CN105794792B - The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil - Google Patents
The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil Download PDFInfo
- Publication number
- CN105794792B CN105794792B CN201610264933.0A CN201610264933A CN105794792B CN 105794792 B CN105794792 B CN 105794792B CN 201610264933 A CN201610264933 A CN 201610264933A CN 105794792 B CN105794792 B CN 105794792B
- Authority
- CN
- China
- Prior art keywords
- wakil
- fluxapyroxad
- bactericidal composition
- application
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses the bactericidal compositions and its application of a kind of Fluxapyroxad-containsterilization and Wakil.The bactericidal composition is using fluxapyroxad and Wakil as principle active component, and wherein the mass ratio of fluxapyroxad and Wakil is 1~70:1~50.The bactericidal composition can be applied to prevention Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduces application cost, and control effect is substantially better than the use of its single dose.The present invention can be used for preventing the fungal disease on crops, it is particularly possible to which, for preventing the fungal diseases such as banded sclerotial blight, gray mold, cucumber downy mildew, the late blight of potato, significant effect is used better than single dose.
Description
Technical field
It is main using fluxapyroxad and Wakil the present invention relates to a kind of bactericidal composition and application thereof, especially one kind
The bactericidal composition of active ingredient and its application.
Background technology
Fluxapyroxad (fluxapyroxad), chemical formula:C18H12F5N3O, chemical name:3- (difluoromethyl) -1- first
Base-N- (3', 4', 5'- trifluoro-biphenyl -2- bases) pyrazole-4-carboxamide.
Fluxapyroxad belongs to benzamide type fungicide, is succinate dehydrogenase inhibitors, is a kind of broad-spectrum germicide,
With excellent treatment, systemic activity, good control effect is respectively provided with to all kinds of crop banded sclerotial blights, gray mold etc..
Wakil (Oxadixyl), molecular formula:C14H18N2O4, chemical name:2- methoxyl groups-N- (2- oxo -1,3- azoles
Alkane -3- ' yls) acetyl amine-n-(2 ', 6 '-dimethyl benzene).Structural formula:
Wakil is a kind of systemic fungicide with protection and therapeutic effect, and the lasting period is long, to Peronosporales pathogen
There is good activity.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity increase, and difficulty increases in prevention;Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the control effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
The content of the invention
The purpose of the present invention is be directed to above-mentioned technical problem to provide a kind of applied widely, at low cost, effect good fluorine-containing
The plant bactericidal composition of azoles bacterium amide and Wakil.
Cause answering on fungal disease in prevention plant epiphyte it is a still further object of the present invention to provide the bactericidal composition
With the especially purposes on prevention banded sclerotial blight, gray mold, cucumber downy mildew, the fungal diseases such as the late blight of potato.
The purpose of the present invention is be achieved through the following technical solutions:
The bactericidal composition of a kind of Fluxapyroxad-containsterilization and Wakil, the bactericidal composition is with fluxapyroxad and Wakil
For principle active component, the wherein mass ratio of fluxapyroxad and Wakil is 1~70:1~50, wherein have in bactericidal composition
Effect composition is present in enhancing effective amount in composition.
The mass ratio of the bactericidal composition, wherein fluxapyroxad and Wakil is preferably 1~50:1~50, into one
Step is preferably 1~20:6~50, it is still more preferably 1~20:20~50.
Fluxapyroxad and the preferred mass of Wakil proportioning or:70:1、50:1、30:1、20:1、10:1、5:
1、2.5:1、1:1、1:2、1:4、1:6、1:10、1:20、1:30、1:50.
In the compositions of the present invention, both fluxapyroxad and Wakil account for the mass percentage of composition for 2~
80%.It is preferred that 5~70%.
The bactericidal composition, wherein using fluxapyroxad and Wakil as principle active component and known auxiliary agent and
Excipient is re-dubbed any one dosage form allowed on pesticide.These known auxiliary agents, excipients have dispersant, diffusant, disappear
Calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene ether, benzyl phenol polyethenoxy may be employed in infusion, wetting agent, disintegrant etc.
Ether, phenethyl phenol polyethenoxy ether, fatty alcohol polyoxyethylene ether and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, nonylphenol polyoxyethylene ether, are spat castor oil polyoxyethylene ether
Warm series, fatty alcohol polyoxyethylene ether, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. combination, excipient include
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water.More than auxiliary agent, excipient and other
Auxiliary material can be applied alone or be used in combination.
The bactericidal composition, dosage form are missible oil, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
Application of the above-mentioned bactericidal composition on prevention fungal diseases of plants drug is prepared.Especially in prevention cereal
Application in terms of class, fruit tree, vegetable crop disease has remarkable result.
Above-mentioned application, the fungal diseases of plants is banded sclerotial blight, gray mold, cucumber downy mildew, the late blight of potato
At least one of.
The characteristics of bactericidal composition of the present invention:
1st, the fluxapyroxad and Wakil used in the present invention, the mechanism of action is different, mutual mixture will not generate it is low touch, can
Synergy reduces dosage, reduces cost.
2nd, the present composition scope of application increase, suitable for prevention Cereal, fruit tree, vegetables refractory fungal disease,
Particularly preventing banded sclerotial blight, gray mold, cucumber downy mildew, late blight of potato etc. has significant effect.Sterilization group of the present invention
Close object has good control effect to fungal diseases such as sac fungus, basidiomycetes, Fungi Imperfectis;And inhibit pest or fungi to single
The drug-fast generation of preparation (fluxapyroxad and Wakil are any).Bactericidal composition of the present invention can generate higher collaboration and increase
Effect acts on, and the dosage of the amount ratio independent reactive compound of the mixture substantially reduces, i.e., the activity of mixture is more than single
The activity of only component.
Beneficial effects of the present invention compared with prior art:(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as banded sclerotial blight, gray mold, cucumber downy mildew, the late blight of potato have apparent synergistic function, overcome and delay
The resistance to the action of a drug expands prevention spectrum, hence it is evident that improve control effect;(2) prevention recruitment, drug cost are reduced;(3) alternative routine
With the pesticide for being also easy to produce resistance;(4) compared with single dose, production and application cost reduces;(5) the drug-fast generation of fungi is inhibited,
Its is with obvious effects higher than the use of its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, and the preparation method of dosage form is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometrics are tested:
Indoors using mycelial growth rate method, EC of the different agents to bacterial strain is measured50Value, using co-toxicity coefficient calculating side
Method calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows:
EC (is generally selected as standard agent using a certain single dose in mixture50Junior), it is calculated:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified:Mixture has synergetic when CTC is more than 120, and CTC exists when being less than 80 for antagonism, CTC
It is summation action between 80-120.
According to active ingredient fluxapyroxad (A):Wakil (B) quality proportioning is:80:1、70:1、50:1、30:1、20:
1、10:1、5:1、2.5:1、1:1、1:2、1:4、1:6、1:10、1:20、1:30、1:50、1:60 are tested, and measure it to Huang
The co-toxicity coefficient of melon Pseudoperonospora cubensis (Pseudoperonospora cubensis (Berk.et Curt.) Rostov.).
Table 1:Fluxapyroxad+Wakil different ratio is to the indoor biometrics result of bacterium of downy mildew of cucumber
Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
25% fluxapyroxad SC | Y=4.020+1.202X | 6.532 | - |
25% Wakil EC | Y=3.672+2.356X | 3.660 | - |
A:B=80:1 | Y=3.932+1.247X | 7.190 | 89.98 |
A:B=70:1 | Y=4.846+0.287X | 3.451 | 187.20 |
A:B=50:1 | Y=3.604+2.365X | 3.892 | 165.29 |
A:B=30:1 | Y=3.903+1.547X | 5.117 | 124.51 |
A:B=20:1 | Y=3.585+2.365X | 3.965 | 158.79 |
A:B=10:1 | Y=4.175+1.634X | 3.197 | 190.69 |
A:B=5:1 | Y=3.739+2.301X | 3.532 | 163.53 |
A:B=2.5:1 | Y=4.232+1.547X | 3.135 | 170.18 |
A:B=1:1 | Y=3.681+2.932X | 2.817 | 166.53 |
A:B=1:2 | Y=3.193+3.596X | 3.181 | 134.82 |
A:B=1:4 | Y=1.896+3.233X | 9.122 | 40.02 |
A:B=1:6 | Y=3.901+2.546X | 2.702 | 144.56 |
A:B=1:10 | Y=4.910+0.217X | 2.601 | 146.59 |
A:B=1:20 | Y=3.281+4.578X | 2.374 | 157.49 |
A:B=1:30 | Y=4.034+2.650X | 2.314 | 160.44 |
A:B=1:50 | Y=4.460+1.556X | 2.225 | 165.93 |
A:B=1:60 | Y=3.401+2.559X | 4.214 | 87.49 |
Field control effectiveness test:
The pesticidal preparations prevention cucumber downy mildew experiment made from above-described embodiment.
1st, test process:This test medicine dosage sets three concentration for the treatment of, comparison medicine respectively according to the difference of each ingredient
Agent is pesticide single dose 25% fluxapyroxad SC and 25% Wakil EC and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times;Investigation drug effect side after investigating and prevent before dispenser
Method is:5 points of grab sample in test process area carry out severity Scaling according to national field trial relevant criterion, calculate preventive effect.
Result of the test is shown in Table 2:
Table 2:Field test effect
By indoor biometrics and field efficacy, the result shows that, fluxapyroxad has with Wakil composition significantly to be cooperateed with
Synergistic effect, the control effect of composition is excellent, and control effect is better than single dose kind, has in agricultural is applied using valency
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1:15% fluxapyroxad Wakil wettable powder (1:2)
By fluxapyroxad 5g, Wakil 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, are made effective
Ingredient percent is 15% fluxapyroxad Wakil wettable powder.
Embodiment 2:15% fluxapyroxad Wakil wettable powder (1:4)
By fluxapyroxad 3g, Wakil 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is made can for 15% fluxapyroxad Wakil
Wet powder.
Embodiment 3:14% fluxapyroxad Wakil wettable powder (1:6)
By fluxapyroxad 2g, Wakil 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is made can for 14% fluxapyroxad Wakil
Wet powder.
Embodiment 4:20% fluxapyroxad Wakil suspending agent (1:1)
10g fluxapyroxads, 10g Wakils, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, in the effect of sand mill
Under effective ingredient percent is made as 20% fluxapyroxad Wakil suspending agent.
Embodiment 5:55% fluxapyroxad Wakil aqueous emulsion (1:10)
Weigh 5g fluxapyroxads, 50g Wakils, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that more than raw material is routinely prepared to aqueous emulsion puts into mixing
Kettle high speed mixes, and effective ingredient percent is made as 55% fluxapyroxad Wakil aqueous emulsion.
Embodiment 6:42% fluxapyroxad Wakil missible oil (1:20)
Weigh 2g fluxapyroxads, 40g Wakils, it is calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent oil is to 100g.More than raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 42% fluxapyroxad Wakil missible oil.
Embodiment 7:70% fluxapyroxad Wakil missible oil (2.5:1)
Weigh 50g fluxapyroxads, 20g Wakils, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.More than raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil
It closes, effective ingredient percent is made as 70% fluxapyroxad Wakil missible oil.
Embodiment 8:18% fluxapyroxad Wakil water dispersion granule (5:1)
15g fluxapyroxads, 3g Wakils are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 28g complement to 100g, and more than raw material is formed with effect ingredient by water dispersible granular agent method
Mass percent is 17% fluxapyroxad Wakil water dispersion granule.
Embodiment 9:11% fluxapyroxad Wakil missible oil (10:1)
Weigh 10g fluxapyroxads, 1g Wakils, it is calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent oil is to 100g.More than raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 11% fluxapyroxad Wakil missible oil.
Embodiment 10:32% fluxapyroxad Wakil microemulsion (20:1)
Weigh 30g fluxapyroxads, 2g Wakils, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.More than raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, effective ingredient percent is made as 32% fluxapyroxad Wakil micro emulsion
Agent.
Embodiment 11:31% fluxapyroxad Wakil missible oil (30:1)
Weigh 30g fluxapyroxads, 1g Wakils, it is calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent oil is to 100g.More than raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 31% fluxapyroxad Wakil missible oil.
Embodiment 12:51% fluxapyroxad Wakil suspending agent (50:1)
50g fluxapyroxads, 1g Wakils, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g, under the action of sand mill with water
Effective ingredient percent is made as 51% fluxapyroxad Wakil suspending agent.
Embodiment 13:32% fluxapyroxad Wakil microemulsion (1:15)
Weigh 2g fluxapyroxads, 30g Wakils, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.More than raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, effective ingredient percent is made as 32% fluxapyroxad Wakil micro emulsion
Agent.
Embodiment 14:6% fluxapyroxad Wakil aqueous emulsion (1:5)
Weigh 1g fluxapyroxads, 5g Wakils, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, solvent naphtha 13g, adds water to 100g.The method that more than raw material is routinely prepared to aqueous emulsion puts into mixing kettle
High speed mixes, and effective ingredient percent is made as 6% fluxapyroxad Wakil aqueous emulsion.
Embodiment 15:62% fluxapyroxad Wakil microemulsion (1:30)
Weigh 2g fluxapyroxads, 60g Wakils, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.More than raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, effective ingredient percent is made as 62% fluxapyroxad Wakil micro emulsion
Agent.
Embodiment 16:51% fluxapyroxad Wakil suspending agent (1:50)
1g fluxapyroxads, 50g Wakils, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g, under the action of sand mill with water
Effective ingredient percent is made as 51% fluxapyroxad Wakil suspending agent.
Embodiment 17:7% fluxapyroxad Wakil water dispersion granule (1:2.5)
Weigh 2g fluxapyroxads, 5g Wakils, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and more than raw material is formed with imitating by water dispersible granular agent method
Ingredient percent is 7% fluxapyroxad Wakil water dispersion granule.
Claims (5)
1. a kind of application of the bactericidal composition of Fluxapyroxad-containsterilization and Wakil on prevention cucumber downy mildew drug is prepared,
The bactericidal composition is characterized in that using fluxapyroxad and Wakil as active ingredient, wherein the matter of fluxapyroxad and Wakil
Amount is than being 70:1~1:2、1:6~1:50.
2. application according to claim 1, it is characterised in that both the fluxapyroxad and Wakil account for composition
Mass percentage be 2-80%.
3. application according to claim 2, it is characterised in that both the fluxapyroxad and Wakil account for composition
Mass percentage be 5-70%.
4. application according to claim 1, it is characterised in that using fluxapyroxad and Wakil as active ingredient and pesticide
Auxiliary agent, excipients are configured to any one dosage form allowed on pesticide.
5. application according to claim 4, it is characterised in that the dosage form is missible oil, suspending agent, aqueous emulsion, wettable
Pulvis or water dispersion granule.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610264933.0A CN105794792B (en) | 2016-04-26 | 2016-04-26 | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610264933.0A CN105794792B (en) | 2016-04-26 | 2016-04-26 | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105794792A CN105794792A (en) | 2016-07-27 |
CN105794792B true CN105794792B (en) | 2018-05-22 |
Family
ID=56457648
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610264933.0A Active CN105794792B (en) | 2016-04-26 | 2016-04-26 | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105794792B (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6235684B1 (en) * | 1997-08-29 | 2001-05-22 | Novartis Crop Protection, Inc. | Fungicidal combinations comprising phenylacrylic acid derivatives |
CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
CN101631465A (en) * | 2007-02-05 | 2010-01-20 | 巴斯夫欧洲公司 | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides |
-
2016
- 2016-04-26 CN CN201610264933.0A patent/CN105794792B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6235684B1 (en) * | 1997-08-29 | 2001-05-22 | Novartis Crop Protection, Inc. | Fungicidal combinations comprising phenylacrylic acid derivatives |
CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
CN101631465A (en) * | 2007-02-05 | 2010-01-20 | 巴斯夫欧洲公司 | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides |
Also Published As
Publication number | Publication date |
---|---|
CN105794792A (en) | 2016-07-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105766952B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet | |
CN105941416B (en) | A kind of bactericidal composition and its application of the bacterium amine of pyrrole containing biphenyl and Tebuconazole | |
CN105794794A (en) | Bactericidal composition containing isopyrazam and tiadinil and application of bactericidal composition | |
CN105994318A (en) | Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite | |
CN106212474A (en) | A kind of Fluxapyroxad-containsterilization and the bactericidal composition of cycloheximide triazole and application thereof | |
CN106889079B (en) | A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine | |
CN105831131B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and probenazole | |
CN105794792B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil | |
CN105941407B (en) | A kind of bactericidal composition and its application of fluorine-containing ether bacterium acid amides and fludioxonil | |
CN105831140B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and thiram | |
CN105941403B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and coumoxystrobin | |
CN107306959A (en) | A kind of bactericidal composition and its application containing isopyrazam and orysastrobin | |
CN105961400B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and olefin conversion | |
CN105766931B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and volution bacterium amine | |
CN106106502B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and simeconazoles | |
CN105994280B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and mepanipyrim | |
CN105831124A (en) | Bactericidal composition containing fluxapyroxad and ethirimol and application thereof | |
CN105746534A (en) | Fungicidal composition containing isopyrazam and isotianil and application thereof | |
CN105766926A (en) | Bactericidal composition containing bixafen and coumoxystrobin and application thereof | |
CN105379753B (en) | A kind of bactericidal composition and its application containing mepanipyrim and different rice blast net | |
CN105941425B (en) | A kind of bactericidal composition and its application of fluorine-containing ether bacterium acid amides and Wakil | |
CN105918335B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and Propamocarb | |
CN105475340B (en) | A kind of bactericidal composition and its application containing Silthiopham and metalaxyl | |
CN105475342B (en) | A kind of bactericidal composition and its application containing Silthiopham and fluazinam | |
CN105360128B (en) | A kind of bactericidal composition and its application containing mepanipyrim and Boscalid |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |