CN106889079A - A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine - Google Patents
A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine Download PDFInfo
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- CN106889079A CN106889079A CN201710130141.9A CN201710130141A CN106889079A CN 106889079 A CN106889079 A CN 106889079A CN 201710130141 A CN201710130141 A CN 201710130141A CN 106889079 A CN106889079 A CN 106889079A
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- Prior art keywords
- fluoxastrobin
- alkene oxime
- oxime amine
- bactericidal composition
- mildew
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
Abstract
The invention discloses a kind of bactericidal composition containing fluoxastrobin and alkene oxime amine and its application.With fluoxastrobin and alkene oxime amine as principle active component, wherein fluoxastrobin and the mass ratio of alkene oxime amine is 70 to the bactericidal composition:1~1:50.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, with synergistic function higher, overcome and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly useful for preventing and treating the fungal diseases such as powdery mildew, wheat glume blotch, wheat rust, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, apple mildew, early blight of tomato, pear scab, effect is better than single dose and uses.
Description
Technical field：
The present invention relates to a kind of bactericidal composition and application thereof, especially it is a kind of with fluoxastrobin and alkene oxime amine be main
The bactericidal composition of active component and its application.
Background technology
Fluoxastrobin (Fluoxastrobin) is mitochondrial respiratory inhibitor, and its mechanism of action is by cytochrome b
Electro transfer suppresses mitochondrial breathing and between C1, and fluoxastrobin has quick-acting and lasting period double grading long, has to crop
Good compatibility, appropriate processing formulation can further improve it and pass through the osmosis that cuticula enters people's leaf portion.Although it
Absorbability by seed and root is poor, during as seed treatment, though have to seedling and kind biography and soil-borne disease
Kill well and lasting effect, to nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease
Such as tens of kinds of diseases of rust, glume blight, net blotch, powdery mildew, downy mildew have good activity.
Alkene oxime amine wide sterilization spectrum, activity be high, with prevention and therapeutic action, have good compatibility with environmental organism,
Plurality of plant diseases to being caused by mastigomycetes, zygomycete, sac fungus, basidiomycetes and Fungi Imperfecti has good prevention effect, right
Powdery mildew, rust prevention effect are remarkable.Can be used to prevent and treat wheat rust, wheat powdery mildew, rice sheath blight disease, false smut, cucumber
Powdery mildew, cucumber downy mildew, downy mildew of garpe, alternaria leaf spot of apple, apple mildew, sigatoka, early blight of tomato,
The plurality of plant diseases such as pear scab, powdery mildew of strawberry, rust of sunflower.Meanwhile, have substantially to plant growth proterties and quality
Improvement result, and yield can be improved.
The difficulty of prevention and cure of current phytopathogen is increasing, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity are increased, and difficulty is increased in preventing and treating；Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
The content of the invention：
The purpose of the present invention is directed to above-mentioned technical problem and provides a kind of applied widely, low cost, effect good fluorine-containing
The plant bactericidal composition of Fluoxastrobin and alkene oxime amine.
Cause answering on fungal disease in preventing and treating plant epiphyte it is a still further object of the present invention to provide the bactericidal composition
With especially in preventing and treating wheat glume blotch, wheat rust, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew
Purposes on the fungal diseases such as disease, downy mildew of garpe, apple mildew, early blight of tomato, pear scab.
The purpose of the present invention is to be achieved through the following technical solutions：
A kind of bactericidal composition containing fluoxastrobin and alkene oxime amine, the bactericidal composition is with fluoxastrobin and alkene oxime amine
It is principle active component, wherein fluoxastrobin and the mass ratio of alkene oxime amine is 70:1~1:50, wherein have in bactericidal composition
Effect composition is present in composition with enhancing effective amount.
Described bactericidal composition, wherein fluoxastrobin are preferably 50 with the mass ratio of alkene oxime amine:1~1:6, further
Preferably 50:1~40:1、20:1~5:1、1:4~1:6.
In the compositions of the present invention, accounted for both fluoxastrobin and alkene oxime amine the weight/mass percentage composition of composition for 2%~
80%.Preferably 5%-70%, more preferably 10~40%.
Described bactericidal composition, wherein with fluoxastrobin and alkene oxime amine as principle active component and known auxiliary agent and
Excipient is re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, disappear
Infusion, wetting agent, disintegrant etc., can use calcium dodecyl benzene sulfonate, APES, benzyl phenol polyethenoxy
Ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Warm series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more combinations in lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc., excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other
Auxiliary material can be with alone or be used in combination.
Described bactericidal composition, its formulation is that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the above-mentioned bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared.Especially in preventing and treating cereal
Application in terms of class, fruit tree, vegetable crop disease.
Above-mentioned application, described fungal diseases of plants is wheat glume blotch, wheat rust, wheat powdery mildew, paddy rice line
In rot, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, apple mildew, early blight of tomato, pear scab at least
It is a kind of.
Beneficial effects of the present invention：
1st, the fluoxastrobin used by the present invention is pyridine series bactericidal agent, and alkene oxime amine is triazole bactericidal agent, the mechanism of action
Difference, mutual mixture will not produce it is low touch, can Synergistic, reduce dosage, reduces cost.
2nd, the present composition scope of application increases, it is adaptable to prevent and treat the refractory fungal disease of Cereal, fruit tree, vegetables,
Particularly prevent and treat wheat glume blotch, wheat rust, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew, Portugal
Grape downy mildew, apple mildew, early blight of tomato, pear scab etc. have significant effect.Bactericidal composition antithetical phrase of the present invention
Capsule bacterium, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease have good prevention effect；And suppress insect or fungi to unitary system
The drug-fast generation of agent (fluoxastrobin and alkene oxime amine are any).Bactericidal composition of the present invention can produce Synergistic higher
Act on, and the consumption of the amount ratio independent reactive compound of the mixture is substantially reduced, i.e., and the activity of mixture is more than independent
The activity of component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
Wheat glume blotch, wheat rust, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, apple
The fungal diseases such as fruit powdery mildew, early blight of tomato, pear scab have obvious synergistic function, overcome and delayed the resistance to the action of a drug,
Expand preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and it is also easy to produce
The agricultural chemicals of resistance；(4) compared with single dose, production and use cost are reduced；(5) the drug-fast generation of fungi is suppressed, its effect is bright
It is aobvious to be used higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, determines EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows：
A certain single dose (generally selects EC as standard agent with mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
According to active ingredient fluoxastrobin (A)：Alkene oxime amine (B) quality proportioning is：70：1、50：1、30：1、20：1、10：
1、5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50 are tested, and determine it to Rhizoctonia solani Kuhn
The co-toxicity coefficient of (Thanatephorus cucumeris (Frank) Donk).
Table 1：Indoor biometricses result of the fluoxastrobin+alkene oxime amine different ratio to Rhizoctonia solani Kuhn
Field control effectiveness test：
Rice sheath blight disease is prevented and treated with pesticidal preparations obtained in above-described embodiment to test.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is respectively the alkene oxime amine EC of agricultural chemicals single dose 5% and 10% fluoxastrobin EC and blank clean water experiment.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates preventive effect.
Result of the test is shown in Table 2：
The field test effect of table 2
Shown by indoor biometricses and field efficacy result, fluoxastrobin and alkene oxime amine composition have and significantly cooperate with
Synergistic effect, the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application valency in agricultural application
Value.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds with specific embodiment below
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% fluoxastrobin alkene oxime amine wettable powder (1:2)
By fluoxastrobin 5g, alkene oxime amine 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, are obtained effective
Ingredient percent is 15% fluoxastrobin alkene oxime amine wettable powder.
Embodiment 2：15% fluoxastrobin alkene oxime amine wettable powder (1:4)
By fluoxastrobin 3g, alkene oxime amine 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is obtained for 15% fluoxastrobin alkene oxime amine can
WP.
Embodiment 3：14% fluoxastrobin alkene oxime amine wettable powder (1:6)
By fluoxastrobin 2g, alkene oxime amine 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is obtained for 14% fluoxastrobin alkene oxime amine can
WP.
Embodiment 4：20% fluoxastrobin alkene oxime amine suspending agent (1:1)
10g fluoxastrobins, 10g alkene oxime amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the effect of sand mill with water
Under be made effective Ingredient percent for 20% fluoxastrobin alkene oxime amine suspending agent.
Embodiment 5：55% fluoxastrobin alkene oxime amine aqueous emulsion (1:10)
Weigh 5g fluoxastrobins, 50g alkene oxime amines, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing
Kettle high speed mixes, and is made effective Ingredient percent for 55% fluoxastrobin alkene oxime amine aqueous emulsion.
Embodiment 6：42% fluoxastrobin alkene oxime amine missible oil (1:20)
Weigh 2g fluoxastrobins, 40g alkene oxime amines, it is calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 42% fluoxastrobin alkene oxime amine missible oil.
Embodiment 7：70% fluoxastrobin alkene oxime amine missible oil (2.5:1)
Weigh 50g fluoxastrobins, 20g alkene oxime amines, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared missible oil
Close, be made effective Ingredient percent for 70% fluoxastrobin alkene oxime amine missible oil.
Embodiment 8：18% fluoxastrobin alkene oxime amine water dispersion granule (5：1)
15g fluoxastrobins, 3g alkene oxime amines are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and above raw material is formed with by water dispersible granular agent method to imitate composition
Mass percent is 18% fluoxastrobin alkene oxime amine water dispersion granule.
Embodiment 9：11% fluoxastrobin alkene oxime amine missible oil (10:1)
Weigh 10g fluoxastrobins, 1g alkene oxime amines, it is calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 11% fluoxastrobin alkene oxime amine missible oil.
Embodiment 10：31.5% fluoxastrobin alkene oxime amine microemulsion (20:1)
Weigh 30g fluoxastrobins, 1.5g alkene oxime amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mix in the method input mixing kettle of microemulsion, be made effective Ingredient percent for 31.5% fluoxastrobin alkene oxime amine
Microemulsion.
Embodiment 11：31% fluoxastrobin alkene oxime amine missible oil (30:1)
Weigh 30g fluoxastrobins, 1g alkene oxime amines, it is calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 31% fluoxastrobin alkene oxime amine missible oil.
Embodiment 12：51% fluoxastrobin alkene oxime amine suspending agent (50:1)
50g fluoxastrobins, 1g alkene oxime amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 51% fluoxastrobin alkene oxime amine suspending agent.
Embodiment 13：32% fluoxastrobin alkene oxime amine microemulsion (1:15)
Weigh 2g fluoxastrobins, 30g alkene oxime amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared micro-
Mix in the method input mixing kettle of emulsion, be made effective Ingredient percent for 32% fluoxastrobin alkene oxime amine micro emulsion
Agent.
Embodiment 14：6% fluoxastrobin alkene oxime amine aqueous emulsion (1:5)
Weigh 1g fluoxastrobins, 5g alkene oxime amines, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
APEO 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing kettle
High speed mixes, and is made effective Ingredient percent for 6% fluoxastrobin alkene oxime amine aqueous emulsion.
Embodiment 15：62% fluoxastrobin alkene oxime amine microemulsion (1:30)
Weigh 2g fluoxastrobins, 60g alkene oxime amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared micro-
Mix in the method input mixing kettle of emulsion, be made effective Ingredient percent for 62% fluoxastrobin alkene oxime amine micro emulsion
Agent.
Embodiment 16：51% fluoxastrobin alkene oxime amine suspending agent (1:50)
1g fluoxastrobins, 50g alkene oxime amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 51% fluoxastrobin alkene oxime amine suspending agent.
Embodiment 17：7% fluoxastrobin alkene oxime amine water dispersion granule (1：2.5)
Weigh 2g fluoxastrobins, 5g alkene oxime amines, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with into effect by water dispersible granular agent method
Ingredient percent is 7% fluoxastrobin alkene oxime amine water dispersion granule.
Claims (9)
1. a kind of bactericidal composition containing fluoxastrobin and alkene oxime amine, it is characterised in that the bactericidal composition with fluoxastrobin and
Alkene oxime amine is principle active component, and wherein fluoxastrobin and the mass ratio of alkene oxime amine is 70:1~1:50.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the fluoxastrobin and alkene oxime amine
It is 50:1~1:6.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the fluoxastrobin and alkene oxime amine
It is 50:1~40:1、20:1~5:1、1:4~1:6.
4. bactericidal composition according to claim 1, it is characterised in that both described fluoxastrobin and alkene oxime amine are accounted for
The weight/mass percentage composition of composition is 2%~80%.
5. bactericidal composition according to claim 5, it is characterised in that both described fluoxastrobin and alkene oxime amine are accounted for
The weight/mass percentage composition of composition is 5%-70%.
6. bactericidal composition according to claim 1, it is characterised in that with fluoxastrobin and alkene oxime amine as it is main effectively
Composition and insecticides adjuvant, excipients are configured to any one formulation allowed on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition described in claim 1 on preventing and treating fungal diseases of plants medicine is prepared.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is wheat glume blotch, wheat rust
Disease, wheat powdery mildew, rice sheath blight disease, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, apple mildew, tomato early epidemic
At least one in disease, pear scab.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108651497A (en) * | 2018-06-21 | 2018-10-16 | 浙江新农化工股份有限公司 | Pyraclostrobin-containing and alkene oxime amine bactericidal composition and application thereof and agriculture chemicals fungicide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0432894A1 (en) * | 1989-12-07 | 1991-06-19 | Ube Industries, Ltd. | Fungicidal composition |
| WO2006040123A2 (en) * | 2004-10-12 | 2006-04-20 | Bayer Cropscience Ag | Fungicidal active ingredient combinations containing fluoxastrobin |
| CN104642341A (en) * | 2013-11-19 | 2015-05-27 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing zinc thiazole |
-
2017
- 2017-03-07 CN CN201710130141.9A patent/CN106889079B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0432894A1 (en) * | 1989-12-07 | 1991-06-19 | Ube Industries, Ltd. | Fungicidal composition |
| WO2006040123A2 (en) * | 2004-10-12 | 2006-04-20 | Bayer Cropscience Ag | Fungicidal active ingredient combinations containing fluoxastrobin |
| CN104642341A (en) * | 2013-11-19 | 2015-05-27 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing zinc thiazole |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108651497A (en) * | 2018-06-21 | 2018-10-16 | 浙江新农化工股份有限公司 | Pyraclostrobin-containing and alkene oxime amine bactericidal composition and application thereof and agriculture chemicals fungicide |
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| CN106889079B (en) | 2018-09-07 |
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