 0.000 claims description 2
- 239000005741 Bromuconazole Substances 0.000 claims description 2
- 244000241235 Citrullus lanatus Species 0.000 claims description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims description 2
- 241000675108 Citrus tangerina Species 0.000 claims description 2
- IWDQPCIQCXRBQP-UHFFFAOYSA-M Fenaminosulf Chemical compound [Na+].CN(C)C1=CC=C(N=NS([O-])(=O)=O)C=C1 IWDQPCIQCXRBQP-UHFFFAOYSA-M 0.000 claims description 2
- 241000220225 Malus Species 0.000 claims description 2
- 235000011430 Malus pumila Nutrition 0.000 claims description 2
- 235000015103 Malus silvestris Nutrition 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 241000220324 Pyrus Species 0.000 claims description 2
- 239000005859 Triticonazole Substances 0.000 claims description 2
- GAMFEMAXLMWCRG-UHFFFAOYSA-N bis(dimethylcarbamothioylsulfanyl)arsanyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)S[As](SC(=S)N(C)C)SC(=S)N(C)C GAMFEMAXLMWCRG-UHFFFAOYSA-N 0.000 claims description 2
- 229940118790 boscalid Drugs 0.000 claims description 2
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 claims description 2
- HJJVPARKXDDIQD-UHFFFAOYSA-N bromuconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCC(Br)C1 HJJVPARKXDDIQD-UHFFFAOYSA-N 0.000 claims description 2
- CWVRPJSBNHNJSI-XQNSMLJCSA-N coumoxystrobin Chemical compound C1=C2OC(=O)C(CCCC)=C(C)C2=CC=C1OCC1=CC=CC=C1\C(=C/OC)C(=O)OC CWVRPJSBNHNJSI-XQNSMLJCSA-N 0.000 claims description 2
- AWZOLILCOUMRDG-UHFFFAOYSA-N edifenphos Chemical compound C=1C=CC=CC=1SP(=O)(OCC)SC1=CC=CC=C1 AWZOLILCOUMRDG-UHFFFAOYSA-N 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- FCOAHACKGGIURQ-UHFFFAOYSA-N iprobenfos Chemical compound CC(C)OP(=O)(OC(C)C)SCC1=CC=CC=C1 FCOAHACKGGIURQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- 235000021017 pears Nutrition 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims 2
- 229920001542 oligosaccharide Polymers 0.000 claims 2
- 150000002482 oligosaccharides Chemical class 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 20
- 238000001228 spectrum Methods 0.000 abstract description 5
- 230000002070 germicidal effect Effects 0.000 abstract 9
- 239000004615 ingredient Substances 0.000 abstract 9
- 239000004480 active ingredient Substances 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- BSDQITJYKQHXQR-UHFFFAOYSA-N methyl prop-2-eneperoxoate Chemical compound COOC(=O)C=C BSDQITJYKQHXQR-UHFFFAOYSA-N 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 description 26
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 239000003814 drug Substances 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- RQFQJYYMBWVMQG-IXDPLRRUSA-N chitotriose Chemical compound O[C@@H]1[C@@H](N)[C@H](O)O[C@H](CO)[C@H]1O[C@H]1[C@H](N)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)N)[C@@H](CO)O1 RQFQJYYMBWVMQG-IXDPLRRUSA-N 0.000 description 6
- 230000000855 fungicidal effect Effects 0.000 description 5
- 241000510928 Erysiphe necator Species 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 244000052363 Cynodon dactylon Species 0.000 description 3
- 241000219095 Vitis Species 0.000 description 3
- 230000035784 germination Effects 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 125000002971 oxazolyl group Chemical group 0.000 description 3
- 244000052769 pathogen Species 0.000 description 3
- 230000001717 pathogenic effect Effects 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000004071 biological effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 241000233652 Chytridiomycota Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000582441 Peronospora tabacina Species 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 239000008223 sterile water Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention provides a cyflufenamid-containing sterilizing composite. The composite mainly comprises an effective dose of A and an effective dose of B, wherein A is cyflufenamid, and B is selected from a methoxy acrylate germicidal ingredient, a germicidal ingredient of azoles, a sulfur-containing germicidal ingredient, a germicidal ingredient of amides, a germicidal ingredient of miazines, a biogenic germicidal ingredient, a germicidal ingredient of imidazoles, a germicidal ingredient of oxazoles or a germicidal ingredient of organophosphates. The active ingredients in the composite provided by the invention have obvious synergism effect; the control spectrum can be spread by using the composite; and the usage cost is reduced.
Description
Technical field
The present invention relates to contain the bactericidal composition of cyflufenamid, be specifically related to a kind of bactericidal composition that contains cyflufenamid, belong to the plant protection field, composition is for the powdery mildew of preventing and treating grain reality, cotton, oil plant, fruit tree, vegetables, flowers etc., leaf spot, scab, bakanae disease, downy mildew, brown spot etc.
Background technology
Cyflufenamid belongs to the new type bactericide of oxime ethers, is a kind of protective fungicide of Japanese Cao Da company exploitation, and the powdery mildew of various plants, leaf spot, scab, bakanae disease, downy mildew, brown spot etc. are had good effect.Carrying out the research of compounded technology, is to carry out synergy research, expanding prevention spectrum, reduce use cost, delay drug-fast effect.At present less about the report of cyflufenamid and the composite research of other sterilization component.The inventor has found some beyond thought effects by the big quantity research to the composite effect of cyflufenamid.
Summary of the invention
The object of the present invention is to provide the bactericidal composition that contains cyflufenamid, it is that sterilization component with two kinds of different structures, the different mechanisms of action carries out composite, be expanding prevention spectrum and the effective way that improves drug effect, the more important thing is and avoid or delay disease to the generation of new composition resistance.For realizing purpose of the present invention, the inventor is composite with the compound with sterilization component with cyflufenamid, is used for the disease on control crop, lawn.
The objective of the invention is to realize by following measures.
The bactericidal composition that contains cyflufenamid, it is characterized in that said composition comprises A and two kinds of components of B of synergy effective dose, A is cyflufenamid, B is selected from methoxy acrylic sterilization component pyraclostrobin, ZJ0712, azoles bacterium ester, SYP-3375, a kind of in the 2-cyano-3-amino-3-phenylancryic acetate, or azole sterilization component propiconazole, Tebuconazole, Flusilazole, Triadimenol, metconazole, fluorine ring azoles, own azoles alcohol, bromuconazole, a kind of in the triticonazole, or sulfur-bearing class sterilization component ambam, S-Ethyl ethylthio sulfonate, tpn, sulphur, tmtd, captan, asomate, sulfonat, a kind of in the fenaminosulf, or amide-type sterilization component dimethomorph, zoxamide, metalaxyl, the fluorine Boscalid, a kind of in the efficient M 9834, or biogenic class sterilization component polyoxin, kasugarnycin, chitosan oligosaccharide, streptomycin, Ningnanmycin, a kind of in the jinggangmeisu, or imidazoles sterilization component Fenamidone, or oxazole class sterilization Cheng Fen oxazole bacterium ketone, a kind of in the Wakil, or the phonetic phenol of miazines sterilization component second, a kind of in the fluorine mepanipyrim, or organic phosphates sterilization component iprobenfos, a kind of in the edifenphos.The ratio of quality and the number of copies of A component and B component is 1:100-20:1 in the composition.
In the composition of the present invention, more preferably technical scheme is: component A is selected from cyflufenamid, B component is selected from B and is selected from methoxy acrylic sterilization component pyraclostrobin, ZJ0712, a kind of in the azoles bacterium ester, or the azole sterilization component is selected from propiconazole, Tebuconazole, Flusilazole, Triadimenol, metconazole, fluorine ring azoles, a kind of in the own azoles alcohol, or sulfur-bearing class sterilization component ambam, S-Ethyl ethylthio sulfonate, tpn, sulphur, tmtd, a kind of in the captan, or amide-type sterilization component dimethomorph, zoxamide, a kind of in the metalaxyl, or biogenic class sterilization component polyoxin, kasugarnycin, chitosan oligosaccharide, streptomycin, a kind of in the Ningnanmycin, or the imidazoles sterilization component is selected from Fenamidone, or oxazole class sterilization Cheng Fen oxazole bacterium ketone, a kind of in the Wakil, or the phonetic phenol of miazines sterilization component second, a kind of in the fluorine mepanipyrim.Between A, B two components more preferably ratio of quality and the number of copies be 1:40-10:1.
The 1-90% of the quality sum composition gross mass of A component and B component in the present composition.
Above-mentioned composition of the present invention can be made into suspending agent, wetting powder, water dispersible granules, aqua, microemulsion, aqueous emulsion, is used for spraying, irritates root, seed dressing etc.
The present invention finds that also above-mentioned composition has good synergy control efficiency to grape powdery mildew, powdery mildew of cucumber and downy mildew, wheat powdery mildew and leaf spot, turfgrass powdery mildew and brown spot, and synergistic effect is obvious.
The present invention also provides above-mentioned composition to prevent and treat the purposes of one or more diseases of one or more plants.The disease of suitable control has, the fungus-caused powdery mildew of Ascomycotina, anthracnose, leaf spot etc., the fungus-caused downy mildew of Mastigomycotina, late blight, peronospora tabacina etc., the rust that Basidiomycotina causes, smut etc., the fungus-caused bakanae disease of Fungi Imperfecti, scab etc.Therefore,
In the such use, the plant that prevents and treats disease is wheat, cucumber, grape, watermelon, apple, grape, oranges and tangerines, pears, lichee, paddy rice, flowers, lawn etc.
The plant disease that the present composition is used for control is preferably powdery mildew, downy mildew, leaf spot, scab, rust or bakanae disease.
Beneficial effect of the present invention is:
1, synergistic effect is obvious: composition is the good synergistic effect of performance in certain ratio range, has improved the protection effect of composition.
2, expanding prevention spectrum: but the multiple diseases on the composition plant.
3, reduce use cost: because of compositely have the preventive effect of raising, the control spectrum increases, and has reduced access times, has reduced use cost;
4, delay pesticide resistance: the composition of two kinds of different mechanism of action is composite, and pathogen is difficult for developing immunity to drugs, and delays pathogen to the drug-fast generation of single agent.
Embodiment
Following examples are to further specify of the present invention, but the present invention is not confined to composition and purposes in the present embodiment.
Embodiment 1 cyflufenamid composition is to the room effect of grape powdery mildew
Adopting the spore germination method, is reference with trial test concentration, respectively with single agent A and the former medicinal suitable solvent dilution of single agent B.Get it filled agent 10 μ L points on slide, dry to make the medicine film under the dustproof condition.To infect the white powder grape and cut, with the mould layer of white powder shape under the writing brush brush, add the spore suspension that sterile water is made debita spissitudo.10 μ L spore suspensions are added drop-wise on the medicine film.Behind the cultivation 16h that preserves moisture under 20 ℃, check the sprouting situation of spore.After about the germination rate of blank reaches 80%, check the germination rate of all processing.Be sprouting with spore germ tube length greater than spore short radius person, be calculated as follows the inhibition germination rate.
X is the preventive effect of the active component A of working concentration when being a, and y is the preventive effect of the active component B of working concentration when being b.Relatively theoretical effect and actual effect are estimated the synergy of composition, are synergistic effect with actual preventive effect during greater than theoretical preventive effect.The results are shown in Table 1.
Table 1 cyflufenamid composition is to the effect of the former bacterium of grape powdery mildew
By potted plant test, as seen from Table 1, the composition of cyflufenamid and pyraclostrobin, the composition of cyflufenamid and ZJ0712, the composition of cyflufenamid and propiconazole, the composition of cyflufenamid and Tebuconazole, the composition of cyflufenamid and Flusilazole, the composition of cyflufenamid and ambam, the composition of cyflufenamid and S-Ethyl ethylthio sulfonate, the composition of cyflufenamid and polyoxin, the composition of cyflufenamid and kasugarnycin, the composition of cyflufenamid and chitosan oligosaccharide, the composition of cyflufenamid and Fenamidone to the effect of bakanae disease of rice all be higher than composition theoretical preventive effect.Obviously, the composite of cyflufenamid and above-mentioned Fungicidal compounds is synergy to grape powdery mildew.
Embodiment 2 cyflufenamid compositions are to the control efficiency of powdery mildew of cucumber
Unification compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to the biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration that needs.During test, cucumber plant is investigated the powdery mildew incidence substantially in 4 leaf phases before the 1st medicine.Carried out the sick pot experiment of powdery mildew of cucumber with the cyflufenamid composition, and established corresponding single agent and blank, adopted the conventional conventional spray of manual sprayer, every medicament sprays 10 strains, and spraying, 7-10d sprays 1 time again after 1 time.10-14d investigation after the 2nd dispenser, whole blades are investigated in every strain, and the total number of sheets of record investigation, the sick number of sheets are calculated disease index and preventive effect according to following stage division.
The blade staging:
0 grade: anosis
1 grade: the continuous area of scab accounts for below 1% of whole leaf area;
3 grades: the continuous area of scab accounts for the 1%-10% of whole leaf area;
5 grades: the continuous area of scab accounts for the 11%-20% of whole leaf area;
7 grades: the continuous area of scab accounts for the 21%-50% of whole leaf area;
9 grades: the continuous area of scab accounts for more than 51% of whole leaf area;
X is the preventive effect of the active component A of working concentration when being a, and y is the preventive effect of the active component B of working concentration when being b.Relatively theoretical effect and actual effect are estimated the synergy of composition, are synergistic effect with actual preventive effect during greater than theoretical preventive effect.The results are shown in Table 2.
Table 2 cyflufenamid composition is to the control efficiency of powdery mildew of cucumber, downy mildew
Annotate: in last row " downy mildew ", the grade scale of disease occurrence degree is in the table 2: " +++" represent that the downy mildew generation is heavier, " ++ " expression downy mildew takes place medium, and "+" expression downy mildew has generation, and "-" represents not take place substantially downy mildew.
The potted plant test of powdery mildew of cucumber is found the composition of cyflufenamid and pyraclostrobin by the cyflufenamid composition, the composition of cyflufenamid and azoles bacterium ester, the composition of cyflufenamid and Triadimenol, the composition of cyflufenamid and metconazole, the composition of cyflufenamid and tpn, the composition of cyflufenamid and sulphur, the composition of cyflufenamid and S-Ethyl ethylthio sulfonate, the composition of cyflufenamid and dimethomorph, the composition of cyflufenamid and zoxamide, the composition of cyflufenamid and chitosan oligosaccharide, the composition of cyflufenamid and streptomycin, cyflufenamid is Yu the composition of oxazole bacterium ketone all is higher than the theoretical preventive effect of correspondent composition to the effect of cucumber downy mildew.Obviously, the composition of cyflufenamid and above-mentioned Fungicidal compounds is synergy to cucumber downy mildew.Beyond thought in addition is that composition is light to the more single agent of the generation of cucumber downy mildew.
Embodiment three: the cyflufenamid composition is to the wheat powdery mildew field trial
Carried out the wheat powdery mildew field trial with composition, and established corresponding single agent and blank, every medicament is established residential quarter 10m
2Adopt the conventional conventional spray of knapsack sprayer, test is respectively sprayed 1 time in booting and flowering initial stage, 7～10d investigates before medicine and after the 2nd dispenser, every processing is by 5 samplings, every 50 strains, whole blades are investigated in every strain, and the total number of sheets of record investigation, the sick number of sheets are calculated disease index and preventive effect according to following stage division.
The blade staging:
0 grade: anosis
1 grade: the continuous area of scab accounts for below 1% of whole leaf area;
3 grades: the continuous area of scab accounts for the 1%-5% of whole leaf area;
5 grades: the continuous area of scab accounts for the 6%-25% of whole leaf area;
7 grades: the continuous area of scab accounts for the 26%-50% of whole leaf area;
9 grades: the continuous area of scab accounts for more than 51% of whole leaf area;
X is the preventive effect of the active component A of working concentration when being a, and y is the preventive effect of the active component B of working concentration when being b.Relatively theoretical effect and actual effect are estimated the synergy of composition, are synergistic effect with actual preventive effect during greater than theoretical preventive effect.The bactericidal composition that contains cyflufenamid the results are shown in Table 3 to the control efficiency of wheat powdery mildew.
Table 3 contains the bactericidal composition of cyflufenamid to wheat powdery mildew, leaf rust field effect
Annotate: in last row in the table 3 " wheat leaf rust ", the grade scale of disease occurrence degree is: " ++ ++ " expression leaf rust takes place heavy, and " +++" expression leaf rust takes place heavier, and " ++ " expression leaf rust takes place medium, "+" expression leaf rust takes place light, and the leaf rust does not take place substantially in "-" expression.
By the cyflufenamid composition wheat powdery mildew is tested discovery, the composition of cyflufenamid and pyraclostrobin, the composition of cyflufenamid and ZJ0712, the composition of cyflufenamid and azoles bacterium ester, the composition of cyflufenamid and fluorine ring azoles, cyflufenamid and own azoles alcohol composition, the composition of cyflufenamid and tmtd, the composition of cyflufenamid and captan, the composition of cyflufenamid and metalaxyl, the composition of cyflufenamid and zoxamide, the composition of cyflufenamid and the phonetic phenol of second, the composition of cyflufenamid and fluorine mepanipyrim, the composition of cyflufenamid and polyoxin, the composition of cyflufenamid and chitosan oligosaccharide, the composition of cyflufenamid and Ningnanmycin, cyflufenamid is Yu the composition of oxazole bacterium ketone, the composition of cyflufenamid and Wakil all is higher than the theoretical preventive effect of correspondent composition to the effect of wheat powdery mildew.Obviously, the composition of cyflufenamid and above-mentioned Fungicidal compounds is synergy to wheat powdery mildew.Beyond thought in addition is that composition is light to the more single agent of generation of wheat leaf rust.
Embodiment four: the cyflufenamid composition is tested the turfgrass disease
Unification compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to the biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration that needs.During mensuration, earlier soup is sprayed on potted plant Bermuda grass weeds, quantitatively inoculate pathogen then, preserve moisture behind the cultivation 24h, place the greenhouse to cultivate, measure the percentage that plant leaf surface infects behind the certain hour.Use the Abbot formula, convert percentage to preventive effect.
X is the preventive effect of the active component A of working concentration when being a, and y is the preventive effect of the active component B of working concentration when being b.Relatively theoretical effect and actual effect are estimated the synergy of composition, are synergistic effect with actual preventive effect during greater than theoretical preventive effect.The results are shown in Table 4.
Table 4 cyflufenamid composition is to the effect of turfgrass disease
Annotate: in last row in the table 4 " a situation arises for brown spot ", the grade scale of disease occurrence degree is: " ++ ++ " represent that brown spot takes place to weigh, " ++ " expression brown spot takes place medium, and "+" expression brown spot takes place light, and brown spot does not take place substantially in "-" expression.
By potted plant test, as seen from Table 1, the composition of cyflufenamid and pyraclostrobin, the composition of cyflufenamid and ZJ0712, the composition of cyflufenamid and Tebuconazole, the composition of cyflufenamid and Flusilazole, the composition of cyflufenamid and ambam, the composition of cyflufenamid and S-Ethyl ethylthio sulfonate, the composition of cyflufenamid and zoxamide, the composition of cyflufenamid and polyoxin, the composition of cyflufenamid and chitosan oligosaccharide, the composition of cyflufenamid and Fenamidone, cyflufenamid Yu the composition of oxazole bacterium ketone to the preventive effect of Bermuda grass powdery mildew all be higher than composition theoretical preventive effect.Obviously, the complex composition of cyflufenamid and above-mentioned Fungicidal compounds is synergy to the Bermuda grass powdery mildew.Beyond thought in addition is that composition is good to the more single agent of the preventive effect of Bermuda grass brown spot.
Claims (7)
1. bactericidal composition that contains cyflufenamid, it is characterized in that said composition comprises A and two kinds of components of B of synergy effective dose, A is cyflufenamid, B is selected from methoxy acrylic sterilization component pyraclostrobin, ZJ0712, azoles bacterium ester, SYP-3375, a kind of in the 2-cyano-3-amino-3-phenylancryic acetate, or azole sterilization component propiconazole, Tebuconazole, Flusilazole, Triadimenol, metconazole, fluorine ring azoles, own azoles alcohol, bromuconazole, a kind of in the triticonazole, or sulfur-bearing class sterilization component ambam, S-Ethyl ethylthio sulfonate, tpn, sulphur, tmtd, captan, asomate, sulfonat, a kind of in the fenaminosulf, or amide-type sterilization component dimethomorph, zoxamide, metalaxyl, the fluorine Boscalid, a kind of in the efficient M 9834, or the phonetic phenol of miazines sterilization component second, a kind of in the fluorine mepanipyrim, or biogenic class sterilization component polyoxin, kasugarnycin, oligosaccharides, streptomycin, Ningnanmycin, a kind of in the jinggangmeisu, or imidazoles sterilization component Fenamidone, or oxazole class sterilization Cheng Fen oxazole bacterium ketone, a kind of in the Wakil, or organic phosphates sterilization component iprobenfos, a kind of in the edifenphos; In the said composition, the ratio of quality and the number of copies of A component and B component is 1:100-20:1.
2. according to the described bactericidal composition of claim 1, it is characterized in that: component A is selected from cyflufenamid, B component is selected from methoxy acrylic sterilization component pyraclostrobin, ZJ0712, a kind of in the azoles bacterium ester, or azole sterilization component propiconazole, Tebuconazole, Flusilazole, Triadimenol, metconazole, fluorine ring azoles, a kind of in the own azoles alcohol, or sulfur-bearing class sterilization component ambam, S-Ethyl ethylthio sulfonate, tpn, sulphur, tmtd, a kind of in the captan, or amide-type sterilization component dimethomorph, zoxamide, a kind of in the metalaxyl, or the phonetic phenol of miazines sterilization component second, a kind of in the fluorine mepanipyrim, or biogenic class sterilization component polyoxin, kasugarnycin, oligosaccharides, streptomycin, a kind of in the Ningnanmycin, or imidazoles sterilization component Fenamidone, or oxazole class sterilization Cheng Fen oxazole bacterium ketone, a kind of in the Wakil; The ratio of quality and the number of copies of A component and B component is 1:40-10:1.
3. according to claim 1 or 2 described bactericidal compositions, it is characterized in that: the quality sum of A component and B component accounts for the 1-90% of composition gross mass.
4. according to the described bactericidal composition of claim 3, it is characterized in that: make suspending agent, wetting powder, water dispersible granules, aqua, microemulsion or aqueous emulsion when said composition is used.
5. the purposes of each described bactericidal composition of claim 1-4 is characterized in that: described composition is used for one or more diseases of one or more plants of control.
6. according to the described purposes of claim 5, wherein plant is wheat, cucumber, grape, watermelon, apple, grape, oranges and tangerines, pears, lichee, paddy rice, flowers or lawn.
7. according to claim 5 or 6 described purposes, it is characterized in that: disease is powdery mildew, downy mildew, leaf spot, scab, rust or bakanae disease.
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| CN201410238282.9A CN103999858B (en) | 2013-04-07 | 2013-04-07 | Bactericidal composition containing cyflufenamid and S-Ethyl ethylthio sulfonate |
| CN201410256893.6A CN103999861B (en) | 2013-04-07 | 2013-04-07 | Bactericidal composition containing cyflufenamid and fenamidone |
| CN201310667629.7A CN103734145B (en) | 2013-04-07 | 2013-04-07 | Sterilization composition containing cyflufenamid and oxazole sterilization components |
| CN201310116683.2A CN103190421B (en) | 2013-04-07 | 2013-04-07 | Cyflufenamid-containing sterilizing composite |
| CN201410256894.0A CN103988838B (en) | 2013-04-07 | 2013-04-07 | Containing cyflufenamid and ethirimol or the bactericidal composition of fluorine mepanipyrim |
| CN201410209509.7A CN103999865B (en) | 2013-04-07 | 2013-04-07 | A kind of bactericidal composition and application containing cyflufenamid and dimethomorph or zoxamide |
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| CN201410256894.0A Division CN103988838B (en) | 2013-04-07 | 2013-04-07 | Containing cyflufenamid and ethirimol or the bactericidal composition of fluorine mepanipyrim |
| CN201410119148.7A Division CN103875669B (en) | 2013-04-07 | 2013-04-07 | Bactericidal composition containing cyflufenamid and chitosan oligosaccharide |
| CN201310667629.7A Division CN103734145B (en) | 2013-04-07 | 2013-04-07 | Sterilization composition containing cyflufenamid and oxazole sterilization components |
| CN201410209509.7A Division CN103999865B (en) | 2013-04-07 | 2013-04-07 | A kind of bactericidal composition and application containing cyflufenamid and dimethomorph or zoxamide |
| CN201410256893.6A Division CN103999861B (en) | 2013-04-07 | 2013-04-07 | Bactericidal composition containing cyflufenamid and fenamidone |
| CN201410209958.1A Division CN103975927B (en) | 2013-04-07 | 2013-04-07 | A kind of bactericidal composition containing cyflufenamid and pyraoxystrobin or ZJ0712 and application |
| CN201410256719.1A Division CN104012543A (en) | 2013-04-07 | 2013-04-07 | Sterilization composition containing cyflufenamid and epoxiconazole |
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| CN106857593A (en) * | 2017-04-17 | 2017-06-20 | 北京科发伟业农药技术中心 | The Fungicidal composition that cyflufenamid goes out with downy mildew |
| CN106857515A (en) * | 2017-04-17 | 2017-06-20 | 北京科发伟业农药技术中心 | Bactericidal composition containing cyflufenamid |
| CN107711851A (en) * | 2017-09-19 | 2018-02-23 | 安徽古尔特科技有限公司 | A kind of composition pesticide containing benzothiostrobin and cyflufenamid |
| CN109717191A (en) * | 2017-10-31 | 2019-05-07 | 江苏龙灯化学有限公司 | A kind of application of the bactericidal composition containing cyflufenamid and Tebuconazole |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103190421B (en) | 2014-06-11 |
| CN103999858B (en) | 2015-09-09 |
| CN103999861B (en) | 2015-07-15 |
| CN103734145B (en) | 2015-07-08 |
| CN103999858A (en) | 2014-08-27 |
| CN103734145A (en) | 2014-04-23 |
| CN103999865A (en) | 2014-08-27 |
| CN103999861A (en) | 2014-08-27 |
| CN103999865B (en) | 2016-04-13 |
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