CN103651337A - Sterilization and synergism suspension agent composition - Google Patents

Sterilization and synergism suspension agent composition Download PDF

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Publication number
CN103651337A
CN103651337A CN201210355820.3A CN201210355820A CN103651337A CN 103651337 A CN103651337 A CN 103651337A CN 201210355820 A CN201210355820 A CN 201210355820A CN 103651337 A CN103651337 A CN 103651337A
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composition
mancozeb
suspending agent
polyvinylpyrrolidone
metalaxyl
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徐依兴
李伟树
庹代松
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YIDEYA (BEIJING) TECHNOLOGY Co Ltd
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YIDEYA (BEIJING) TECHNOLOGY Co Ltd
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Abstract

The invention relates to application of utilizing polyvinylpyrrolidone as a farm-oriented sterilization suspension agent. Preferably, the average molecular weight of the polyvinylpyrrolidone is 500-1100000; more preferably, the average molecular weight of the polyvinylpyrrolidone is 1000-900000; most preferably, the average molecular weight of the polyvinylpyrrolidone is 5000-700000. Furthermore, the invention further relates to a sterilization and synergism suspension agent composition which is used as a non-seed treatment agent; the sterilization and synergism suspension agent composition is characterized by comprising following components (a) a sterilization synergist polyvinylpyrrolidone and (b) at least one bactericide with a sterilization effective dose.

Description

A kind of sterilization synergy suspension agent composition
Technical field
The invention belongs to pesticide field, more particularly relate to the purposes as the synergist of the bactericidal suspending agent of non-seed treatment by polyvinylpyrrolidone.
In the present invention, bactericidal suspending agent refers to the suspending agent preparation in bactericide.
Background technology
Polyvinylpyrrolidone compound itself does not almost have activity to disease fungus sterilization, and conventionally in medicine and field of veterinary, be used as adhesive, suspending agent, perforating agent and thickener, and in pesticide field, only find to be used as adhesive in the seed treatment of minority, have no in disinfectant use in agriculture field it as synergist, to improve bactericidal effect and to accelerate the report of sterilization speed.
Polyvinylpyrrolidone is commercially produced, and can buy acquisition by commercial sources.
Cell wall outermost one deck of most hypha,hyphaes is to consist of β-(1,3) glucan or α-(1,3) glucan.This class β-(1,3) glucan or α-(1,3) glucan is that helical form is without the dense matter of branch's backbone.This class dense matter can effectively intercept other material and enter in fungal cell.Therefore, the bactericidal action approach of traditional disinfectant use in agriculture is after absorbing by plant, then the picked-up to plant nutrient by fungi, and follows nutrient to enter in fungal cell, thereby realizes direct sterilizing function; Or when fungus spore germination, because spore surface is not by β-(1,3) glucan or this class dense matter parcel of α-(1,3) glucan, by direct absorption of spore, played bactericidal action.
Therefore, up to the present, the R&D direction of disinfectant use in agriculture is to continually develop to be more conducive to the Fungicidal active compound that plant absorbs always, or, extend the ability that Fungicidal active compound continues to suppress spore germination or kills spore at plant surface.
By plant, absorb the method that plays bactericidal action, must first guarantee that the bactericide guarantee fungi of plant absorption sufficient amount absorbs the bactericide of enough sterilization doses.This method causes invalid (biological target utilization ratio is low) and the residue problem of unnecessary bactericide in plant corpus on the one hand, meanwhile, also easily plant is produced to poisoning.And this mode of action, has extended the time that bactericide arrives target thalline, generally, use traditional bactericide needs just can take effect at least 48 hours later; So, for the disease of systemic infection, as epidemic disease etc., when finding to make deposits yields disease, use bactericide, while telling on to bactericide, crop has produced heavy losses again.
Prolongation Fungicidal active compound, in the method for plant surface duration, also causes plant surface bactericide to keep higher concentration, and residual quantity increases.
Therefore, aforementioned these two kinds of R&D directions have all increased bactericide in making object or surface residual.
Summary of the invention
We are in research process; unexpected discovery; polyvinylpyrrolidone can help bactericide directly to break through the β on hypha,hyphae cell wall surface-(1; 3) glucan or α-(1; 3) iris action of this layer of dense matter of glucan; thereby play the lethal dose that is subject to that can directly reach target thalline with the bactericide of less dosage; thereby improve the sterilization speed of bactericide, the consumption of minimizing bactericide; to realize the crop protection object with environmentally friendly, low cost and low-residual mode, and improve the safety of bactericide to crop.
By following test, can illustrate well that polyvinylpyrrolidone can be broken through hypha,hyphae cell wall outermost 1, this layer of fine and close barrier material of 3-glucan.
We are respectively with the polyvinylpyrrolidone (K15 that commonly uses model, K30, K60, K90, all be purchased from German BASF AG), conventional emulsifier tween 80 (Tween80) and dispersant sodium lignin sulfonate, and the PVP K30 of the most frequently used model and conventional emulsifier tween 80 (Tween80) and the mixture of sodium lignin sulfonate, and clear water, acidity and alkaline aqueous solution, by representative hypha,hyphae [the raw single shaft mould (Plasmopara viticola (Berk et.Curt) BerletdeToui) of grape, Siberian cocklebur monofilament shell bacterium (Sphaerothecafuliginea (Schl.) Poll.F.xanthii Jacz.), mushroom bacterium (Lentinus edodes (Berk.) Sing.) and Penicillium citrinum (Penicillium citrinum Thom)] soak 2 minutes, then use 0.01% Coomassie brilliant blue (G-250) dyeing 2 minutes, rinsing 2 minutes in clear water respectively, and with repeating rinsing in clear water once, then mycelia is placed in to the coloration result of observation to mycelia under 160 power microscopes.The results are shown in subordinate list 1.
Subordinate list 1: representative hypha,hyphae is contrasted the coloration result after processing
Figure BSA00000781261600021
Figure BSA00000781261600031
Note: in subordinate list 1, "+" represents that mycelia is dyed to as vivid blueness, "-" represent mycelia and be not colored.
The result of the test explanation of subordinate list 1:
1) after the HC1 aqueous solution that the NaOH aqueous solution that is 9 through clear water, pH value, pH value are 4, the 0.3% Tween 80 aqueous solution, 0.3% sodium lignin sulfonate aqueous solution soaking, hypha,hyphae can not be by coomassie brilliant blue staining, reason is that these aqueous solution cannot be broken through hypha,hyphae cell wall outermost layer structure, thereby can not make Coomassie brilliant blue enter cell wall internal layer, its protein is dyeed.
2) after the polyvinylpyrrolidone aqueous solution soaking of variable concentrations, different model, the raw single shaft of grape is mould, Siberian cocklebur monofilament shell bacterium, mushroom bacterium and Penicillium citrinum can be by coomassie brilliant blue stainings, reason is that these hypha,hyphae cell wall outermost layers are by 1,3-glucan forms, the polyvinylpyrrolidone of variable concentrations, different model all can be broken through the fungal cell wall skin that 1,3-glucan forms.
Based on above-mentioned unexpected discovery, the present invention proposes following technical scheme:
Polyvinylpyrrolidone is as the purposes of the synergist of agricultural bactericidal suspending agent, and wherein, the mean molecule quantity of polyvinylpyrrolidone is preferably 500-1, and 100,000, more preferably 1,000-900,000, most preferably be 5,000-700,000.
In addition, the invention still further relates to a kind of bactericidal suspending agent synergistic composition as non-seed treatment, it is characterized in that the following ingredients that comprises synergy effective dose:
A) sterilizing synergistic agent polyvinylpyrrolidone, and
B) bactericide of at least one sterilization effective dose.
Wherein, should be as in the bactericidal suspending agent synergistic composition of non-seed treatment, the mean molecule quantity of polyvinylpyrrolidone is preferably 500-110, and 000, bactericide is preferably selected from:
Frost urea cyanogen, dodine, the pungent salt of biguanides, iminoctadine, M 9834, essence M 9834, metalaxyl, Metalaxyl-M, cyflufenamid, two chlorine zarilamids, thifluzamide, flutolanil, fenhexamid (fenhexamid), fenoxanil (fenoxanil), Silthiopham, good fortune Lapie (furametpyr), pyrrole metsulfovax (penthiopyrad), mandipropamid, zoxamide, carboxin, furalaxyl (furalaxyl), ofurace (ofurace), mebenil (mepronil), probenazole, furidazol (fuberidazole), imazalil and salt thereof, efficient imazalil and salt thereof, Fenamidone (fenamidone), Evil imidazoles (oxpoconazole), pefurazoate (pefurazoate), Prochloraz and mantoquita thereof and manganese salt, prothioconazoles (prothioconazole), polyoxin, jinggangmeisu, kasugarnycin, Polyoxin, tpn, benomyl (benomyl), carbendazim, the mould prestige of second, iprovalicarb (iprovalicarb), benzene metsulfovax (benthiavalicarb), thiophanate-methyl, Propamocarb and salt thereof, benthiozole (benthiazole), probenazole, allicin, carvacrol, Kocide SD, copper sulphate, cuprous oxide, Cupravit (copper oxychloride), sulphur, bordeaux mixture, Thiodiazole-copper, iprodione, procymidone, sclex (dichlozolin), fluoromide (Fluoromide), vinclozolin, captan (captan), folpet (folpet), iprodione, tmtd, ziram, Polycarbamate (polycarbamate), Carbatene, mancozeb, zineb, Propineb, Isoprothiolane, dimethomorph, tridemorph, dodemorph, butadiene morpholine, pyrimorph, flumorph, edifenphos, kitazine (CAS No.: 13286-32-3), iprobenfos, Rabcide, pyrazophos (pyrazophos), tolelofos-methyl, phosethyl-Al, fentin, famoxadone, SYP-Z048, hymexazo, the spirit of Evil frost, pyraclostrobin, azoles bacterium ester (pyraoxystrobin), azoles amine bacterium ester (pyrametostrobin), fluorine azoles bacterium acid amides (fluxapyroxad), fluazinam, pyrifenox (pyrifenox), ring pyridine bacterium amine (CAS No.: 112860-04-5), Boscalid, fluopicolide (nuopicolide), cyprodinil, fluorine mepanipyrim (diflumetorim), ferimzone (ferimzone), mepanipyrim (mepanipyrim), phonetic mould amine, Fenarimol, nuarimol, the phonetic phenol of second (ethirimol), bupirimate (bupirimate), dimethirimol (dimethirimol), fludioxonil, fenpiclonil (fenpiclonil), the third oxygen quinoline (proquinazid), benzene oxygen quinoline (quinoxyfen), dithianon, Grandox fumigant, probenazole, Guardian, Grandox fumigant, oxygen ring azoles, bromuconazole (bromuconazole), Tebuconazole, nitrile bacterium azoles, propiconazole, azoles alcohol, Difenoconazole, epoxiconazole, Cyproconazole, alkene azoles alcohol, efficient alkene azoles alcohol, RH-7592, Fluquinconazole (Fluquinconazole), Flutriafol, glyoxalin (imibenconazole), plant bacterium azoles (ipconazole), metconazole (metconazole), penconazole, simeconazoles (simeconazole), tetraconazole (tetraconazole), Triadimenol, triazolone, triticonazole, bitertanol, Pencycuron, Fluoxastrobin, dimoxystrobin (dimoxystrobin), fluoxastrobin (fluoxastrobin), SSF 126 (metominostrobin) orysastrobin (orysastrobin), ZEN 90160 (picoxystrobin), pyraclostrobin, oxime bacterium ester, Enestroburin (enestroburin), kresoxim-methyl, Metrafenone, bixafen, fenpropidin (fenpropidine), volution bacterium amine (spiroxamine) and tricyclazole.
Further, in the bactericidal suspending agent synergistic composition of this non-seed treatment, the mean molecule quantity of polyvinylpyrrolidone is preferably 1,000-900, and 000, b) composition is preferably:
Carbendazim; Benomyl (benomyl); Tpn; Tmtd; Copper sulphate; Hymexazo; Boscalid; Flusilazole; Procymidone; Metalaxyl; Metalaxyl-M; Dimethomorph; Frost urea cyanogen; Kocide SD; Polyoxin; Cyanogen bacterium azoles; Mancozeb; Thiophanate-methyl; Zineb; Polyoxin; Fluoxastrobin; Pyraclostrobin; Triazolone; Tricyclazole; Difenoconazole; Prochloraz and manganese salt and mantoquita; Tebuconazole; Kresoxim-methyl; Iprodione; Jinggangmeisu; Polyoxin; Dithianon; Propiconazole; Own azoles alcohol; Fluorine bacterium azoles; The phonetic phenol of second; The composition of carbendazim and mancozeb; The composition of carbendazim and tricyclazole; The composition of carbendazim and tmtd; The composition of carbendazim and tricyclazole; The composition of thiophanate-methyl and mancozeb; The composition of phosethyl-Al and mancozeb; The composition of metalaxyl and mancozeb; The composition of Metalaxyl-M and mancozeb; The composition of dimethomorph and mancozeb; The composition of frost urea cyanogen and mancozeb; The composition of iprodione and thiophanate-methyl; Polyoxin is with the composition of hymexazo.
Further, in the bactericidal suspending agent synergistic composition of this non-seed treatment, the mean molecule quantity of polyvinylpyrrolidone is preferably 5,000-700, and 000, b) composition is preferably:
Carbendazim; Benomyl (benomyl); Tpn; Tmtd; Copper sulphate; Hymexazo; Boscalid; Flusilazole; Procymidone; Metalaxyl; Metalaxyl-M; Dimethomorph; Frost urea cyanogen; Kocide SD; Polyoxin; Cyanogen bacterium azoles; Prochloraz nantokite; The composition of carbendazim and tmtd; The composition of carbendazim and mancozeb; The composition of carbendazim and tricyclazole; The composition of thiophanate-methyl and mancozeb; The composition of phosethyl-Al and mancozeb; The composition of metalaxyl and mancozeb; The composition of Metalaxyl-M and mancozeb; The composition of dimethomorph and mancozeb; The composition of frost urea cyanogen and mancozeb; The composition of iprodione and thiophanate-methyl; Polyoxin is with the composition of hymexazo.
These synergistic compositions, surpass the addition of expecting in principle to wish control fungi, first, reduced the consumption of single or several bactericide, simultaneously, kept good and bactericidal effect fast, secondly, under the low amount ranges of single or multiple bactericide, from agriculture viewpoint, in the situation that becomes invalid, the present invention's combination has also obtained the level of preventing and treating of high disease, especially fungal disease, and has widened the fungicidal spectrum of bactericide.
The present composition in principle can be containing polyvinylpyrrolidone and the above-mentioned fungicide active ingredient of any mixing ratio, preferably the mixed weight ratio of active component and polyvinylpyrrolidone be 800: 1 to: 1: 20, more preferably mixed weight ratio be 200: 1 to: 1: 10.
In addition, the invention still further relates to a kind of method of preventing and treating the harmful germ of crop, it is characterized in that, use above-mentioned arbitrary non-granula sterilization synergistic composition as non-seed treatment.
Composition of the present invention can be for control grain, fruit, vegetables, cotton, epidemic disease on oil plant and other economic crops, damping off, pod pinta, leaf spot, stem is burst sick, leaf blight, leaf blotch pinta, early blight, balck shank, anthracnose, root rot, gray mold, downy mildew, ring leaf spot, scab, shot hole, aspergillus niger is sick, damping off, banded sclerotial blight, climing rot, smut, powdery mildew, fusarium wilt, leaf mold, bakanae disease, rust, rice blast, dark green mildew, penicilliosis, gummosis, eye spot, leaf rust, white blister, stalk break, false smut, smut, full rot, mould dirty sick.
Composition of the present invention is usual auxiliaries in preferably with the conventional mode of production and preparation processing technology, as solvent, cosolvent, defoamer or surfactant, is mixed with together suspending agent, includes but not limited to aqueous suspension agent, oil-suspending agent and dry suspending agent.According to the character of the active component of wish preparation, suitable surfactant is nonionic, anion or cationic surfactant and the surfactant mixture with good emulsification, dispersiveness.
The concentrate that composition of the present invention is normally prepared with mix preparation form, uses after dilute with water while using in a usual manner.Composition of the present invention also can the mixed form water of bucket by preparation respectively or part respectively the component of preparation after diluting in the lump, use.In aforementioned water diluent, the concentration of polyvinylpyrrolidone is 0.1ppm-700ppm, is preferably 0.5ppm-100ppm.
Embodiment
Following Preparation Example and the raw embodiment that surveys can be used to further illustrate the present invention, but never mean protection scope of the present invention is construed as limiting.
In following Preparation Example, polyvinylpyrrolidone can be the mixture of single model or Multiple Type.Preparation Example
Preparation Example 1: the preparation of aqueous suspension agent
Polyvinylpyrrolidone: 0.1-50%, preferably 1-30%
Fungicide active ingredient: 4-75%, preferably 10-50%
Surfactant: 1-30%, preferably 2-20%
Water: 94-20%, preferably 85-21%
Preparation Example 2: the preparation of oil-suspending agent
Polyvinylpyrrolidone: 0.1-5%, preferably 0.2-2%
Fungicide active ingredient: 0.5-80%, preferably 1-70%
Solvent: 1-30%, preferably 5-20%
Cosolvent: 1-15%, preferably 2-10%
Surfactant: 1-30%, preferably 2-20%
Vegetable oil or mineral oil: 95-15%, preferably 80-20%
Preparation Example 3: the preparation of dry suspending agent
Polyvinylpyrrolidone: 1-12%, preferably 2-9%
Fungicide active ingredient: 0.1-20%, preferably 1-12%
Parent nucleus: 30-90%, preferably 40-70%
Separation layer: 2-9%, preferably 3-5%
Film-coating: 3-12%, preferably 5-10%
Suspending agent: 1-30%, preferably 2-25%
Other compositions of sterilization synergistic composition of the present invention can make by above similarly method.
Following concrete formulation Example to be to further illustrate the present invention, and " synergy " in following formula all refer to " polyvinylpyrrolidone synergy ", and the polyvinylpyrrolidone of various models is all purchased from BASF AG.
Formula 1:40% synergy tpn suspending agent
Figure BSA00000781261600071
Formula 2:40% synergy carbendazim suspending agent
Figure BSA00000781261600072
Formula 3:10% Zeng Xiao hymexazo suspending agent
Figure BSA00000781261600073
Figure BSA00000781261600081
Formula 4:40% synergy tmtd suspending agent
Figure BSA00000781261600082
Formula 5:25% synergy copper sulphate suspending agent
Figure BSA00000781261600083
Formula 6:25% synergy Fluoxastrobin suspending agent
Formula 7:30% synergy Boscalid suspending agent
Formula 8:25% synergy Flusilazole suspending agent
Figure BSA00000781261600092
Formula 9:43% synergy tebuconazole suspension concentrates
Figure BSA00000781261600093
Formula 10:20% synergy prochloraz nantokite suspending agent
Figure BSA00000781261600094
Formula 11:22.7% synergy dithianon suspending agent
Figure BSA00000781261600101
Formula 12:40% synergy Metalaxyl suspending agent
Formula 13:35% synergy Metalaxyl-M suspending agent
Figure BSA00000781261600103
Formula 14:25% Myristicin morpholide suspending agent
Figure BSA00000781261600104
Figure BSA00000781261600111
Formula 15:5% synergy frost urea cyanogen suspending agent
Figure BSA00000781261600112
Formula 16:30% synergy copper Hydroxide Suspension Concentrate
The phonetic phenol suspending agent of formula 17:25% synergy second
Figure BSA00000781261600114
Formula 18:20% synergy nitrile bacterium azole suspending agent
Figure BSA00000781261600115
Figure BSA00000781261600121
Formula 19:40% synergy thiophanate-methyl aqueous suspension
Formula 20:25% synergy procymidone suspending agent
Figure BSA00000781261600123
Formula 21:20% synergy benomyl oil-suspending agent
Figure BSA00000781261600124
The dry outstanding agent of formula 22:7% synergy Polyoxin
Figure BSA00000781261600132
Formula 23:50% synergy iprodione suspending agent
Figure BSA00000781261600133
Formula 24:15% synergy carbendazim tmtd suspending agent
Formula 25:25% synergy carbendazim mancozeb suspending agent
Figure BSA00000781261600135
Figure BSA00000781261600141
Formula 26:20% synergy thiophanate-methyl mancozeb suspending agent
Figure BSA00000781261600142
Formula 27:25% synergy carbendazim tricyclazole suspending agent
Figure BSA00000781261600143
Formula 28:20% synergy phosethyl-Al mancozeb suspending agent
Figure BSA00000781261600144
Formula 29:29% synergy metalaxyl mancozeb suspending agent
Figure BSA00000781261600152
Formula 30:34% synergy Metalaxyl-M mancozeb suspending agent
Figure BSA00000781261600153
Formula 31:25% Myristicin morpholide mancozeb suspending agent
Figure BSA00000781261600161
Formula 32:36% synergy frost urea cyanogen mancozeb suspending agent
Figure BSA00000781261600162
Formula 33:40% synergy iprodione thiophanate-methyl aqueous suspension
Formula 34:15% synergy Duo Kang Mei Su hymexazo suspending agent
Figure BSA00000781261600171
The raw embodiment that surveys
The raw survey of co-toxicity coefficient comparative example:
The inventor has carried out the mensuration of co-toxicity coefficient to 30% synergy copper Hydroxide Suspension Concentrate in aforementioned formula embodiment of the present invention, 50% synergy iprodione suspending agent, 40% synergy thiophanate-methyl aqueous suspension agent; 30% synergy copper Hydroxide Suspension Concentrate adopts target bacterium for supplying examination bacterial classification; 50% synergy iprodione suspending agent adopts botrytis cinerea for supplying examination bacterial classification; 40% synergy thiophanate-methyl aqueous suspension agent adopts Colletotrichum capsici for supplying examination bacterial classification; With growth rate method, measure.Test data adopts probit value analysis to return, and obtains concentration EC50 in regression equation and inhibition, then by the abundant method of Sun Yun, obtains the co-toxicity coefficient CTC of each synergy proportioning.CTC > 120 is synergy.Wherein, control formula is except containing polyvinylpyrrolidone, surplus water polishing.
Raw survey comparative example 1: polyvinylpyrrolidone is the synergistic effect on target bacterium to Kocide SD
Medicament Regression equation EC 50mg/L CTC
30% synergy copper Hydroxide Suspension Concentrate y=0.2832x+4.5188 50.00 185.5
30% copper Hydroxide Suspension Concentrate y=0.4221x+4.1696 92.75
Raw survey comparative example 2: polyvinylpyrrolidone is the synergistic effect on botrytis cinerea to iprodione
Medicament Regression equation EC 50mg/L CTC
50% synergy iprodione suspending agent y=3.5778x+6.4236 0.40 187.5
50% iprodione suspending agent y=3.7370x+5.4601 0.75
Raw survey comparative example 3: polyvinylpyrrolidone is the synergistic effect on Colletotrichum capsici to thiophanate-methyl
Medicament Regression equation EC 50mg/L CTC
40% synergy thiophanate-methyl aqueous suspension agent y=0.8638x+4.9575 1.12 157.1
40% thiophanate-methyl aqueous suspension agent y=1.3296x+4.6744 1.76
The mixed potted plant raw embodiment of survey of bucket: after polyvinylpyrrolidone mixes with bactericidal suspending agent bucket to the synergistic effect of indoor pot powdery mildew of cucumber bacterium (while using separately as a comparison, extension rate is identical)
Following bactericidal suspending agent is from market purchasing.
The mixed raw embodiment 1 that surveys of bucket: the synergistic effect of polyvinylpyrrolidone+Fluoxastrobin on indoor pot powdery mildew of cucumber bacterium
Note: spray after the mixed 0.15 gram of polyvinylpyrrolidone K15+5 milliliter 25% Fluoxastrobin suspending agent of bucket is watered 15 liters of dilutions.
The mixed raw embodiment 2 that surveys of bucket: the synergistic effect of polyvinylpyrrolidone+Tebuconazole on indoor pot powdery mildew of cucumber bacterium
Figure BSA00000781261600182
Note: spray after mixed 0.1 gram of polyvinylpyrrolidone K17+2 milliliter 43% tebuconazole suspension concentrates of bucket is watered 15 liters of dilutions.
The mixed raw embodiment 3 that surveys of bucket: the synergistic effect of the phonetic phenol of polyvinylpyrrolidone+second on indoor pot powdery mildew of cucumber bacterium
Figure BSA00000781261600183
Note: spray after the mixed 0.3 gram of phonetic phenol suspending agent of polyvinylpyrrolidone K60+12 milliliter 25% second of bucket is watered 15 liters of dilutions.
Field comparative example:
The composition of polyvinylpyrrolidone and preferably fungicide active ingredient is the control efficiency to disease in field.Control formula is except containing polyvinylpyrrolidone, the surplus water polishing of aqueous suspension agent, the surplus of oil-suspending agent cottonseed oil polishing, the surplus of dry suspending agent sucrose polishing.
Figure BSA00000781261600192
Figure BSA00000781261600201
Figure BSA00000781261600211
The composition of polyvinylpyrrolidone and preferably fungicide active ingredient is the lasting control efficiency to disease in field
Figure BSA00000781261600212
Evidence: polyvinylpyrrolidone has very strong synergistic effect to agricultural bactericidal suspending agent, and sterilization speed improves greatly, is reaching crop pest under the prerequisite of identical control efficiency, and the dosage of agricultural bactericidal suspending agent can reduce 30-80%.Under same dose, preventive effect significantly improves, and the duration obviously extends.The present invention can be mixed polyvinylpyrrolidone and disinfectant use in agriculture to make various suitable synergistic complex agricultural bactericidal suspending agents.Synergistic complex agricultural bactericidal suspending agent of the present invention, not only high to the diseases control of crop, environmental pollution is little simultaneously.

Claims (10)

1. polyvinylpyrrolidone is as the purposes of the synergist of agricultural bactericidal suspending agent.
2. according to the polyvinylpyrrolidone of claim 1, be used as the purposes of the synergist of agricultural bactericidal suspending agent, wherein, mean molecule quantity is preferably 500-1, and 100,000.
3. according to the polyvinylpyrrolidone of claim 2, be used as the purposes of the synergist of agricultural bactericidal suspending agent, wherein, mean molecule quantity is preferably 1,000-900, and 000.
4. according to the polyvinylpyrrolidone of claim 3, be used as the purposes of the synergist of agricultural bactericidal suspending agent, wherein, mean molecule quantity is preferably 5,000-700, and 000.
5. as a bactericidal suspending agent synergistic composition for non-seed treatment, it is characterized in that, comprise following ingredients:
A) sterilizing synergistic agent polyvinylpyrrolidone, and
B) bactericide of at least one sterilization effective dose;
Wherein, the mean molecule quantity of polyvinylpyrrolidone is preferably 500-110, and 000, bactericide is preferred
Be selected from:
Frost urea cyanogen, dodine, the pungent salt of biguanides, iminoctadine, M 9834, essence M 9834, metalaxyl, Metalaxyl-M, cyflufenamid, two chlorine zarilamids, thifluzamide, flutolanil, fenhexamid (fenhexamid), fenoxanil (fenoxanil), Silthiopham, good fortune Lapie (furametpyr), pyrrole metsulfovax (penthi opyrad), mandipropamid, zoxamide, carboxin, furalaxyl (furalaxyl), ofurace (ofurace), mebenil (mepronil), probenazole, furidazol (fuberidazole), imazalil and salt thereof, efficient imazalil and salt thereof, Fenamidone (fenamidone), Evil imidazoles (oxpoconazole), pefurazoate (pefurazoate), Prochloraz and mantoquita thereof and manganese salt, prothioconazoles (prothioconazole), polyoxin, jinggangmeisu, kasugarnycin, Polyoxin, tpn, benomyl (benomyl), carbendazim, the mould prestige of second, iprovalicarb (iprovalicarb), benzene metsulfovax (benthiavalicarb), thiophanate-methyl, Propamocarb and salt thereof, benthiozole (benthiazole), probenazole, allicin, carvacrol, Kocide SD, copper sulphate, cuprous oxide, Cupravit (copper oxychloride), sulphur, bordeaux mixture, Thiodiazole-copper, iprodione, procymidone, sclex (dichlozolin), fluoromide (Fluoromide), vinclozolin, captan (captan), folpet (folpet), iprodione, tmtd, ziram, Polycarbamate (polycarbamate), Carbatene, mancozeb, zineb, Propineb, Isoprothiolane, dimethomorph, tridemorph, dodemorph, butadiene morpholine, pyrimorph, flumorph, edifenphos, kitazine (CAS No.:13286-32-3), iprobenfos, Rabcide, pyrazophos (pyrazophos), tolelofos-methyl, phosethyl-Al, fentin, famoxadone, SYP-Z048, hymexazo, the spirit of Evil frost, pyraclostrobin, azoles bacterium ester (pyraoxystrobin), azoles amine bacterium ester (pyrametostrobin), fluorine azoles bacterium acid amides (fluxapyroxad), fluazinam, pyrifenox (pyrifenox), ring pyridine bacterium amine (CASNo.:112860-04-5), Boscalid, fluopicolide (fluopicolide), cyprodinil, fluorine mepanipyrim (diflumetorim), ferimzone (ferimzone), mepanipyrim (mepanipyrim), phonetic mould amine, Fenarimol, nuarimol, the phonetic phenol of second (ethirimol), bupirimate (bupirimate), dimethirimol (dimethirimol), fludioxonil, fenpiclonil (fenpiclonil), the third oxygen quinoline (proquinazid), benzene oxygen quinoline (quinoxyfen), dithianon, Grandox fumigant, probenazole, Guardian, Grandox fumigant, oxygen ring azoles, bromuconazole (bromuconazole), Tebuconazole, nitrile bacterium azoles, propiconazole, own azoles alcohol, Difenoconazole, epoxiconazole, Cyproconazole, alkene azoles alcohol, efficient alkene azoles alcohol, RH-7592, Fluquinconazole (Fluquinconazole), Flutriafol, glyoxalin (imibenconazole), plant bacterium azoles (ipconazole), metconazole (metconazole), penconazole, simeconazoles (simeconazole), tetraconazole (tetraconazole), Triadimenol, triazolone, triticonazole, bitertanol, Pencycuron, Fluoxastrobin, dimoxystrobin (dimoxystrobin), fluoxastrobin (fluoxastrobin), SSF 126 (metominostrobin) orysastrobin (orysastrobin), ZEN 90160 (picoxystrobin), pyraclostrobin, oxime bacterium ester, Enestroburin (enestroburin), kresoxim-methyl, Metrafenone, bixafen, fenpropidin (fenpropi dine), volution bacterium amine (spiroxamine) and tricyclazole.
6. according to the bactericidal suspending agent synergistic composition as non-seed treatment of claim 5, wherein, the mean molecule quantity of polyvinylpyrrolidone is preferably 1,000-900, and 000, b) composition is preferably: carbendazim; Benomyl (benomyl); Tpn; Tmtd; Copper sulphate; Hymexazo; Boscalid; Flusilazole; Procymidone; Metalaxyl; Metalaxyl-M; Dimethomorph; Frost urea cyanogen; Kocide SD; Polyoxin; Cyanogen bacterium azoles; Mancozeb; Thiophanate-methyl; Zineb; Polyoxin; Fluoxastrobin; Pyraclostrobin; Triazolone; Tricyclazole; Difenoconazole; Prochloraz and manganese salt and mantoquita; Tebuconazole; Kresoxim-methyl; Iprodione; Jinggangmeisu; Polyoxin; Dithianon; Propiconazole; Own azoles alcohol; Fluorine bacterium azoles; The phonetic phenol of second; The composition of carbendazim and mancozeb; The composition of carbendazim and tricyclazole; The composition of carbendazim and tmtd; The composition of carbendazim and tricyclazole; The composition of thiophanate-methyl and mancozeb; The composition of phosethyl-Al and mancozeb; The composition of metalaxyl and mancozeb; The composition of Metalaxyl-M and mancozeb; The composition of dimethomorph and mancozeb; The composition of frost urea cyanogen and mancozeb; The composition of iprodione and thiophanate-methyl; Polyoxin is with the composition of hymexazo.
7. according to the bactericidal suspending agent synergistic composition as non-seed treatment of claim 6, wherein, the mean molecule quantity of polyvinylpyrrolidone is preferably 5,000-700, and 000, b) composition is preferably: carbendazim; Benomyl (benomyl); Tpn; Tmtd; Copper sulphate; Hymexazo; Boscalid; Flusilazole; Procymidone; Metalaxyl; Metalaxyl-M; Dimethomorph; Frost urea cyanogen; Kocide SD; Polyoxin; Cyanogen bacterium azoles; Prochloraz nantokite; The composition of carbendazim and tmtd; The composition of carbendazim and mancozeb; The composition of carbendazim and tricyclazole; The composition of thiophanate-methyl and mancozeb; The composition of phosethyl-Al and mancozeb; The composition of metalaxyl and mancozeb; The composition of Metalaxyl-M and mancozeb; The composition of dimethomorph and mancozeb; The composition of frost urea cyanogen and mancozeb; The composition of iprodione and thiophanate-methyl; Polyoxin is with the composition of hymexazo.
8. a method of preventing and treating the harmful germ of crop, is characterized in that, uses arbitrary bactericidal suspending agent synergistic composition as non-seed treatment of claim 5-7.
9. control crop according to claim 8 is harmful to the method for germ, it is characterized in that, by arbitrary concentrate of preparing with mix preparation form as the bactericidal suspending agent synergistic composition of non-seed treatment of claim 5-7, while using, after dilute with water, use in a usual manner.
10. the method for the harmful germ of control crop according to claim 8, is characterized in that, the type of service of arbitrary bactericidal suspending agent sterilization synergistic composition as non-seed treatment of claim 5-7 is that bucket is mixed.
CN201210355820.3A 2012-09-24 2012-09-24 Sterilization and synergism suspension agent composition Pending CN103651337A (en)

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CN104115860A (en) * 2014-06-30 2014-10-29 中国水稻研究所 Compound pesticide containing fosetyl-aluminum
CN104351204A (en) * 2014-11-11 2015-02-18 济南新起点医药科技有限公司 Tebuconazole-allicin microcapsule suspension
CN104621150A (en) * 2015-02-28 2015-05-20 夏永锋 Thifluzamide containing bactericide composition for preventing and treating plant diseases and application thereof
CN104839220A (en) * 2015-05-12 2015-08-19 柳州市耕青科技有限公司 Special anti-rot agent for succulent echeveria desmetiana
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CN105766952A (en) * 2016-04-26 2016-07-20 南京华洲药业有限公司 Sterilization composition containing isopyrazam and folpet and application of sterilization composition
CN105766931A (en) * 2016-04-26 2016-07-20 南京华洲药业有限公司 Sterilization composition containing isopyrazam and spiroxamine and application of sterilization composition
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CN104094958A (en) * 2014-06-30 2014-10-15 中国水稻研究所 Ternary compound bactericide containing thiram and ziram
CN105265456A (en) * 2014-07-02 2016-01-27 江苏龙灯化学有限公司 Bactericidal composition
CN105265456B (en) * 2014-07-02 2018-03-20 江苏龙灯化学有限公司 A kind of bactericidal composition
CN104351204A (en) * 2014-11-11 2015-02-18 济南新起点医药科技有限公司 Tebuconazole-allicin microcapsule suspension
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CN104621150A (en) * 2015-02-28 2015-05-20 夏永锋 Thifluzamide containing bactericide composition for preventing and treating plant diseases and application thereof
CN104839220A (en) * 2015-05-12 2015-08-19 柳州市耕青科技有限公司 Special anti-rot agent for succulent echeveria desmetiana
CN104855423A (en) * 2015-05-12 2015-08-26 柳州市耕青科技有限公司 Special rot resistant agent for succulent sedum sarmentosum
CN104839219A (en) * 2015-05-12 2015-08-19 柳州市耕青科技有限公司 Special anti-rot agent for succulent pelargonium odoratissimum
CN104957143A (en) * 2015-06-22 2015-10-07 广东中迅农科股份有限公司 Insecticide composition containing fluxapyroxad and fludioxonil
CN104957143B (en) * 2015-06-22 2018-06-19 广东中迅农科股份有限公司 Bactericidal composition containing fluxapyroxad and fludioxonil
CN105191706A (en) * 2015-08-20 2015-12-30 贵阳中医学院 Method for effectively preventing and controlling pseudostellaria heterophylla (Miq.) pax leaf spot diseases
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