CN105994296A - Antibacterial composition containing C15H8ClF7N2O2 and triadimenol as well as application of antibacterial composition - Google Patents

Antibacterial composition containing C15H8ClF7N2O2 and triadimenol as well as application of antibacterial composition Download PDF

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Publication number
CN105994296A
CN105994296A CN201610365077.8A CN201610365077A CN105994296A CN 105994296 A CN105994296 A CN 105994296A CN 201610365077 A CN201610365077 A CN 201610365077A CN 105994296 A CN105994296 A CN 105994296A
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triadimenol
ether bacterium
bacterium amide
fluorine ether
bactericidal composition
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杨琴
白杰
高瑞花
夏小云
孙会杰
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN201610365077.8A priority Critical patent/CN105994296A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses antibacterial composition containing C15H8ClF7N2O2 and triadimenol, as well as application of the antibacterial composition. The antibacterial composition comprises C15H8ClF7N2O2 and triadimenol as main effective components, wherein the mass ratio of C15H8ClF7N2O2 to triadimenol is (1-70):(1-50). The antibacterial composition can be applied to control on cereal, fruit tree and vegetable diseases, is relatively good in synergistic interaction, overcomes and retards drug resistance of bacteria, and is high in sterilization speed, long in lasting period and low in application cost, and the control effect of the bacterial composition is remarkably superior to that of a single agent. The antibacterial composition can be used for controlling fungal diseases on crops, particularly for controlling fungal diseases such as grape downy mildew, potato late blight, rice sheath blight, wheat powdery mildew, wheat rust and rice blast, and the effect is remarkably superior to that of the single agent.

Description

A kind of fluorine-containing ether bacterium amide and the bactericidal composition of Triadimenol and application thereof
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially one live with fluorine ether bacterium amide and Triadimenol for main The bactericidal composition of property composition and application thereof.
Background technology
Fluorine ether bacterium amide molecule formula: C15H8ClF7N2O2, chemical name: N-(3-chloro-5-(trichloromethyl) pyridine-2-first Base)-2,3,5,6-four chloro-4-methoxy benzamide.Structural formula is as follows:
Fluorine ether bacterium amide acts on the respiratory chain of fungal mitochondria, the activity of suppression succinate dehydrogenase, thus blocks electronics Transmission, suppresses fungus spore germination, and germ tube extends, and mycelial growth and spore mother cell form fungus growth and the master of breeding Want stage, bactericidal action directly to be caused by parent active agent, there is no corresponding metabolic activity, for downy mildew of garpe, peppery The multiple fungal diseases such as green pepper phytophthora, the late blight of potato, rice sheath blight disease, cotton seedling blight all have higher preventive effect, It it is a kind of New-type wide-spectrum antibacterial.
Triadimenol (Triadimenol), molecular formula: C14H18ClN3O2, chemical name: 1-(4-chlorophenoxy)-1-(1H-1,2,4- Triazol-1-yl)-3,3-dimethyl-butyl-2-alcohol.Structural formula:
Triadimenol is a kind of high-efficiency low-toxicity wide-spectrum bactericide.For preventing and treating wheat and barley, Oryza sativa L. rust, powdery mildew, banded sclerotial blight etc. Disease, has obvious effect of increasing production.Also can be as Cereal seed treatment and prevent and treat frumentum head smut.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, along with the change of pattern of farming, melon fruits and vegetables etc. Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty strengthens; On the other hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, Control of plant disease is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, low cost, effective fluorine-containing ether for above-mentioned technical problem Bacterium amide and the plant bactericidal composition of Triadimenol.
It is a still further object of the present invention to provide this bactericidal composition and cause the application on fungal disease at preventing and treating plant epiphyte, Especially preventing and treating downy mildew of garpe, the late blight of potato, rice sheath blight disease, wheat powdery mildew, wheat rust, Oryza sativa L. Purposes on the fungal diseases such as rice blast.
It is an object of the invention to be achieved through the following technical solutions:
A kind of fluorine-containing ether bacterium amide and the bactericidal composition of Triadimenol, this bactericidal composition with fluorine ether bacterium amide with Triadimenol is Principle active component, wherein fluorine ether bacterium amide is 1~70:1~50 with the mass ratio of Triadimenol, wherein in bactericidal composition Active ingredient is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein fluorine ether bacterium amide is preferably 1~30:1~50 with the mass ratio of Triadimenol, enters one Step be preferably 1~10:1~10, the most preferably 1~, 5:1~4, the preferred mass of fluorine ether bacterium amide and Triadimenol is joined Ratio can also be: 70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4, 1:6,1:10,1:20,1:30,1:50.
In the compositions of the present invention, the weight/mass percentage composition accounting for compositions both fluorine ether bacterium amide and Triadimenol is 2~80%. Preferably 5~70%.
Described bactericidal composition, wherein with fluorine ether bacterium amide and Triadimenol for principle active component and known auxiliary agent and tax Shape agent is re-dubbed on pesticide any one dosage form allowed.Auxiliary agent known to these, excipient have dispersant, diffusant, Defoamer, wetting agent, disintegrating agent etc., can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, benzylphenol Polyoxyethylene ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products, aliphatic amine polyoxyethylene Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, nonyl Phenol polyethenoxy ether, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfur Hydrochlorate, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc. In one or more combinations, excipient includes that Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent are (such as the third two Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.Especially preventing and treating Cereal, Application in terms of fruit tree, vegetable crop disease has significant effect.
Above-mentioned application, described fungal diseases of plants is downy mildew of garpe, the late blight of potato, rice sheath blight disease, little At least one in wheat powdery mildew, wheat rust, rice blast.
The feature of bactericidal composition of the present invention:
1, the fluorine ether bacterium amide used by the present invention and Triadimenol, the mechanism of action is different, and mutual mixture will not produce low touching, Can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating Cereal, fruit tree, the refractory fungal disease of vegetable, Particularly prevent and treat downy mildew of garpe, the late blight of potato, rice sheath blight disease, wheat powdery mildew, wheat rust, Oryza sativa L. rice Pestilence etc. all have significant effect.Bactericidal composition of the present invention is sick to ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal Evil has good prevention effect;And (fluorine ether bacterium amide and Triadimenol are appointed to unitary agent to suppress insect or fungus or antibacterial One) drug-fast generation.Bactericidal composition of the present invention can produce higher synergistic function, and this mixture The consumption of the independent reactive compound of amount ratio is substantially reduced, and i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism fungal disease is such as The funguses such as downy mildew of garpe, the late blight of potato, rice sheath blight disease, wheat powdery mildew, wheat rust, rice blast Disease has obvious synergistic function, overcomes and delayed Drug resistance, and expanding prevention is composed, hence it is evident that improve prevention effect; (2) preventing and treating recruitment, drug cost are reduced;(3) alternative routine and the pesticide being easily generated resistance;(4) with single dose phase Ratio, produces and use cost reduces;(5) the suppression drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is conventional method, " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient calculating side Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A the single dose of theoretical toxicity index=A single dose in mixture the toxicity index of proportion+B single dose × B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, CTC It it is summation action between 80-120.
According to effective ingredient fluorine ether bacterium amide (A): Triadimenol (B) quality proportioning is: 80:1,70:1,50:1, 30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1: 30,1:50,1:60,1:70 test, and measure it to wheat powdery mildew (Erysipe graminis.f.sp.triti.) Co-toxicity coefficient.
Table 1: fluorine ether bacterium amide+Triadimenol different ratio indoor biometrics result to wheat powdery mildew
Medicament Virulence regression equation EC50(mg/L) Co-toxicity coefficient
50% fluorine ether bacterium amide WP Y=3.301X+3.774 2.352 -
15% Triadimenol WP Y=2.541X+2.815 7.241 -
A:B=80:1 Y=2.635X+2.751 7.136 102.32
A:B=70:1 Y=3.632X+2.638 4.471 163.50
A:B=50:1 Y=2.001X+3.458 5.894 124.51
A:B=30:1 Y=2.547X+3.218 5.009 147.78
A:B=20:1 Y=1.635X+3.751 5.809 128.79
A:B=10:1 Y=2.087X+3.426 5.676 135.92
A:B=5:1 Y=4.225X+2.267 4.434 184.01
A:B=2.5:1 Y=2.568X+3.382 4.268 210.20
A:B=1:1 Y=1.424X+3.946 5.500 198.75
A:B=1:2 Y=1.325X+3.917 6.566 200.56
A:B=1:4 Y=3.026X+2.108 9.029 174.40
A:B=1:6 Y=2.554X+2.328 11.124 154.52
A:B=1:10 Y=1.326X+3.601 11.348 165.23
A:B=1:20 Y=2.080X+2.676 13.106 154.78
A:B=1:30 Y=1.478X+3.463 10.970 190.44
A:B=1:50 Y=3.236X+1.499 12.071 177.45
A:B=1:60 Y=1.020X+3.641 21.508 100.23
A:B=1:70 Y=2.578X+1.540 21.984 98.52
Field control effectiveness test:
The pesticidal preparations preventing and treating wheat powdery mildew test prepared with above-described embodiment.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, compares medicine Agent is pesticide single dose 50% fluorine ether bacterium amide WP and 50% Triadimenol WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times;Investigation drug effect after investigating before dispenser and preventing and treating Method is: in test treatment region, (every takes 5m to randomization 5 point2), according to country's field test relevant criterion Carry out severity Scaling, calculate preventive effect.Result of the test is shown in Table 2:
Table 2 field test effect
Being shown by indoor biometrics and field efficacy result, fluorine ether bacterium amide and Triadimenol compositions have the most collaborative increasing Effect effect, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has application valency in agricultural is applied Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates that two kinds have with specific embodiment below The preparation that effect composition is processed into, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% fluorine ether bacterium amide Triadimenol wettable powder (1:2)
By fluorine ether bacterium amide 5g, Triadimenol 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, Dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out air-flow powder Broken, preparing effective ingredient mass percent is 15% fluorine ether bacterium amide Triadimenol wettable powder.
Embodiment 2:15% fluorine ether bacterium amide Triadimenol wettable powder (1:4)
By fluorine ether bacterium amide 3g, Triadimenol 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 15% fluorine ether bacterium amide three Azoles alcohol wettable powder.
Embodiment 3:14% fluorine ether bacterium amide Triadimenol wettable powder (1:6)
By fluorine ether bacterium amide 2g, Triadimenol 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 14% fluorine ether bacterium amide three Azoles alcohol wettable powder.
Embodiment 4:20% fluorine ether bacterium amide Triadimenol suspending agent (1:1)
Weigh 10g fluorine ether bacterium amide, 10g Triadimenol, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand mill Effect under to make effective Ingredient percent be 20% fluorine ether bacterium amide Triadimenol suspending agent.
Embodiment 5:55% fluorine ether bacterium amide Triadimenol aqueous emulsion (1:10)
Weigh 5g fluorine ether bacterium amide, 50g Triadimenol, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, Alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Above raw material is prepared aqueous emulsion routinely Method puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 55% fluorine ether bacterium amide Triadimenol water and milk Agent.
Embodiment 6:42% fluorine ether bacterium amide Triadimenol cream (1:20)
Weigh 2g fluorine ether bacterium amide, 40g Triadimenol, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effectively one-tenth Point mass percent is 42% fluorine ether bacterium amide Triadimenol cream.
Embodiment 7:70% fluorine ether bacterium amide Triadimenol cream (2.5:1)
Weigh 50g fluorine ether bacterium amide, 20g Triadimenol, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, Castor oil polyoxyethylene ether 2g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixed Closing in still and mix, making effective Ingredient percent is 70% fluorine ether bacterium amide Triadimenol cream.
Embodiment 8:18% fluorine ether bacterium amide Triadimenol water dispersion granule (5:1)
Weigh 15g fluorine ether bacterium amide, 3g Triadimenol, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, Polyvinyl alcohol 5g, Borax 2g, kieselguhr complements to 100g, and by water dispersible granular agent method, above raw material is formed with effect Ingredient percent is 17% fluorine ether bacterium amide Triadimenol water dispersion granule.
Embodiment 9:11% fluorine ether bacterium amide Triadimenol cream (10:1)
Weigh 10g fluorine ether bacterium amide, 1g Triadimenol, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effectively one-tenth Point mass percent is 11% fluorine ether bacterium amide Triadimenol cream.
Embodiment 10:31.5% fluorine ether bacterium amide Triadimenol microemulsion (20:1)
Weigh 30g fluorine ether bacterium amide, 1.5g Triadimenol, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 31.5% fluorine ether bacterium Amide Triadimenol microemulsion.
Embodiment 11:31% fluorine ether bacterium amide Triadimenol cream (30:1)
Weigh 30g fluorine ether bacterium amide, 1g Triadimenol, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effectively one-tenth Point mass percent is 31% fluorine ether bacterium amide Triadimenol cream.
Embodiment 12:51% fluorine ether bacterium amide Triadimenol suspending agent (50:1)
Weigh 50g fluorine ether bacterium amide, 1g Triadimenol, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand mill Effect under to make effective Ingredient percent be 51% fluorine ether bacterium amide Triadimenol suspending agent.
Embodiment 13:32% fluorine ether bacterium amide Triadimenol microemulsion (1:15)
Weigh 2g fluorine ether bacterium amide, 30g Triadimenol, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 32% fluorine ether bacterium acyl Amine Triadimenol microemulsion.
Embodiment 14:6% fluorine ether bacterium amide Triadimenol aqueous emulsion (1:5)
Weigh 1g fluorine ether bacterium amide, 5g Triadimenol, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkane Base phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.Above raw material is prepared routinely the side of aqueous emulsion Method puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 6% fluorine ether bacterium amide Triadimenol aqueous emulsion. Embodiment 15:62% fluorine ether bacterium amide Triadimenol microemulsion (1:30)
Weigh 2g fluorine ether bacterium amide, 60g Triadimenol, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 62% fluorine ether bacterium acyl Amine Triadimenol microemulsion.
Embodiment 16:51% fluorine ether bacterium amide Triadimenol suspending agent (1:50)
Weigh 1g fluorine ether bacterium amide, 50g Triadimenol, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand mill Effect under to make effective Ingredient percent be 51% fluorine ether bacterium amide Triadimenol suspending agent.
Embodiment 17:7% fluorine ether bacterium amide Triadimenol water dispersion granule (1:2.5)
Weigh 2g fluorine ether bacterium amide, 5g Triadimenol, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, Polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, above raw material are pressed water dispersion granule side It is 7% fluorine ether bacterium amide Triadimenol water dispersion granule that method makes effective ingredient mass percent.

Claims (10)

1. a fluorine-containing ether bacterium amide and the bactericidal composition of Triadimenol, it is characterised in that this bactericidal composition is with fluorine ether bacterium Amide and Triadimenol are principle active component, and wherein fluorine ether bacterium amide is 1~70:1~50 with the mass ratio of Triadimenol.
Bactericidal composition the most according to claim 1, it is characterised in that described fluorine ether bacterium amide and the matter of Triadimenol Amount ratio is 1~30:1~50.
Bactericidal composition the most according to claim 2, it is characterised in that described fluorine ether bacterium amide and the matter of Triadimenol Amount ratio is 1~10:1~10.
Bactericidal composition the most according to claim 3, it is characterised in that described fluorine ether bacterium amide and the matter of Triadimenol Amount ratio is 1~5:1~4.
Bactericidal composition the most according to claim 1, it is characterised in that described fluorine ether bacterium amide and Triadimenol two It is 2-80% that person accounts for the weight/mass percentage composition of compositions.
Bactericidal composition the most according to claim 5, it is characterised in that described fluorine ether bacterium amide and Triadimenol two It is 5-70% that person accounts for the weight/mass percentage composition of compositions.
Bactericidal composition the most according to claim 1, it is characterised in that be main with fluorine ether bacterium amide and Triadimenol Effective ingredient and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.
Bactericidal composition the most according to claim 7, it is characterised in that described dosage form is cream, suspending agent, water Emulsion, wettable powder or water dispersion granule.
9. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
Application the most according to claim 9, it is characterised in that described fungal diseases of plants be downy mildew of garpe, At least one in the late blight of potato, rice sheath blight disease, wheat powdery mildew, wheat rust, rice blast.
CN201610365077.8A 2016-05-26 2016-05-26 Antibacterial composition containing C15H8ClF7N2O2 and triadimenol as well as application of antibacterial composition Pending CN105994296A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102086173A (en) * 2010-09-07 2011-06-08 唐剑峰 Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing
CN104412988A (en) * 2013-08-28 2015-03-18 张通 Antibacterial composition containing fluoride ether bacteria amide and triazoles
CN105685054A (en) * 2015-12-29 2016-06-22 张通 Sterilization composition containing fluoride ether bacteria amide and triazoles

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102086173A (en) * 2010-09-07 2011-06-08 唐剑峰 Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing
CN104412988A (en) * 2013-08-28 2015-03-18 张通 Antibacterial composition containing fluoride ether bacteria amide and triazoles
CN105685054A (en) * 2015-12-29 2016-06-22 张通 Sterilization composition containing fluoride ether bacteria amide and triazoles

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Application publication date: 20161012