CN104115860B - Compound pesticide containing fosetyl-aluminum - Google Patents
Compound pesticide containing fosetyl-aluminum Download PDFInfo
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- CN104115860B CN104115860B CN201410304236.4A CN201410304236A CN104115860B CN 104115860 B CN104115860 B CN 104115860B CN 201410304236 A CN201410304236 A CN 201410304236A CN 104115860 B CN104115860 B CN 104115860B
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- prochloraz
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Abstract
The invention relates to a compound pesticide containing fosetyl-aluminum, belonging to the technical field of compound pesticides. The compound pesticide comprises an effective component A and an effective component B, wherein the effective component A is fosetyl-aluminum, the effective component B is prochloraz or prochloraz manganese salt, and the weight ratio of the effective component A to the effective component B is (1 to 90)-(90 to 1). The compound pesticide has the beneficial effects that by effectively compounding fosetyl-aluminum with prochloraz (prochloraz manganese salt), a complementary action is generated between fosetyl-aluminum and prochloraz (prochloraz manganese salt), so that the defects that prochloraz (prochloraz manganese salt) is poor in systemic action and has a poor prevention effect on lower funguses are effectively made up, the synergistic effect is remarkable, the prevention and control range is expanded, and the pesticide effect is improved.
Description
Technical field
The invention belongs to technical field of compounded pesticide, and in particular to a kind of Recompounded pesticide containing phosethyl-Al.
Background technology
High efficiency and broad spectrum activity are basic demand of the modern agriculture to outstanding bactericide agricultural chemicals, but are difficult have antibacterial simultaneous
Tool high efficiency and broad spectrum activity.Many diseases are often that various pathogen mixed infections cause in production, and for example rice seedling stands withered
Disease is caused by various funguses such as continuous mycete, pythium spp, phytophthora, rhizoctonia, Fusarium spp., and Oryza sativa L. ear rot is also by various cause of diseases
Bacterium Combined Infection causes.Also there are many such as ear rot, fringe rot and panicle blasts in same position, the disease of same occurrent time all
Rice Panicle is betided, and in contemporaneity.If energy a drug solves the disease of many cause of disease Combined Infections or with for the moment
The disease that phase, same position occur, can substantially reduce cost accounting, and this is accomplished by the pesticide of broad-spectrum high efficacy.However, efficient sterilizing
Single dose often has that preventing and treating spectrum is narrow, and two kinds of prevention and treatment range medicament mixtures different with mechanism of action are made into built agent,
Preventing and treating spectrum can be then greatly expanded, while improving drug effect, Drug resistance is reduced and is produced risk.
Prochloraz (Prochloraz), chemical name is N- propyl group-N- [2- (2,4,6- Trichlorophenoxy) ethyl]-miaow
Azoles -1- Methanamides, structural formula is：
Prochloraz-manganese chloride complex is the complex that 4 Prochlorazs of manganese chloride complexation form Prochloraz, and bactericidal active ingredient is still miaow
Fresh amine.Compare with Prochloraz, its mechanism of action is identical, preventive effect and safety are better than the latter.Prochloraz (manganese salt) mechanism of action master
If being worked by suppressing the biosynthesiss of sterol, various crop is had by the disease that ascomycetess and Fungi Imperfecti cause bright
Aobvious preventive effect, has the advantages that efficient, wide spectrum and low toxicity.Therefore, Prochloraz is widely used in what various pathogenic fungi caused
The preventing and treating of plant disease, seed treatment and melon and fruit class are fresh-keeping, are that usage amount is maximum and one of most wide antibacterial of use range.It is many
Nian Lai, Prochloraz prevents and treats bakanae disease on Oryza sativa L. for seed soaking, achieves significant prevention effect, and the medicine is removed to bakanae disease of rice
Have outside good preventive effect, soaked seed with Prochloraz, it is bent to rice blast, banded sclerotial blight, rice in rice growing season optimum period spray pesticide, can be prevented and treated
The diseases such as disease.Prochloraz is typically used as protective agent, and it is the big shortcoming of one that absorbability is poor, and mechanism of action determines that it cannot be used for
The preventing and treating of the lower funguses such as continuous mycete, pythium spp, phytophthora.
Phosethyl-Al (phosethyl-Al), chemical name is 31 (ethylphosphonic acid) aluminum, and structural formula is：
It is a kind of organic phosphates efficiently, low toxicity systemic fungicide, have protection concurrently and treat with Bidirectional Conduction function and make
With reaching the purpose of diseases prevention by stimulating the system of defense of host plant.The medicament has good water solubility, and interior suction permeability is strong,
Lasting period is longer, using it is safe the characteristics of, have specially good effect to oomycetes pathogen.The medicament and Prochloraz (manganese salt) have very strong mutual
Benefit property, can effectively make up poor, poor to the lower fungus preventive effect defect of Prochloraz (manganese salt) absorbability.
The content of the invention
For the problem that prior art is present, it is an object of the invention to design a kind of compounding containing phosethyl-Al of offer
The technical scheme of pesticide.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that containing effective constituents A and effective ingredient B,
Described effective constituents A is phosethyl-Al, and described effective ingredient B is Prochloraz or prochloraz-manganese chloride complex, it is described it is effective into
The weight ratio for dividing A and effective ingredient B is 1：90～90：1.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that described effective constituents A and effective ingredient B
Weight ratio be 1：50～50：1.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that described effective constituents A and effective ingredient B
Weight ratio be 1：10～10：1.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that described effective constituents A and effective ingredient B
Weight ratio be 1：9～9：1.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that described effective constituents A and effective ingredient B
Weight ratio be 1：9～1：1.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that described effective constituents A and effective ingredient B
Weight ratio be 1：1～9：1.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that described effective constituents A and effective ingredient B
Weight ratio be 1：4～4：1.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that described effective constituents A and effective ingredient B
Weight ratio be 3：7～7：3.
Described a kind of Recompounded pesticide containing phosethyl-Al, it is characterised in that described effective constituents A and effective ingredient B
Weight ratio be 2：3～3：2.
A kind of above-mentioned Recompounded pesticide containing phosethyl-Al, has by phosethyl-Al and Prochloraz (prochloraz-manganese chloride complex)
Effect compounding, makes phosethyl-Al and Prochloraz (prochloraz-manganese chloride complex) produce complementary action, effectively makes up Prochloraz (prochloraz-manganese chloride complex
Salt) poor, poor to the lower fungus preventive effect defect of absorbability, with notable potentiation, prevention and treatment range is expanded, improve medicine
Effect.
Specific embodiment
With reference to embodiments further illustrating the present invention.
The ratio of the phosethyl-Al of embodiment 1 and Prochloraz (manganese salt) is 1：90～90：1.
The total active constituent content 50% of the medicament of embodiment 2, the active constituent content of phosethyl-Al is 45%, Prochloraz
Active constituent content is 5%.
The total active constituent content 50% of the medicament of embodiment 3, the active constituent content of phosethyl-Al is 40%, Prochloraz
Active constituent content is 10%.
The total active constituent content of the medicament of embodiment 4 is 50%, and the active constituent content of phosethyl-Al is 35%, Prochloraz
Active constituent content be 15%.
The total active constituent content of the medicament of embodiment 5 is 50%, and the active constituent content of phosethyl-Al is 30%, Prochloraz
Active constituent content be 20%.
The total active constituent content of the medicament of embodiment 6 is 50%, and the active constituent content of phosethyl-Al is 25%, Prochloraz
Active constituent content be 25%.
The total active constituent content of the medicament of embodiment 7 is 50%, and the active constituent content of phosethyl-Al is 20%, Prochloraz
Active constituent content be 30%.
The total active constituent content of the medicament of embodiment 8 is 50%, and the active constituent content of phosethyl-Al is 15%, Prochloraz
Active constituent content be 35%.
The total active constituent content of the medicament of embodiment 9 is 50%, and the active constituent content of phosethyl-Al is 10%, Prochloraz
Active constituent content be 40%.
The total active constituent content of the medicament of embodiment 10 is 50%, and the active constituent content of phosethyl-Al is 5%, Prochloraz
Active constituent content be 45%.
The total active constituent content 50% of the medicament of embodiment 11, the active constituent content of phosethyl-Al is 45%, Prochloraz
The active constituent content of manganese salt is 5%.
The total active constituent content 50% of the medicament of embodiment 12, the active constituent content of phosethyl-Al is 40%, Prochloraz
The active constituent content of manganese salt is 10%.
The total active constituent content of the medicament of embodiment 13 is 50%, and the active constituent content of phosethyl-Al is 35%, and miaow is fresh
The active constituent content of amine manganese salt is 15%.
The total active constituent content of the medicament of embodiment 14 is 50%, and the active constituent content of phosethyl-Al is 30%, and miaow is fresh
The active constituent content of amine manganese salt is 20%.
The total active constituent content of the medicament of embodiment 15 is 50%, and the active constituent content of phosethyl-Al is 25%, and miaow is fresh
The active constituent content of amine manganese salt is 25%.
The total active constituent content of the medicament of embodiment 16 is 50%, and the active constituent content of phosethyl-Al is 20%, and miaow is fresh
The active constituent content of amine manganese salt is 30%.
The total active constituent content of the medicament of embodiment 17 is 50%, and the active constituent content of phosethyl-Al is 15%, and miaow is fresh
The active constituent content of amine manganese salt is 35%.
The total active constituent content of the medicament of embodiment 18 is 50%, and the active constituent content of phosethyl-Al is 10%, and miaow is fresh
The active constituent content of amine manganese salt is 40%.
The total active constituent content of the medicament of embodiment 19 is 50%, and the active constituent content of phosethyl-Al is 5%, Prochloraz
The active constituent content of manganese salt is 45%.
The total active constituent content of the medicament of embodiment 20 can be configured to any concentration between 5%～90%, between the two
Proportioning it is close with 1～embodiment of embodiment 19 or identical, but be not limited to above-mentioned concentration.
The prevention effect of the phosethyl-Al of embodiment 21 and Prochloraz compounding seed dressing to rice seedling damping-off
1st, kind is tested
Imperial Jing 40
2nd, process and arrange and test method
Process 1 50% 3 miaow (phosethyl-Al 10%, Prochloraz 40%) 1：200 seed dressings
Process 2 50% 3 miaows (phosethyl-Al 20%, Prochloraz 30%) 1：200 seed dressings
Process 3 50% 3 miaows (phosethyl-Al 25%, Prochloraz 25%) 1：200 seed dressings
Process 4 50% 3 miaows (phosethyl-Al 30%, Prochloraz 20%) 1：200 seed dressings
Process 5 50% 3 miaows (phosethyl-Al 40%, Prochloraz 10%) 1：200 seed dressings
Process 6 75% 3 miaows (phosethyl-Al 25%, Prochloraz 50%) 1：300 seed dressings
Process 7 75% 3 miaows (phosethyl-Al 30%, Prochloraz 45%) 1：300 seed dressings
Process 8 75% 3 miaows (phosethyl-Al 40%, Prochloraz 35%) 1：300 seed dressings
Process 9 75% 3 miaows (phosethyl-Al 50%, Prochloraz 25%) 1：300 seed dressings
Compare 1 80% phosethyl-Al water dispersible granules 1：320 seed dressings
Compare 2 25% Prochloraz cream 1：100 seed dressings
Compare 3 clear water
Rice paddy seed seed soaking is picked up after showing money or valuables one carries unintentionally within 48 hours, adds medicament or clear water control, then adds proper amount of clear water, and stirring is equal
It is even, sow after drying.Before rice transplanting, the sickness rate of rice seedling blight is investigated, while observing upgrowth situation, the neat degree of rice shoot
With root system development situation.
And the preventive effect of Oryza sativa L. disease is calculated according to following equation：
3rd, result of the test
Each chemicals treatment and control are as shown in table 1 to the prevention effect of rice seedling blight：
The prevention effect of the phosethyl-Al of table 1 and Prochloraz compounding seed dressing to rice seedling damping-off
From the point of view of result of the test, the prevention effect of phosethyl-Al and each process of Prochloraz compounding to rice seedling damping-off
90.84%～95.14%, far above the 78.90% and 81.11% of control.Illustrate that phosethyl-Al and Prochloraz compounding exist
Strong potentiation is shown in preventing and treating to rice seedling damping-off.
The phosethyl-Al of embodiment 22 and prochloraz-manganese chloride complex are compounded to Rice blast and the prevention effect of Oryza sativa L. ear rot
1st, kind is tested
Zhejiang is excellent No. one in Hybrid Rice Varieties
2nd, controlling object
Rice blast and Oryza sativa L. ear rot
3rd, planting patternss
Dry rice seedling, transplants, late rice in single cropping.
4th, process and arrange
Process 50 grams/acre of 1 80% 3 miaow (phosethyl-Al 15%, prochloraz-manganese chloride complex 65%)
Process 50 grams/acre of 2 80% 3 miaows (phosethyl-Al 20%, prochloraz-manganese chloride complex 60%)
Process 50 grams/acre of 3 80% 3 miaows (phosethyl-Al 25%, prochloraz-manganese chloride complex 55%)
Process 50 grams/acre of 4 80% 3 miaows (phosethyl-Al 30%, prochloraz-manganese chloride complex 50%)
Process 50 grams/acre of 5 80% 3 miaows (phosethyl-Al 35%, prochloraz-manganese chloride complex 45%)
Process 50 grams/acre of 6 80% 3 miaows (phosethyl-Al 40%, prochloraz-manganese chloride complex 40%)
Process 50 grams/acre of 7 80% 3 miaows (phosethyl-Al 50%, prochloraz-manganese chloride complex 30%)
Process 50 grams/acre of 880% 3 miaow (phosethyl-Al 60%, prochloraz-manganese chloride complex 20%)
Compare 50 grams/acre of 1 80% phosethyl-Al WDG；
Compare 80 grams/acre of 2 50% prochloraz-manganese chloride complex WP；
Compare 3 clear water
Each reagent combination is watered 30 kgs/acre, and in the Oryza sativa L. cut phase, mist sprays portion.
5th, investigate
According to following standard：
The generation disease index of 25 days investigation Rice blasts after dispenser, the morbidity of 35 days investigation Oryza sativa L. ear rots after dispenser
Clump sickness rate, by cell harvesting statistics yield.
The grade scale of Rice blast is as shown in the table
| Sick level | Panicle blast victimization state | Single fringe victimization state |
| 0 | Disease tassel yield is less than 1% | It is disease-free on fringe |
| 1 | Disease tassel yield 1-5% | Per fringe loss rate≤5% (indivedual sprig stalk morbidities) |
| 3 | Disease tassel yield is 5.1-10% | Per fringe loss rate 5.1-15% (the stalk morbidity of 1/10～1/5 or so branch) |
| 5 | Disease tassel yield is 10.1-25% | Per fringe loss rate 15.1-30% (the stalk morbidity of 1/5～1/3 or so branch) |
| 7 | Disease tassel yield is 25.1-50% | Per fringe loss rate 30.1-50% (fringe neck or main shaft are fallen ill, and grain half is flat) |
| 9 | Disease tassel yield >=50.1% | Per fringe loss rate >=50.1% (fringe neck is fallen ill, most of shrivelled kernel or cause dead ears) |
Oryza sativa L. ear rot Disease investigation Recording criteria
| Sick level | Grade scale |
| 0 grade | Disease-free spot |
| 1 grade | The loss less than 1% per fringe |
| 3 grades | The loss 2%～5% per fringe |
| 5 grades | The loss 6%～15% per fringe |
| 7 grades | The loss 16%～25% per fringe |
| 9 grades | The loss more than 26% per fringe |
Preventive effect computational methods：
6th, result of the test
Result of the test is as shown in the table：
The phosethyl-Al of table 2 and prochloraz-manganese chloride complex are compounded to Rice blast and the prevention effect of ear rot
In the preventive effect to Rice blast, 8 process preventive effects between 86.40%～95.95%, much larger than the positive
The 67.43% of comparison medicament and 81.22%.In the preventive effect to Oryza sativa L. ear rot, the preventive effects of 8 process 85.39%～
It is same much larger than the 73.47% and 75.39% of positive control medicament between 90.32%.Show yield in shape, process
It is obvious that yield compares effect of increasing production in 416.11～428.24 contrasts three.
Thus illustrate, phosethyl-Al and prochloraz-manganese chloride complex compounding show strong potentiation.
The indoor biological determination of activity of the phosethyl-Al of embodiment 23 and prochloraz-manganese chloride complex compounding to fusarium moniliforme.
1st, medicament is prepared
Prochloraz active compound infrequent menstruation amount acetone solution, phosethyl-Al is directly water-soluble, and is diluted to respectively using sterilized water
800mg/ml and 400mg/ml mother solutions.Multigroup dosages distribution is arranged according to mixture purpose, 1:9,1:4,3:7,2:3,1:1,3:2,
7:3,4:1,9:1, each proportioning is the mass ratio of two kinds of medicament effective ingredient.
2nd, test strain
Fusarium moniliforme.
3rd, test method
Indoor virulence test to fusarium moniliforme is carried out using mycelia performance rate method.
Under aseptic technique, the advance sterilising medium for melting quantitative (generally 60ml) is added according to test process
In entering aseptic conical flask, medicinal liquid is quantitatively drawn successively from low concentration to high concentration, in being separately added into above-mentioned conical flask, fully shake
It is even.Then equivalent is poured in the culture dish that 3 diameter above are 9cm, makes the pastille flat board of respective concentration.Test sets not pastille
Blank is made in the process of agent, and each processes and is no less than 3 repetitions.
The Fusarium moniliforme Sheld (cell age 5 days or so) that culture medium is supported, is aseptically punched with the sterilizing of diameter 5mm
Device, from colony edge bacteria cake is cut, and bacteria cake is connected to into pastille flat board central authorities with inoculator, and mycelia faces up, and covers ware lid, puts suitable
Preferably cultivate in the incubator of temperature.
According to the growing state investigation pathogen mycelial growth situation of bacterium in blank culture dish.Use kind of calliper bacterium colony
Diameter, unit is millimeter (mm).Each bacterium colony is each once with crossing method vertical survey diameter.
According to survey result, calculate each concentration for the treatment of using formula 1 and formula 2 and the mycelial growth for examination target bacterium is suppressed
Rate, unit is percentage rate (%), and result of calculation retains 2 significant digits.
D0=D1-D2... ... ... ... ... ... ... ... ... formula (1)
In formula：
D0- bacterium colony increases diameter；
D1- colony diameter；
D2- bacteria cake diameter.
In formula：
I- mycelial growth inhibition rates；
D0- blank bacterium colony increases diameter；
D1- chemicals treatment bacterium colony increases diameter.
Using Tang Qi justice DPS data analysis software, according to each drug concentration logarithm value and corresponding mycelial growth inhibition rate
NiqueMin makees regression analyses, calculates each medicament.
4. compounding effect evaluation
On the basis of each single dose and built agent EC50 values, each built agent coefficient of synergism (SR) is calculated according to Wadley methods,
Compounding effect is evaluated using SR values.SR >=1.5 represent there is potentiation；SR≤0.5 represents there is antagonism；0.5<SR<
1.5 is summation action.
Coefficient of synergism (SR) presses formula (3) and formula (4) is calculated：
In formula：
X1The theoretical value of-mixture, unit is milligrams per liter (mg/L)；
PAThe percentage composition of A in-mixture, unit is percentage rate (%)；
PBThe percentage composition of B in-mixture, unit is percentage rate (%)；
The theoretical value of A in A- mixtures, unit is milligrams per liter (mg/L)；
The theoretical value of B in B- mixtures, unit is milligrams per liter (mg/L).
In formula：
The coefficient of synergism of SR- mixtures；
X1- mixture theoretical value, unit is milligrams per liter (mg/L)；
X2- mixture measured value, unit is milligrams per liter (mg/L).
5th, result of the test
Phosethyl-Al and Prochloraz compounding are as shown in the table to the indoor biological determination of activity result of fusarium moniliforme：
| Reagent agent | Actual EC50(ppm) | Theoretical EC50(ppm) | Coefficient of synergism |
| Phosethyl-Al | 64.37 | / | / |
| Prochloraz | 0.032 | / | / |
| Three miaow proportionings 1: 9 | 0.008 | 0.036 | 4.50 |
| Three miaow proportionings 1: 4 | 0.010 | 0.040 | 4.00 |
| Three miaow proportionings 3: 7 | 0.019 | 0.046 | 2.42 |
| Three miaow proportionings 2: 3 | 0.021 | 0.053 | 2.52 |
| Three miaow proportionings 1: 1 | 0.022 | 0.064 | 2.91 |
| Three miaow proportionings 3: 2 | 0.053 | 0.080 | 1.51 |
| Three miaow proportionings 7: 3 | 0.022 | 0.107 | 4.86 |
| Three miaow proportionings 4: 1 | 0.028 | 0.160 | 5.71 |
| Three miaow proportionings 9: 1 | 0.153 | 0.319 | 2.08 |
From the point of view of the result of the test of indoor biometricses, actual EC50 values are than theoretical EC50 values after three second aluminum phosphate and Prochloraz compounding
Improve a lot, coefficient of synergism has been above 1.5 between 1.51～5.71, illustrate both compoundings to bakanae disease of rice
Strong potentiation is shown in inhibition.
The indoor bioassay of the phosethyl-Al of embodiment 24 and prochloraz-manganese chloride complex compounding to rice blast
1st, medicament is prepared
Prochloraz-manganese chloride complex active compound is configured to suspension, and phosethyl-Al is directly water-soluble, and is diluted to respectively using sterilized water
800mg/ml and 400mg/ml mother solutions.Multigroup dosages distribution is arranged according to mixture purpose, 1: 9,1: 4,3: 7,2: 3,1: 1,3: 2,7
: 3,4: 1, each proportioning is the mass ratio of two kinds of medicament effective ingredient.
2nd, test strain
Pathogen of Rice Blast Fungus bacterial strain：Magnaporthe grisea Pyriculariaoryae WZ30, the bacterial strain belongs to the strong of ZB populations
Pathogenic strain.
3rd, test method
While example 23
4th, compounding effect evaluation
With embodiment 23
5th, result of the test
Phosethyl-Al and Prochloraz compounding are as shown in the table to the indoor biological determination of activity result of rice blast fungus：
| Reagent agent | Actual EC50(ppm) | Theoretical EC50(ppm) | Coefficient of synergism |
| Phosethyl-Al | 36.48 | / | / |
| Prochloraz-manganese chloride complex | 0.052 | / | / |
| Three miaow proportionings 1: 9 | 0.008 | 0.058 | 7.25 |
| Three miaow proportionings 3: 7 | 0.019 | 0.074 | 3.89 |
| Three miaow proportionings 2: 3 | 0.021 | 0.087 | 4.14 |
| Three miaow proportionings 1: 1 | 0.022 | 0.104 | 4.73 |
| Three miaow proportionings 3: 2 | 0.053 | 0.130 | 2.45 |
| Three miaow proportionings 7: 3 | 0.022 | 0.173 | 7.86 |
| Three miaow proportionings 4: 1 | 0.028 | 0.259 | 9.25 |
From the point of view of the result of the test of indoor biometricses, rice blast fungus are suppressed after three second aluminum phosphate and Prochloraz compounding imitate
The coefficient of synergism of fruit has been reached between 2.45～9.25, illustrates that the two compounding is showed in the inhibitory action to rice blast fungus
Go out strong potentiation.
Claims (1)
1. a kind of Recompounded pesticide containing phosethyl-Al is in preventing and treating rice seedling damping-off, Rice blast, Oryza sativa L. ear rot, water
Application in the Bakanae disease of rice and rice blast, it is characterised in that this contain the Recompounded pesticide of phosethyl-Al by effective constituents A and
Effective ingredient B is constituted, and described effective constituents A is phosethyl-Al, and described effective ingredient B is Prochloraz or prochloraz-manganese chloride complex
Salt, described effective constituents A and the weight ratio of effective ingredient B is 1：9～9：1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410304236.4A CN104115860B (en) | 2014-06-30 | 2014-06-30 | Compound pesticide containing fosetyl-aluminum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410304236.4A CN104115860B (en) | 2014-06-30 | 2014-06-30 | Compound pesticide containing fosetyl-aluminum |
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| Publication Number | Publication Date |
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| CN104115860B true CN104115860B (en) | 2017-04-12 |
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| CN1461590A (en) * | 2002-05-26 | 2003-12-17 | 汪建利 | Sterilizing composition contg. ethylicin |
| CN103651337A (en) * | 2012-09-24 | 2014-03-26 | 宜德雅(北京)科技有限公司 | Sterilization and synergism suspension agent composition |
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