CN106889079B - A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine - Google Patents
A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine Download PDFInfo
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- CN106889079B CN106889079B CN201710130141.9A CN201710130141A CN106889079B CN 106889079 B CN106889079 B CN 106889079B CN 201710130141 A CN201710130141 A CN 201710130141A CN 106889079 B CN106889079 B CN 106889079B
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- fluoxastrobin
- alkene oxime
- oxime amine
- bactericidal composition
- mildew
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
Abstract
The invention discloses a kind of bactericidal composition containing fluoxastrobin and alkene oxime amine and its applications.The bactericidal composition is using fluoxastrobin and alkene oxime amine as principle active component, and wherein the mass ratio of fluoxastrobin and alkene oxime amine is 70:1~1:50.The bactericidal composition can be applied to prevention Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the drug resistance of germ, and sterilization speed is fast, the lasting period is long, reduces application cost, and control effect is substantially better than the use of its single dose.The present invention can be used for preventing the fungal disease on crops, the fungal diseases such as prevention powdery mildew, wheat glume blotch, wheat rust, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, apple mildew, early blight of tomato, pear scab are particularly useful for, effect is better than single dose use.
Description
Technical field：
It is main with fluoxastrobin and alkene oxime amine the present invention relates to a kind of bactericidal composition and application thereof, especially one kind
The bactericidal composition of active constituent and its application.
Background technology
Fluoxastrobin (Fluoxastrobin) is mitochondrial respiratory inhibitor, and the mechanism of action is by cytochrome b
Electronics transfer inhibits the breathing of mitochondria, fluoxastrobin to have quick-acting and lasting period long double grading, have to crop between C1
Good compatibility, processing dosage form appropriate can further improve its osmosis by cuticula into people's leaf portion.Although it
Absorbability by seed and root is poor, when being used as seed treatment, though have to seedling and kind biography and soil-borne disease
Killing and lasting effect well, to nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease
Such as tens of kinds of diseases of rust, glume blight, net blotch, powdery mildew, downy mildew have good activity.
Alkene oxime amine wide sterilization spectrum, activity are high, have prevention and therapeutic effect, have good compatibility with environmental organism,
There is good control effect to the plurality of plant diseases caused by mastigomycetes, zygomycete, sac fungus, basidiomycetes and Fungi Imperfecti, it is right
Powdery mildew, rust control effect are remarkable.It can be used for preventing wheat rust, wheat powdery mildew, rice sheath blight disease, false smut, cucumber
Powdery mildew, cucumber downy mildew, downy mildew of garpe, alternaria leaf spot of apple, apple mildew, sigatoka, early blight of tomato,
The plurality of plant diseases such as pear scab, powdery mildew of strawberry, rust of sunflower.Meanwhile having obviously to plant growth character and quality
Improvement result, and yield can be improved.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area gradually expands, and disease occurrence degree, generation quantity increase, and is increased in the upper difficulty of prevention；Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the control effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
Invention content：
The purpose of the present invention is provide a kind of applied widely, at low cost, effect good fluorine-containing in view of the above technical problems
The plant bactericidal composition of Fluoxastrobin and alkene oxime amine.
It is a still further object of the present invention to provide the bactericidal compositions to cause answering on fungal disease in prevention plant epiphyte
With especially in prevention wheat glume blotch, wheat rust, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew
Purposes on the fungal diseases such as disease, downy mildew of garpe, apple mildew, early blight of tomato, pear scab.
The purpose of the present invention is be achieved through the following technical solutions：
A kind of bactericidal composition containing fluoxastrobin and alkene oxime amine, the bactericidal composition is with fluoxastrobin and alkene oxime amine
For principle active component, the wherein mass ratio of fluoxastrobin and alkene oxime amine is 70:1~1:50, wherein have in bactericidal composition
Effect composition is present in enhancing effective amount in composition.
The mass ratio of the bactericidal composition, wherein fluoxastrobin and alkene oxime amine is preferably 50:1~1:6, further
Preferably 50:1~40:1、20:1~5:1、1:4~1:6.
In the compositions of the present invention, both fluoxastrobin and alkene oxime amine account for composition mass percentage be 2%~
80%.Preferably 5%-70%, further preferably 10~40%.
The bactericidal composition, wherein using fluoxastrobin and alkene oxime amine as principle active component and known auxiliary agent and
Excipient is re-dubbed any one dosage form allowed on pesticide.These known auxiliary agents, excipients have dispersant, diffusant, disappear
Calcium dodecyl benzene sulfonate, alkyl phenol polyoxyethylene ether, benzyl phenol polyethenoxy may be used in infusion, wetting agent, disintegrant etc.
Ether, phenethyl phenol polyethenoxy ether, fatty alcohol polyoxyethylene ether and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, castor oil polyoxyethylene ether, nonylphenol polyoxyethylene ether, is spat at polyoxyethylene polyoxy propylene block compound
Warm series, fatty alcohol polyoxyethylene ether, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. combine, and excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water.The above auxiliary agent, excipient and other
Auxiliary material can be applied alone or be used in combination.
The bactericidal composition, dosage form are missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or water-dispersed
Granule.
Application of the above-mentioned bactericidal composition on preparing prevention fungal diseases of plants drug.Especially in prevention cereal
Application in terms of class, fruit tree, vegetable crop disease.
Above-mentioned application, the fungal diseases of plants are wheat glume blotch, wheat rust, wheat powdery mildew, rice line
In blight, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, apple mildew, early blight of tomato, pear scab at least
It is a kind of.
Beneficial effects of the present invention：
1, the fluoxastrobin used in the present invention is pyridine series bactericidal agent, and alkene oxime amine is triazole bactericidal agent, the mechanism of action
Difference, mutual mixture not will produce it is low touch, can be synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, suitable for preventing the refractory fungal disease of Cereal, fruit tree, vegetables,
Especially prevent wheat glume blotch, wheat rust, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew, Portugal
Grape downy mildew, apple mildew, early blight of tomato, pear scab etc. have significant effect.Bactericidal composition antithetical phrase of the present invention
Capsule bacterium, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease have good control effect；And inhibit pest or fungi to unitary system
The generation of the drug resistance of agent (fluoxastrobin and alkene oxime amine are any).Bactericidal composition of the present invention can generate higher synergy
Effect, and the dosage of the amount ratio independent reactive compound of the mixture substantially reduces, i.e., and the activity of mixture is more than independent
The activity of component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, the composition antagonism fungal disease is such as
Wheat glume blotch, wheat rust, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, apple
The fungal diseases such as fruit powdery mildew, early blight of tomato, pear scab have apparent synergistic function, overcome and delayed drug resistance,
Expand prevention spectrum, hence it is evident that improve control effect；(2) prevention recruitment, drug cost are reduced；(3) it alternative routine and is also easy to produce
The pesticide of resistance；(4) compared with single dose, production and application cost reduces；(5) inhibit the generation of fungi drug resistance, effect bright
It is aobvious to be used higher than its single dose.
Specific implementation mode
The invention will be further described with reference to embodiments, and the preparation method of dosage form is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometrics experiment：
Mycelial growth rate method is used indoors, measures EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows：
Using a certain single dose in mixture (EC is generally selected as standard agent50Junior), it is calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
The EC of survey toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=survey toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：It is antagonism when being less than 80 that mixture, which has synergetic, CTC, when CTC is more than 120, and CTC exists
It is summation action between 80-120.
According to active ingredient fluoxastrobin (A)：Alkene oxime amine (B) quality proportioning is：70：1、50：1、30：1、20：1、10：
1、5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50 are tested, and measure it to Rhizoctonia solani Kuhn
The co-toxicity coefficient of (Thanatephorus cucumeris (Frank) Donk).
Table 1：Indoor biometrics result of the fluoxastrobin+alkene oxime amine different ratio to Rhizoctonia solani Kuhn
Field control effectiveness test：
The pesticidal preparations prevention rice sheath blight disease experiment made from above-described embodiment.
1, test process：This test medicine dosage sets three concentration for the treatment of, comparison medicine respectively according to the difference of each ingredient
Agent is pesticide single dose 5% alkene oxime amine EC and 10% fluoxastrobin EC and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent before dispenser
Method is：5 points of grab sample in test process area carry out severity Scaling according to national field trial relevant criterion, calculate preventive effect.
Test result is shown in Table 2：
2 field test effect of table
By indoor biometrics and field efficacy, the result shows that, fluoxastrobin has with alkene oxime amine composition significantly to be cooperateed with
The control effect of synergistic effect, composition is excellent, and control effect is better than single dose kind, has the valence of applying in agricultural is applied
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% fluoxastrobin alkene oxime amine wettable powder (1:2)
By fluoxastrobin 5g, alkene oxime amine 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, are made effective
Ingredient percent is 15% fluoxastrobin alkene oxime amine wettable powder.
Embodiment 2：15% fluoxastrobin alkene oxime amine wettable powder (1:4)
By fluoxastrobin 3g, alkene oxime amine 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and it is that 15% fluoxastrobin alkene oxime amine can that active ingredient mass percent, which is made,
Wet powder.
Embodiment 3：14% fluoxastrobin alkene oxime amine wettable powder (1:6)
By fluoxastrobin 2g, alkene oxime amine 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and it is that 14% fluoxastrobin alkene oxime amine can that active ingredient mass percent, which is made,
Wet powder.
Embodiment 4：20% fluoxastrobin alkene oxime amine suspending agent (1:1)
10g fluoxastrobins, 10g alkene oxime amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, in the effect of sand mill
Under be made effective ingredient percent be 20% fluoxastrobin alkene oxime amine suspending agent.
Embodiment 5：55% fluoxastrobin alkene oxime amine aqueous emulsion (1:10)
Weigh 5g fluoxastrobins, 50g alkene oxime amines, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that the above raw material routinely prepares aqueous emulsion is put into mixing
Kettle high speed mixes, and it is 55% fluoxastrobin alkene oxime amine aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 6：42% fluoxastrobin alkene oxime amine missible oil (1:20)
Weigh 2g fluoxastrobins, 40g alkene oxime amines, it is calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 42% fluoxastrobin alkene oxime amine missible oil.
Embodiment 7：70% fluoxastrobin alkene oxime amine missible oil (2.5:1)
Weigh 50g fluoxastrobins, 20g alkene oxime amines, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil
It closes, it is 70% fluoxastrobin alkene oxime amine missible oil that effective ingredient percent, which is made,.
Embodiment 8：18% fluoxastrobin alkene oxime amine water dispersion granule (5：1)
15g fluoxastrobins, 3g alkene oxime amines are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 28g complement to 100g, and the above raw material is formed with effect ingredient by water dispersible granular agent method
Mass percent is 18% fluoxastrobin alkene oxime amine water dispersion granule.
Embodiment 9：11% fluoxastrobin alkene oxime amine missible oil (10:1)
Weigh 10g fluoxastrobins, 1g alkene oxime amines, it is calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 11% fluoxastrobin alkene oxime amine missible oil.
Embodiment 10：31.5% fluoxastrobin alkene oxime amine microemulsion (20:1)
Weigh 30g fluoxastrobins, 1.5g alkene oxime amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared
It is mixed in the method input mixing kettle of microemulsion, it is 31.5% fluoxastrobin alkene oxime amine that effective ingredient percent, which is made,
Microemulsion.
Embodiment 11：31% fluoxastrobin alkene oxime amine missible oil (30:1)
Weigh 30g fluoxastrobins, 1g alkene oxime amines, it is calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 31% fluoxastrobin alkene oxime amine missible oil.
Embodiment 12：51% fluoxastrobin alkene oxime amine suspending agent (50:1)
50g fluoxastrobins, 1g alkene oxime amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, under the action of sand mill
It is 51% fluoxastrobin alkene oxime amine suspending agent that effective ingredient percent, which is made,.
Embodiment 13：32% fluoxastrobin alkene oxime amine microemulsion (1:15)
Weigh 2g fluoxastrobins, 30g alkene oxime amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, it is 32% fluoxastrobin alkene oxime amine micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 14：6% fluoxastrobin alkene oxime amine aqueous emulsion (1:5)
Weigh 1g fluoxastrobins, 5g alkene oxime amines, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, solvent naphtha 13g, adds water to 100g.The method that the above raw material routinely prepares aqueous emulsion is put into mixing kettle
High speed mixes, and it is 6% fluoxastrobin alkene oxime amine aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 15：62% fluoxastrobin alkene oxime amine microemulsion (1:30)
Weigh 2g fluoxastrobins, 60g alkene oxime amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, it is 62% fluoxastrobin alkene oxime amine micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 16：51% fluoxastrobin alkene oxime amine suspending agent (1:50)
1g fluoxastrobins, 50g alkene oxime amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, under the action of sand mill
It is 51% fluoxastrobin alkene oxime amine suspending agent that effective ingredient percent, which is made,.
Embodiment 17：7% fluoxastrobin alkene oxime amine water dispersion granule (1：2.5)
Weigh 2g fluoxastrobins, 5g alkene oxime amines, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and the above raw material is formed with imitating by water dispersible granular agent method
Ingredient percent is 7% fluoxastrobin alkene oxime amine water dispersion granule.
Claims (9)
1. a kind of bactericidal composition containing fluoxastrobin and alkene oxime amine, it is characterised in that the bactericidal composition with fluoxastrobin and
Alkene oxime amine is that the mass ratio of principle active component, wherein fluoxastrobin and alkene oxime amine is 70:1~1:50.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the fluoxastrobin and alkene oxime amine
It is 50:1~1:6.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the fluoxastrobin and alkene oxime amine
It is 50:1~40:1、20:1~5:1、1:4~1:6.
4. bactericidal composition according to claim 1, it is characterised in that both described fluoxastrobin and alkene oxime amine account for
The mass percentage of composition is 2% ~ 80%.
5. bactericidal composition according to claim 4, it is characterised in that both described fluoxastrobin and alkene oxime amine account for
The mass percentage of composition is 5%-70%.
6. bactericidal composition according to claim 1, it is characterised in that with fluoxastrobin and alkene oxime amine be it is main effectively
Ingredient and insecticides adjuvant, excipients are configured to any one dosage form allowed on pesticide.
7. bactericidal composition according to claim 6, it is characterised in that the dosage form be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition described in claim 1 on preparing prevention fungal diseases of plants drug.
9. application according to claim 8, it is characterised in that the fungal diseases of plants is wheat glume blotch, wheat rust
Disease, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, apple mildew, tomato early epidemic
At least one of disease, pear scab.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0432894A1 (en) * | 1989-12-07 | 1991-06-19 | Ube Industries, Ltd. | Fungicidal composition |
| WO2006040123A2 (en) * | 2004-10-12 | 2006-04-20 | Bayer Cropscience Ag | Fungicidal active ingredient combinations containing fluoxastrobin |
| CN104642341A (en) * | 2013-11-19 | 2015-05-27 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing zinc thiazole |
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2017
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0432894A1 (en) * | 1989-12-07 | 1991-06-19 | Ube Industries, Ltd. | Fungicidal composition |
| WO2006040123A2 (en) * | 2004-10-12 | 2006-04-20 | Bayer Cropscience Ag | Fungicidal active ingredient combinations containing fluoxastrobin |
| CN104642341A (en) * | 2013-11-19 | 2015-05-27 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing zinc thiazole |
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