CN106106502B - A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles - Google Patents
A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles Download PDFInfo
- Publication number
- CN106106502B CN106106502B CN201610482824.6A CN201610482824A CN106106502B CN 106106502 B CN106106502 B CN 106106502B CN 201610482824 A CN201610482824 A CN 201610482824A CN 106106502 B CN106106502 B CN 106106502B
- Authority
- CN
- China
- Prior art keywords
- fluxapyroxad
- simeconazoles
- bactericidal composition
- application
- banded sclerotial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The invention discloses the bactericidal compositions and its application of a kind of Fluxapyroxad-containsterilization and simeconazoles.The bactericidal composition is using fluxapyroxad and simeconazoles as principle active component, and wherein the mass ratio of fluxapyroxad and simeconazoles is 1~70:1~50.The bactericidal composition can be applied to prevention and treatment Cereal, fruit tree, vegetable disease, and synergistic function with higher overcomes and delayed the drug resistance of germ, and sterilization speed is fast, the lasting period is long, reduces application cost, and control efficiency is substantially better than the use of its single dose.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as powdery mildew, scab, rust, damping-off, banded sclerotial blight, banded sclerotial blight, gray mold, significant effect is used better than single dose.
Description
Technical field:
It is main with fluxapyroxad and simeconazoles the present invention relates to a kind of bactericidal composition and application thereof, especially one kind
The bactericidal composition of active constituent and its application.
Background technique
Fluxapyroxad (fluxapyroxad), chemical formula: C18H12F5N3O, chemical name: 3- (difluoromethyl) -1- first
Base-N- (3', 4', 5'- trifluoro-biphenyl -2- base) pyrazole-4-carboxamide.
Fluxapyroxad belongs to benzamide type fungicide, is succinate dehydrogenase inhibitors, is a kind of broad-spectrum germicide,
With excellent treatment, systemic activity, good control effect is all had to all kinds of crop banded sclerotial blights, gray mold etc..
Simeconazoles (simeconazole), molecular formula: C14H20F N3O Si, chemical name: (RS) -2- (4- fluorophenyl) -
1- (1H-1,2,4-1 tri- -1- bases) -3- trimethyl silicon substrate propane -2- alcohol.Structural formula:
Simeconazoles are the siliceous triazole bactericidal agents that company develops altogether of Japan three, are a kind of ergosterol class synthesis inhibition
Agent destroys and prevents the biosynthesis of the cell membrane important composition ingredient ergosterol of germ, causes cell membrane that cannot be formed, make
Germ is dead.Due to good absorbability, there is brilliant osmosis in plant, therefore can be inhaled by plant rapidly
It receives, and is conducted in inside.Disease caused by a variety of sac fungus, basidiomycetes and Fungi Imperfecti can be effectively prevented, especially to all kinds of white powder
Disease, scab, rust, damping-off, banded sclerotial blight etc. have excellent preventive effect.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area gradually expands, and disease occurrence degree, generation quantity increase, and increases preventing and treating upper difficulty；Separately
On the one hand, the resistance of pathogen selects to rise year by year under pressure in lasting medicament, and the control efficiency of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
Summary of the invention:
The purpose of the present invention is provide a kind of applied widely, at low cost, effect good fluorine-containing in view of the above technical problems
The plant bactericidal composition of azoles bacterium amide and simeconazoles.
It is a still further object of the present invention to provide the bactericidal compositions to cause answering on fungal disease in prevention and treatment plant epiphyte
With the especially use on prevention and treatment powdery mildew, scab, rust, damping-off, banded sclerotial blight, banded sclerotial blight, the fungal diseases such as gray mold
On the way.
The purpose of the present invention is be achieved through the following technical solutions:
A kind of bactericidal composition of Fluxapyroxad-containsterilization and simeconazoles, the bactericidal composition is with fluxapyroxad and simeconazoles
For principle active component, wherein the mass ratio of fluxapyroxad and simeconazoles is 1~70:1~50, is wherein had in bactericidal composition
Effect composition is present in composition with enhancing effective amount.
The bactericidal composition, wherein the mass ratio of fluxapyroxad and simeconazoles is preferably 1~50:1~30, into one
Step is preferably 1~20:1~30, is still more preferably 1~20:1~20.
Fluxapyroxad and the preferred mass of simeconazoles proportion may be: 70:1,50:1,30:1,20:1,10:1,5:
1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50.
In the compositions of the present invention, both fluxapyroxad and simeconazoles account for composition mass percentage be 2~
80%.It is preferred that 5~70%.
The bactericidal composition, wherein using fluxapyroxad and simeconazoles as principle active component and known auxiliary agent and
Excipient is re-dubbed any one dosage form allowed on pesticide.These known auxiliary agents, excipients have dispersing agent, diffusant, disappear
Infusion, wetting agent, disintegrating agent etc. can use calcium dodecyl benzene sulfonate, alkyl phenol polyoxyethylene ether, benzyl phenol polyethenoxy
Ether, phenethyl phenol polyethenoxy ether, fatty alcohol polyoxyethylene ether and its similar products, aliphatic amine polyoxyethylene ether, fatty acid ring
Oxidative ethane addition product, castor oil polyoxyethylene ether, nonylphenol polyoxyethylene ether, is spat at polyoxyethylene polyoxy propylene block compound
Warm series, fatty alcohol polyoxyethylene ether, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more combinations in lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., excipient include
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water.The above auxiliary agent, excipient and other
Auxiliary material can be applied alone or be used in combination.
The bactericidal composition, dosage form are missible oil, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
Application of the above-mentioned bactericidal composition on preparation prevention and treatment fungal diseases of plants drug.Especially in prevention and treatment cereal
Application in terms of class, fruit tree, vegetable crop disease has remarkable result.
Above-mentioned application, the fungal diseases of plants are that powdery mildew, scab, rust, damping-off, banded sclerotial blight, line are withered
At least one of disease, gray mold.
The characteristics of bactericidal composition of the present invention:
1, the fluxapyroxad and simeconazoles used in the present invention, the mechanism of action is different, and mutual mixture will not generate low touching, can
Synergy reduces dosage, reduces cost.
2, the present composition scope of application increases, suitable for preventing and treating the refractory fungal disease of Cereal, fruit tree, vegetables,
Especially preventing and treating powdery mildew, scab, rust, damping-off, banded sclerotial blight, banded sclerotial blight, gray mold etc. has significant effect.This hair
Bright bactericidal composition has good control efficiency to fungal diseases such as sac fungus, basidiomycetes, Fungi Imperfectis；And inhibit pest or true
Generation of the bacterium to the drug resistance of single formulation (fluxapyroxad and simeconazoles are any).Bactericidal composition of the present invention can generate higher
Synergistic function, and the dosage of the amount ratio independent reactive compound of the mixture substantially reduces, i.e. the work of mixture
Property be greater than independent component activity.
Beneficial effects of the present invention compared with prior art: (1) compared with single dose, the composition antagonism fungal disease is such as
The fungal diseases such as powdery mildew, scab, rust, damping-off, banded sclerotial blight, banded sclerotial blight, gray mold have obvious synergistic function, gram
Drug resistance is taken and delayed, expands prevention spectrum, hence it is evident that improve control efficiency；(2) prevention and treatment recruitment, drug cost are reduced；(3) may be used
Substitution is conventional and is also easy to produce the pesticide of resistance；(4) compared with single dose, production and application cost is reduced；(5) inhibit fungi drug resistance
Generation, effect be apparently higher than its single dose use.
Specific embodiment
The invention will be further described with reference to embodiments, and the preparation method of dosage form is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometrics experiment:
Mycelial growth rate method, EC of the measurement different agents to bacterial strain are used indoors50Value, using co-toxicity coefficient calculating side
Method calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows:
(EC is generally selected using single dose a certain in mixture as standard agent50Junior), it is calculated:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Theoretical toxicity index=A single dose toxicity index × A single dose proportion+B single dose in mixture toxicity index
× B single dose proportion in mixture
Survey toxicity index=standard single dose EC50Value/mixture EC50Value × 100
Co-toxicity coefficient=survey toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient classification: mixture has synergetic when CTC is greater than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
According to effective component fluxapyroxad (A): simeconazoles (B) quality proportioning are as follows: 80:1,70:1,50:1,30:1,20:
1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50,1:60 are tested, and measure it to water
The co-toxicity coefficient of sheath and culm blight of rice germ (Thanatephorus cucumeris.).
Table 1: indoor biometrics result of the fluxapyroxad+simeconazoles different ratio to Rhizoctonia solani Kuhn
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% fluxapyroxad SC | Y=4.616+2.002X | 1.555 | - |
| 20% simeconazoles WP | Y=2.468+3.632X | 4.980 | - |
| A:B=80:1 | Y=3.265+2.596X | 4.661 | 107.75 |
| A:B=70:1 | Y=4.122+1.548X | 3.690 | 136.29 |
| A:B=50:1 | Y=3.939+2.035X | 3.321 | 152.02 |
| A:B=30:1 | Y=4.305+1.254X | 3.583 | 142.15 |
| A:B=20:1 | Y=3.770+2.698X | 2.857 | 180.23 |
| A:B=10:1 | Y=3.102+3.620X | 3.345 | 158.79 |
| A:B=5:1 | Y=3.642+2.487X | 3.515 | 160.02 |
| A:B=2.5:1 | Y=4.132+1.549X | 3.636 | 170.48 |
| A:B=1:1 | Y=3.514+2.532X | 3.861 | 196.56 |
| A:B=1:2 | Y=1.934+3.625X | 7.012 | 157.90 |
| A:B=1:4 | Y=3.748+1.324X | 8.825 | 125.46 |
| A:B=1:6 | Y=2.556+2.602X | 8.695 | 139.53 |
| A:B=1:10 | Y=3.303+1.874X | 8.050 | 165.08 |
| A:B=1:20 | Y=0.562+4.784X | 8.467 | 170.49 |
| A:B=1:30 | Y=1.459+3.150X | 10.625 | 140.15 |
| A:B=1:50 | Y=2.853+2.003X | 11.796 | 129.61 |
| A:B=1:60 | Y=3.616+1.227X | 13.414 | 114.75 |
Field control effectiveness test:
The pesticidal preparations made from above-described embodiment prevent and treat rice sheath blight disease test.
1, test process: this test medicine dosage sets three concentration for the treatment of, comparison medicine according to the difference of each ingredient respectively
Agent is pesticide single dose 25% fluxapyroxad SC and 20% simeconazoles WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before application
Method are as follows: 5 points of grab sample in test process area carry out severity Scaling according to national field trial relevant criterion, calculate preventive effect.
Test result is shown in Table 2:
2 field test effect of table
By indoor biometrics and field efficacy, the result shows that, fluxapyroxad has with simeconazoles composition significantly to be cooperateed with
The control efficiency of synergistic effect, composition is excellent, and control efficiency is better than single dose kind, has the valence of applying in agricultural application
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrate two kinds below with specific embodiment
The preparation that effective component is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1:15% fluxapyroxad simeconazoles wettable powder (1:2)
By fluxapyroxad 5g, simeconazoles 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon black 5g, kaolin add to 100g mixture and carry out air-flow crushing, are made effective
Ingredient percent is 15% fluxapyroxad simeconazoles wettable powder.
Embodiment 2:15% fluxapyroxad simeconazoles wettable powder (1:4)
By fluxapyroxad 3g, simeconazoles 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon black 5g, kaolinite
Soil adds to 100g mixture and carries out air-flow crushing, and it is that 15% fluxapyroxad simeconazoles can that effective component mass percent, which is made,
Wet powder.
Embodiment 3:14% fluxapyroxad simeconazoles wettable powder (1:6)
By fluxapyroxad 2g, simeconazoles 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon black 5g, kaolinite
Soil adds to 100g mixture and carries out air-flow crushing, and it is that 14% fluxapyroxad simeconazoles can that effective component mass percent, which is made,
Wet powder.
Embodiment 4:20% fluxapyroxad fluosilicic azole suspending agent (1:1)
10g fluxapyroxad, 10g simeconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthan gum 0.15g, ethylene glycol 5g, silicon oxidative ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, in the effect of sand mill
Under be made effective ingredient percent be 20% fluxapyroxad fluosilicic azole suspending agent.
Embodiment 5:55% fluxapyroxad simeconazoles aqueous emulsion (1:10)
Weigh 5g fluxapyroxad, 50g simeconazoles, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The above raw material is routinely prepared to the method investment mixing of aqueous emulsion
The mixing of kettle high speed, it is 55% fluxapyroxad simeconazoles aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 6:42% fluxapyroxad simeconazoles missible oil (1:20)
Weigh 2g fluxapyroxad, 40g simeconazoles, it is calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 42% fluxapyroxad simeconazoles missible oil.
Embodiment 7:70% fluxapyroxad simeconazoles missible oil (2.5:1)
Weigh 50g fluxapyroxad, 20g simeconazoles, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil
It closes, it is 70% fluxapyroxad simeconazoles missible oil that effective ingredient percent, which is made,.
Embodiment 8:18% fluxapyroxad simeconazoles water dispersion granule (5:1)
15g fluxapyroxad, 3g simeconazoles are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 28g complement to 100g, and the above raw material is formed with effect ingredient by water dispersible granular agent method
Mass percent is 17% fluxapyroxad simeconazoles water dispersion granule.
Embodiment 9:11% fluxapyroxad simeconazoles missible oil (10:1)
Weigh 10g fluxapyroxad, 1g simeconazoles, it is calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 11% fluxapyroxad simeconazoles missible oil.
Embodiment 10:32% fluxapyroxad simeconazoles microemulsion (20:1)
Weigh 30g fluxapyroxad, 2g simeconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method investment mixing kettle of emulsion, it is 32% fluxapyroxad simeconazoles micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 11:31% fluxapyroxad simeconazoles missible oil (30:1)
Weigh 30g fluxapyroxad, 1g simeconazoles, it is calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method investment mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 31% fluxapyroxad simeconazoles missible oil.
Embodiment 12:51% fluxapyroxad fluosilicic azole suspending agent (50:1)
50g fluxapyroxad, 1g simeconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silicon oxidative ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, under the action of sand mill
It is 51% fluxapyroxad fluosilicic azole suspending agent that effective ingredient percent, which is made,.
Embodiment 13:32% fluxapyroxad simeconazoles microemulsion (1:15)
Weigh 2g fluxapyroxad, 30g simeconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method investment mixing kettle of emulsion, it is 32% fluxapyroxad simeconazoles micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 14:6% fluxapyroxad simeconazoles aqueous emulsion (1:5)
Weigh 1g fluxapyroxad, 5g simeconazoles, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, solvent naphtha 13g, adds water to 100g.The method that the above raw material routinely prepares aqueous emulsion is put into mixing kettle
High speed mixing, it is 6% fluxapyroxad simeconazoles aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 15:62% fluxapyroxad simeconazoles microemulsion (1:30)
Weigh 2g fluxapyroxad, 60g simeconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method investment mixing kettle of emulsion, it is 62% fluxapyroxad simeconazoles micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 16:51% fluxapyroxad fluosilicic azole suspending agent (1:50)
1g fluxapyroxad, 50g simeconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silicon oxidative ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, under the action of sand mill
It is 51% fluxapyroxad fluosilicic azole suspending agent that effective ingredient percent, which is made,.
Embodiment 17:7% fluxapyroxad simeconazoles water dispersion granule (1:2.5)
Weigh 2g fluxapyroxad, 5g simeconazoles, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, white carbon black 3g, diatomite complement to 100g, and the above raw material is formed with imitating by water dispersible granular agent method
Ingredient percent is 7% fluxapyroxad simeconazoles water dispersion granule.
Claims (8)
1. a kind of application of the bactericidal composition of Fluxapyroxad-containsterilization and simeconazoles on preparation prevention and treatment rice banded sclerotial blight medicine,
Be characterized in that the bactericidal composition using fluxapyroxad and simeconazoles as principle active component, wherein fluxapyroxad and fluosilicic
The mass ratio of azoles is 1~70:1~50.
2. application of the bactericidal composition according to claim 1 on preparation prevention and treatment rice banded sclerotial blight medicine, feature exist
In the mass ratio of the fluxapyroxad and simeconazoles be 1~50:1~30.
3. application of the bactericidal composition according to claim 2 on preparation prevention and treatment rice banded sclerotial blight medicine, feature exist
In the mass ratio of the fluxapyroxad and simeconazoles be 1~20:1~30.
4. application of the bactericidal composition according to claim 3 on preparation prevention and treatment rice banded sclerotial blight medicine, feature exist
In the mass ratio of the fluxapyroxad and simeconazoles be 1~20:1~20.
5. application of the bactericidal composition according to claim 1 on preparation prevention and treatment rice banded sclerotial blight medicine, feature exist
The mass percentage of composition is accounted in both the fluxapyroxad and simeconazoles as 2-80%.
6. application of the bactericidal composition according to claim 5 on preparation prevention and treatment rice banded sclerotial blight medicine, feature exist
The mass percentage of composition is accounted in both the fluxapyroxad and simeconazoles as 5-70%.
7. application of the bactericidal composition according to claim 1 on preparation prevention and treatment rice banded sclerotial blight medicine, feature exist
It is any one in being configured to allow on pesticide using fluxapyroxad and simeconazoles as principle active component and insecticides adjuvant, excipients
Kind dosage form.
8. application of the bactericidal composition according to claim 7 on preparation prevention and treatment rice banded sclerotial blight medicine, feature exist
In the dosage form be missible oil, suspending agent, aqueous emulsion, wettable powder or water dispersion granule.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610482824.6A CN106106502B (en) | 2016-06-27 | 2016-06-27 | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610482824.6A CN106106502B (en) | 2016-06-27 | 2016-06-27 | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106106502A CN106106502A (en) | 2016-11-16 |
| CN106106502B true CN106106502B (en) | 2019-03-01 |
Family
ID=57266763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610482824.6A Active CN106106502B (en) | 2016-06-27 | 2016-06-27 | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106106502B (en) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104365610A (en) * | 2010-08-05 | 2015-02-25 | 拜耳知识产权有限责任公司 | Active compounds combinations comprising prothioconazole and fluxapyroxad |
| CN103385256A (en) * | 2012-05-07 | 2013-11-13 | 陕西韦尔奇作物保护有限公司 | Synergistic sterilization composition containing Xemium and triazoles |
| CN103444783B (en) * | 2012-05-29 | 2017-07-18 | 陕西韦尔奇作物保护有限公司 | A kind of bactericidal composition of Fluxapyroxad-containsterilization |
-
2016
- 2016-06-27 CN CN201610482824.6A patent/CN106106502B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106106502A (en) | 2016-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105766952B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet | |
| CN104642331A (en) | Bactericidal composition containing prothioconazole and tebuconazole and application thereof | |
| CN105941416B (en) | A kind of bactericidal composition and its application of the bacterium amine of pyrrole containing biphenyl and Tebuconazole | |
| CN107027778A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and Tebuconazole | |
| CN105831131B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and probenazole | |
| CN105794794A (en) | Bactericidal composition containing isopyrazam and tiadinil and application of bactericidal composition | |
| CN105766927A (en) | Bactericidal composition containing bixafen and phenamacril and application thereof | |
| CN106889079B (en) | A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine | |
| CN106106502B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles | |
| CN105961400B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and olefin conversion | |
| CN105831140B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and thiram | |
| CN105794792B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil | |
| CN105831124A (en) | Bactericidal composition containing fluxapyroxad and ethirimol and application thereof | |
| CN105941403B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and coumoxystrobin | |
| CN105766931B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and volution bacterium amine | |
| CN105766926A (en) | Bactericidal composition containing bixafen and coumoxystrobin and application thereof | |
| CN107306983A (en) | A kind of bactericidal composition and its application of the pyrrole bacterium ketone of benzene containing amine and Tebuconazole | |
| CN107306990A (en) | A kind of bactericidal composition and its application containing isopyrazam and Flusilazole | |
| CN107494564A (en) | A kind of bactericidal composition and its application containing isopyrazam and zineb | |
| CN107467051A (en) | A kind of bactericidal composition and its application of the pyrrole bacterium ketone of benzene containing amine and penconazole | |
| CN107494587A (en) | A kind of bactericidal composition and its application of the pyrrole bacterium ketone of benzene containing amine and simeconazoles | |
| CN106889075A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and RH-7592 | |
| CN109169677A (en) | A kind of composition and its application of fluorine-containing azoles bacterium acyl azanol and fludioxonil | |
| CN107333782A (en) | A kind of bactericidal composition and its application of the pyrrole bacterium ketone of benzene containing amine and cyazofamid | |
| CN107306960A (en) | A kind of bactericidal composition and its application containing isopyrazam and volution bacterium amine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |