CN107027778A - A kind of bactericidal composition and its application containing fluoxastrobin and Tebuconazole - Google Patents
A kind of bactericidal composition and its application containing fluoxastrobin and Tebuconazole Download PDFInfo
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- CN107027778A CN107027778A CN201710130138.7A CN201710130138A CN107027778A CN 107027778 A CN107027778 A CN 107027778A CN 201710130138 A CN201710130138 A CN 201710130138A CN 107027778 A CN107027778 A CN 107027778A
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- fluoxastrobin
- tebuconazole
- bactericidal composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing fluoxastrobin and Tebuconazole and its application.The bactericidal composition is using fluoxastrobin and Tebuconazole as principle active component, and wherein the mass ratio of fluoxastrobin and Tebuconazole is 70:1~1:50.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and used.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as head blight, rust, powdery mildew, net blotch, root rot, smut, downy mildew and rice sheath blight disease, effect is better than single dose and used.
Description
Technical field：
It is especially a kind of using fluoxastrobin and Tebuconazole to be main living the present invention relates to a kind of bactericidal composition and application thereof
The bactericidal composition of property composition and its application.
Background technology
Fluoxastrobin (Fluoxastrobin) is mitochondrial respiratory inhibitor, and its mechanism of action is by cytochrome b
Electro transfer suppresses mitochondrial breathing between C1, and fluoxastrobin has quick-acting and lasting period long double grading, had to crop
Good compatibility, appropriate processing formulation can further improve its osmosis for entering people's leaf portion by cuticula.Although it
Absorbability by seed and root is poor, when being used as seed treatment, though have to seedling and kind biography and soil-borne disease
Kill well and lasting effect, to nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease
Such as tens of kinds of diseases of rust, glume blight, net blotch, powdery mildew, downy mildew have good activity.
Tebuconazole (Tebuconazole), molecular formula：C16H22ClN3O.Chemical name：：(RS) -1- (4- chlorphenyls) -4,
4- dimethyl -3- (1H-1,2,4 triazol-1-yls methyl) amyl- 3- alcohol.Structural formula：
Tebuconazole belongs to triazole bactericidal agent, is sterol demethylation inhibitor, is the seed treatment for Important Economic crop
Or the efficient germicide of foliage spray, can effectively prevent and treat a variety of rust of cereal crop, powdery mildew, net blotch, root rot,
Head blight, smut and kind pass zonate spot etc..
But head blight, rust, powdery mildew, net blotch, root rot, smut, downy mildew and rice sheath blight disease etc. are fallen ill
It is more serious, cause catastrophic loss to agricultural production, although fluoxastrobin, Tebuconazole single dose have to Some Disease more manages
The prevention effect thought, but in actual applications, it has been found that the difficulty of prevention and cure of phytopathogen is increasing, and main cause has：One is
With the change of pattern of farming, the industrial crops cultivated area such as melon fruits and vegetables progressively expands, disease occurrence degree, generation quantity
Increase, difficulty is increased in preventing and treating；Two be that current climate is abnormal, and the outburst to disease provides certain condition；Three
It is the selectivity influence of long-term chemical medication so that the resistance of pathogen rises year by year under lasting medicament selection pressure,
The prevention effect of single dose is had a greatly reduced quality.In summary, current control of plant disease work faces big challenge emphatically.
The content of the invention：
The purpose of the present invention be provide that a kind of applied widely, cost is low for above-mentioned technical problem, that effect is good is fluorine-containing
The plant bactericidal composition of Fluoxastrobin and Tebuconazole.
It is a still further object of the present invention to provide the bactericidal composition preventing and treating fungal diseases of plants on application, especially
On the fungal diseases such as head blight, rust, powdery mildew, net blotch, root rot, smut, downy mildew and rice sheath blight disease are prevented and treated
Purposes.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing fluoxastrobin and Tebuconazole, the bactericidal composition is based on fluoxastrobin and Tebuconazole
Active ingredient is wanted, the wherein mass ratio of fluoxastrobin and Tebuconazole is 70:1~1:50.Wherein effective ingredient in bactericidal composition
It is present in enhancing effective amount in composition.
The mass ratio of described bactericidal composition, wherein fluoxastrobin and Tebuconazole is preferably 50:1~1:2, it is further excellent
Elect 10 as:1~1:2.
In the compositions of the present invention, the weight/mass percentage composition for composition being accounted for both described fluoxastrobin and Tebuconazole is
2%~80%.It is preferred that 5%~70, more preferably 10%~40%.
Described bactericidal composition, wherein using fluoxastrobin and Tebuconazole as principle active component and known auxiliary agent and tax
Shape agent is re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, froth breaking
Agent, wetting agent, disintegrant etc., can use calcium dodecyl benzene sulfonate, APES, benzyl phenol polyethenoxy
Ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Warm series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. are combined, and excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other
Auxiliary material can be with alone or be used in combination.
Described bactericidal composition, its formulation is that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the above-mentioned bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared.Especially in preventing and treating cereal
Application in terms of class, fruit tree, vegetable crop disease.
Described fungal diseases of plants be head blight, rust, powdery mildew, net blotch, root rot, smut, downy mildew and
Rice sheath blight disease.
Beneficial effects of the present invention：
1st, the fluoxastrobin used in the present invention is methoxy acrylic bactericide, and Tebuconazole is azoles fungicide, is made
It is different with mechanism, mutual mixture will not produce it is low touch, can Synergistic, reduce dosage, reduce cost.
2nd, present composition scope of application increase, it is adaptable to prevent and treat Cereal, fruit tree, the fungal disease of vegetables, it is special
It is not answering on head blight, rust, powdery mildew, net blotch, root rot, smut, downy mildew and rice sheath blight disease etc. is prevented and treated
With there is significant effect.Bactericidal composition of the present invention has very to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease
Good prevention effect；And suppress the drug-fast generation of insect or fungi to unitary agent (fluoxastrobin and Tebuconazole are any).
Bactericidal composition of the present invention can produce higher synergistic function, and the amount ratio independent reactive compound of the mixture
Consumption is substantially reduced, i.e., the activity of mixture is more than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as head blight, rust, powdery mildew, net blotch, root rot, smut, downy mildew and rice sheath blight disease have obvious association
Same synergistic effect, overcomes and has delayed the resistance to the action of a drug, expands preventing and treating spectrum, hence it is evident that improve prevention effect；(2) reduce preventing and treating recruitment,
Drug cost；(3) alternative routine and the agricultural chemicals for being also easy to produce resistance；(4) compared with single dose, production and use cost reduction；(5)
Suppress the drug-fast generation of fungi, its effect is used apparently higher than its single dose.
Embodiment：
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, is determined different agents to the EC50 values of bacterial strain, is calculated using co-toxicity coefficient
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows：
A certain single dose is calculated as standard agent (generally selecting EC50 juniors) using in mixture：
Single dose toxicity index=standard agent EC50/ single doses EC50 × 100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey EC50 value × 100 of EC50 values/mixture of toxicity index=standard single dose
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, and CTC exists when being less than 80 for antagonism, CTC
It is summation action between 80-120.
According to active ingredient fluoxastrobin (A)：Tebuconazole (B) quality proportioning is：70：1、50：1、30：1、20：1、10：1、
5：1、2.5：1、1：1、1：2、1：4、1：7、1：10、1：20、1：30、1：50 are tested, and determine it and rice sheath blight disease is total to
Malicious coefficient.
Table 1：Indoor biometricses result of the fluoxastrobin+Tebuconazole different ratio to rice sheath blight disease
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| Fluoxastrobin | Y=1.6350X+2.9813 | 17.1652 | - |
| Tebuconazole | Y=2.0213X+2.5982 | 15.4263 | - |
| A:B=70:1 | Y=2.5362X+2.1594 | 13.1831 | 130.00 |
| A:B=50:1 | Y=1.1543X+3.7996 | 10.9622 | 156.24 |
| A:B=30:1 | Y=2.2259X+2.7799 | 9.9407 | 172.05 |
| A:B=20:1 | Y=1.6425X+3.2942 | 10.9272 | 158.95 |
| A:B=10:1 | Y=2.3659X+2.7185 | 9.2118 | 184.45 |
| A:B=5:1 | Y=1.4785X+3.5272 | 9.9110 | 170.00 |
| A:B=2.5:1 | Y=2.6389X+2.3562 | 10.0426 | 165.59 |
| A:B=1:1 | Y=1.2015X+3.8731 | 8.6686 | 187.45 |
| A:B=1:2 | Y=1.3621X+3.8001 | 7.6019 | 210.02 |
| A:B=1:4 | Y=2.0030X+2.8714 | 11.5536 | 136.28 |
| A:B=1:7 | Y=2.1246X+2.8826 | 9.9226 | 157.46 |
| A:B=1:10 | Y=1.1111X+3.8170 | 11.6062 | 134.15 |
| A:B=1:20 | Y=2.5487X+2.3796 | 10.6691 | 145.29 |
| A:B=1:30 | Y=2.3200X+2.5061 | 11.8843 | 130.23 |
| A:B=1:50 | Y=2.9235X+1.7700 | 12.7302 | 121.42 |
Field control effectiveness test：
Rice sheath blight disease experiment is prevented and treated with pesticidal preparations made from following examples.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is the Tebuconazole WP of agricultural chemicals single dose 25% and 10% fluoxastrobin EC and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates preventive effect.
Result of the test is shown in Table 2：
The field control effectiveness test result of table 2
Shown by indoor biometricses and field efficacy result, fluoxastrobin has with Tebuconazole composition significantly cooperates with increasing
Effect is acted on, and the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application value in agricultural application.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% fluoxastrobin Tebuconazole wettable powder (1:2)
By fluoxastrobin 5g, Tebuconazole 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusant
NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures carry out air-flow crushing, be made effectively into
It is 15% fluoxastrobin Tebuconazole wettable powder to divide mass percent.
Embodiment 2：15% fluoxastrobin Tebuconazole wettable powder (1:4)
By fluoxastrobin 3g, Tebuconazole 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
Add to 100g mixtures and carry out air-flow crushing, it is 15% fluoxastrobin Tebuconazole wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 3：16% fluoxastrobin Tebuconazole wettable powder (1:7)
By fluoxastrobin 2g, Tebuconazole 14g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
Add to 100g mixtures and carry out air-flow crushing, it is 16% fluoxastrobin Tebuconazole wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 4：20% fluoxastrobin tebuconazole suspension concentrates (1:1)
10g fluoxastrobins, 10g Tebuconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 20% fluoxastrobin tebuconazole suspension concentrates.
Embodiment 5：55% fluoxastrobin tebuconazole aqueous emulsion (1:10)
Weigh 5g fluoxastrobins, 50g Tebuconazoles, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
APEO 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared into aqueous emulsion puts into mixing kettle
High speed is mixed, and effective Ingredient percent is made for 55% fluoxastrobin tebuconazole aqueous emulsion.
Embodiment 6：42% fluoxastrobin Tebuconazole missible oil (1:20)
Weigh 2g fluoxastrobins, 40g Tebuconazoles, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent
Oil is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality percentage is made
Than for 42% fluoxastrobin Tebuconazole missible oil.
Embodiment 7：70% fluoxastrobin Tebuconazole missible oil (2.5:1)
Weigh 50g fluoxastrobins, 20g Tebuconazoles, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Sesame oil APEO 2g, solvent naphtha to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil,
Effective Ingredient percent is made for 70% fluoxastrobin Tebuconazole missible oil.
Embodiment 8：18% fluoxastrobin Tebuconazole water dispersion granule (5：1)
Weigh 15g fluoxastrobins, 3g Tebuconazoles, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, diatomite 28g complements to 100g, and above raw material is formed with imitating into sub-prime by water dispersible granular agent method
Amount percentage is 18% fluoxastrobin Tebuconazole water dispersion granule.
Embodiment 9：11% fluoxastrobin Tebuconazole missible oil (10:1)
Weigh 10g fluoxastrobins, 1g Tebuconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent
Oil is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality percentage is made
Than for 11% fluoxastrobin Tebuconazole missible oil.
Embodiment 10：31.5% fluoxastrobin tebuconazole microemulsion (20:1)
Weigh 30g fluoxastrobins, 1.5g Tebuconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared micro-
Mixed in the method input mixing kettle of emulsion, effective Ingredient percent is made for 31.5% fluoxastrobin Tebuconazole micro emulsion
Agent.
Embodiment 11：31% fluoxastrobin Tebuconazole missible oil (30:1)
Weigh 30g fluoxastrobins, 1g Tebuconazoles, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent
Oil is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality percentage is made
Than for 31% fluoxastrobin Tebuconazole missible oil.
Embodiment 12：51% fluoxastrobin tebuconazole suspension concentrates (50:1)
Weigh 50g fluoxastrobins, 1g Tebuconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, 100g is complemented to water, is made in the presence of sand mill
It is 51% fluoxastrobin tebuconazole suspension concentrates into active ingredient mass percent.
Embodiment 13：32% fluoxastrobin tebuconazole microemulsion (1:15)
Weigh 2g fluoxastrobins, 30g Tebuconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared into micro emulsion
Mixed in the method input mixing kettle of agent, effective Ingredient percent is made for 32% fluoxastrobin tebuconazole microemulsion.
Embodiment 14：6% fluoxastrobin tebuconazole aqueous emulsion (1:5)
1g fluoxastrobins, 5g Tebuconazoles, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol is weighed to gather
Oxygen vinethene 1g, solvent naphtha 13g, add water to 100g.In the method input mixing kettle that above raw material is routinely prepared to aqueous emulsion
Mixed at high speed, is made effective Ingredient percent for 6% fluoxastrobin tebuconazole aqueous emulsion.
Embodiment 15：62% fluoxastrobin tebuconazole microemulsion (1:30)
Weigh 2g fluoxastrobins, 60g Tebuconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared into micro emulsion
Mixed in the method input mixing kettle of agent, effective Ingredient percent is made for 62% fluoxastrobin tebuconazole microemulsion.
Embodiment 16：51% fluoxastrobin tebuconazole suspension concentrates (1:50)
Weigh 1g fluoxastrobins, 50g Tebuconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, 100g is complemented to water, is made in the presence of sand mill
It is 51% fluoxastrobin tebuconazole suspension concentrates into active ingredient mass percent.
Embodiment 17：7% fluoxastrobin Tebuconazole water dispersion granule (1：2.5)
Weigh 2g fluoxastrobins, 5g Tebuconazoles, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyethylene
Alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with imitating into by water dispersible granular agent method
It is 7% fluoxastrobin Tebuconazole water dispersion granule to divide mass percent.
Claims (9)
1. a kind of bactericidal composition containing fluoxastrobin and Tebuconazole, it is characterised in that the bactericidal composition is with fluoxastrobin and penta
Azoles alcohol is principle active component, and wherein the mass ratio of fluoxastrobin and Tebuconazole is 70:1~1:50.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the fluoxastrobin and Tebuconazole is
50:1~1:2.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the fluoxastrobin and Tebuconazole is
10:1~1:2.
4. bactericidal composition according to claim 1, it is characterised in that both described fluoxastrobin and Tebuconazole account for group
The weight/mass percentage composition of compound is 2%~80%.
5. bactericidal composition according to claim 4, it is characterised in that both described fluoxastrobin and Tebuconazole account for group
The weight/mass percentage composition of compound is 5%~70%.
6. bactericidal composition according to claim 1, it is characterised in that using fluoxastrobin and Tebuconazole as it is main effectively into
Point and insecticides adjuvant, excipients be configured to any one formulation for allowing on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared described in claim 1.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is head blight, rust, white powder
At least one of disease, net blotch, root rot, smut, downy mildew and rice sheath blight disease.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107410331A (en) * | 2017-05-08 | 2017-12-01 | 江苏富田农化有限公司 | A kind of bactericidal composition and its application containing fluoxastrobin and Tebuconazole |
| CN115644188A (en) * | 2022-05-23 | 2023-01-31 | 江苏艾津作物科技集团有限公司 | Suspending agent containing fluoxastrobin and tebuconazole and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005104847A1 (en) * | 2004-04-30 | 2005-11-10 | Basf Aktiengesellschaft | Fungicidal mixtures |
| CN102763656A (en) * | 2012-07-13 | 2012-11-07 | 王学权 | Fungicide containing tebuconazole |
| CN103371184A (en) * | 2013-06-27 | 2013-10-30 | 王学权 | Fungicidal composition containing prochloraz manganese complex |
-
2017
- 2017-03-07 CN CN201710130138.7A patent/CN107027778A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005104847A1 (en) * | 2004-04-30 | 2005-11-10 | Basf Aktiengesellschaft | Fungicidal mixtures |
| CN102763656A (en) * | 2012-07-13 | 2012-11-07 | 王学权 | Fungicide containing tebuconazole |
| CN103371184A (en) * | 2013-06-27 | 2013-10-30 | 王学权 | Fungicidal composition containing prochloraz manganese complex |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107410331A (en) * | 2017-05-08 | 2017-12-01 | 江苏富田农化有限公司 | A kind of bactericidal composition and its application containing fluoxastrobin and Tebuconazole |
| CN115644188A (en) * | 2022-05-23 | 2023-01-31 | 江苏艾津作物科技集团有限公司 | Suspending agent containing fluoxastrobin and tebuconazole and preparation method thereof |
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Application publication date: 20170811 |