CN105994318A - Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite - Google Patents
Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite Download PDFInfo
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- CN105994318A CN105994318A CN201610365444.4A CN201610365444A CN105994318A CN 105994318 A CN105994318 A CN 105994318A CN 201610365444 A CN201610365444 A CN 201610365444A CN 105994318 A CN105994318 A CN 105994318A
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- captan
- bacterium amide
- ether bacterium
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- bactericidal composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing >N—S—C≡(Hal)3 groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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Abstract
The invention discloses a sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of the sterilizing composite. The sterilizing composite uses C15H8ClF7N2O2 and captan as main effective components, wherein the mass ratio of C15H8ClF7N2O2 to captan is (1 to 70):(1 to 50). The sterilizing composite can be used for controlling cereal, fruit tree and vegetable diseases, has relatively high synergetic effects, overcomes and delays the drug resistance of germs, and is high in sterilizing speed and long in lasting period, so that the application cost is lowered; the control effect is obviously better than that of a single agent. The sterilizing composite can be used for controlling fungal diseases of crops, particularly for controlling fungal diseases including grape downy mildew, phytophthora capsici, potato late blight, rice sheath blight, cotton seedling damping-off, rice blast and the like; the effect of the sterilizing composite is obviously better than that of the single agent.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially one is main with fluorine ether bacterium amide and captan
The bactericidal composition of active component and application thereof.
Background technology
Fluorine ether bacterium amide molecule formula: C15H8ClF7N2O2, chemical name: N-(3-chloro-5-(trichloromethyl) pyridine-2-first
Base)-2,3,5,6-four chloro-4-methoxy benzamide.Structural formula is as follows:
Fluorine ether bacterium amide acts on the respiratory chain of fungal mitochondria, the activity of suppression succinate dehydrogenase, thus blocks electricity
Son transmission, suppress fungus spore germination, germ tube extend, mycelial growth and spore mother cell formed fungus growth and breeding main
In the stage, bactericidal action is directly caused by parent active agent, does not has corresponding metabolic activity, for downy mildew of garpe, Phytophthora capsici,
The multiple fungal diseases such as the late blight of potato, rice sheath blight disease, cotton seedling blight all have higher preventive effect, are that one is novel extensively
Spectrum antibacterial.
Captan (Captan), molecular formula: C9H8Cl3NO2S, chemical name: N-(trichloromethylthio) phthalimide.Knot
Structure formula:
Captan is an important kind of organic bactericide, to wheat, barley and highland barley, Oryza sativa L., Semen Maydis, Cotton Gossypii, vegetable, fruit tree, melon
The crop multiple diseases such as class, Nicotiana tabacum L. all has good prevention effect.Wheat, barley and highland barley head blight prevention effect is only second to carbendazim, to water
The sheath and culm blight of rice, rice blast, wheat-straw are embroidered disease, Alternaria alternate, disease in cotton seedling stage, canker of apple fruit etc. and are also had good preventing
Control effect.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, along with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty strengthens；Separately
On the one hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, low cost, effective fluorine-containing for above-mentioned technical problem
Ether bacterium amide and the plant bactericidal composition of captan.
It is a still further object of the present invention to provide this bactericidal composition and cause answering on fungal disease at preventing and treating plant epiphyte
With, especially preventing and treating downy mildew of garpe, Phytophthora capsici, the late blight of potato, rice sheath blight disease, cotton seedling blight, Oryza sativa L. rice
Purposes on the fungal diseases such as pestilence.
It is an object of the invention to be achieved through the following technical solutions:
A kind of fluorine-containing ether bacterium amide and the bactericidal composition of captan, this bactericidal composition is with fluorine ether bacterium amide and captan
For principle active component, wherein fluorine ether bacterium amide is 1～70:1～50 with the mass ratio of captan, wherein has in bactericidal composition
Effective constituent is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein fluorine ether bacterium amide is preferably 1～50:1～50 with the mass ratio of captan, enters one
Step is preferably 1～30:1～30.
In the compositions of the present invention, account for both fluorine ether bacterium amide and captan the weight/mass percentage composition of compositions be 2～
80%.Preferably 5～70%.Fluorine ether bacterium amide with the preferred mass proportioning of captan can also be: 70:1,50:1,30:1,20:
1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50.
In the compositions of the present invention, account for both fluorine ether bacterium amide and captan the weight/mass percentage composition of compositions be 2～
80%.Preferably 5～70%.
Described bactericidal composition, wherein with fluorine ether bacterium amide and captan for principle active component and known auxiliary agent and
Excipient is re-dubbed on pesticide any one dosage form allowed.Known to these, auxiliary agent, excipient have dispersant, diffusant, disappear
Infusion, wetting agent, disintegrating agent etc., can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, benzylphenol polyoxyethylene
Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products thereof, aliphatic amine polyoxyethylene ether, fatty acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Temperature series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more combinations in lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., excipient includes
Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other
Adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.Especially preventing and treating cereal
Application in terms of class, fruit tree, vegetable crop disease has significant effect.
Above-mentioned application, described fungal diseases of plants is downy mildew of garpe, Phytophthora capsici, the late blight of potato, Oryza sativa L.
At least one in banded sclerotial blight, cotton seedling blight, rice blast.
The feature of bactericidal composition of the present invention:
1, the fluorine ether bacterium amide used by the present invention and captan, the mechanism of action is different, and mutual mixture will not produce low touching, can
Synergistic, reduces dosage, reduces cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating Cereal, fruit tree, the refractory fungal disease of vegetable,
Particularly prevent and treat downy mildew of garpe, Phytophthora capsici, the late blight of potato, rice sheath blight disease, cotton seedling blight, rice blast etc.
All there is significant effect.Ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease are had very well by bactericidal composition of the present invention
Prevention effect；And suppress drug-fast to unitary agent (fluorine ether bacterium amide and captan are arbitrary) of insect or fungus or antibacterial
Produce.Bactericidal composition of the present invention can produce higher synergistic function, and the independent activation of amount ratio of this mixture
The consumption of compound is substantially reduced, and i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as downy mildew of garpe, Phytophthora capsici, the late blight of potato, rice sheath blight disease, cotton seedling blight, rice blast have
Substantially synergistic function, overcomes and has delayed Drug resistance, and expanding prevention is composed, hence it is evident that improve prevention effect；(2) preventing and treating is reduced
Recruitment, drug cost；(3) alternative routine and the pesticide being easily generated resistance；(4) compared with single dose, produce and use cost drops
Low；(5) the suppression drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is routine side
Method, " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A single dose toxicity index of proportion+B single dose in mixture of theoretical toxicity index=A single dose
× B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, and CTC exists
It it is summation action between 80-120.
According to effective ingredient fluorine ether bacterium amide (A): captan (B) quality proportioning is: 80:1,70:1,50:1,30:1,20:
1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50,1:60,1:70 test, and measure it
Co-toxicity coefficient to the late blight of potato (Phytophthora infestans (Mont.) de Bary.).
Table 1: fluorine ether bacterium amide+captan different ratio indoor biometrics result to the late blight of potato
Field control effectiveness test:
The pesticidal preparations prepared with above-described embodiment prevents and treats late blight of potato test.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, compares medicine
Agent is pesticide single dose 50% fluorine ether bacterium amide WP and 50% captan WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating before dispenser and preventing and treating
Method is: randomization 5 point in test treatment region, carries out severity Scaling according to country's field test relevant criterion, calculates preventive effect.
Result of the test is shown in Table 2:
Table 2 field test effect
Being shown by indoor biometrics and field efficacy result, fluorine ether bacterium amide and captan compositions have the most collaborative
Potentiation, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has application valency in agricultural is applied
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates two kinds with specific embodiment below
The preparation that effective ingredient is processed into, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% fluorine ether bacterium amide captan wettable powder (1:2)
By fluorine ether bacterium amide 5g, captan 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, prepares effectively
Ingredient percent is 15% fluorine ether bacterium amide captan wettable powder.
Embodiment 2:15% fluorine ether bacterium amide captan wettable powder (1:4)
By fluorine ether bacterium amide 3g, captan 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is that 15% fluorine ether bacterium amide captan can
WP.
Embodiment 3:14% fluorine ether bacterium amide captan wettable powder (1:6)
By fluorine ether bacterium amide 2g, captan 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is that 14% fluorine ether bacterium amide captan can
WP.
Embodiment 4:20% fluorine ether bacterium amide captan suspending agent (1:1)
Weigh 10g fluorine ether bacterium amide, 10g captan, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof,
Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill
Making effective Ingredient percent is 20% fluorine ether bacterium amide captan suspending agent.
Embodiment 5:55% fluorine ether bacterium amide captan aqueous emulsion (1:10)
Weigh 5g fluorine ether bacterium amide, 50g captan, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into
Mixing kettle high speed mixes, and making effective Ingredient percent is 55% fluorine ether bacterium amide captan aqueous emulsion.
Embodiment 6:42% fluorine ether bacterium amide captan cream (1:20)
Weigh 2g fluorine ether bacterium amide, 40g captan, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient
Mass percent is 42% fluorine ether bacterium amide captan cream.
Embodiment 7:70% fluorine ether bacterium amide captan cream (2.5:1)
Weigh 50g fluorine ether bacterium amide, 20g captan, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing kettle
Middle mixing, making effective Ingredient percent is 70% fluorine ether bacterium amide captan cream.
Embodiment 8:18% fluorine ether bacterium amide captan water dispersion granule (5:1)
Weigh 15g fluorine ether bacterium amide, 3g captan, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, gather
Vinyl alcohol 5g, Borax 2g, kieselguhr complements to 100g, is formed with imitating composition quality by water dispersible granular agent method by above raw material
Percentage ratio is 17% fluorine ether bacterium amide captan water dispersion granule.
Embodiment 9:11% fluorine ether bacterium amide captan cream (10:1)
Weigh 10g fluorine ether bacterium amide, 1g captan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient
Mass percent is 11% fluorine ether bacterium amide captan cream.
Embodiment 10:31.5% fluorine ether bacterium amide captan microemulsion (20:1)
Weigh 30g fluorine ether bacterium amide, 1.5g captan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is prepared routinely
The method of microemulsion puts in mixing kettle and mixes, and making effective Ingredient percent is 31.5% fluorine ether bacterium amide captan
Microemulsion.
Embodiment 11:31% fluorine ether bacterium amide captan cream (30:1)
Weigh 30g fluorine ether bacterium amide, 1g captan, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g,
150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient
Mass percent is 31% fluorine ether bacterium amide captan cream.
Embodiment 12:51% fluorine ether bacterium amide captan suspending agent (50:1)
Weigh 50g fluorine ether bacterium amide, 1g captan, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, Huang
Virgin rubber 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, makes under the effect of sand mill
Becoming effective ingredient mass percent is 51% fluorine ether bacterium amide captan suspending agent.
Embodiment 13:32% fluorine ether bacterium amide captan microemulsion (1:15)
Weigh 2g fluorine ether bacterium amide, 30g captan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is prepared micro-routinely
The method of Emulsion puts in mixing kettle and mixes, and making effective Ingredient percent is 32% fluorine ether bacterium amide captan microemulsion
Agent.
Embodiment 14:6% fluorine ether bacterium amide captan aqueous emulsion (1:5)
Weigh 1g fluorine ether bacterium amide, 5g captan, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into mixed
Closing the mixing of still high speed, making effective Ingredient percent is 6% fluorine ether bacterium amide captan aqueous emulsion.Embodiment 15:
62% fluorine ether bacterium amide captan microemulsion (1:30)
Weigh 2g fluorine ether bacterium amide, 60g captan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is prepared micro-routinely
The method of Emulsion puts in mixing kettle and mixes, and making effective Ingredient percent is 62% fluorine ether bacterium amide captan microemulsion
Agent.
Embodiment 16:51% fluorine ether bacterium amide captan suspending agent (1:50)
Weigh 1g fluorine ether bacterium amide, 50g captan, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, Huang
Virgin rubber 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, makes under the effect of sand mill
Becoming effective ingredient mass percent is 51% fluorine ether bacterium amide captan suspending agent.
Embodiment 17:7% fluorine ether bacterium amide captan water dispersion granule (1:2.5)
Weigh 2g fluorine ether bacterium amide, 5g captan, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, poly-second
Enol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, by water dispersible granular agent method, above raw material are formed with effect
Ingredient percent is 7% fluorine ether bacterium amide captan water dispersion granule.
Claims (9)
1. a fluorine-containing ether bacterium amide and the bactericidal composition of captan, it is characterised in that this bactericidal composition is with fluorine ether bacterium amide
Being principle active component with captan, wherein fluorine ether bacterium amide is 1～70:1～50 with the mass ratio of captan.
Bactericidal composition the most according to claim 1, it is characterised in that described fluorine ether bacterium amide and the mass ratio of captan
It is 1～50:1～50.
Bactericidal composition the most according to claim 2, it is characterised in that described fluorine ether bacterium amide and the mass ratio of captan
It is 1～30:1～30.
Bactericidal composition the most according to claim 1, it is characterised in that both described fluorine ether bacterium amide and captan account for
The weight/mass percentage composition of compositions is 2-80%.
Bactericidal composition the most according to claim 4, it is characterised in that both described fluorine ether bacterium amide and captan account for
The weight/mass percentage composition of compositions is 5-70%.
Bactericidal composition the most according to claim 1, it is characterised in that with fluorine ether bacterium amide and captan for main effectively
Composition and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.
Bactericidal composition the most according to claim 6, it is characterised in that described dosage form be cream, suspending agent, aqueous emulsion,
Wettable powder or water dispersion granule.
8. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
Application the most according to claim 8, it is characterised in that described fungal diseases of plants is downy mildew of garpe, Fructus Capsici epidemic disease
At least one in mould, the late blight of potato, rice sheath blight disease, cotton seedling blight, rice blast.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610365444.4A CN105994318A (en) | 2016-05-26 | 2016-05-26 | Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610365444.4A CN105994318A (en) | 2016-05-26 | 2016-05-26 | Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109566637A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN110651794A (en) * | 2019-10-18 | 2020-01-07 | 安徽江淮园艺种业股份有限公司 | Bactericide composition containing fluorobenzene ether amide and captan |
| WO2024184886A1 (en) * | 2023-03-09 | 2024-09-12 | Adama Makhteshim Ltd. | Suspension concentrates of phthalimide fungicides |
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| CN102845426A (en) * | 2012-09-19 | 2013-01-02 | 山东省联合农药工业有限公司 | Bactericide combination containing fluorine ether bacteria amide and chlorothalonil |
| CN103416428A (en) * | 2012-05-26 | 2013-12-04 | 陕西韦尔奇作物保护有限公司 | Fluxapyroxad-containing sterilization composition |
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- 2016-05-26 CN CN201610365444.4A patent/CN105994318A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103416428A (en) * | 2012-05-26 | 2013-12-04 | 陕西韦尔奇作物保护有限公司 | Fluxapyroxad-containing sterilization composition |
| CN102845426A (en) * | 2012-09-19 | 2013-01-02 | 山东省联合农药工业有限公司 | Bactericide combination containing fluorine ether bacteria amide and chlorothalonil |
| CN103355304A (en) * | 2012-09-19 | 2013-10-23 | 刘杰 | Bactericide composition containing fluoride ether bacteria amide and chlorothalonil |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109566637A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN110651794A (en) * | 2019-10-18 | 2020-01-07 | 安徽江淮园艺种业股份有限公司 | Bactericide composition containing fluorobenzene ether amide and captan |
| WO2024184886A1 (en) * | 2023-03-09 | 2024-09-12 | Adama Makhteshim Ltd. | Suspension concentrates of phthalimide fungicides |
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Application publication date: 20161012 |