CN105961400B - A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and olefin conversion - Google Patents
A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and olefin conversion Download PDFInfo
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- CN105961400B CN105961400B CN201610266323.4A CN201610266323A CN105961400B CN 105961400 B CN105961400 B CN 105961400B CN 201610266323 A CN201610266323 A CN 201610266323A CN 105961400 B CN105961400 B CN 105961400B
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- fluxapyroxad
- olefin conversion
- olefin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The invention discloses the bactericidal compositions and its application of a kind of Fluxapyroxad-containsterilization and olefin conversion.The bactericidal composition is using fluxapyroxad and olefin conversion as principle active component, and wherein the mass ratio of fluxapyroxad and olefin conversion is 1~70：1~50.The bactericidal composition can be applied to prevention Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the drug resistance of germ, and sterilization speed is fast, the lasting period is long, reduces application cost, and control effect is substantially better than the use of its single dose.The present invention can be used for preventing the fungal disease on crops, it is particularly possible to which, for fungal diseases such as control rust, smut, banded sclerotial blight, gray mold, scabs, effect is better than single dose use.
Description
Technical field
The present invention relates to a kind of bactericidal compositions and application thereof, especially using fluxapyroxad and olefin conversion as chief active
The bactericidal composition of ingredient and its application.
Background technology
Fluxapyroxad (fluxapyroxad), chemical formula：C18H12F5N3O, chemical name：3- (difluoromethyl) -1- first
Base-N- (3', 4', 5'- trifluoro-biphenyl -2- bases) pyrazole-4-carboxamide.
Fluxapyroxad belongs to benzamide type fungicide, is succinate dehydrogenase inhibitors, is a kind of broad-spectrum germicide,
With excellent treatment, systemic activity, good control effect is all had to all kinds of crop banded sclerotial blights, gray mold etc..
Olefin conversion (Diniconazole), molecular formula：C15H17Cl2N3O, chemical name：(E)-(RS) -1- (2,4- dichloros
Phenyl) the amyl- 1 alkene -3- alcohol of -4,4- dimethyl -2- (1H-1,2,4- triazol-1-yls).Structural formula：
Olefin conversion belongs to triazole bactericidal agent, inhibits 14 α-demethylations to be turned into the ergosterol biosynthesis of fungi
With causing ergosterol to lack, cause fungal cell membrane abnormal, final fungi is dead, and the lasting period is permanent.With protecting, control
It treats, the broad-spectrum germicide of eradicant action；For plurality of plant diseases caused by capsule bacterium, basidiomycetes such as powdery mildew, rust, black powder
Disease, scab etc. have special efficacy.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area gradually expands, and disease occurrence degree, generation quantity increase, and is increased in the upper difficulty of prevention；Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the control effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
Invention content：
The purpose of the present invention is provide a kind of applied widely, at low cost, effect good fluorine-containing in view of the above technical problems
The plant bactericidal composition of azoles bacterium amide and olefin conversion.
It is a still further object of the present invention to provide the bactericidal compositions to cause answering on fungal disease in prevention plant epiphyte
With the especially purposes on the fungal diseases such as control rust, smut, banded sclerotial blight, gray mold, scab.
The purpose of the present invention is be achieved through the following technical solutions：
A kind of bactericidal composition of Fluxapyroxad-containsterilization and olefin conversion, the bactericidal composition is with fluxapyroxad and olefin conversion
For principle active component, the wherein mass ratio of fluxapyroxad and olefin conversion is 1~70：1~50, wherein have in bactericidal composition
Effect composition is present in enhancing effective amount in composition.
The mass ratio of the bactericidal composition, wherein fluxapyroxad and olefin conversion is preferably 1~50：1~30, into one
Step preferably 1~30：1~30, it is still more preferably 10~30：2~6.
Fluxapyroxad and the preferred mass of olefin conversion proportioning may be：70：1、50：1、30：1、20：1、10：1、5：
1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50.
In the compositions of the present invention, both fluxapyroxad and olefin conversion account for composition mass percentage be 2~
80%.It is preferred that 5~70%.
The bactericidal composition, wherein using fluxapyroxad and olefin conversion as principle active component and known auxiliary agent and
Excipient is re-dubbed any one dosage form allowed on pesticide.These known auxiliary agents, excipients have dispersant, diffusant, disappear
Calcium dodecyl benzene sulfonate, alkyl phenol polyoxyethylene ether, benzyl phenol polyethenoxy may be used in infusion, wetting agent, disintegrant etc.
Ether, phenethyl phenol polyethenoxy ether, fatty alcohol polyoxyethylene ether and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, castor oil polyoxyethylene ether, nonylphenol polyoxyethylene ether, is spat at polyoxyethylene polyoxy propylene block compound
Warm series, fatty alcohol polyoxyethylene ether, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. combine, and excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water.The above auxiliary agent, excipient and other
Auxiliary material can be applied alone or be used in combination.
The bactericidal composition, dosage form are missible oil, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
Application of the above-mentioned bactericidal composition on preparing prevention fungal diseases of plants drug.Especially in prevention cereal
Application in terms of class, fruit tree, vegetable crop disease has remarkable result.
Above-mentioned application, the fungal diseases of plants be rust, smut, banded sclerotial blight, gray mold, in scab extremely
Few one kind.
The characteristics of bactericidal composition of the present invention：
1, the fluxapyroxad and olefin conversion used in the present invention, the mechanism of action is different, mutual mixture not will produce it is low touch, can
Synergy reduces dosage, reduces cost.
2, the present composition scope of application increases, special suitable for preventing the refractory fungal disease of Cereal, fruit tree, vegetables
Not being control rust, smut, banded sclerotial blight, gray mold, scab etc. has significant effect.Bactericidal composition of the present invention is to ascus
Bacterium, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease have good control effect；And inhibit pest or fungi to single formulation (fluorine
Azoles bacterium amide and olefin conversion are any) drug resistance generation.Bactericidal composition of the present invention can generate higher synergistic function, and
And the dosage of the amount ratio independent reactive compound of the mixture substantially reduces, i.e., the activity of mixture is more than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, the composition antagonism fungal disease is such as
The fungal diseases such as rust, smut, banded sclerotial blight, gray mold, scab have apparent synergistic function, overcome and delayed anti-medicine
Property, expand prevention spectrum, hence it is evident that improve control effect；(2) prevention recruitment, drug cost are reduced；(3) alternative routine and easily production
The pesticide of raw resistance；(4) compared with single dose, production and application cost reduces；(5) inhibit the generation of fungi drug resistance, effect
It is apparently higher than the use of its single dose.
Specific implementation mode
The invention will be further described with reference to embodiments, and the preparation method of dosage form is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometrics experiment：
Mycelial growth rate method is used indoors, measures EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows：
Using a certain single dose in mixture (EC is generally selected as standard agent50Junior), it is calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
The EC of survey toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=survey toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：It is antagonism when being less than 80 that mixture, which has synergetic, CTC, when CTC is more than 120, and CTC exists
It is summation action between 80-120.
According to active ingredient fluxapyroxad (A)：Olefin conversion (B) quality proportioning is：80：1、70：1、50：1、30：1、20：
1、10：1、5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50、1：60 are tested, and measure it to pears
The co-toxicity coefficient of scab germ (Venturia piritna Aderh.).
Table 1：Indoor biometrics result of the fluxapyroxad+olefin conversion different ratio to pear cucumerinum
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% fluxapyroxad SC | Y=1.890+4.574X | 4.785 | - |
| 12.5% olefin conversion WP | Y=4.011+2.653X | 2.359 | - |
| A:B=80:1 | Y=4.144+1.129X | 5.731 | 82.45 |
| A:B=70:1 | Y=4.243+1.471X | 3.270 | 144.24 |
| A:B=50:1 | Y=3.829+2.655X | 2.761 | 169.86 |
| A:B=30:1 | Y=3.228+3.621X | 3.085 | 150.13 |
| A:B=20:1 | Y=2.377+5.008X | 3.340 | 136.59 |
| A:B=10:1 | Y=3.180+4.127X | 2.761 | 158.47 |
| A:B=5:1 | Y=3.227+3.528X | 3.180 | 128.46 |
| A:B=2.5:1 | Y=4.400+1.323X | 2.839 | 130.29 |
| A:B=1:1 | Y=4.251+2.078X | 2.292 | 137.85 |
| A:B=1:2 | Y=4.340+3.666X | 1.514 | 187.45 |
| A:B=1:4 | Y=4.661+1.489X | 1.689 | 155.45 |
| A:B=1:6 | Y=4.606+2.040X | 1.560 | 163.01 |
| A:B=1:10 | Y=3.549+4.751X | 2.020 | 122.45 |
| A:B=1:20 | Y=3.954+4.875X | 1.639 | 147.48 |
| A:B=1:30 | Y=4.538+2.635X | 1.497 | 160.20 |
| A:B=1:50 | Y=4.722+1.545X | 1.514 | 157.36 |
| A:B=1:60 | Y=4.242+2.003X | 2.390 | 99.52 |
Field control effectiveness test：
The pesticidal preparations prevention pear scab experiment made from above-described embodiment.
1, test process：This test medicine dosage sets three concentration for the treatment of, comparison medicine respectively according to the difference of each ingredient
Agent is pesticide single dose 25% fluxapyroxad SC and 12.5% olefin conversion WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent before dispenser
Method is：5 points of grab sample in test process area carry out severity Scaling according to national field trial relevant criterion, calculate preventive effect.
Test result is shown in Table 2：
2 field test effect of table
By indoor biometrics and field efficacy, the result shows that, fluxapyroxad has with olefin conversion composition significantly to be cooperateed with
The control effect of synergistic effect, composition is excellent, and control effect is better than single dose kind, has the valence of applying in agricultural is applied
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% fluxapyroxad olefin conversion wettable powder (1:2)
By fluxapyroxad 5g, olefin conversion 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, are made effective
Ingredient percent is 15% fluxapyroxad olefin conversion wettable powder.
Embodiment 2：15% fluxapyroxad olefin conversion wettable powder (1:4)
By fluxapyroxad 3g, olefin conversion 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and it is that 15% fluxapyroxad olefin conversion can that active ingredient mass percent, which is made,
Wet powder.
Embodiment 3：14% fluxapyroxad olefin conversion wettable powder (1:6)
By fluxapyroxad 2g, olefin conversion 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and it is that 14% fluxapyroxad olefin conversion can that active ingredient mass percent, which is made,
Wet powder.
Embodiment 4：20% fluxapyroxad diniconazole suspending agent (1:1)
10g fluxapyroxads, 10g olefin conversions, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, in the effect of sand mill
Under be made effective ingredient percent be 20% fluxapyroxad diniconazole suspending agent.
Embodiment 5：55% fluxapyroxad diniconazole water emulsion (1:10)
Weigh 5g fluxapyroxads, 50g olefin conversions, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that the above raw material routinely prepares aqueous emulsion is put into mixing
Kettle high speed mixes, and it is 55% fluxapyroxad diniconazole water emulsion that effective ingredient percent, which is made,.Embodiment 6：
42% fluxapyroxad olefin conversion missible oil (1:20)
Weigh 2g fluxapyroxads, 40g olefin conversions, it is calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 42% fluxapyroxad olefin conversion missible oil.
Embodiment 7：70% fluxapyroxad olefin conversion missible oil (2.5:1)
Weigh 50g fluxapyroxads, 20g olefin conversions, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil
It closes, it is 70% fluxapyroxad olefin conversion missible oil that effective ingredient percent, which is made,.
Embodiment 8：18% fluxapyroxad olefin conversion water dispersion granule (5：1)
15g fluxapyroxads, 3g olefin conversions are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 28g complement to 100g, and the above raw material is formed with effect ingredient by water dispersible granular agent method
Mass percent is 17% fluxapyroxad olefin conversion water dispersion granule.
Embodiment 9：11% fluxapyroxad olefin conversion missible oil (10:1)
Weigh 10g fluxapyroxads, 1g olefin conversions, it is calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 11% fluxapyroxad olefin conversion missible oil.
Embodiment 10：32% fluxapyroxad olefin conversion microemulsion (20:1)
Weigh 30g fluxapyroxads, 2g olefin conversions, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, it is 32% fluxapyroxad olefin conversion micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 11：31% fluxapyroxad olefin conversion missible oil (30:1)
Weigh 30g fluxapyroxads, 1g olefin conversions, it is calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent oil is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, effective composition quality hundred is made
Divide than being 31% fluxapyroxad olefin conversion missible oil.
Embodiment 12：51% fluxapyroxad diniconazole suspending agent (50:1)
50g fluxapyroxads, 1g olefin conversions, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, under the action of sand mill
It is 51% fluxapyroxad diniconazole suspending agent that effective ingredient percent, which is made,.
Embodiment 13：32% fluxapyroxad olefin conversion microemulsion (1:15)
Weigh 2g fluxapyroxads, 30g olefin conversions, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, it is 32% fluxapyroxad olefin conversion micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 14：6% fluxapyroxad diniconazole water emulsion (1:5)
Weigh 1g fluxapyroxads, 5g olefin conversions, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, solvent naphtha 13g, adds water to 100g.The method that the above raw material routinely prepares aqueous emulsion is put into mixing kettle
High speed mixes, and it is 6% fluxapyroxad diniconazole water emulsion that effective ingredient percent, which is made,.
Embodiment 15：62% fluxapyroxad olefin conversion microemulsion (1:30)
Weigh 2g fluxapyroxads, 60g olefin conversions, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkyl phenol polyoxyethylene ether 1g, isopropanol 10g add water to 100g.The above raw material is routinely prepared micro-
It is mixed in the method input mixing kettle of emulsion, it is 62% fluxapyroxad olefin conversion micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 16：51% fluxapyroxad diniconazole suspending agent (1:50)
1g fluxapyroxads, 50g olefin conversions, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g complement to 100g with water, under the action of sand mill
It is 51% fluxapyroxad diniconazole suspending agent that effective ingredient percent, which is made,.
Embodiment 17：7% fluxapyroxad olefin conversion water dispersion granule (1：2.5)
Weigh 2g fluxapyroxads, 5g olefin conversions, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and the above raw material is formed with imitating by water dispersible granular agent method
Ingredient percent is 7% fluxapyroxad olefin conversion water dispersion granule.
Claims (8)
1. a kind of application of the bactericidal composition of Fluxapyroxad-containsterilization and olefin conversion on preparing prevention plant pear scab drug,
It is characterized in that the bactericidal composition is using fluxapyroxad and olefin conversion as active ingredient, wherein fluxapyroxad and olefin conversion
Mass ratio is 1~70：1~50.
2. application according to claim 1, it is characterised in that the mass ratio of the fluxapyroxad and olefin conversion be 1~
50：1~30.
3. application according to claim 2, it is characterised in that the mass ratio of the fluxapyroxad and olefin conversion be 1~
30：1~30.
4. application according to claim 3, it is characterised in that the mass ratio of the fluxapyroxad and olefin conversion be 10~
30：2~6.
5. application according to claim 1, it is characterised in that both described fluxapyroxad and olefin conversion account for composition
Mass percentage be 2-80%.
6. application according to claim 5, it is characterised in that both described fluxapyroxad and olefin conversion account for composition
Mass percentage be 5-70%.
7. application according to claim 1, it is characterised in that using fluxapyroxad and olefin conversion as principle active component and
Insecticides adjuvant, excipients are configured to any one dosage form allowed on pesticide.
8. application according to claim 7, it is characterised in that the dosage form is missible oil, suspending agent, aqueous emulsion, wettable
Pulvis or water dispersion granule.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
| WO2009007233A2 (en) * | 2007-07-11 | 2009-01-15 | Basf Se | Pesticidal mixtures comprising sulfonamides and one or more fungicides |
| CN101631465A (en) * | 2007-02-05 | 2010-01-20 | 巴斯夫欧洲公司 | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides |
| CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
-
2016
- 2016-04-26 CN CN201610266323.4A patent/CN105961400B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
| CN101631465A (en) * | 2007-02-05 | 2010-01-20 | 巴斯夫欧洲公司 | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides |
| WO2009007233A2 (en) * | 2007-07-11 | 2009-01-15 | Basf Se | Pesticidal mixtures comprising sulfonamides and one or more fungicides |
| CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
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