CN105766952B - The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet - Google Patents
The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet Download PDFInfo
- Publication number
- CN105766952B CN105766952B CN201610268207.6A CN201610268207A CN105766952B CN 105766952 B CN105766952 B CN 105766952B CN 201610268207 A CN201610268207 A CN 201610268207A CN 105766952 B CN105766952 B CN 105766952B
- Authority
- CN
- China
- Prior art keywords
- folpet
- fluxapyroxad
- bactericidal composition
- composition according
- mass ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing >N—S—C≡(Hal)3 groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses the bactericidal compositions and its application of a kind of Fluxapyroxad-containsterilization and folpet.The bactericidal composition is using fluxapyroxad and folpet as principle active component, and wherein the mass ratio of fluxapyroxad and folpet is 1~70：1~50.The bactericidal composition can be applied to prevention Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduces application cost, and control effect is substantially better than the use of its single dose.The present invention can be used for preventing the fungal disease on crops, it is particularly possible to which, for preventing the fungal diseases such as banded sclerotial blight, gray mold, apple anthracnose, early blight of tomato, rice blast, significant effect is used better than single dose.
Description
Technical field：
It is main using fluxapyroxad and folpet the present invention relates to a kind of bactericidal composition and application thereof, especially one kind
The bactericidal composition of active ingredient and its application.
Background technology
Fluxapyroxad (fluxapyroxad), chemical formula：C18H12F5N3O, chemical name：3- (difluoromethyl) -1- first
Base-N- (3', 4', 5'- trifluoro-biphenyl -2- bases) pyrazole-4-carboxamide.
Fluxapyroxad belongs to benzamide type fungicide, is succinate dehydrogenase inhibitors, is a kind of broad-spectrum germicide,
With excellent treatment, systemic activity, good control effect is respectively provided with to all kinds of crop banded sclerotial blights, gray mold etc..
Folpet (folpet), molecular formula：C9H4Cl3NO2S, chemical name：The different Yin of 2- [(trichloromethyl) is thio] -1H-
Diindyl -1,3 (2H)-diketone.Structural formula：
Folpet is organosulfureous fungicide, is mainly used for preventing the multiple diseases such as cereal crops vegetables, fruit tree, and to plant
There is stimulation growth.It can prevent rice blast, rice sheath blight disease, wheat rust, head blight, oilseed rape downy mildew, leaf spot of peanut,
The late blight of potato, tomato early blight, anthracnose of tobacco, apple anthracnose etc..
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity increase, and difficulty increases in prevention；Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the control effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
The content of the invention：
The purpose of the present invention is be directed to above-mentioned technical problem to provide a kind of applied widely, at low cost, effect good fluorine-containing
The plant bactericidal composition of azoles bacterium amide and folpet.
Cause answering on fungal disease in prevention plant epiphyte it is a still further object of the present invention to provide the bactericidal composition
With the especially use on prevention banded sclerotial blight, gray mold, apple anthracnose, early blight of tomato, the fungal diseases such as rice blast
On the way.
The purpose of the present invention is be achieved through the following technical solutions：
The bactericidal composition of a kind of Fluxapyroxad-containsterilization and folpet, the bactericidal composition is with fluxapyroxad and folpet
For principle active component, the wherein mass ratio of fluxapyroxad and folpet is 1~70：1~50, wherein have in bactericidal composition
Effect composition is present in enhancing effective amount in composition.
The mass ratio of the bactericidal composition, wherein fluxapyroxad and folpet is preferably 1~50：1~50, into one
Step is preferably 5~50：1~30, it is still more preferably 10~50：1~4.
Fluxapyroxad and the preferred mass of folpet proportioning or：70：1、50：1、30：1、20：1、10：1、5：
1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50.
In the compositions of the present invention, both fluxapyroxad and folpet account for the mass percentage of composition for 2~
80%.It is preferred that 5~70%.
The bactericidal composition, wherein using fluxapyroxad and folpet as principle active component and known auxiliary agent and
Excipient is re-dubbed any one dosage form allowed on pesticide.These known auxiliary agents, excipients have dispersant, diffusant, disappear
Calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene ether, benzyl phenol polyethenoxy may be employed in infusion, wetting agent, disintegrant etc.
Ether, phenethyl phenol polyethenoxy ether, fatty alcohol polyoxyethylene ether and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, nonylphenol polyoxyethylene ether, are spat castor oil polyoxyethylene ether
Warm series, fatty alcohol polyoxyethylene ether, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. combination, excipient include
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water.More than auxiliary agent, excipient and other
Auxiliary material can be applied alone or be used in combination.
The bactericidal composition, dosage form are missible oil, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
Application of the above-mentioned bactericidal composition on prevention fungal diseases of plants drug is prepared.Especially in prevention cereal
Application in terms of class, fruit tree, vegetable crop disease has remarkable result.
Above-mentioned application, the fungal diseases of plants is banded sclerotial blight, gray mold, apple anthracnose, early blight of tomato, water
At least one of rice rice blast.
The characteristics of bactericidal composition of the present invention：
1st, the fluxapyroxad and folpet used in the present invention, the mechanism of action is different, mutual mixture will not generate it is low touch, can
Synergy reduces dosage, reduces cost.
2nd, the present composition scope of application increase, suitable for prevention Cereal, fruit tree, vegetables refractory fungal disease,
Particularly preventing banded sclerotial blight, gray mold, apple anthracnose, early blight of tomato, rice blast etc. has significant effect.This hair
Bright bactericidal composition has good control effect to fungal diseases such as sac fungus, basidiomycetes, Fungi Imperfectis；And inhibit pest or true
Drug-fast generation of the bacterium to unitary agent (fluxapyroxad and folpet are any).Bactericidal composition of the present invention can generate higher
Synergistic function, and the dosage of the amount ratio independent reactive compound of the mixture substantially reduces, i.e. the work of mixture
Property be more than independent component activity.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as banded sclerotial blight, gray mold, apple anthracnose, early blight of tomato, rice blast have apparent synergistic function, gram
It takes and has delayed the resistance to the action of a drug, expand prevention spectrum, hence it is evident that improve control effect；(2) prevention recruitment, drug cost are reduced；(3) may be used
Substitute pesticide that is conventional and being also easy to produce resistance；(4) compared with single dose, production and application cost reduces；(5) the fungi resistance to the action of a drug is inhibited
Generation, it is with obvious effects higher than its single dose use.
Specific embodiment
The invention will be further described with reference to embodiments, and the preparation method of dosage form is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometrics are tested：
Indoors using mycelial growth rate method, EC of the different agents to bacterial strain is measured50Value, using co-toxicity coefficient calculating side
Method calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows：
EC (is generally selected as standard agent using a certain single dose in mixture50Junior), it is calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, and CTC exists when being less than 80 for antagonism, CTC
It is summation action between 80-120.
According to active ingredient fluxapyroxad (A)：Folpet (B) quality proportioning is：80：1、70：1、50：1、30：1、20：
1、10：1、5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50、1：60 are tested, measure its to kind
The co-toxicity coefficient of eggplant early epidemic germ (Alternaria solani (Ellis et Martin) Jones et Grout.).
Table 1：Fluxapyroxad+folpet different ratio is to the indoor biometrics result of tomato early blight bacterium
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% fluxapyroxad SC | Y=4.025+1.225X | 6.254 | - |
| 50% folpet WP | Y=2.600+3.652X | 4.540 | - |
| A:B=80:1 | Y=2.468+2.789X | 8.090 | 76.95 |
| A:B=70:1 | Y=3.467+2.205X | 4.957 | 125.49 |
| A:B=50:1 | Y=3.106+3.220X | 3.874 | 160.23 |
| A:B=30:1 | Y=4.146+1.540X | 3.583 | 172.45 |
| A:B=20:1 | Y=3.275+2.880X | 3.973 | 154.63 |
| A:B=10:1 | Y=4.168+1.598X | 3.314 | 182.45 |
| A:B=5:1 | Y=3.719+2.302X | 3.603 | 163.29 |
| A:B=2.5:1 | Y=3.615+2.225X | 4.193 | 134.63 |
| A:B=1:1 | Y=3.912+1.635X | 4.628 | 200.20 |
| A:B=1:2 | Y=4.698+0.698X | 2.704 | 184.75 |
| A:B=1:4 | Y=4.479+1.321X | 2.481 | 193.63 |
| A:B=1:6 | Y=3.674+2.302X | 3.766 | 125.48 |
| A:B=1:10 | Y=3.224+3.663X | 3.054 | 152.45 |
| A:B=1:20 | Y=4.245+1.522X | 3.132 | 146.89 |
| A:B=1:30 | Y=3.188+4.210X | 2.694 | 170.04 |
| A:B=1:50 | Y=3.430+3.636X | 2.702 | 168.94 |
| A:B=1:60 | Y=3.103+3.220X | 3.882 | 101.47 |
Field control effectiveness test：
The pesticidal preparations prevention early blight of tomato experiment made from above-described embodiment.
1st, test process：This test medicine dosage sets three concentration for the treatment of, comparison medicine respectively according to the difference of each ingredient
Agent is pesticide single dose 25% fluxapyroxad SC and 50% folpet WP and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent before dispenser
Method is：5 points of grab sample in test process area carry out severity Scaling according to national field trial relevant criterion, calculate preventive effect.
Result of the test is shown in Table 2：
2 field test effect of table
By indoor biometrics and field efficacy, the result shows that, fluxapyroxad has with folpet composition significantly to be cooperateed with
Synergistic effect, the control effect of composition is excellent, and control effect is better than single dose kind, has in agricultural is applied using valency
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% fluxapyroxad folpet wettable powder (1:2)
By fluxapyroxad 5g, folpet 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, are made effective
Ingredient percent is 15% fluxapyroxad folpet wettable powder.
Embodiment 2：15% fluxapyroxad folpet wettable powder (1:4)
By fluxapyroxad 3g, folpet 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is made can for 15% fluxapyroxad folpet
Wet powder.
Embodiment 3：14% fluxapyroxad folpet wettable powder (1:6)
By fluxapyroxad 2g, folpet 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is made can for 14% fluxapyroxad folpet
Wet powder.
Embodiment 4：20% fluxapyroxad folpet suspending agent (1:1)
10g fluxapyroxads, 10g folpets, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, in the effect of sand mill
Under effective ingredient percent is made as 20% fluxapyroxad folpet suspending agent.
Embodiment 5：55% fluxapyroxad folpet aqueous emulsion (1:10)
Weigh 5g fluxapyroxads, 50g folpets, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that more than raw material is routinely prepared to aqueous emulsion puts into mixing
Kettle high speed mixes, and effective ingredient percent is made as 55% fluxapyroxad folpet aqueous emulsion.Embodiment 6：
42% fluxapyroxad folpet missible oil (1:20)
Weigh 2g fluxapyroxads, 40g folpets, it is calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent oil is to 100g.More than raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 42% fluxapyroxad folpet missible oil.
Embodiment 7：70% fluxapyroxad folpet missible oil (2.5:1)
Weigh 50g fluxapyroxads, 20g folpets, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.More than raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil
It closes, effective ingredient percent is made as 70% fluxapyroxad folpet missible oil.
Embodiment 8：18% fluxapyroxad folpet water dispersion granule (5：1)
15g fluxapyroxads, 3g folpets are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 28g complement to 100g, and more than raw material is formed with effect ingredient by water dispersible granular agent method
Mass percent is 17% fluxapyroxad folpet water dispersion granule.
Embodiment 9：11% fluxapyroxad folpet missible oil (10:1)
Weigh 10g fluxapyroxads, 1g folpets, it is calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent oil is to 100g.More than raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 11% fluxapyroxad folpet missible oil.
Embodiment 10：32% fluxapyroxad folpet microemulsion (20:1)
Weigh 30g fluxapyroxads, 2g folpets, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.More than raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, effective ingredient percent is made as 32% fluxapyroxad folpet micro emulsion
Agent.
Embodiment 11：31% fluxapyroxad folpet missible oil (30:1)
Weigh 30g fluxapyroxads, 1g folpets, it is calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent oil is to 100g.More than raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 31% fluxapyroxad folpet missible oil.
Embodiment 12：51% fluxapyroxad folpet suspending agent (50:1)
50g fluxapyroxads, 1g folpets, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g, under the action of sand mill with water
Effective ingredient percent is made as 51% fluxapyroxad folpet suspending agent.
Embodiment 13：32% fluxapyroxad folpet microemulsion (1:15)
Weigh 2g fluxapyroxads, 30g folpets, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.More than raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, effective ingredient percent is made as 32% fluxapyroxad folpet micro emulsion
Agent.
Embodiment 14：6% fluxapyroxad folpet aqueous emulsion (1:5)
Weigh 1g fluxapyroxads, 5g folpets, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, solvent naphtha 13g, adds water to 100g.The method that more than raw material is routinely prepared to aqueous emulsion puts into mixing kettle
High speed mixes, and effective ingredient percent is made as 6% fluxapyroxad folpet aqueous emulsion.
Embodiment 15：62% fluxapyroxad folpet microemulsion (1:30)
Weigh 2g fluxapyroxads, 60g folpets, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.More than raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, effective ingredient percent is made as 62% fluxapyroxad folpet micro emulsion
Agent.
Embodiment 16：51% fluxapyroxad folpet suspending agent (1:50)
1g fluxapyroxads, 50g folpets, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g, under the action of sand mill with water
Effective ingredient percent is made as 51% fluxapyroxad folpet suspending agent.
Embodiment 17：7% fluxapyroxad folpet water dispersion granule (1：2.5)
Weigh 2g fluxapyroxads, 5g folpets, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and more than raw material is formed with imitating by water dispersible granular agent method
Ingredient percent is 7% fluxapyroxad folpet water dispersion granule.
Claims (10)
1. the bactericidal composition of a kind of Fluxapyroxad-containsterilization and folpet, it is characterised in that the bactericidal composition is with fluxapyroxad
It is active ingredient with folpet, wherein the mass ratio of fluxapyroxad and folpet is 1~70：1~50.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the fluxapyroxad and folpet
For 1~50：1~50.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the fluxapyroxad and folpet
For 5~50：1~30.
4. bactericidal composition according to claim 3, it is characterised in that the mass ratio of the fluxapyroxad and folpet
For 10~50：1~4.
5. bactericidal composition according to claim 1, it is characterised in that both the fluxapyroxad and folpet account for
The mass percentage of composition is 2-80%.
6. bactericidal composition according to claim 5, it is characterised in that both the fluxapyroxad and folpet account for
The mass percentage of composition is 5-70%.
7. bactericidal composition according to claim 1, it is characterised in that using fluxapyroxad and folpet to be main effective
Ingredient and insecticides adjuvant, excipients are configured to any one dosage form allowed on pesticide.
8. bactericidal composition according to claim 7, it is characterised in that the dosage form be missible oil, suspending agent, aqueous emulsion,
Wettable powder or water dispersion granule.
9. application of the bactericidal composition described in claim 1 on prevention fungal diseases of plants drug is prepared.
10. application according to claim 9, it is characterised in that the fungal diseases of plants is banded sclerotial blight, gray mold, apple
At least one of fruit anthracnose, early blight of tomato, rice blast.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610268207.6A CN105766952B (en) | 2016-04-26 | 2016-04-26 | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610268207.6A CN105766952B (en) | 2016-04-26 | 2016-04-26 | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105766952A CN105766952A (en) | 2016-07-20 |
| CN105766952B true CN105766952B (en) | 2018-05-22 |
Family
ID=56398744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610268207.6A Active CN105766952B (en) | 2016-04-26 | 2016-04-26 | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105766952B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106879614A (en) * | 2017-04-19 | 2017-06-23 | 广东广康生化科技股份有限公司 | A kind of bactericidal composition and application thereof |
| CN108935495A (en) * | 2017-05-22 | 2018-12-07 | 广东广康生化科技股份有限公司 | A kind of effective component includes the Bactericidal composite of folpet and thifluzamide |
| CN107279161A (en) * | 2017-08-02 | 2017-10-24 | 广东广康生化科技股份有限公司 | A kind of bactericidal composition containing folpet and fluopyram |
| CN108184876A (en) * | 2017-12-29 | 2018-06-22 | 广东广康生化科技股份有限公司 | Bactericidal composition and application containing folpet and iprodione |
| CN108477193A (en) * | 2018-07-03 | 2018-09-04 | 广东广康生化科技股份有限公司 | A kind of composition pesticide containing folpet and nitrile bacterium azoles |
| CN108477192A (en) * | 2018-07-03 | 2018-09-04 | 广东广康生化科技股份有限公司 | A kind of efficient bactericidal composite containing folpet and hexaconazole |
| CN113490416A (en) * | 2018-12-31 | 2021-10-08 | 安道麦马克西姆有限公司 | Fungicidal mixtures |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101965128A (en) * | 2008-02-05 | 2011-02-02 | 巴斯夫欧洲公司 | Plant health composition |
| CN102302024A (en) * | 2011-04-23 | 2012-01-04 | 陕西韦尔奇作物保护有限公司 | Bactericidal composition containing spiroxamine and thiocarbamate |
| CN103651338A (en) * | 2012-09-24 | 2014-03-26 | 宜德雅(北京)科技有限公司 | Sterilization and synergism composition |
| CN103651337A (en) * | 2012-09-24 | 2014-03-26 | 宜德雅(北京)科技有限公司 | Sterilization and synergism suspension agent composition |
-
2016
- 2016-04-26 CN CN201610268207.6A patent/CN105766952B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101965128A (en) * | 2008-02-05 | 2011-02-02 | 巴斯夫欧洲公司 | Plant health composition |
| CN102302024A (en) * | 2011-04-23 | 2012-01-04 | 陕西韦尔奇作物保护有限公司 | Bactericidal composition containing spiroxamine and thiocarbamate |
| CN103651338A (en) * | 2012-09-24 | 2014-03-26 | 宜德雅(北京)科技有限公司 | Sterilization and synergism composition |
| CN103651337A (en) * | 2012-09-24 | 2014-03-26 | 宜德雅(北京)科技有限公司 | Sterilization and synergism suspension agent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105766952A (en) | 2016-07-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105766952B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet | |
| CN105994318A (en) | Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite | |
| CN105941416B (en) | A kind of bactericidal composition and its application of the bacterium amine of pyrrole containing biphenyl and Tebuconazole | |
| CN105766933A (en) | Bixafen and prothioconazole containing bactericidal composition and application thereof | |
| CN105831131B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and probenazole | |
| CN105941438B (en) | A kind of bactericidal composition and its application of fluorine-containing ether bacterium amide and folpet | |
| CN105794794A (en) | Bactericidal composition containing isopyrazam and tiadinil and application of bactericidal composition | |
| CN106212474A (en) | A kind of Fluxapyroxad-containsterilization and the bactericidal composition of cycloheximide triazole and application thereof | |
| CN106889079B (en) | A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine | |
| CN105941407B (en) | A kind of bactericidal composition and its application of fluorine-containing ether bacterium acid amides and fludioxonil | |
| CN104642367A (en) | Bactericidal composition containing prothioconazole and prochloraz and application thereof | |
| CN105794792B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil | |
| CN105831140B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and thiram | |
| CN105766931B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and volution bacterium amine | |
| CN106106502B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles | |
| CN105941403B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and coumoxystrobin | |
| CN105831124A (en) | Bactericidal composition containing fluxapyroxad and ethirimol and application thereof | |
| CN105961400B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and olefin conversion | |
| CN105794815B (en) | A kind of bactericidal composition and its application containing isopyrazam and thiophanate-methyl | |
| CN105941425B (en) | A kind of bactericidal composition and its application of fluorine-containing ether bacterium acid amides and Wakil | |
| CN105918335B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and Propamocarb | |
| CN105475340B (en) | A kind of bactericidal composition and its application containing Silthiopham and metalaxyl | |
| CN105475342B (en) | A kind of bactericidal composition and its application containing Silthiopham and fluazinam | |
| CN105379753B (en) | A kind of bactericidal composition and its application containing mepanipyrim and different rice blast net | |
| CN107494564A (en) | A kind of bactericidal composition and its application containing isopyrazam and zineb |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |