CN105918335B - A kind of bactericidal composition and its application containing volution bacterium amine and Propamocarb - Google Patents
A kind of bactericidal composition and its application containing volution bacterium amine and Propamocarb Download PDFInfo
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- CN105918335B CN105918335B CN201610342116.2A CN201610342116A CN105918335B CN 105918335 B CN105918335 B CN 105918335B CN 201610342116 A CN201610342116 A CN 201610342116A CN 105918335 B CN105918335 B CN 105918335B
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- propamocarb
- volution bacterium
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing volution bacterium amine and Propamocarb and its applications.The bactericidal composition is using volution bacterium amine and Propamocarb as principle active component, and wherein the mass ratio of volution bacterium amine and Propamocarb is 1~90：1~90.The bactericidal composition can be applied to prevention Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the drug resistance of germ, and sterilization speed is fast, the lasting period is long, reduces application cost, and control effect is substantially better than the use of its single dose.The present invention can be used for preventing the fungal disease on crops, it is particularly possible to which, for preventing the fungal diseases such as wheat powdery mildew, rust, downy mildew, late blight, effect is better than single dose use.
Description
Technical field：
The present invention relates to a kind of bactericidal compositions and application thereof, especially a kind of to be lived to be main with volution bacterium amine and Propamocarb
The bactericidal composition of property ingredient and its application.
Background technology
Volution bacterium amine (Spiroxamine), chemical formula：C18H35NO2, chemical name：The tertiary fourths of N- ethyl-N- propyl -8-
Base -1,4- dioxo spiros [4.5] decane -2- methylamines.Structural formula：
Volution bacterium amine is substitutional amine-group fungicide, and sterol biosynthesis inhibitor is main to inhibit germ C-14 deoxidation methyl
Change the synthesis of enzyme.Controlling object is wheat powdery mildew and various rust, barley leaf blotch and stripe disease.Volution bacterium amine is a kind of new
The foliage fungicide of type, absorbability, is effective for white powder disease.The work fast and lasting period is long, has both protection and therapeutic effect.
Propamocarb (Propamocarb), molecular formula：C9H20N2O2, chemical name：N- [3- (dimethylaminopropyl) ammonia
Base] propyl formate.Structural formula：
A kind of efficient, wide spectrum, safety carbamate fungicide of Propamocarb, has efficiently killing for local systemic action
Microbial inoculum can be used as cauline leaf process, soil treatment and seed treatment, to prevent Peronosporales fungi etc. caused by various crop disease.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area gradually expands, and disease occurrence degree, generation quantity increase, and is increased in the upper difficulty of prevention；Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the control effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
Invention content：
The purpose of the present invention is provide in view of the above technical problems a kind of applied widely, at low cost, effect it is good contain spiral shell
The plant bactericidal composition of ring bacterium amine and Propamocarb.
It is a still further object of the present invention to provide the bactericidal compositions to cause answering on fungal disease in prevention plant epiphyte
With the especially purposes on prevention wheat powdery mildew, rust, downy mildew, the fungal diseases such as late blight.
The purpose of the present invention is be achieved through the following technical solutions：
A kind of bactericidal composition containing volution bacterium amine and Propamocarb, the bactericidal composition is based on volution bacterium amine and Propamocarb
Active ingredient is wanted, the wherein mass ratio of volution bacterium amine and Propamocarb is 1~90：1~90, wherein effective ingredient in bactericidal composition
It is present in composition with enhancing effective amount.
The mass ratio of the bactericidal composition, wherein volution bacterium amine and Propamocarb is preferably 1~70：1~50, further
Preferably 70：1、50：1、30：1、20：1、10：1、5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50.
The mass ratio of the bactericidal composition, wherein volution bacterium amine and Propamocarb is most preferably 1：1.
In the compositions of the present invention, the mass percentage that both volution bacterium amine and Propamocarb account for composition is 2~80%.
It is preferred that 10~40%.
The bactericidal composition, wherein using volution bacterium amine and Propamocarb as principle active component and known auxiliary agent and tax
Shape agent is re-dubbed any one dosage form allowed on pesticide.These known auxiliary agents, excipients have dispersant, diffusant, defoaming
Calcium dodecyl benzene sulfonate, alkyl phenol polyoxyethylene ether, benzyl phenol polyethenoxy may be used in agent, wetting agent, disintegrant etc.
Ether, phenethyl phenol polyethenoxy ether, fatty alcohol polyoxyethylene ether and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, castor oil polyoxyethylene ether, nonylphenol polyoxyethylene ether, is spat at polyoxyethylene polyoxy propylene block compound
Warm series, fatty alcohol polyoxyethylene ether, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. combine, and excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water.The above auxiliary agent, excipient and other
Auxiliary material can be applied alone or be used in combination.
The bactericidal composition, dosage form are missible oil, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
Application of the above-mentioned bactericidal composition on preparing prevention fungal diseases of plants drug.Especially in prevention cereal
Application in terms of class, fruit tree, vegetable crop disease.
Above-mentioned application, the fungal diseases of plants be wheat powdery mildew, rust, downy mildew, in late blight at least
It is a kind of.
Beneficial effects of the present invention：
1, the volution bacterium amine and Propamocarb used in the present invention, the mechanism of action is different, mutual mixture not will produce it is low touch, can assist
Same synergy reduces dosage, reduces cost.
2, the present composition scope of application increases, suitable for preventing the refractory fungal disease of Cereal, fruit tree, vegetables,
Especially preventing wheat powdery mildew, rust, downy mildew, late blight etc. has significant effect.Bactericidal composition antithetical phrase of the present invention
Capsule bacterium, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease have good control effect；And inhibit pest or fungi to unitary system
The generation of the drug resistance of agent (volution bacterium amine and Propamocarb are any).Bactericidal composition of the present invention can generate higher synergistic work
With, and the dosage of the amount ratio independent reactive compound of the mixture substantially reduces, i.e., and the activity of mixture is more than independent group
The activity divided.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, the composition antagonism fungal disease is such as
The fungal diseases such as wheat powdery mildew, rust, downy mildew, late blight have apparent synergistic function, overcome and delayed drug resistance,
Expand prevention spectrum, hence it is evident that improve control effect；(2) prevention recruitment, drug cost are reduced；(3) it alternative routine and is also easy to produce
The pesticide of resistance；(4) compared with single dose, production and application cost reduces；(5) inhibit the generation of fungi drug resistance, effect bright
It is aobvious to be used higher than its single dose.
Specific implementation mode
The invention will be further described with reference to embodiments, and the preparation method of dosage form is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometrics experiment：
Mycelial growth rate method is used indoors, measures EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows：
Using a certain single dose in mixture (EC is generally selected as standard agent50Junior), it is calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
The EC of survey toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=survey toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：It is antagonism when being less than 80 that mixture, which has synergetic, CTC, when CTC is more than 120, and CTC exists
It is summation action between 80-120.
According to active ingredient volution bacterium amine (A)：Propamocarb (B) quality proportioning is：70：1、50：1、30：1、20：1、10：1、
5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50 are tested, and measure it to Phytophthora infestans germ
The co-toxicity coefficient of (Phytophthora infestans.).
Table 1：Indoor biometrics result of the volution bacterium amine+Propamocarb different ratio to tomato late blight
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% volution bacterium amine EC | Y=2.73+3.52X | 4.42 | - |
| 15% Propamocarb WP | Y=3.72+1.54X | 6.75 | - |
| A:B=70:1 | Y=4.41+1.00X | 3.934 | 112.90 |
| A:B=50:1 | Y=3.50+2.36X | 4.315 | 103.13 |
| A:B=30:1 | Y=3.45+2.53X | 4.103 | 108.94 |
| A:B=20:1 | Y=2.42+3.54X | 5.341 | 84.14 |
| A:B=10:1 | Y=3.96+1.48X | 5.070 | 90.00 |
| A:B=5:1 | Y=3.23+2.57X | 4.872 | 96.26 |
| A:B=2.5:1 | Y=3.52+1.88X | 6.132 | 79.97 |
| A:B=1:1 | Y=3.73+2.07X | 4.123 | 129.57 |
| A:B=1:2 | Y=3.90+1.48X | 5.569 | 103.09 |
| A:B=1:4 | Y=3.36+2.30X | 5.179 | 117.90 |
| A:B=1:6 | Y=3.96+1.41X | 5.506 | 114.01 |
| A:B=1:10 | Y=1.47+4.12X | 7.202 | 89.44 |
| A:B=1:20 | Y=2.01+3.65X | 6.578 | 100.10 |
| A:B=1:30 | Y=3.12+2.07X | 8.058 | 82.37 |
| A:B=1:50 | Y=3.73+1.44X | 7.654 | 87.29 |
Field control effectiveness test：
The pesticidal preparations prevention tomato late blight experiment made from above-described embodiment.
1, test process：This test medicine dosage sets three concentration for the treatment of, comparison medicine respectively according to the difference of each ingredient
Agent is pesticide single dose 25% volution bacterium amine EC and 15% Propamocarb WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent before dispenser
Method is：5 points of grab sample in test process area carry out severity Scaling according to national field trial relevant criterion, calculate preventive effect.
Test result is shown in Table 2：
2 field test effect of table
By indoor biometrics and field efficacy, the result shows that, volution bacterium amine has with Propamocarb composition significantly cooperates with increasing
Effect acts on, and the control effect of composition is excellent, and control effect is better than single dose kind, has application value in agricultural is applied.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% volution bacterium amine Propamocarb wettable powder (1:2)
By volution bacterium amine 5g, Propamocarb 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusant
NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures carry out air-flow crushing, be made effectively at
It is 15% volution bacterium amine Propamocarb wettable powder to divide mass percent.
Embodiment 2：15% volution bacterium amine Propamocarb wettable powder (1:4)
By volution bacterium amine 3g, Propamocarb 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
It adds to 100g mixtures and carries out air-flow crushing, it is 15% volution bacterium amine Propamocarb wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 3：14% volution bacterium amine Propamocarb wettable powder (1:6)
By volution bacterium amine 2g, Propamocarb 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
It adds to 100g mixtures and carries out air-flow crushing, it is 14% volution bacterium amine Propamocarb wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 4：20% volution bacterium amine Propamocarb suspending agent (1:1)
10g volution bacterium amines, 10g Propamocarbs, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, under the action of sand mill
It is 20% volution bacterium amine Propamocarb suspending agent that effective ingredient percent, which is made,.
Embodiment 5：55% volution bacterium amine Propamocarb aqueous emulsion (1:10)
Weigh 5g volution bacterium amines, 50g Propamocarbs, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, solvent naphtha 13g, adds water to 100g.The method that the above raw material routinely prepares aqueous emulsion is put into mixing kettle
High speed mixes, and it is 55% volution bacterium amine Propamocarb aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 6：42% volution bacterium amine Propamocarb missible oil (1:20)
Weigh 2g volution bacterium amines, 40g Propamocarbs, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent
Oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 42% volution bacterium amine Propamocarb missible oil.
Embodiment 7：70% volution bacterium amine Propamocarb missible oil (2.5:1)
Weigh 50g volution bacterium amines, 20g Propamocarbs, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Sesame oil polyoxyethylene ether 2g, solvent naphtha to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil,
It is 70% volution bacterium amine Propamocarb missible oil that effective ingredient percent, which is made,.
Embodiment 8：18% volution bacterium amine Propamocarb water dispersion granule (5：1)
Weigh 15g volution bacterium amines, 3g Propamocarbs, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, diatomite 28g complement to 100g, and the above raw material is formed with effect into sub-prime by water dispersible granular agent method
Amount percentage is 17% volution bacterium amine Propamocarb water dispersion granule.
Embodiment 9：11% volution bacterium amine Propamocarb missible oil (10:1)
Weigh 10g volution bacterium amines, 1g Propamocarbs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent
Oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 11% volution bacterium amine Propamocarb missible oil.
Embodiment 10：31.5% volution bacterium amine Propamocarb microemulsion (20:1)
Weigh 30g volution bacterium amines, 1.5g Propamocarbs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, it is 32% volution bacterium amine Propamocarb micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 11：31% volution bacterium amine Propamocarb missible oil (30:1)
Weigh 30g volution bacterium amines, 1g Propamocarbs, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent
Oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 31% volution bacterium amine Propamocarb missible oil.
Embodiment 12：51% volution bacterium amine Propamocarb suspending agent (50:1)
Weigh 50g volution bacterium amines, 1g Propamocarbs, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, in sand mill under the action of system
It is 51% volution bacterium amine Propamocarb suspending agent at active ingredient mass percent.
Embodiment 13：32% volution bacterium amine Propamocarb microemulsion (1:15)
Weigh 2g volution bacterium amines, 30g Propamocarbs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared into micro emulsion
It is mixed in the method input mixing kettle of agent, it is 32% volution bacterium amine Propamocarb microemulsion that effective ingredient percent, which is made,.
Embodiment 14：6% volution bacterium amine Propamocarb aqueous emulsion (1:5)
It is poly- to weigh 1g volution bacterium amines, 5g Propamocarbs, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Ethylene oxide ether 1g, solvent naphtha 13g add water to 100g.In the method input mixing kettle that the above raw material is routinely prepared to aqueous emulsion
Mixed at high speed, it is 6% volution bacterium amine Propamocarb aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 15：62% volution bacterium amine Propamocarb microemulsion (1:30)
Weigh 2g volution bacterium amines, 60g Propamocarbs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared into micro emulsion
It is mixed in the method input mixing kettle of agent, it is 62% volution bacterium amine Propamocarb microemulsion that effective ingredient percent, which is made,.
Embodiment 16：51% volution bacterium amine Propamocarb suspending agent (1:50)
Weigh 1g volution bacterium amines, 50g Propamocarbs, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, in sand mill under the action of system
It is 51% volution bacterium amine Propamocarb suspending agent at active ingredient mass percent.
Embodiment 17：7% volution bacterium amine Propamocarb water dispersion granule (1：2.5)
Weigh 2g volution bacterium amines, 5g Propamocarbs, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyethylene
Alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, by the above raw material by water dispersible granular agent method be formed with effect at
It is 7% volution bacterium amine Propamocarb water dispersion granule to divide mass percent.
Claims (1)
1. a kind of application of bactericidal composition on preparing prevention late blight medicine, it is characterised in that：The bactericidal composition has
It is volution bacterium amine and Propamocarb to imitate ingredient, and the mass ratio of volution bacterium amine and Propamocarb is 1：1.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103121989A (en) * | 2013-02-05 | 2013-05-29 | 江苏中旗作物保护股份有限公司 | Synthesis method of spiroxamine as bactericide |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103121989A (en) * | 2013-02-05 | 2013-05-29 | 江苏中旗作物保护股份有限公司 | Synthesis method of spiroxamine as bactericide |
Non-Patent Citations (1)
| Title |
|---|
| 霜霉威AS 防治马铃薯晚疫病效果试验;王巍;《农业科技通讯》;20120417(第4期);第63页摘要 * |
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