CN101257798A - Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides - Google Patents

Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides Download PDF

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CN101257798A
CN101257798A CNA2006800289443A CN200680028944A CN101257798A CN 101257798 A CN101257798 A CN 101257798A CN A2006800289443 A CNA2006800289443 A CN A2006800289443A CN 200680028944 A CN200680028944 A CN 200680028944A CN 101257798 A CN101257798 A CN 101257798A
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methyl
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chlorine
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J·迪茨
M·格韦尔
S·施特拉特曼
R·施蒂尔
F·维尔纳
M·舍勒尔
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BASF SE
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Abstract

The invention relates to fungicidal mixtures containing the following as active components: 1) at least one 1-methyl pyrazol-4-yl carboxylic acid anilide of formula (I), in which X = O or S, R<1> = C1-C4 alkyl or C1-C4 haloalkyl, R<2> = hydrogen or halogen, R<3>, R<4> and R<5> = independently of one another cyano, nitro, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy or C1-C4 alkylthio; and 2) at least one active ingredient II, selected from the active ingredient groups A) to F) in a synergistically active quantity: A) azoles; B) strobilurins; C) carboxamides; D) heterocyclic compounds; E) carbamates; F) other fungicides.; The invention also relates to a method for controlling pathogenic fungi using mixtures of at least one compound I and at least one active ingredient II, to the use of the compound(s) I and active ingredients II for producing mixtures of this type and to agents and seeds containing said mixtures.

Description

The Fungicidal mixture that comprises the 1-methyl-pyrazol-4-yl carboxylic acid anilides of replacement
The present invention relates to Fungicidal mixture, it comprises following compound as active component with the Synergistic effective dose:
1) the 1-methyl-pyrazol-4-yl carboxylic acid anilides of at least a formula I:
Figure A20068002894400071
Wherein each substituting group is following defines:
X is oxygen or sulphur;
R 1Be C 1-C 4Alkyl or C 1-C 4Haloalkyl;
R 2Be hydrogen or halogen;
R 3, R 4And R 5Be cyano group, nitro, halogen, C independently of each other 1-C 4Alkyl, C 1-C 4Haloalkyl, C 1-C 4Alkoxyl, C 1-C 4Halogenated alkoxy or C 1-C 4Alkylthio group;
With
2) the reactive compound II at least a reactive compound group A that is selected from)-F):
A) be selected from following azole: Bitertanol (bitertanol), bromuconazole (bromuconazole), cyproconazole (cyproconazole) Difenoconazole (difenoconazole), alkene azoles alcohol (diniconazole), IMAZALIL (enilconazole), oxole bacterium (epoxiconazole), Fluquinconazole (fluquinconazole), RH-7592 (fenbuconazole), Flusilazole (flusilazole), Flutriafol (flutriafol), own azoles alcohol (hexaconazole), acid amides azoles (imibenconazole), cycltebuconazole (ipconazole), encircle penta azoles bacterium (metconazole), nitrile bacterium azoles (myclobutanil), penconazole (penconazole), propiconazole (propiconazole), prothioconazoles (prothioconazole), simeconazoles (simeconazole), triazolone (triadimefon), triadimenol (triadimenol), Tebuconazole (tebuconazole), fluorine ether azoles (tetraconazole), triticonazole (triticonazole), Prochloraz (prochloraz), pefurazoate (pefurazoate), IMAZALIL (imazalil), fluorine bacterium azoles (triflumizole), cyanogen frost azoles (cyazofamid), benomyl (benomyl), carbendazim (carbendazim), thiabendazole (thiabendazole), furidazol (fuberidazole), Guardian (ethaboxam), kobam (etridiazole) and hydroxyisoxazole (hymexazole);
B) be selected from following strobilurins class (strobilurins): nitrile Fluoxastrobin (azoxystrobin), ether bacterium amine (dimoxystrobin), Enestroburin (enestroburin), fluoxastrobin (fluoxastrobin), imines bacterium (kresoxim-methyl), fork phenalgin acid amides (metominostrobin), orysastrobin (orysastrobin), ZEN 90160 (picoxystrobin), pyraclostrobin (pyraclostrobin), oxime bacterium ester (trifloxystrobin) or (2-chloro-5-[1-(3-methyl benzyloxy imino) ethyl] benzyl) methyl carbamate, (2-chloro-5-[1-(6-picoline-2-base methoxyimino) ethyl] benzyl) methyl carbamate, 2-(neighbour-(2,5-dimethyl phenoxy methylene) phenyl)-3-methoxy-methyl acrylate;
C) be selected from following carboxylic acid amides: carboxin (carboxin), M 9834 (benalaxyl), Boscalid (boscalid), fenhexamid (fenhexamid), flutolanil (flutolanil), furan pyrazoles spirit (furametpyr), third oxygen goes out and embroiders amine (mepronil), metalaxyl (metalaxyl), Metalaxyl-M (mefenoxam), fenfuram (ofurace) Evil frost spirit (oxadixyl), oxycarboxin (oxycarboxin), pyrrole metsulfovax (penthiopyrad), thifluzamide (thifluzamide), tiadinil (tiadinil), 3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide, dimethomorph (dimethomorph), flumorph (flumorph), fluorine biphenyl bacterium (flumetover), fluorine pyrrole bacterium amine (picobenzamid), zoxamide (zoxamide), carpropamide (carpropamid), two chlorine zarilamids (diclocymet), mandipropamid amine (mandipropamid), N-(2-{4-[3-(4-chlorphenyl) third-2-alkynyloxy group]-the 3-anisyl } ethyl)-2-methanesulfonamido-3-methylbutyryl amine, N-(2-{4-[3-(4-chlorphenyl)-third-2-alkynyloxy group]-the 3-anisyl } ethyl)-2-second sulfonamido-3-methylbutyryl amine, 3-(4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) methyl propionate, the formula III compound:
R wherein 4Be methyl or ethyl,
N-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide, N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-and 3-difluoromethyl-1-methylpyrazole-4-formamide and N-(2-cyano-phenyl)-3,4-two chloroisothiazoles-5-formamide;
D) be selected from following heterocyclic compound: fluazinam (fluazinam), pyrifenox (pyrifenox), the phonetic bacterium spirit of sulphur (bupirimate), encircle third pyrimidine (cyprodinil), fenarimol (fenarimol), ferimzone (ferimzone), mepanipyrim (mepanipyrim), nuarimol (nuarimol), pyrimethanil (pyrimethanil), triforine (triforine), fenpiclonil (fenpiclonil) Fu Evil bacterium (fludioxonil), 4-dodecyl-2,6-thebaine (aldimorph), dodemorfe (dodemorph); butadiene morpholine (fenpropimorph); tridemorph (tridemorph); fenpropidin (fenpropidin); different third fixed (iprodione); sterilization profit (procymidone); vinclozolin (vinclozolin); azolactone bacterium (famoxadone); Fenamidone (fenamidone); different thiophene bacterium ketone (octhilinone); probenazole (probenazole); 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2; 4; the 6-trifluorophenyl)-[1; 2; 4] triazols [1,5-a] pyrimidine; anilazine (anilazine); diclomezine (diclomezine); pyroquilon (pyroquilon); the third oxygen quinoline (proquinazid); tricyclazole (tricyclazole); formula IV compound (2-butoxy-6-iodo-3-propyl group chromene-4-ketone):
Figure A20068002894400091
The N of thiadiazoles element (acibenzolar-S-methyl), difoltan (captafol), captan (captan), dazomet (dazomet), folpet (folpet), zarilamid (fenoxanil), quinoxyfen (quinoxyfen) and formula V; N-dimethyl-3-(3-bromo-6-fluoro-2 methyl indole-1-sulfonyl)-[1; 2,4] triazole-1-sulfonamide:
Figure A20068002894400092
E) be selected from following Carbamates: mancozeb (mancozeb); maneb (maneb); metham-sodium (metam); Carbatene (metiram); ferbam (ferbam); propineb (propineb); tmtd (thiram); zineb (zineb); ziram (ziram); the mould prestige of second (diethofencarb); iprovalicarb (iprovalicarb); benzene metsulfovax (flubenthiavalicarb); hundred dimension spirits (propamocarb); N-(1-(1-(4-cyano-phenyl) ethylsulfonyl) fourth-2-yl) carbamic acid 4-fluorophenyl ester; the 3-of formula VI (4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) methyl propionate:
Figure A20068002894400101
Carbamic acid lactazone ether with formula VII:
Figure A20068002894400102
Wherein Z is N or CH;
F) be selected from other following fungicides: the guanidine class: dodine (dodine), biguanide spicy acid salt (iminoctadine), guazatine (guazatine), antibiotic class: spring thunder element (kasugamycin), streptomycin (streptomycin), Polyoxin (polyoxins), jinggangmeisu (validamycin A), nitrophenyl derivative: binapacryl (binapacryl), karathane (dinocap), dinobuton (dinobuton), sulfur heterocyclic ring based compound: Delan (dithianon), Isoprothiolane (isoprothiolane), organo-metallic compound: triphenyltin salt, as fentinacetate (fentinacetate), organic phosphorus compound: Hinosan (edifenphos), iprobenfos (iprobenfos), fosetyl (fosetyl), ethyl phosphine aluminium (fosetyl-aluminum), phosphorous acid and salt thereof, Ppyrazophos (pyrazophos), tolelofos-methyl (tolclofos-methyl), organochlorine compound: tpn (chlorothalonil), Euparen (dichlofluanid), flusulfamide (flusulfamide), hexachloro-benzene (hexachlorobenzene), Rabcide (phthalide), Pencycuron (pencycuron), pcnb (quintozene), thiophanate methyl (thiophanate-methyl), tolyfluanid (tolylfluanid), inorganic active compound: bordeaux mixture (Bordeaux mixture), Schweinfurt green, Kocide SD, Cupravit, basic copper sulfate, sulphur, other: cyflufenamid (cyflufenamid), cymoxanil (cymoxanil), Milcurb (dimethirimol), Milstem (ethirimol), Furalaxyl (furalaxyl), (metrafenone) is with the luxuriant amine of Luo Evil (spiroxamine) for metrafenone.
In addition, the present invention relates to a kind of mixture methods for fighting harmful mushrooms of using at least a Compound I and at least a reactive compound II, Compound I and reactive compound II preparation in such mixture purposes and composition and the seed that comprises these mixtures.
Be called component 1 above) formula I 1-methyl-pyrazol-4-yl carboxylic acid anilides, its preparation and to the effect of harmful fungoid by document known (for example referring to EP-A 545 099, EP-A 589 301 and WO99/09013), perhaps they can wherein said mode prepare.
Wherein X is that the Compound I of sulphur can be that the corresponding Compound I of oxygen prepares (for example referring to D.Petrova﹠amp by vulcanizing X wherein for example; K.Jakobcic, Croat.Chem.Acta 48, 49 (1976) and WO 01/42223).
Yet the 1-methyl-pyrazol-4-yl carboxylic acid anilides of known formula I especially is not entirely satisfactory under low rate of application.
As component 2) above-mentioned reactive compound II, its preparation and to the effect of harmful fungoid normally known (for example referring to Http:// www.hclrss.demon.co.uk/index.html); They can be commercial.
M 9834, N-(phenyl acetyl)-N-(2, the 6-xylyl)-DL-methyl lactamine (DE 29 03 612);
Metalaxyl, N-(methoxyl group acetyl group)-N-(2, the 6-xylyl)-DL-methyl lactamine (GB 15 00581);
Fenfuram, (RS)-α-(2-chloro-N-2,6-xylyl acetamido)-gamma-butyrolacton [CAS RN58810-48-3];
The spirit of Evil frost, N-(2, the 6-3,5-dimethylphenyl)-2-methoxyl group-N-(2-oxo-3-oxazole alkyl) acetamide (GB20 58 059);
4-dodecyl-2, the 6-thebaine, comprise 65-75%2,6-thebaine and 25-35%2, " the 4-alkyl-2,5 (or 2; 6)-thebaine " of 5-thebaine, wherein surpass 85% be 4-dodecyl-2,5 (or 2,6)-thebaine and wherein " alkyl " comprise that also octyl group, decyl, myristyl and cetyl and wherein suitable/inverse ratio are 1: 1[CAS RN 91315-15-0];
Dodine, 1-dodine acetate (Plant Dis.Rep., the 41st volume, the 1029th page (1957)); Dodemorfe, 4-cyclo-dodecyl-2,6-thebaine (DE-A 1198125);
Butadiene morpholine, (RS)-cis-4-[3-(4-tert-butyl-phenyl)-2-methyl-propyl]-2,6-thebaine (DE-A 27 52 096);
Fenpropidin, (RS)-1-[3-(4-tert-butyl-phenyl)-2-methyl-propyl] piperidines (DE-A 27 52 096);
Guazatine, the mixture of the product that is obtained by the amidatioon of technical grade imino-diacetic (eight methylene) diamines comprises various guanidines and polyamines [CAS RN 108173-90-6];
Biguanide spicy acid salt, 1,1 '-imino-diacetic (eight methylene) biguanides (Congr.Plant Pathol., 1., the 27th page (1968));
The luxuriant amine of Luo Evil, (the 8-tert-butyl group-1,4-dioxo spiro [4.5] last of the ten Heavenly stems-2-yl) diethylamide (EP-A 281 842); Tridemorph, 2,6-dimethyl-4-tridecyl morpholine (DE-A 11 64 152);
Pyrimethanil, 4,6-dimethyl pyrimidine-2-base phenyl amine (DD-A 151 404);
Mepanipyrim, (4-methyl-6-third-1-alkynyl pyrimidine-2-base) phenyl amine (EP-A 224 339);
Encircle third pyrimidine, (4-cyclopropyl-6-methylpyrimidine-2-yl) phenyl amine (EP-A 310 550);
Cycloheximide, 4-{ (2R)-2-[(1S, 3S, 5S)-3,5-dimethyl-2-oxo cyclohexyl]-the 2-hydroxyethyl } piperidines-2,6-diketone [CAS RN 66-81-9];
Griseofulvin, 7-chloro-2 ', 4,6-trimethoxy-6 '-methylspiro [benzofuran-2 (3H), 1 '-hexamethylene-2 '-alkene]-3,4 '-diketone [CAS RN 126-07-8];
The spring thunder element, 3-O-[2-amino-4-[(carboxyl iminomethyl) amino]-2,3,4, the Arabic pyranohexose base of 6-four deoxidations-α-D-]-D-chiro-inositol [CAS RN 6980-18-3];
Myprozine, (8E, 14E, 16E, 18E, 20E)-(1R, 3S, 5R, 7R, 12R, 22R, 24S, 25R, 26S)-and 22-(3-amino-3,6-dideoxy-β-D-mannopyranose base oxygen base)-1,3,26-trihydroxy-12-methyl isophthalic acid 0-oxo-6,11,28-trioxa three ring [22.3.1.0 5,7] 28 carbon-8,14,16,18,20-pentaene-25-formic acid [CASRN 7681-93-8];
Polyoxin, 5-(2-amino-5-O-carbamoyl-2-deoxidation-L-xylonamide base)-1-(5-carboxyl-1,2,3,4-tetrahydrochysene-2,4-dioxo pyrimidine-1-yl)-1,5-dideoxy-β-D-furans allose aldehydic acid [CASRN 22976-86-9];
Streptomycin, 1,1 '-{ 1-L-(1,3,5/2,4,6)-and 4-[5-deoxidation-2-O-(2-deoxidation-2-methylamino-α-L-glycopyranosyl)-3-C-formoxyl-α-L-furans lysol glycosyl oxygen base]-2,5, the inferior hexamethylene-1 of 6-trihydroxy, the 3-yl } biguanides (J.Am.Chem.Soc., the 69th volume, the 1234th page (1947));
Bitertanol, β-([1,1 '-biphenyl]-4-base oxygen base)-α-(1, the 1-dimethyl ethyl)-1H-1,2,4-triazole-1-ethanol (DE 2324020);
Bromuconazole, 1-[[4-bromo-2-(2,4 dichloro benzene base) tetrahydrochysene-2-furyl] methyl]-1H-[1,2,4]-triazole (Proc.1990Br.Crop.Prot.Conf.-Pests Dis., the 1st volume, the 459th page);
Cyproconazole, 2-(4-chlorphenyl)-3-cyclopropyl-1-[1,2,4] triazol-1-yl fourth-2-alcohol (US 4 664 696);
Difenoconazole, 1-{2-[2-chloro-4-(4-chlorophenoxy) phenyl]-4-methyl-[1,3] dioxolanes-2-ylmethyl }-1H-[1,2,4] triazole (GB-A 2 098 607);
Alkene azoles alcohol, (β E)-β-[(2,4 dichloro benzene base) methylene]-α-(1, the 1-dimethyl ethyl)-1H-1,2,4-triazole-1-ethanol (Noyaku Kagaku, 1983, the 8 volumes, the 575th page);
IMAZALIL, 1-[2-(2,4 dichloro benzene base)-2-(2-propenyloxy group) ethyl]-1H-imidazoles (Fruits, 1973, the 28 volumes, the 545th page);
Oxole bacterium, (2RS, 3SR)-1-[3-(2-chlorphenyl)-2,3-epoxy-2-(4-fluorophenyl) propyl group]-1H-1,2,4-triazole (EP-A 196 038);
RH-7592, α-[2-(4-chlorphenyl) ethyl]-4-benzopyrone H-1,2,4-triazole-1-propionitrile (Proc.1988 Br.Crop Prot.Conf.-Pests Dis., the 1st volume, the 33rd page);
Fluquinconazole, 3-(2,4 dichloro benzene base)-6-fluoro-2-[1,2,4] triazol-1-yl-3H-quinazoline-4-one (Proc.Br.Crop Prot.Conf.-Pests Dis., 5-3,411 (1992));
Flusilazole, 1-{[two (4-fluorophenyl) methyl-monosilane base] methyl }-1H-[1,2,4] triazole (Proc.Br.CropProt.Conf.-Pests Dis., the 1st volume, the 413rd page (1984));
Flutriafol, α-(2-fluorophenyl)-α-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol (EP-A 15 756);
Own azoles alcohol, 2-(2,4 dichloro benzene base)-1-[1,2,4] triazol-1-yl oneself-2-alcohol (CAS RN 79983-71-4); Cycltebuconazole, the 2-[(4-chlorphenyl) methyl]-5-(1-Methylethyl)-1-(1H-1,2,4-triazol-1-yl methyl) cyclopentanol (EP-A 267 778);
Encircle penta azoles bacterium, 5-(4-benzyl chloride base)-2,2-dimethyl-1-[1,2,4] triazol-1-yl methylcyclopentanol (GB 857383);
Nitrile bacterium azoles, 2-(4-chlorphenyl)-2-[1,2,4] triazol-1-yl methyl valeronitrile (CAS RN 88671-89-0);
Penconazole, 1-[2-(2,4 dichloro benzene base) amyl group]-1H-[1,2,4] triazole (Pesticide Manual, the 12nd edition (2000), the 712nd page);
Propiconazole, 1-[[2-(2,4 dichloro benzene base)-4-propyl group-1,3-dioxolanes-2-yl] methyl]-1H-1,2,4-triazole (BE 835 579);
Prochloraz, N-(propyl group-[2-(2,4, the 6-Trichlorophenoxy) ethyl]) imidazoles-1-formamide (US 3 991 071);
Prothioconazoles, 2-[2-(1-chlorine cyclopropyl)-3-(2-chlorphenyl)-2-hydroxypropyl]-2,4-dihydro [1,2,4] triazole-3-thioketones (WO 96/16048);
Simeconazoles, α-(4-fluorophenyl)-α-[(trimethyl silyl) methyl]-1H-1,2,4-triazole-1-ethanol [CAS RN 149508-90-7],
Tebuconazole, 1-(4-chlorphenyl)-4,4-dimethyl-3-[1,2,4] triazol-1-yl methylpent-3-alcohol (EP-A 40345);
Fluorine ether azoles, 1-[2-(2,4 dichloro benzene base)-3-(1,1,2,2-tetrafluoro ethyoxyl) propyl group]-1H-1,2,4-triazole (EP-A 234 242);
Triazolone, 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-2-butanone (BE 793867);
Triadimenol, β-(4-chlorophenoxy)-α-(1, the 1-dimethyl ethyl)-1H-1,2,4-triazole-1-ethanol (DE-A 2,324 010);
Fluorine bacterium azoles, (4-chloro-2-trifluoromethyl)-(2-propoxyl group-1-[1,2,4] the triazol-1-yl ethylidene) amine (JP-A 79/,119 462);
Triticonazole, (5E)-the 5-[(4-chlorphenyl) methylene]-2,2-dimethyl-1-(1H-1,2,4-triazol-1-yl methyl) cyclopentanol (FR 26 41 277);
Different third is fixed, N-isopropyl-3-(3, the 5-dichlorophenyl)-2,4-dioxo alkyl imidazole-1-formamide (GB 13 12536);
Myclozolin, (RS)-3-(3, the 5-dichlorophenyl)-5-methoxy-5-methyl isophthalic acid, 3-oxazolidine-2,4-diketone [CAS RN 54864-61-8];
The sterilization profit, N-(3, the 5-dichlorophenyl)-1,2-dimethylcyclopropane-1,2-dicarboximide (US 3 903090);
Vinclozolin, 3-(3, the 5-dichlorophenyl)-5-methyl-5-Yi Xi Ji oxazolidine-2,4-diketone (DE-A22 07 576);
Ferbam, ferric dimethyl dithiocarbamate (3+) (US 1 972 961);
Dithane A40, ethylene (aminodithioformic acid) disodium (US 2 317 765);
Maneb, ethylene (aminodithioformic acid) manganese (US 2 504 404);
Mancozeb, ethylene (aminodithioformic acid) manganese polymer zinc salt complex (GB 996 264);
Metham-sodium, methyl aminodithioformic acid (US 2 791 605);
Carbatene, ethylene (aminodithioformic acid) zinc ammonate (US 3 248 400);
Propineb, propylidene two (aminodithioformic acid) zinc polymer (BE 611 960);
Polycarbamate, two (the dimethyl dithiocarbamic acid root closes-κ S, κ S ') [μ-[[1,2-ethylene [the aminodithioformic acid root closes-κ S, κ S ']] (2-)]] two [zinc] [CAS RN 64440-88-6];
Tmtd, two (dimethyl thiocarbamoyl) disulphide (DE-A 642 532);
Ziram, dimethyl dithiocarbamate [CAS RN 137-30-4];
Zineb, ethylene (aminodithioformic acid) zinc (US 2 45 7674);
Anilazine, 4,6-two chloro-N-(2-chlorphenyl)-1,3,5-triazines-2-amine (US 2 720 480);
Benomyl, N-butyl-2-acetylamino benzo imidazoles-1-formamide (US 3 631 176);
Boscalid, 2-chloro-N-(4 '-chlordiphenyl-2-yl) vitamin PP (EP-A 545 099);
Carbendazim, (the methyl carbamate (US 3 657 443) of 1H-benzimidazolyl-2 radicals-yl);
Carboxin, 5,6-dihydro-2-methyl-N-phenyl-1,4-oxygen thiapyran-3-formamide (US 3 249 499);
Oxycarboxin, 5,6-dihydro-2-methyl isophthalic acid, 4-oxygen thiapyran-3-formailide 4,4-dioxide (US 3,399 214);
Cyanogen frost azoles, 4-chloro-2-cyano group-N, N-dimethyl-5-(4-aminomethyl phenyl)-1H-imidazoles-1-sulfonamide (CASRN 120116-88-3);
Dazomet, 3,5-dimethyl-1,3,5-thiadiazine alkane-2-thioketones (Bull.Soc.Chim.Fr., the 15th volume, the 891st page (1897));
The difluoro pyrrole swells (diflufenzopyr), 2-{1-[4-(3, the 5-difluorophenyl) semicarbazino] ethyl } nicotinic acid [CASRN 109293-97-2];
The Delan, 5,10-dioxo-5,10-dihydro-naphtho [2,3-b] [1,4] two thiophene English-2,3-dimethoxy nitrile (GB857 383);
The azolactone bacterium, (RS)-3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1,3-oxazolidine-2,4-diketone [CAS RN 131807-57-3];
Fenamidone, (S)-1-anilino--4-methyl-2-methyl mercapto-4-benzylimidazoline-5-ketone [CAS RN161326-34-7];
Fenarimol, α-(2-chlorphenyl)-α-(4-chlorphenyl)-5-rubigan (GB 12 18 623); Furidazol, 2-(2-furyl)-1H-benzimidazole (DE-A 12 09 799);
Flutolanil, α, α, α-three fluoro-3 '-isopropoxy-adjacent toluyl aniline (JP 1104514);
The spirit of furan pyrazoles, 5-chloro-N-(1,3-dihydro-1,1,3-trimethyl-4-isobenzofuran-base)-1,3-dimethyl-1H-pyrazole-4-carboxamide [CAS RN 123572-88-3];
Isoprothiolane, 1, the inferior dithiolane of 3--2-propylmalonic acid diisopropyl ester (Proc.Insectic.Fungic.Conf.8., the 2nd volume, the 715th page (1975));
Third oxygen embroidery amine that goes out, 3 '-isopropoxy-adjacent toluyl aniline (US 3 937 840);
Nuarimol, α-(2-chlorphenyl)-α-(4-fluorophenyl)-5-rubigan (GB 12 18 623);
Fluorine pyrrole bacterium amine (picobenzamid), 2,6-two chloro-N-(3-chloro-5-5-flumethiazine-2-ylmethyl) benzamide (WO 99/42447);
Probenazole, 3-allyloxy-1,2-[4-morpholinodithio 1,1-dioxide (Agric.Biol.Chem., the 37th volume, the 737th page (1973));
The third oxygen quinoline, 6-iodo-2-propoxyl group-3-propyl group quinazoline-4 (3H)-ketone (WO 97/48684);
Pyrifenox, 2 ', 4 '-two chloro-2-(3-pyridine radicals) acetophenones (EZ)-O-methyloxime (EP 49 854);
Pyroquilon, 1,2,5, the 6-nafoxidine is [3,2,1-ij] quinoline-4-ketone (GB 13 94 373) also;
Quinoxyfen, 5,7-two chloro-4-(4-fluorophenoxy) quinoline (US 5 24 0940);
The silicon metsulfovax, N-pi-allyl-4,5-dimethyl-2-(trimethyl silyl) thiophene-3-formamide [CAS RN175217-20-6];
Thiabendazole, 2-(1,3-thiazoles-4-yl) benzimidazole (US 3 017 415);
Thifluzamide, 2 ', 6 '-two bromo-2-methyl-4 '-trifluoromethoxy-4-Trifluoromethyl-1s, 3-thiazole-5-formailide [CAS RN 130000-40-7];
Thiophanate methyl, 1,2-phenylene two (imino group thiocarbonyl) two (carbamic acid methyl ester) (DE-A 19 30540);
Tiadinil, 3 '-chloro-4,4 '-dimethyl-1,2,3-thiadiazoles-5-formailide [CAS RN223580-51-6];
Tricyclazole, 5-methyl isophthalic acid, 2,4-triazol [3,4-b] benzothiazole [CAS RN 41814-78-2];
Triforine, N, N '-{ piperazine-1,4-two bases two [(trichloromethyl) methylene] } diformamide (DE-A 19 01421);
5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazol [1,5-a] pyrimidines (WO98/46607);
Bordeaux mixture, CuSO 4* 3Cu (OH) 2* 3CaSO 4Mixture [CAS RN 8011-63-0];
Schweinfurt green, Cu (OCOCH 3) 2[CAS RN 8011-63-0];
Cupravit, Cu 2Cl (OH) 3[CAS RN 1332-40-7];
Basic copper sulfate, CuSO 4[CAS RN 1344-73-6];
Binapacryl, 3-methylcrotonic acid (RS)-2-sec-butyl-4,6-dinitrophenyl ester [CAS RN 485-31-4];
Karathane, crotonic acid 2,6-dinitro-4-octyl phenyl ester and crotonic acid 2, the mixture of 4-dinitro-6-octyl phenyl ester, wherein " octyl group " is the mixture (US2 526 660) of 1-methylheptyl, 1-ethylhexyl and 1-propyl group amyl group;
Dinobuton, carbonic acid (RS)-2-sec-butyl-4,6-dinitrophenyl isopropyl esters [CAS RN 973-21-7];
Different third disappears (nitrothal-isopropyl), 5-nitroisophthalic acid diisopropyl ester (Proc.Br.Insectic.Fungic.Conf.7., the 2nd volume, the 673rd page (1973));
Fenpiclonil, 4-(2, the 3-dichlorophenyl)-1H-pyrroles-3-formonitrile HCN (Proc.1988Br.Crop Prot.Conf.-Pests Dis., the 1st volume, the 65th page);
Fu Evil bacterium, 4-(2,2-difluoro benzo [1,3] Dioxol-4-yl)-1H-pyrroles-3-formonitrile HCN (ThePesticide Manual, publ.The British Crop Protection Council, the 10th edition, 1995, the 482 pages);
The thiadiazoles element, 1,2,3-diazosulfide-7-carbithionic acid methyl ester [CAS RN 135158-54-2];
Benzene metsulfovax (benthiavalicarb), (S)-1-[(1R)-1-(6-fluoro benzothiazole-2-yl) ethylamino formoxyl]-the 2-methyl-propyl } carbamic acid isopropyl ester (JP-A 09/,323 984);
Carpropamide, 2,2-two chloro-N-[1-(4-chlorphenyl) ethyl]-1-ethyl-3-methyl cyclopropane formamide [CAS RN 104030-54-8];
Tpn, 2,4,5,6-termil (US 3 290 353);
Cyflufenamid, (Z)-N-[α-(cyclopropyl methoxyimino)-2,3--two fluoro-6-(trifluoromethyl) benzyls]-2-phenyl-acetamides (WO 96/19442);
Cymoxanil, 1-(2-cyano group-2-methoxyimino acetyl group)-3-ethyl carbamide (US 3 957 847);
Diclomezine, 6-(3,5-dichlorophenyl p-methylphenyl) pyridazine-3 (2H)-ketone (US 4 052 395);
Two chlorine zarilamids, (RS)-2-cyano group-N-[(R)-1-(2,4 dichloro benzene base) ethyl]-3,3-amide dimethyl butyrate [CAS RN 139920-32-4];
The mould prestige of second, 3,4-diethoxybenzene amido formic acid isopropyl esters (EP-A 78 663);
Hinosan, phosphonodithioic acid O-ethyl S, S-diphenyl (DE-A 14 93 736);
Guardian, N-(cyano group-2-thienyl methyl)-4-ethyl-2-(ethylamino)-5-thiazole carboxamides (EP-A639 574);
Fenhexamid, N-(2,3-two chloro-4-hydroxy phenyls)-1-hexahydrotoluene formamide (Proc.Br.CropProt.Conf.-Pests Dis., 1998, the 2 volumes, the 327th page);
Fentinacetate, fentinacetate (US 3 499 086);
Zarilamid, N-(1-cyano group-1,2-dimethyl propyl)-2-(2,4 dichloro benzene oxygen base) propionamide (EP-A262 393);
Ferimzone, (Z)-2 '-methyl acetophenone-4,6-dimethyl pyrimidine-2-base hydrazone [CAS RN 89269-64-7];
Fluazinam, 3-chloro-N-[3-chloro-2,6-dinitro-4-(trifluoromethyl) phenyl]-5-(trifluoromethyl)-2-pyridine amine (The Pesticide Manual, publ.The British Crop Protection Council, the 10th edition (1995), the 474th page);
Fosetyl, ethyl phosphine aluminium, phosphinic acid ethyl ester (FR 22 54 276);
Iprovalicarb, [(1S)-and 2-methyl 1-(1-p-methylphenyl ethylamino formoxyl) propyl group] carbamic acid isopropyl ester (EP-A 472 996);
Hexachloro-benzene (C.R.Seances Acad.Agric.Fr., the 31st volume, the 24th page (1945));
Mandipropamid amine, (RS)-2-(4-chlorphenyl)-N-[3-methoxyl group-4-(Propargyl oxygen base) phenethyl]-2-(Propargyl oxygen base) acetamide (WO 03/042166);
Metrafenone, 3 '-bromo-2,3,4,6 '-tetramethoxy-2 ', 6-dimethyl benzophenone (US 5 945 567);
Pencycuron, 1-(4-benzyl chloride base)-1-cyclopenta-3-phenylurea (DE-A 27 32 257);
The pyrrole metsulfovax, (RS)-N-[2-(1, the 3-dimethylbutyl)-3-thienyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide (JP 10/130268);
Hundred dimension spirits, 3-(dimethylamino) propyl carbamic acid propyl ester (DE-A 15 67 169);
Rabcide (DE-A 16 43 347);
Tolelofos-methyl, phosphonothiolic acid O-2,6-dichloro-p-toluene base O, O-dimethyl esters (GB 14 67 561);
Pcnb, pcnb (DE-A 682 048);
Zoxamide, (RS)-3,5-two chloro-N-(3-chloro-1-ethyl-1-methyl-2-oxopropyl)-to toluamide [CAS RN 156052-68-5];
Difoltan, N-(1,1,2,2-tetrachloro ethylmercapto group) hexamethylene-4-alkene-1,2-dicarboximide (Phytopathology, the 52nd volume, the 754th page (1962));
Captan, N-(trichloro-methylthio) hexamethylene-4-alkene-1,2-dicarboximide (US 2 553 770);
Euparen, N-dichloro one fluorine methyl mercapto-N ', N '-dimethyl-N-phenyl-sulfamide (DE-A 11 93 498);
Folpet, N-(trichloro-methylthio) phthalimide (US 2 553 770);
Tolyfluanid, N-dichloro one fluorine methyl mercapto-N ', N '-dimethyl-N-p-methylphenyl sulfonamide (DE-A11 93 498);
Dimethomorph, 3-(4-chlorphenyl)-3-(3, the 4-Dimethoxyphenyl)-1-morpholine-4-base propenone (EP-A 120321);
Fluorine biphenyl bacterium, 2-(3, the 4-Dimethoxyphenyl)-N-ethyl-α, α, α-three fluoro-N-methyl is to toluamide [AGROW no.243,22 (1995)];
Flumorph, 3-(4-fluorophenyl)-3-(3, the 4-Dimethoxyphenyl)-1-morpholine-4-base propenone (EP-A 860438);
N-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide (WO 03/66610)
N-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide and N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide (WO 03/70705);
N-(2-cyano-phenyl)-3,4-two chloroisothiazoles-5-formamide (WO 99/24413);
N-(2-(4-[3-(4-chlorphenyl) Propargyl oxygen base]-3-methoxyphenyl) ethyl)-2-methanesulfonamido-3-methylbutyryl amine, N-(2-(4-[3-(4-chlorphenyl) Propargyl oxygen base]-the 3-methoxyphenyl) ethyl)-2-second sulfonamido-3-methylbutyryl amine (WO 04/49804);
3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazole alkane-3-yl] pyridine (EP-A 10 35 122); 2-butoxy-6-iodo-3-propyl group chromene-4-ketone (WO 03/14103);
N, N-dimethyl-3-(3-bromo-6-fluoro-2 methyl indole-1-sulfonyl)-[1,2,4] triazole-1-sulfonamide (EP-A1031571);
(2-chloro-5-[1-(3-methyl benzyloxy imino) ethyl] benzyl) methyl carbamate, (2-chloro-5-[1-(6-picoline-2-base methoxyimino) ethyl] benzyl) methyl carbamate (EP-A 12 01 648);
3-(4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) methyl propionate (EP-A 10 28125);
The nitrile Fluoxastrobin, 2-{2-[6-(2-cyano group-1-vinyl penta-1,3-diene oxygen base) pyrimidine-4-base oxygen base] phenyl }-3-methoxy-methyl acrylate (EP-A 382 375),
Ether bacterium amine, (E)-2-(methoxyimino)-N-methyl-2-[α-(2, the 5-xylyloxy)-o-tolyl] acetamide (EP-A 477 631);
Fluoxastrobin, (E)-2-[6-(2-chlorophenoxy)-5-fluorine pyrimidine-4-base oxygen base] phenyl } (5,6-dihydro-1,4,2-dioxazine-3-yl) ketone O-methyloxime (WO 97/27189);
The imines bacterium, (E)-methoxyimino [α-(oxy-o-cresyl)-o-tolyl] methyl acetate (EP-A 253 213); Fork phenalgin acid amides, (E)-2-(methoxyimino)-N-methyl-2-(2-Phenoxyphenyl) acetamide (EP-A 398692);
Orysastrobin, (2E)-2-(methoxyimino)-2-{2-[(3E, 5E, 6E)-and 5-(methoxyimino)-4,6-dimethyl-2,8-two oxa-s-3, the 7-diaza ninth of the ten Heavenly Stems-3,6-diene-1-yl] phenyl }-N-methylacetamide (WO97/15552);
ZEN 90160,3-methoxyl group-2-[2-(6-5-flumethiazine-2-base oxygen ylmethyl) phenyl] methyl acrylate (EP-A 278 595);
Pyraclostrobin, N-{2-[1-(4-chlorphenyl)-1H-pyrazole-3-yl oxygen ylmethyl] phenyl } (N-methoxyl group) methyl carbamate (WO 96/01256);
Oxime bacterium ester, (E)-methoxyimino-(E)-α-[1-(α, α, tolyl between α-three fluoro-) ethyleneimino oxygen base]-o-tolyl } methyl acetate (EP-A 460 575);
2-[neighbour-(2,5-dimethyl phenoxy methylene) phenyl]-3-methoxy-methyl acrylate (EP-A 226917);
5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazol [1,5-a] pyrimidines (WO98/46608);
3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide (WO 99/24413),
Formula III compound (WO 04/049804);
N-(2-(4-[3-(4-chlorphenyl) Propargyl oxygen base]-3-methoxyphenyl) ethyl)-2-methanesulfonamido-3-methylbutyryl amine and N-(2-(4-[3-(4-chlorphenyl) Propargyl oxygen base]-the 3-methoxyphenyl) ethyl)-2-second sulfonamido-3-methylbutyryl amine (WO 03/66609);
2-butoxy-6-iodo-3-propyl group chromene-4-ketone (WO 03/14103);
N, N-dimethyl-3-(3-bromo-6-fluoro-2 methyl indole-1-sulfonyl)-[1,2,4] triazole-1-sulfonamide (WO03/053145);
3-(4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) methyl propionate (EP-A1028125).
For the rate of application that reduces reactive compound I and II and widen its activity profile, the purpose of this invention is to provide under total amount of application of reactive compound reduces harmful fungoid, especially have and improve active mixture for some indication.
Therefore we found that this purpose is realized by the mixture of defined reactive compound I of beginning and II.In addition, we find to compare with the unification compound, simultaneously, i.e. associating or at least a Compound I of separate administration and at least a reactive compound II or administered compound I and at least a reactive compound II can prevent and treat harmful fungoid (Synergistic mixture) better successively.
Compound I can be as the synergetic effect additive of a large amount of different Fungicidal active compounds.Simultaneously, promptly associating or separate administration Compound I and at least a reactive compound II are super adds and ground has increased Fungicidally active.
Compound I may may exist by different crystal formations with various biologically actives.
In formula I, halogen is fluorine, chlorine, bromine or iodine, preferred fluorine or chlorine;
C 1-C 4Alkyl is methyl, ethyl, n-pro-pyl, 1-Methylethyl, normal-butyl, 1-methyl-propyl, 2-methyl-propyl or 1,1-dimethyl ethyl, preferable methyl or ethyl;
C 1-C 4Haloalkyl is the C of halo partially or completely 1-C 4Alkyl, wherein halogen atom especially is fluorine, chlorine and/or bromine, i.e. for example chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, methyl fluoride, difluoromethyl, trifluoromethyl, chlorine methyl fluoride, dichloro one methyl fluoride, a chlorodifluoramethyl-, 1-chloroethyl, 1-bromoethyl, 1-fluoro ethyl, 2-fluoro ethyl, 2,2-two fluoro ethyls, 2,2,2-trifluoroethyl, 2-chloro-2-fluoro ethyl, 2-chloro-2,2-two fluoro ethyls, 2,2-two chloro-2-fluoro ethyls, 2,2,2-three chloroethyls, pentafluoroethyl group, seven fluoropropyls or nine fluorine butyl, especially halogenated methyls, preferred especially CH 2-Cl, CH (Cl) 2, CH 2-F, CHF 2, CF 3, CHFCl, CF 2Cl or CF (Cl) 2, CHF especially 2Or CF 3
C 1-C 4Alkoxyl is OCH 3, OC 2H 5, OCH 2-C 2H 5, OCH (CH 3) 2, n-butoxy, OCH (CH 3)-C 2H 5, OCH 2-CH (CH 3) 2Or OC (CH 3) 3, preferred OCH 3Or OC 2H 5
C 1-C 4Halogenated alkoxy is the C of halo partially or completely 1-C 4Alkoxyl, wherein halogen atom especially is a fluorine, chlorine and/or bromine, i.e. chlorine methoxyl group for example, the bromine methoxyl group, the dichloro methoxyl group, the trichlorine methoxyl group, the fluorine methoxyl group, difluoro-methoxy, trifluoromethoxy, chlorine fluorine methoxyl group, dichloro one fluorine methoxyl group, one chlorine difluoro-methoxy, the 1-chloroethoxy, the 1-bromine oxethyl, 1-fluorine ethyoxyl, 2-fluorine ethyoxyl, 2, the 2-difluoroethoxy, 2,2, the 2-trifluoro ethoxy, 2-chloro-2-fluorine ethyoxyl, 2-chloro-2, the 2-difluoroethoxy, 2,2-two chloro-2-fluorine ethyoxyls, 2,2,2-three chloroethoxies, five fluorine ethyoxyls, seven fluorine propoxyl group or nine fluorine butoxy, especially halogenated methoxies, preferred especially OCH 2-Cl, OCH (Cl) 2, OCH 2-F, OCH (F) 2, OCF 3, OCHFCl, OCF 2Cl or OCF (Cl) 2
C 1-C 4Alkylthio group is SCH 3, SC 2H 5, SCH 2-C 2H 5, SCH (CH 3) 2, positive butylthio, SCH (CH 3)-C 2H 5, SCH 2-CH (CH 3) 2Or SC (CH 3) 3, preferred SCH 3Or SC 2H 5
Preferred 1-methyl-pyrazol-4-yl carboxylic acid anilides I is that wherein X is those of oxygen on the one hand.
On the other hand, preferred compound I is that wherein X is those of sulphur.
For mixture of the present invention, preferred R wherein 1Be methyl or halogenated methyl, especially CH 3, CHF 2, CH 2F, CF 3, CHFCl or CF 2The formula I compound of Cl.
Preferred R wherein in addition 2Compound I for hydrogen, fluorine or chlorine, especially hydrogen.
Preferred R wherein in addition 3Be halogen, C 1-C 4Alkyl, C 1-C 4Haloalkyl, C 1-C 4Alkoxyl, C 1-C 4Halogenated alkoxy or C 1-C 4Alkylthio group, preferred halogen, methyl, halogenated methyl, methoxyl group, halogenated methoxy or methyl mercapto, especially F, Cl, CH 3, CF 3, OCH 3, OCHF 2, OCF 3Or SCH 3, those Compound I of preferred especially fluorine.
Preferred R wherein in addition 4Be halogen, especially those Compound I of fluorine.
Preferred R wherein in addition 5Be halogen, especially those Compound I of fluorine.
The wherein X that especially preferably is listed in the table below in 1 is the Compound I of oxygen.
Table 1
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
1 CH 3 H 2-F 3-F 4-F
2 CH 3 H 2-F 3-F 5-F
3 CH 3 H 2-F 4-F 5-F
4 CH 3 H 2-F 4-F 6-F
5 CH 3 H 3-F 4-F 5-F
6 CH 3 H 3-F 5-F 6-F
7 CH 2F H 2-F 3-F 4-F
8 CH 2F H 2-F 3-F 5-F
9 CH 2F H 2-F 4-F 5-F
10 CH 2F H 2-F 4-F 6-F
11 CH 2F H 3-F 4-F 5-F
12 CH 2F H 3-F 5-F 6-F
13 CHF 2 H 2-F 3-F 4-F
14 CHF 2 H 2-F 3-F 5-F
15 CHF 2 H 2-F 4-F 5-F
16 CHF 2 H 2-F 4-F 6-F
17 CHF 2 H 3-F 4-F 5-F
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [C]
18 CHF 2 H 3-F 5-F 6-F
19 CF 3 H 2-F 3-F 4-F
20 CF 3 H 2-F 3-F 5-F
21 CF 3 H 2-F 4-F 5-F
22 CF 3 H 2-F 4-F 6-F
23 CF 3 H 3-F 4-F 5-F
24 CF 3 H 3-F 5-F 6-F
25 CHFCl H 2-F 3-F 4-F
26 CHFCl H 2-F 3-F 5-F
27 CHFCl H 2-F 4-F 5-F
28 CHFCl H 2-F 4-F 6-F
29 CHFCl H 3-F 4-F 5-F
30 CHFCl H 3-F 5-F 6-F
31 CF 2Cl H 2-F 3-F 4-F
32 CF 2Cl H 2-F 3-F 5-F
33 CF 2Cl H 2-F 4-F 5-F
34 CF 2Cl H 2-F 4-F 6-F
35 CF 2Cl H 3-F 4-F 5-F
36 CF 2Cl H 3-F 5-F 6-F
37 CH 3 F 2-F 3-F 4-F
38 CH 3 F 2-F 3-F 5-F
39 CH 3 F 2-F 4-F 5-F
40 CH 3 F 2-F 4-F 6-F
41 CH 3 F 3-F 4-F 5-F
42 CH 3 F 3-F 5-F 6-F
43 CH 2F F 2-F 3-F 4-F
44 CH 2F F 2-F 3-F 5-F
45 CH 2F F 2-F 4-F 5-F
46 CH 2F F 2-F 4-F 6-F
47 CH 2F F 3-F 4-F 5-F
48 CH 2F F 3-F 5-F 6-F
49 CHF 2 F 2-F 3-F 4-F
50 CHF 2 F 2-F 3-F 5-F
51 CHF 2 F 2-F 4-F 5-F
52 CHF 2 F 2-F 4-F 6-F
53 CHF 2 F 3-F 4-F 5-F
54 CHF 2 F 3-F 5-F 6-F
55 CF 3 F 2-F 3-F 4-F
56 CF 3 F 2-F 3-F 5-F
57 CF 3 F 2-F 4-F 5-F
58 CF 3 F 2-F 4-F 6-F
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
59 CF 3 F 3-F 4-F 5-F
60 CF 3 F 3-F 5-F 6-F
61 CHFCl F 2-F 3-F 4-F
62 CHFCl F 2-F 3-F 5-F
63 CHFCl F 2-F 4-F 5-F
64 CHFCl F 2-F 4-F 6-F
65 CHFCl F 3-F 4-F 5-F
66 CHFCl F 3-F 5-F 6-F
67 CF 2Cl F 2-F 3-F 4-F
68 CF 2Cl F 2-F 3-F 5-F
69 CF 2Cl F 2-F 4-F 5-F
70 CF 2Cl F 2-F 4-F 6-F
71 CF 2Cl F 3-F 4-F 5-F
72 CF 2Cl F 3-F 5-F 6-F
73 CH 3 Cl 2-F 3-F 4-F
74 CH 3 Cl 2-F 3-F 5-F
75 CH 3 Cl 2-F 4-F 5-F
76 CH 3 Cl 2-F 4-F 6-F
77 CH 3 Cl 3-F 4-F 5-F
78 CH 3 Cl 3-F 5-F 6-F
79 CH 2F Cl 2-F 3-F 4-F
80 CH 2F Cl 2-F 3-F 5-F
81 CH 2F Cl 2-F 4-F 5-F
82 CH 2F Cl 2-F 4-F 6-F
83 CH 2F Cl 3-F 4-F 5-F
84 CH 2F Cl 3-F 5-F 6-F
85 CHF 2 Cl 2-F 3-F 4-F
86 CHF 2 Cl 2-F 3-F 5-F
87 CHF 2 Cl 2-F 4-F 5-F
88 CHF 2 Cl 2-F 4-F 6-F
89 CHF 2 Cl 3-F 4-F 5-F
90 CHF 2 Cl 3-F 5-F 6-F
91 CF 3 Cl 2-F 3-F 4-F
92 CF 3 Cl 2-F 3-F 5-F
93 CF 3 Cl 2-F 4-F 5-F
94 CF 3 Cl 2-F 4-F 6-F
95 CF 3 Cl 3-F 4-F 5-F
96 CF 3 Cl 3-F 5-F 6-F
97 CHFCl Cl 2-F 3-F 4-F
98 CHFCl Cl 2-F 3-F 5-F
99 CHFCl Cl 2-F 4-F 5-F
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
100 CHFCl Cl 2-F 4-F 6-F
101 CHFCl Cl 3-F 4-F 5-F
102 CHFCl Cl 3-F 5-F 6-F
103 CF 2Cl Cl 2-F 3-F 4-F
104 CF 2Cl Cl 2-F 3-F 5-F
105 CF 2Cl Cl 2-F 4-F 5-F
106 CF 2Cl Cl 2-F 4-F 6-F
107 CF 2Cl Cl 3-F 4-F 5-F
108 CF 2Cl Cl 3-F 5-F 6-F
In addition, the 1-methyl-pyrazol-4-yl carboxylic acid anilides of special preferred formula Ia (I, X=O wherein, R 1=CF 3And R 2=H):
Figure A20068002894400251
Especially Ia.1-Ia.1009 in 2 is listed in the table below:
Table 2:
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.1 CF 3 H The 2-fluorine The 3-fluorine The 4-fluorine 123-125
Ia.2 CF 3 H The 2-fluorine 3-chlorine The 4-fluorine
Ia.3 CF 3 H The 2-fluorine 3-CN The 4-fluorine
Ia.4 CF 3 H The 2-fluorine The 3-methyl The 4-fluorine
Ia.5 CF 3 H The 2-fluorine 3-CF 3 The 4-fluorine
Ia.6 CF 3 H The 2-fluorine 3-OCH 3 The 4-fluorine
Ia.7 CF 3 H The 2-fluorine 3-OCF 3 The 4-fluorine
Ia.8 CF 3 H 2-chlorine The 3-fluorine The 4-fluorine
Ia.9 CF 3 H 2-chlorine 3-chlorine The 4-fluorine
Ia.10 CF 3 H 2-chlorine 3-CN The 4-fluorine
Ia.11 CF 3 H 2-chlorine The 3-methyl The 4-fluorine
Ia.12 CF 3 H 2-chlorine 3-CF 3 The 4-fluorine
Ia.13 CF 3 H 2-chlorine 3-OCH 3 The 4-fluorine
Ia.14 CF 3 H 2-chlorine 3-OCF 3 The 4-fluorine
Ia.15 CF 3 H 2-CN The 3-fluorine The 4-fluorine
Ia.16 CF 3 H 2-CN 3-chlorine The 4-fluorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.17 CF 3 H 2-CN 3-CN The 4-fluorine
Ia.18 CF 3 H 2-CN The 3-methyl The 4-fluorine
Ia.19 CF 3 H 2-CN 3-CF 3 The 4-fluorine
Ia.20 CF 3 H 2-CN 3-OCH 3 The 4-fluorine
Ia.21 CF 3 H 2-CN 3-OCF 3 The 4-fluorine
Ia.22 CF 3 H The 2-methyl The 3-fluorine The 4-fluorine
Ia.23 CF 3 H The 2-methyl 3-chlorine The 4-fluorine
Ia.24 CF 3 H The 2-methyl 3-CN The 4-fluorine
Ia.25 CF 3 H The 2-methyl The 3-methyl The 4-fluorine
Ia.26 CF 3 H The 2-methyl 3-CF 3 The 4-fluorine
Ia.27 CF 3 H The 2-methyl 3-OCH 3 The 4-fluorine
Ia.28 CF 3 H The 2-methyl 3-OCF 3 The 4-fluorine
Ia.29 CF 3 H 2-CF 3 The 3-fluorine The 4-fluorine
Ia.30 CF 3 H 2-CF 3 3-chlorine The 4-fluorine
Ia.31 CF 3 H 2-CF 3 3-CN The 4-fluorine
Ia.32 CF 3 H 2-CF 3 The 3-methyl The 4-fluorine
Ia.33 CF 3 H 2-CF 3 3-CF 3 The 4-fluorine
Ia.34 CF 3 H 2-CF 3 3-OCH 3 The 4-fluorine
Ia.35 CF 3 H 2-CF 3 3-OCF 3 The 4-fluorine
Ia.36 CF 3 H 2-OCH 3 The 3-fluorine The 4-fluorine
Ia.37 CF 3 H 2-OCH 3 3-chlorine The 4-fluorine
Ia.38 CF 3 H 2-OCH 3 3-CN The 4-fluorine
Ia.39 CF 3 H 2-OCH 3 The 3-methyl The 4-fluorine
Ia.40 CF 3 H 2-OCH 3 3-CF 3 The 4-fluorine
Ia.41 CF 3 H 2-OCH 3 3-OCH 3 The 4-fluorine
Ia.42 CF 3 H 2-OCH 3 3-OCF 3 The 4-fluorine
Ia.43 CF 3 H 2-OCF 3 The 3-fluorine The 4-fluorine
Ia.44 CF 3 H 2-OCF 3 3-chlorine The 4-fluorine
Ia.45 CF 3 H 2-OCF 3 3-CN The 4-fluorine
Ia.46 CF 3 H 2-OCF 3 The 3-methyl The 4-fluorine
Ia.47 CF 3 H 2-OCF 3 3-CF 3 The 4-fluorine
Ia.48 CF 3 H 2-OCF 3 3-OCH 3 The 4-fluorine
Ia.49 CF 3 H 2-OCF 3 3-OCF 3 The 4-fluorine
Ia.50 CF 3 H The 2-fluorine The 3-fluorine 4-chlorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.51 CF 3 H The 2-fluorine 3-chlorine 4-chlorine
Ia.52 CF 3 H The 2-fluorine 3-CN 4-chlorine
Ia.53 CF 3 H The 2-fluorine The 3-methyl 4-chlorine
Ia.54 CF 3 H The 2-fluorine 3-CF 3 4-chlorine
Ia.55 CF 3 H The 2-fluorine 3-OCH 3 4-chlorine
Ia.56 CF 3 H The 2-fluorine 3-OCF 3 4-chlorine
Ia.57 CF 3 H 2-chlorine The 3-fluorine 4-chlorine
Ia.58 CF 3 H 2-chlorine 3-chlorine 4-chlorine
Ia.59 CF 3 H 2-chlorine 3-CN 4-chlorine
Ia.60 CF 3 H 2-chlorine The 3-methyl 4-chlorine
Ia.61 CF 3 H 2-chlorine 3-CF 3 4-chlorine
Ia.62 CF 3 H 2-chlorine 3-OCH 3 4-chlorine
Ia.63 CF 3 H 2-chlorine 3-OCF 3 4-chlorine
Ia.64 CF 3 H 2-CN The 3-fluorine 4-chlorine
Ia.65 CF 3 H 2-CN 3-chlorine 4-chlorine
Ia.66 CF 3 H 2-CN 3-CN 4-chlorine
Ia.67 CF 3 H 2-CN The 3-methyl 4-chlorine
Ia.68 CF 3 H 2-CN 3-CF 3 4-chlorine
Ia.69 CF 3 H 2-CN 3-OCH 3 4-chlorine
Ia.70 CF 3 H 2-CN 3-OCF 3 4-chlorine
Ia.71 CF 3 H The 2-methyl The 3-fluorine 4-chlorine
Ia.72 CF 3 H The 2-methyl 3-chlorine 4-chlorine
Ia.73 CF 3 H The 2-methyl 3-CN 4-chlorine
Ia.74 CF 3 H The 2-methyl The 3-methyl 4-chlorine
Ia.75 CF 3 H The 2-methyl 3-CF 3 4-chlorine
Ia.76 CF 3 H The 2-methyl 3-OCH 3 4-chlorine
Ia.77 CF 3 H The 2-methyl 3-OCF 3 4-chlorine
Ia.78 CF 3 H 2-CF 3 The 3-fluorine 4-chlorine
Ia.79 CF 3 H 2-CF 3 3-chlorine 4-chlorine
Ia.80 CF 3 H 2-CF 3 3-CN 4-chlorine
Ia.81 CF 3 H 2-CF 3 The 3-methyl 4-chlorine
Ia.82 CF 3 H 2-CF 3 3-CF 3 4-chlorine
Ia.83 CF 3 H 2-CF 3 3-OCH 3 4-chlorine
Ia.84 CF 3 H 2-CF 3 3-OCF 3 4-chlorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.85 CF 3 H 2-OCH 3 The 3-fluorine 4-chlorine
Ia.86 CF 3 H 2-OCH 3 3-chlorine 4-chlorine
Ia.87 CF 3 H 2-OCH 3 3-CN 4-chlorine
Ia.88 CF 3 H 2-OCH 3 The 3-methyl 4-chlorine
Ia.89 CF 3 H 2-OCH 3 3-CF 3 4-chlorine
Ia.90 CF 3 H 2-OCH 3 3-OCH 3 4-chlorine
Ia.91 CF 3 H 2-OCH 3 3-OCF 3 4-chlorine
Ia.92 CF 3 H 2-OCF 3 The 3-fluorine 4-chlorine
Ia.93 CF 3 H 2-OCF 3 3-chlorine 4-chlorine
Ia.94 CF 3 H 2-OCF 3 3-CN 4-chlorine
Ia.95 CF 3 H 2-OCF 3 The 3-methyl 4-chlorine
Ia.96 CF 3 H 2-OCF 3 3-CF 3 4-chlorine
Ia.97 CF 3 H 2-OCF 3 3-OCH 3 4-chlorine
Ia.98 CF 3 H 2-OCF 3 3-OCF 3 4-chlorine
Ia.99 CF 3 H The 2-fluorine The 3-fluorine 4-CN
Ia.100 CF 3 H The 2-fluorine 3-chlorine 4-CN
Ia.101 CF 3 H The 2-fluorine 3-CN 4-CN
Ia.102 CF 3 H The 2-fluorine The 3-methyl 4-CN
Ia.103 CF 3 H The 2-fluorine 3-CF 3 4-CN
Ia.104 CF 3 H The 2-fluorine 3-OCH 3 4-CN
Ia.105 CF 3 H The 2-fluorine 3-OCF 3 4-CN
Ia.106 CF 3 H 2-chlorine The 3-fluorine 4-CN
Ia.107 CF 3 H 2-chlorine 3-chlorine 4-CN
Ia.108 CF 3 H 2-chlorine 3-CN 4-CN
Ia.109 CF 3 H 2-chlorine The 3-methyl 4-CN
Ia.110 CF 3 H 2-chlorine 3-CF 3 4-CN
Ia.111 CF 3 H 2-chlorine 3-OCH 3 4-CN
Ia.112 CF 3 H 2-chlorine 3-OCF 3 4-CN
Ia.113 CF 3 H 2-CN The 3-fluorine 4-CN
Ia.114 CF 3 H 2-CN 3-chlorine 4-CN
Ia.115 CF 3 H 2-CN 3-CN 4-CN
Ia.116 CF 3 H 2-CN The 3-methyl 4-CN
Ia.117 CF 3 H 2-CN 3-CF 3 4-CN
Ia.118 CF 3 H 2-CN 3-OCH 3 4-CN
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.119 CF 3 H 2-CN 3-OCF 3 4-CN
Ia.120 CF 3 H The 2-methyl The 3-fluorine 4-CN
Ia.121 CF 3 H The 2-methyl 3-chlorine 4-CN
Ia.122 CF 3 H The 2-methyl 3-CN 4-CN
Ia.123 CF 3 H The 2-methyl The 3-methyl 4-CN
Ia.124 CF 3 H The 2-methyl 3-CF 3 4-CN
Ia.125 CF 3 H The 2-methyl 3-OCH 3 4-CN
Ia.126 CF 3 H The 2-methyl 3-OCF 3 4-CN
Ia.127 CF 3 H 2-CF 3 The 3-fluorine 4-CN
Ia.128 CF 3 H 2-CF 3 3-chlorine 4-CN
Ia.129 CF 3 H 2-CF 3 3-CN 4-CN
Ia.130 CF 3 H 2-CF 3 The 3-methyl 4-CN
Ia.131 CF 3 H 2-CF 3 3-CF 3 4-CN
Ia.132 CF 3 H 2-CF 3 3-OCH 3 4-CN
Ia.133 CF 3 H 2-CF 3 3-OCF 3 4-CN
Ia.134 CF 3 H 2-OCH 3 The 3-fluorine 4-CN
Ia.135 CF 3 H 2-OCH 3 3-chlorine 4-CN
Ia.136 CF 3 H 2-OCH 3 3-CN 4-CN
Ia.137 CF 3 H 2-OCH 3 The 3-methyl 4-CN
Ia.138 CF 3 H 2-OCH 3 3-CF 3 4-CN
Ia.139 CF 3 H 2-OCH 3 3-OCH 3 4-CN
Ia.140 CF 3 H 2-OCH 3 3-OCF 3 4-CN
Ia.141 CF 3 H 2-OCF 3 The 3-fluorine 4-CN
Ia.142 CF 3 H 2-OCF 3 3-chlorine 4-CN
Ia.143 CF 3 H 2-OCF 3 3-CN 4-CN
Ia.144 CF 3 H 2-OCF 3 The 3-methyl 4-CN
Ia.145 CF 3 H 2-OCF 3 3-CF 3 4-CN
Ia.146 CF 3 H 2-OCF 3 3-OCH 3 4-CN
Ia.147 CF 3 H 2-OCF 3 3-OCF 3 4-CN
Ia.148 CF 3 H The 2-fluorine The 3-fluorine The 4-methyl
Ia.149 CF 3 H The 2-fluorine 3-chlorine The 4-methyl
Ia.150 CF 3 H The 2-fluorine 3-CN The 4-methyl
Ia.151 CF 3 H The 2-fluorine The 3-methyl The 4-methyl
Ia.152 CF 3 H The 2-fluorine 3-CF 3 The 4-methyl
Ia.153 CF 3 H The 2-fluorine 3-OCH 3 The 4-methyl
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.154 CF 3 H The 2-fluorine 3-OCF 3 The 4-methyl
Ia.155 CF 3 H 2-chlorine The 3-fluorine The 4-methyl
Ia.156 CF 3 H 2-chlorine 3-chlorine The 4-methyl
Ia.157 CF 3 H 2-chlorine 3-CN The 4-methyl
Ia.158 CF 3 H 2-chlorine The 3-methyl The 4-methyl
Ia.159 CF 3 H 2-chlorine 3-CF 3 The 4-methyl
Ia.160 CF 3 H 2-chlorine 3-OCH 3 The 4-methyl
Ia.161 CF 3 H 2-chlorine 3-OCF 3 The 4-methyl
Ia.162 CF 3 H 2-CN The 3-fluorine The 4-methyl
Ia.163 CF 3 H 2-CN 3-chlorine The 4-methyl
Ia.164 CF 3 H 2-CN 3-CN The 4-methyl
Ia.165 CF 3 H 2-CN The 3-methyl The 4-methyl
Ia.166 CF 3 H 2-CN 3-CF 3 The 4-methyl
Ia.167 CF 3 H 2-CN 3-OCH 3 The 4-methyl
Ia.168 CF 3 H 2-CN 3-OCF 3 The 4-methyl
Ia.169 CF 3 H The 2-methyl The 3-fluorine The 4-methyl
Ia.170 CF 3 H The 2-methyl 3-chlorine The 4-methyl
Ia.171 CF 3 H The 2-methyl 3-CN The 4-methyl
Ia.172 CF 3 H The 2-methyl The 3-methyl The 4-methyl
Ia.173 CF 3 H The 2-methyl 3-CF 3 The 4-methyl
Ia.174 CF 3 H The 2-methyl 3-OCH 3 The 4-methyl
Ia.175 CF 3 H The 2-methyl 3-OCF 3 The 4-methyl
Ia.176 CF 3 H 2-CF 3 The 3-fluorine The 4-methyl
Ia.177 CF 3 H 2-CF 3 3-chlorine The 4-methyl
Ia.178 CF 3 H 2-CF 3 3-CN The 4-methyl
Ia.179 CF 3 H 2-CF 3 The 3-methyl The 4-methyl
Ia.180 CF 3 H 2-CF 3 3-CF 3 The 4-methyl
Ia.181 CF 3 H 2-CF 3 3-OCH 3 The 4-methyl
Ia.182 CF 3 H 2-CF 3 3-OCF 3 The 4-methyl
Ia.183 CF 3 H 2-OCH 3 The 3-fluorine The 4-methyl
Ia.184 CF 3 H 2-OCH 3 3-chlorine The 4-methyl
Ia.185 CF 3 H 2-OCH 3 3-CN The 4-methyl
Ia.186 CF 3 H 2-OCH 3 The 3-methyl The 4-methyl
Ia.187 CF 3 H 2-OCH 3 3-CF 3 The 4-methyl
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.188 CF 3 H 2-OCH 3 3-OCH 3 The 4-methyl
Ia.189 CF 3 H 2-OCH 3 3-OCF 3 The 4-methyl
Ia.190 CF 3 H 2-OCF 3 The 3-fluorine The 4-methyl
Ia.191 CF 3 H 2-OCF 3 3-chlorine The 4-methyl
Ia.192 CF 3 H 2-OCF 3 3-CN The 4-methyl
Ia.193 CF 3 H 2-OCF 3 The 3-methyl The 4-methyl
Ia.194 CF 3 H 2-OCF 3 3-CF 3 The 4-methyl
Ia.195 CF 3 H 2-OCF 3 3-OCH 3 The 4-methyl
Ia.196 CF 3 H 2-OCF 3 3-OCF 3 The 4-methyl
Ia.197 CF 3 H The 2-fluorine The 3-fluorine 4-CF3
Ia.198 CF 3 H The 2-fluorine 3-chlorine 4-CF3
Ia.199 CF 3 H The 2-fluorine 3-CN 4-CF3
Ia.200 CF 3 H The 2-fluorine The 3-methyl 4-CF3
Ia.201 CF 3 H The 2-fluorine 3-CF 3 4-CF3
Ia.202 CF 3 H The 2-fluorine 3-OCH 3 4-CF3
Ia.203 CF 3 H The 2-fluorine 3-OCF 3 4-CF3
Ia.204 CF 3 H 2-chlorine The 3-fluorine 4-CF 3
Ia.205 CF 3 H 2-chlorine 3-chlorine 4-CF 3
Ia.206 CF 3 H 2-chlorine 3-CN 4-CF 3
Ia.207 CF 3 H 2-chlorine The 3-methyl 4-CF 3
Ia.208 CF 3 H 2-chlorine 3-CF 3 4-CF 3
Ia.209 CF 3 H 2-chlorine 3-OCH 3 4-CF 3
Ia.210 CF 3 H 2-chlorine 3-OCF 3 4-CF 3
Ia.211 CF 3 H 2-CN The 3-fluorine 4-CF 3
Ia.212 CF 3 H 2-CN 3-chlorine 4-CF 3
Ia.213 CF 3 H 2-CN 3-CN 4-CF 3
Ia.214 CF 3 H 2-CN The 3-methyl 4-CF 3
Ia.215 CF 3 H 2-CN 3-CF 3 4-CF 3
Ia.216 CF 3 H 2-CN 3-OCH 3 4-CF 3
Ia.217 CF 3 H 2-CN 3-OCF 3 4-CF 3
Ia.218 CF 3 H The 2-methyl The 3-fluorine 4-CF3
Ia.219 CF 3 H The 2-methyl 3-chlorine 4-CF3
Ia.220 CF 3 H The 2-methyl 3-CN 4-CF3
Ia.221 CF 3 H The 2-methyl The 3-methyl 4-CF3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.222 CF 3 H The 2-methyl 3-CF 3 4-CF3
Ia.223 CF 3 H The 2-methyl 3-OCH 3 4-CF3
Ia.224 CF 3 H The 2-methyl 3-OCF 3 4-CF3
Ia.225 CF 3 H 2-CF 3 The 3-fluorine 4-CF3
Ia.226 CF 3 H 2-CF 3 3-chlorine 4-CF 3
Ia.227 CF 3 H 2-CF 3 3-CN 4-CF3
Ia.228 CF 3 H 2-CF 3 The 3-methyl 4-CF3
Ia.229 CF 3 H 2-CF 3 3-CF 3 4-CF3
Ia.230 CF 3 H 2-CF 3 3-OCH 3 4-CF3
Ia.231 CF 3 H 2-CF 3 3-OCF 3 4-CF3
Ia.232 CF 3 H 2-OCH 3 The 3-fluorine 4-CF3
Ia.233 CF 3 H 2-OCH 3 3-chlorine 4-CF3
Ia.234 CF 3 H 2-OCH 3 3-CN 4-CF3
Ia.235 CF 3 H 2-OCH 3 The 3-methyl 4-CF3
Ia.236 CF 3 H 2-OCH 3 3-CF 3 4-CF3
Ia.237 CF 3 H 2-OCH 3 3-OCH 3 4-CF 3
Ia.238 CF 3 H 2-OCH 3 3-OCF 3 4-CF 3
Ia.239 CF 3 H 2-OCF 3 The 3-fluorine 4-CF 3
Ia.240 CF 3 H 2-OCF 3 3-chlorine 4-CF 3
Ia.241 CF 3 H 2-OCF 3 3-CN 4-CF 3
Ia.242 CF 3 H 2-OCF 3 The 3-methyl 4-CF 3
Ia.243 CF 3 H 2-OCF 3 3-CF 3 4-CF 3
Ia.244 CF 3 H 2-OCF 3 3-OCH 3 4-CF 3
Ia.245 CF 3 H 2-OCF 3 3-OCF 3 4-CF 3
Ia.246 CF 3 H The 2-fluorine The 3-fluorine 4-OCH 3
Ia.247 CF 3 H The 2-fluorine 3-chlorine 4-OCH 3
Ia.248 CF 3 H The 2-fluorine 3-CN 4-OCH 3
Ia.249 CF 3 H The 2-fluorine The 3-methyl 4-OCH 3
Ia.250 CF 3 H The 2-fluorine 3-CF 3 4-OCH 3
Ia.251 CF 3 H The 2-fluorine 3-OCH 3 4-OCH 3
Ia.252 CF 3 H The 2-fluorine 3-OCF 3 4-OCH 3
Ia.253 CF 3 H 2-chlorine The 3-fluorine 4-OCH 3
Ia.254 CF 3 H 2-chlorine 3-chlorine 4-OCH 3
Ia.255 CF 3 H 2-chlorine 3-CN 4-OCH 3
Ia.256 CF 3 H 2-chlorine The 3-methyl 4-OCH 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.257 CF 3 H 2-chlorine 3-CF 3 4-OCH 3
Ia.258 CF 3 H 2-chlorine 3-OCH 3 4-OCH 3
Ia.259 CF 3 H 2-chlorine 3-OCF 3 4-OCH 3
Ia.260 CF 3 H 2-CN The 3-fluorine 4-OCH 3
Ia.261 CF 3 H 2-CN 3-chlorine 4-OCH 3
Ia.262 CF 3 H 2-CN 3-CN 4-OCH 3
Ia.263 CF 3 H 2-CN The 3-methyl 4-OCH 3
Ia.264 CF 3 H 2-CN 3-CF 3 4-OCH 3
Ia.265 CF 3 H 2-CN 3-OCH 3 4-OCH 3
Ia.266 CF 3 H 2-CN 3-OCF 3 4-OCH 3
Ia.267 CF 3 H The 2-methyl The 3-fluorine 4-OCH 3
Ia.268 CF 3 H The 2-methyl 3-chlorine 4-OCH 3
Ia.269 CF 3 H The 2-methyl 3-CN 4-OCH 3
Ia.270 CF 3 H The 2-methyl The 3-methyl 4-OCH 3
Ia.271 CF 3 H The 2-methyl 3-CF 3 4-OCH 3
Ia.272 CF 3 H The 2-methyl 3-OCH 3 4-OCH 3
Ia.273 CF 3 H The 2-methyl 3-OCF 3 4-OCH 3
Ia.274 CF 3 H 2-CF 3 The 3-fluorine 4-OCH 3
Ia.275 CF 3 H 2-CF 3 3-chlorine 4-OCH 3
Ia.276 CF 3 H 2-CF 3 3-CN 4-OCH 3
Ia.277 CF 3 H 2-CF 3 The 3-methyl 4-OCH 3
Ia.278 CF 3 H 2-CF 3 3-CF 3 4-OCH 3
Ia.279 CF 3 H 2-CF 3 3-OCH 3 4-OCH 3
Ia.280 CF 3 H 2-CF 3 3-OCF 3 4-OCH 3
Ia.281 CF 3 H 2-OCH 3 The 3-fluorine 4-OCH 3
Ia.282 CF 3 H 2-OCH 3 3-chlorine 4-OCH 3
Ia.283 CF 3 H 2-OCH 3 3-CN 4-OCH 3
Ia.284 CF 3 H 2-OCH 3 The 3-methyl 4-OCH 3
Ia.285 CF 3 H 2-OCH 3 3-CF 3 4-OCH 3
Ia.286 CF 3 H 2-OCH 3 3-OCH 3 4-OCH 3
Ia.287 CF 3 H 2-OCH 3 3-OCF 3 4-OCH 3
Ia.288 CF 3 H 2-OCF 3 The 3-fluorine 4-OCH 3
Ia.289 CF 3 H 2-OCF 3 3-chlorine 4-OCH 3
Ia.290 CF 3 H 2-OCF 3 3-CN 4-OCH 3
Ia.291 CF 3 H 2-OCF 3 The 3-methyl 4-OCH 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.292 CF 3 H 2-OCF 3 3-CF 3 4-OCH 3
Ia.293 CF 3 H 2-OCF 3 3-OCH 3 4-OCH 3
Ia.294 CF 3 H 2-OCF 3 3-OCF 3 4-OCH 3
Ia.295 CF 3 H The 2-fluorine The 3-fluorine 4-OCF 3
Ia.296 CF 3 H The 2-fluorine 3-chlorine 4-OCF 3
Ia.297 CF 3 H The 2-fluorine 3-CN 4-OCF 3
Ia.298 CF 3 H The 2-fluorine The 3-methyl 4-OCF 3
Ia.299 CF 3 H The 2-fluorine 3-CF 3 4-OCF 3
Ia.300 CF 3 H The 2-fluorine 3-OCH 3 4-OCF 3
Ia.301 CF 3 H The 2-fluorine 3-OCF 3 4-OCF 3
Ia.302 CF 3 H 2-chlorine The 3-fluorine 4-OCF 3
Ia.303 CF 3 H 2-chlorine 3-chlorine 4-OCF 3
Ia.304 CF 3 H 2-chlorine 3-CN 4-OCF 3
Ia.305 CF 3 H 2-chlorine The 3-methyl 4-OCF 3
Ia.306 CF 3 H 2-chlorine 3-CF 3 4-OCF 3
Ia.307 CF 3 H 2-chlorine 3-OCH 3 4-OCF 3
Ia.308 CF 3 H 2-chlorine 3-OCF 3 4-OCF 3
Ia.309 CF 3 H 2-CN The 3-fluorine 4-OCF 3
Ia.310 CF 3 H 2-CN 3-chlorine 4-OCF 3
Ia.311 CF 3 H 2-CN 3-CN 4-OCF 3
Ia.312 CF 3 H 2-CN The 3-methyl 4-OCF 3
Ia.313 CF 3 H 2-CN 3-CF 3 4-OCF 3
Ia.314 CF 3 H 2-CN 3-OCH 3 4-OCF 3
Ia.315 CF 3 H 2-CN 3-OCF 3 4-OCF 3
Ia.316 CF 3 H The 2-methyl The 3-fluorine 4-OCF 3
Ia.317 CF 3 H The 2-methyl 3-chlorine 4-OCF 3
Ia.318 CF 3 H The 2-methyl 3-CN 4-OCF 3
Ia.319 CF 3 H The 2-methyl The 3-methyl 4-OCF 3
Ia.320 CF 3 H The 2-methyl 3-CF 3 4-OCF 3
Ia.321 CF 3 H The 2-methyl 3-OCH 3 4-OCF 3
Ia.322 CF 3 H The 2-methyl 3-OCF 3 4-OCF 3
Ia.323 CF 3 H 2-CF 3 The 3-fluorine 4-OCF 3
Ia.324 CF 3 H 2-CF 3 3-chlorine 4-OCF 3
Ia.325 CF 3 H 2-CF 3 3-CN 4-OCF 3
Ia.326 CF 3 H 2-CF 3 The 3-methyl 4-OCF 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.327 CF 3 H 2-CF 3 3-CF 3 4-OCF 3
Ia.328 CF 3 H 2-CF 3 3-OCH 3 4-OCF 3
Ia.329 CF 3 H 2-CF 3 3-OCF 3 4-OCF 3
Ia.330 CF 3 H 2-OCH 3 The 3-fluorine 4-OCF 3
Ia.331 CF 3 H 2-OCH 3 3-chlorine 4-OCF 3
Ia.332 CF 3 H 2-OCH 3 3-CN 4-OCF 3
Ia.333 CF 3 H 2-OCH 3 The 3-methyl 4-OCF 3
Ia.334 CF 3 H 2-OCH 3 3-CF 3 4-OCF 3
Ia.335 CF 3 H 2-OCH 3 3-OCH 3 4-OCF 3
Ia.336 CF 3 H 2-OCH 3 3-OCF 3 4-OCF 3
Ia.337 CF 3 H 2-OCF 3 The 3-fluorine 4-OCF 3
Ia.338 CF 3 H 2-OCF 3 3-chlorine 4-OCF 3
Ia.339 CF 3 H 2-OCF 3 3-CN 4-OCF 3
Ia.340 CF 3 H 2-OCF 3 The 3-methyl 4-OCF 3
Ia.341 CF 3 H 2-OCF 3 3-CF 3 4-OCF 3
Ia.342 CF 3 H 2-OCF 3 3-OCH 3 4-OCF 3
Ia.343 CF 3 H 2-OCF 3 3-OCF 3 4-OCF 3
Ia.344 CF 3 H The 3-fluorine The 4-fluorine The 5-fluorine 120-124
Ia.345 CF 3 H 3-chlorine The 4-fluorine The 5-fluorine
Ia.346 CF 3 H 3-CN The 4-fluorine The 5-fluorine
Ia.347 CF 3 H 3-CH 3 The 4-fluorine The 5-fluorine
Ia.348 CF 3 H 3-CF 3 The 4-fluorine The 5-fluorine
Ia.349 CF 3 H 3-OCH 3 The 4-fluorine The 5-fluorine
Ia.350 CF 3 H 3-OCF 3 The 4-fluorine The 5-fluorine
Ia.351 CF 3 H The 3-fluorine The 4-fluorine 5-chlorine
Ia.352 CF 3 H 3-chlorine The 4-fluorine 5-chlorine
Ia.353 CF 3 H 3-CN The 4-fluorine 5-chlorine
Ia.354 CF 3 H 3-CH 3 The 4-fluorine 5-chlorine
Ia.355 CF 3 H 3-CF 3 The 4-fluorine 5-chlorine
Ia.356 CF 3 H 3-OCH 3 The 4-fluorine 5-chlorine
Ia.357 CF 3 H 3-OCF 3 The 4-fluorine 5-chlorine
Ia.358 CF 3 H The 3-fluorine The 4-fluorine 5-CN
Ia.359 CF 3 H 3-chlorine The 4-fluorine 5-CN
Ia.360 CF 3 H 3-CN The 4-fluorine 5-CN
Ia.361 CF 3 H 3-CH 3 The 4-fluorine 5-CN
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.362 CF 3 H 3-CF 3 The 4-fluorine 5-CN
Ia.363 CF 3 H 3-OCH 3 The 4-fluorine 5-CN
Ia.364 CF 3 H 3-OCF 3 The 4-fluorine 5-CN
Ia.365 CF 3 H The 3-fluorine The 4-fluorine 5-CH 3
Ia.366 CF 3 H 3-chlorine The 4-fluorine 5-CH 3
Ia.367 CF 3 H 3-CN The 4-fluorine 5-CH 3
Ia.368 CF 3 H 3-CH 3 The 4-fluorine 5-CH 3
Ia.369 CF 3 H 3-CF 3 The 4-fluorine 5-CH 3
Ia.370 CF 3 H 3-OCH 3 The 4-fluorine 5-CH 3
Ia.371 CF 3 H 3-OCF 3 The 4-fluorine 5-CH 3
Ia.372 CF 3 H The 3-fluorine The 4-fluorine 5-CF 3
Ia.373 CF 3 H 3-chlorine The 4-fluorine 5-CF 3
Ia.374 CF 3 H 3-CN The 4-fluorine 5-CF 3
Ia.375 CF 3 H 3-CH 3 The 4-fluorine 5-CF 3
Ia.376 CF 3 H 3-CF 3 The 4-fluorine 5-CF 3
Ia.377 CF 3 H 3-OCH 3 The 4-fluorine 5-CF 3
Ia.378 CF 3 H 3-OCF 3 The 4-fluorine 5-CF 3
Ia.379 CF 3 H The 3-fluorine The 4-fluorine 5-OCH 3
Ia.380 CF 3 H 3-chlorine The 4-fluorine 5-OCH 3
Ia.381 CF 3 H 3-CN The 4-fluorine 5-OCH 3
Ia.382 CF 3 H 3-CH 3 The 4-fluorine 5-OCH 3
Ia.383 CF 3 H 3-CF 3 The 4-fluorine 5-OCH 3
Ia.384 CF 3 H 3-OCH 3 The 4-fluorine 5-OCH 3
Ia.385 CF 3 H 3-OCF 3 The 4-fluorine 5-OCH 3
Ia.386 CF 3 H The 3-fluorine The 4-fluorine 5-OCF 3
Ia.387 CF 3 H 3-chlorine The 4-fluorine 5-OCF 3
Ia.388 CF 3 H 3-CN The 4-fluorine 5-OCF 3
Ia.389 CF 3 H 3-CH 3 The 4-fluorine 5-OCF 3
Ia.390 CF 3 H 3-CF 3 The 4-fluorine 5-OCF 3
Ia.391 CF 3 H 3-OCH 3 The 4-fluorine 5-OCF 3
Ia.392 CF 3 H 3-OCF 3 The 4-fluorine 5-OCF 3
Ia.393 CF 3 H The 3-fluorine 4-chlorine The 5-fluorine
Ia.394 CF 3 H 3-chlorine 4-chlorine The 5-fluorine
Ia.395 CF 3 H 3-CN 4-chlorine The 5-fluorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.396 CF 3 H 3-CH 3 4-chlorine The 5-fluorine
Ia.397 CF 3 H 3-CF 3 4-chlorine The 5-fluorine
Ia.398 CF 3 H 3-OCH 3 4-chlorine The 5-fluorine
Ia.399 CF 3 H 3-OCF 3 4-chlorine The 5-fluorine
Ia.400 CF 3 H The 3-fluorine 4-chlorine 5-chlorine
Ia.401 CF 3 H 3-chlorine 4-chlorine 5-chlorine
Ia.402 CF 3 H 3-CN 4-chlorine 5-chlorine
Ia.403 CF 3 H 3-CH 3 4-chlorine 5-chlorine
Ia.404 CF 3 H 3-CF 3 4-chlorine 5-chlorine
Ia.405 CF 3 H 3-OCH 3 4-chlorine 5-chlorine
Ia.406 CF 3 H 3-OCF 3 4-chlorine 5-chlorine
Ia.407 CF 3 H The 3-fluorine 4-chlorine 5-CN
Ia.408 CF 3 H 3-chlorine 4-chlorine 5-CN
Ia.409 CF 3 H 3-CN 4-chlorine 5-CN
Ia.410 CF 3 H 3-CH 3 4-chlorine 5-CN
Ia.411 CF 3 H 3-CF 3 4-chlorine 5-CN
Ia.412 CF 3 H 3-OCH 3 4-chlorine 5-CN
Ia.413 CF 3 H 3-OCF 3 4-chlorine 5-CN
Ia.414 CF 3 H The 3-fluorine 4-chlorine 5-CH 3
Ia.415 CF 3 H 3-chlorine 4-chlorine 5-CH 3
Ia.416 CF 3 H 3-CN 4-chlorine 5-CH 3
Ia.417 CF 3 H 3-CH 3 4-chlorine 5-CH 3
Ia.418 CF 3 H 3-CF 3 4-chlorine 5-CH 3
Ia.419 CF 3 H 3-OCH 3 4-chlorine 5-CH 3
Ia.420 CF 3 H 3-OCF 3 4-chlorine 5-CH 3
Ia.421 CF 3 H The 3-fluorine 4-chlorine 5-CF 3
Ia.422 CF 3 H 3-chlorine 4-chlorine 5-CF 3
Ia.423 CF 3 H 3-CN 4-chlorine 5-CF 3
Ia.424 CF 3 H 3-CH 3 4-chlorine 5-CF 3
Ia.425 CF 3 H 3-CF 3 4-chlorine 5-CF 3
Ia.426 CF 3 H 3-OCH 3 4-chlorine 5-CF 3
Ia.427 CF 3 H 3-OCF 3 4-chlorine 5-CF 3
Ia.428 CF 3 H The 3-fluorine 4-chlorine 5-OCH 3
Ia.429 CF 3 H 3-chlorine 4-chlorine 5-OCH 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.430 CF 3 H 3-CN 4-chlorine 5-OCH 3
Ia.431 CF 3 H 3-CH 3 4-chlorine 5-OCH 3
Ia.432 CF 3 H 3-CF 3 4-chlorine 5-OCH 3
Ia.433 CF 3 H 3-OCH 3 4-chlorine 5-OCH 3
Ia.434 CF 3 H 3-OCF 3 4-chlorine 5-OCH 3
Ia.435 CF 3 H The 3-fluorine 4-chlorine 5-OCF 3
Ia.436 CF 3 H 3-chlorine 4-chlorine 5-OCF 3
Ia.437 CF 3 H 3-CN 4-chlorine 5-OCF 3
Ia.438 CF 3 H 3-CH 3 4-chlorine 5-OCF 3
Ia.439 CF 3 H 3-CF 3 4-chlorine 5-OCF 3
Ia.440 CF 3 H 3-OCH 3 4-chlorine 5-OCF 3
Ia.441 CF 3 H 3-OCF 3 4-chlorine 5-OCF 3
Ia.442 CF 3 H The 3-fluorine 4-CN The 5-fluorine
Ia.443 CF 3 H 3-chlorine 4-CN The 5-fluorine
Ia.444 CF 3 H 3-CN 4-CN The 5-fluorine
Ia.445 CF 3 H 3-CH 3 4-CN The 5-fluorine
Ia.446 CF 3 H 3-CF 3 4-CN The 5-fluorine
Ia.447 CF 3 H 3-OCH 3 4-CN The 5-fluorine
Ia.448 CF 3 H 3-OCF 3 4-CN The 5-fluorine
Ia.449 CF 3 H The 3-fluorine 4-CN 5-chlorine
Ia.450 CF 3 H 3-chlorine 4-CN 5-chlorine
Ia.451 CF 3 H 3-CN 4-CN 5-chlorine
Ia.452 CF 3 H 3-CH 3 4-CN 5-chlorine
Ia.453 CF 3 H 3-CF 3 4-CN 5-chlorine
Ia.454 CF 3 H 3-OCH 3 4-CN 5-chlorine
Ia.455 CF 3 H 3-OCF 3 4-CN 5-chlorine
Ia.456 CF 3 H The 3-fluorine 4-CN 5-CN
Ia.457 CF 3 H 3-chlorine 4-CN 5-CN
Ia.458 CF 3 H 3-CN 4-CN 5-CN
Ia.459 CF 3 H 3-CH 3 4-CN 5-CN
Ia.460 CF 3 H 3-CF 3 4-CN 5-CN
Ia.461 CF 3 H 3-OCH 3 4-CN 5-CN
Ia.462 CF 3 H 3-OCF 3 4-CN 5-CN
Ia.463 CF 3 H The 3-fluorine 4-CN 5-CH 3
Ia.464 CF 3 H 3-chlorine 4-CN 5-CH 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.465 CF 3 H 3-CN 4-CN 5-CH 3
Ia.466 CF 3 H 3-CH 3 4-CN 5-CH 3
Ia.467 CF 3 H 3-CF 3 4-CN 5-CH 3
Ia.468 CF 3 H 3-OCH 3 4-CN 5-CH 3
Ia.469 CF 3 H 3-OCF 3 4-CN 5-CH 3
Ia.470 CF 3 H The 3-fluorine 4-CN 5-CF 3
Ia.471 CF 3 H 3-chlorine 4-CN 5-CF 3
Ia.472 CF 3 H 3-CN 4-CN 5-CF 3
Ia.473 CF 3 H 3-CH 3 4-CN 5-CF 3
Ia.474 CF 3 H 3-CF 3 4-CN 5-CF 3
Ia.475 CF 3 H 3-OCH 3 4-CN 5-CF 3
Ia.476 CF 3 H 3-OCF 3 4-CN 5-CF 3
Ia.477 CF 3 H The 3-fluorine 4-CN 5-OCH 3
Ia.478 CF 3 H 3-chlorine 4-CN 5-OCH 3
Ia.479 CF 3 H 3-CN 4-CN 5-OCH 3
Ia.480 CF 3 H 3-CH 3 4-CN 5-OCH 3
Ia.481 CF 3 H 3-CF 3 4-CN 5-OCH 3
Ia.482 CF 3 H 3-OCH 3 4-CN 5-OCH 3
Ia.483 CF 3 H 3-OCF 3 4-CN 5-OCH 3
Ia.484 CF 3 H The 3-fluorine 4-CN 5-OCF 3
Ia.485 CF 3 H 3-chlorine 4-CN 5-OCF 3
Ia.486 CF 3 H 3-CN 4-CN 5-OCF 3
Ia.487 CF 3 H 3-CH 3 4-CN 5-OCF 3
Ia.488 CF 3 H 3-CF 3 4-CN 5-OCF 3
Ia.489 CF 3 H 3-OCH 3 4-CN 5-OCF 3
Ia.490 CF 3 H 3-OCF 3 4-CN 5-OCF 3
Ia.491 CF 3 H The 3-fluorine 4-CH 3 The 5-fluorine
Ia.492 CF 3 H 3-chlorine 4-CH 3 The 5-fluorine
Ia.493 CF 3 H 3-CN 4-CH 3 The 5-fluorine
Ia.494 CF 3 H 3-CH 3 4-CH 3 The 5-fluorine
Ia.495 CF 3 H 3-CF 3 4-CH 3 The 5-fluorine
Ia.496 CF 3 H 3-OCH 3 4-CH 3 The 5-fluorine
Ia.497 CF 3 H 3-OCF 3 4-CH 3 The 5-fluorine
Ia.498 CF 3 H The 3-fluorine 4-CH 3 5-chlorine
Ia.499 CF 3 H 3-chlorine 4-CH 3 5-chlorine
Ia.500 CF 3 H 3-CN 4-CH 3 5-chlorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.501 CF 3 H 3-CH 3 4-CH 3 5-chlorine
Ia.502 CF 3 H 3-CF 3 4-CH 3 5-chlorine
Ia.503 CF 3 H 3-OCH 3 4-CH 3 5-chlorine
Ia.504 CF 3 H 3-OCF 3 4-CH 3 5-chlorine
Ia.505 CF 3 H The 3-fluorine 4-CH 3 5-CN
Ia.506 CF 3 H 3-chlorine 4-CH 3 5-CN
Ia.507 CF 3 H 3-CN 4-CH 3 5-CN
Ia.508 CF 3 H 3-CH 3 4-CH 3 5-CN
Ia.509 CF 3 H 3-CF 3 4-CH 3 5-CN
Ia.510 CF 3 H 3-OCH 3 4-CH 3 5-CN
Ia.511 CF 3 H 3-OCF 3 4-CH 3 5-CN
Ia.512 CF 3 H The 3-fluorine 4-CH 3 5-CH 3
Ia.513 CF 3 H 3-chlorine 4-CH 3 5-CH 3
Ia.514 CF 3 H 3-CN 4-CH 3 5-CH 3
Ia.515 CF 3 H 3-CH 3 4-CH 3 5-CH 3
Ia.516 CF 3 H 3-CF 3 4-CH 3 5-CH 3
Ia.517 CF 3 H 3-OCH 3 4-CH 3 5-CH 3
Ia.518 CF 3 H 3-OCF 3 4-CH 3 5-CH 3
Ia.519 CF 3 H The 3-fluorine 4-CH 3 5-CF 3
Ia.520 CF 3 H 3-chlorine 4-CH 3 5-CF 3
Ia.521 CF 3 H 3-CN 4-CH 3 5-CF 3
Ia.522 CF 3 H 3-CH 3 4-CH 3 5-CF 3
Ia.523 CF 3 H 3-CF 3 4-CH 3 5-CF 3
Ia.524 CF 3 H 3-OCH 3 4-CH 3 5-CF 3
Ia.525 CF 3 H 3-OCF 3 4-CH 3 5-CF 3
Ia.526 CF 3 H The 3-fluorine 4-CH 3 5-OCH 3
Ia.527 CF 3 H 3-chlorine 4-CH 3 5-OCH 3
Ia.528 CF 3 H 3-CN 4-CH 3 5-OCH 3
Ia.529 CF 3 H 3-CH 3 4-CH 3 5-OCH 3
Ia.530 CF 3 H 3-CF 3 4-CH 3 5-OCH 3
Ia.531 CF 3 H 3-OCH 3 4-CH 3 5-OCH 3
Ia.532 CF 3 H 3-OCF 3 4-CH 3 5-OCH 3
Ia.533 CF 3 H The 3-fluorine 4-CH 3 5-OCF 3
Ia.534 CF 3 H 3-chlorine 4-CH 3 5-OCF 3
Ia.535 CF 3 H 3-CN 4-CH 3 5-OCF 3
Ia.536 CF 3 H 3-CH 3 4-CH 3 5-OCF 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.537 CF 3 H 3-CF 3 4-CH 3 5-OCF 3
Ia.538 CF 3 H 3-OCH 3 4-CH 3 5-OCF 3
Ia.539 CF 3 H 3-OCF 3 4-CH 3 5-OCF 3
Ia.540 CF 3 H The 3-fluorine 4-CF 3 The 5-fluorine
Ia.541 CF 3 H 3-chlorine 4-CF 3 The 5-fluorine
Ia.542 CF 3 H 3-CN 4-CF 3 The 5-fluorine
Ia.543 CF 3 H 3-CH 3 4-CF 3 The 5-fluorine
Ia.544 CF 3 H 3-CF 3 4-CF 3 The 5-fluorine
Ia.545 CF 3 H 3-OCH 3 4-CF 3 The 5-fluorine
Ia.546 CF 3 H 3-OCF 3 4-CF 3 The 5-fluorine
Ia.547 CF 3 H The 3-fluorine 4-CF 3 5-chlorine
Ia.548 CF 3 H 3-chlorine 4-CF 3 5-chlorine
Ia.549 CF 3 H 3-CN 4-CF 3 5-chlorine
Ia.550 CF 3 H 3-CH 3 4-CF 3 5-chlorine
Ia.551 CF 3 H 3-CF 3 4-CF 3 5-chlorine
Ia.552 CF 3 H 3-OCH 3 4-CF 3 5-chlorine
Ia.553 CF 3 H 3-OCF 3 4-CF 3 5-chlorine
Ia.554 CF 3 H The 3-fluorine 4-CF 3 5-CN
Ia.555 CF 3 H 3-chlorine 4-CF 3 5-CN
Ia.556 CF 3 H 3-CN 4-CF 3 5-CN
Ia.557 CF 3 H 3-CH 3 4-CF 3 5-CN
Ia.558 CF 3 H 3-CF 3 4-CF 3 5-CN
Ia.559 CF 3 H 3-OCH 3 4-CF 3 5-CN
Ia.560 CF 3 H 3-OCF 3 4-CF 3 5-CN
Ia.561 CF 3 H The 3-fluorine 4-CF 3 5-CH 3
Ia.562 CF 3 H 3-chlorine 4-CF 3 5-CH 3
Ia.563 CF 3 H 3-CN 4-CF 3 5-CH 3
Ia.564 CF 3 H 3-CH 3 4-CF 3 5-CH 3
Ia.565 CF 3 H 3-CF 3 4-CF 3 5-CH 3
Ia.566 CF 3 H 3-OCH 3 4-CF 3 5-CH 3
Ia.567 CF 3 H 3-OCF 3 4-CF 3 5-CH 3
Ia.568 CF 3 H The 3-fluorine 4-CF 3 5-CF 3
Ia.569 CF 3 H 3-chlorine 4-CF 3 5-CF 3
Ia.570 CF 3 H 3-CN 4-CF 3 5-CF 3
Ia.571 CF 3 H 3-CH 3 4-CF 3 5-CF 3
Ia.572 CF 3 H 3-CF 3 4-CF 3 5-CF 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.573 CF 3 H 3-OCH 3 4-CF 3 5-CF 3
Ia.574 CF 3 H 3-OCF 3 4-CF 3 5-CF 3
Ia.575 CF 3 H The 3-fluorine 4-CF 3 5-OCH 3
Ia.576 CF 3 H 3-chlorine 4-CF 3 5-OCH 3
Ia.577 CF 3 H 3-CN 4-CF 3 5-OCH 3
Ia.578 CF 3 H 3-CH 3 4-CF 3 5-OCH 3
Ia.579 CF 3 H 3-CF 3 4-CF 3 5-OCH 3
Ia.560 CF 3 H 3-OCH 3 4-CF 3 5-OCH 3
Ia.561 CF 3 H 3-OCF 3 4-CF 3 5-OCH 3
Ia.562 CF 3 H The 3-fluorine 4-CF 3 5-OCF 3
Ia.563 CF 3 H 3-chlorine 4-CF 3 5-OCF 3
Ia.564 CF 3 H 3-CN 4-CF 3 5-OCF 3
Ia.565 CF 3 H 3-CH 3 4-CF 3 5-OCF 3
Ia.566 CF 3 H 3-CF 3 4-CF 3 5-OCF 3
Ia.567 CF 3 H 3-OCH 3 4-CF 3 5-OCF 3
Ia.568 CF 3 H 3-OCF 3 4-CF 3 5-OCF 3
Ia.569 CF 3 H The 3-fluorine 4-OCH 3 The 5-fluorine
Ia.570 CF 3 H 3-chlorine 4-OCH 3 The 5-fluorine
Ia.571 CF 3 H 3-CN 4-OCH 3 The 5-fluorine
Ia.572 CF 3 H 3-CH 3 4-OCH 3 The 5-fluorine
Ia.573 CF 3 H 3-CF 3 4-OCH 3 The 5-fluorine
Ia.574 CF 3 H 3-OCH 3 4-OCH 3 The 5-fluorine
Ia.575 CF 3 H 3-OCF 3 4-OCH 3 The 5-fluorine
Ia.576 CF 3 H The 3-fluorine 4-OCH 3 5-chlorine
Ia.577 CF 3 H 3-chlorine 4-OCH 3 5-chlorine
Ia.578 CF 3 H 3-CN 4-OCH 3 5-chlorine
Ia.579 CF 3 H 3-CH 3 4-OCH 3 5-chlorine
Ia.580 CF 3 H 3-CF 3 4-OCH 3 5-chlorine
Ia.581 CF 3 H 3-OCH 3 4-OCH 3 5-chlorine
Ia.582 CF 3 H 3-OCF 3 4-OCH 3 5-chlorine
Ia.583 CF 3 H The 3-fluorine 4-OCH 3 5-CN
Ia.584 CF 3 H 3-chlorine 4-OCH 3 5-CN
Ia.585 CF 3 H 3-CN 4-OCH 3 5-CN
Ia.586 CF 3 H 3-CH 3 4-OCH 3 5-CN
Ia.587 CF 3 H 3-CF 3 4-OCH 3 5-CN
Ia.588 CF 3 H 3-OCH 3 4-OCH 3 5-CN
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.589 CF 3 H 3-OCF 3 4-OCH 3 5-CN
Ia.590 CF 3 H The 3-fluorine 4-OCH 3 5-CH 3
Ia.591 CF 3 H 3-chlorine 4-OCH 3 5-CH 3
Ia.592 CF 3 H 3-CN 4-OCH 3 5-CH 3
Ia.593 CF 3 H 3-CH 3 4-OCH 3 5-CH 3
Ia.594 CF 3 H 3-CF 3 4-OCH 3 5-CH 3
Ia.595 CF 3 H 3-OCH 3 4-OCH 3 5-CH 3
Ia.596 CF 3 H 3-OCF 3 4-OCH 3 5-CH 3
Ia.597 CF 3 H The 3-fluorine 4-OCH 3 5-CF 3
Ia.598 CF 3 H 3-chlorine 4-OCH 3 5-CF 3
Ia.599 CF 3 H 3-CN 4-OCH 3 5-CF 3
Ia.600 CF 3 H 3-CH 3 4-OCH 3 5-CF 3
Ia.601 CF 3 H 3-CF 3 4-OCH 3 5-CF 3
Ia.602 CF 3 H 3-OCH 3 4-OCH 3 5-CF 3
Ia.603 CF 3 H 3-OCF 3 4-OCH 3 5-CF 3
Ia.604 CF 3 H The 3-fluorine 4-OCH 3 5-OCH 3
Ia.605 CF 3 H 3-chlorine 4-OCH 3 5-OCH 3
Ia.606 CF 3 H 3-CN 4-OCH 3 5-OCH 3
Ia.607 CF 3 H 3-CH 3 4-OCH 3 5-OCH 3
Ia.608 CF 3 H 3-CF 3 4-OCH 3 5-OCH 3
Ia.609 CF 3 H 3-OCH 3 4-OCH 3 5-OCH 3
Ia.610 CF 3 H 3-OCF 3 4-OCH 3 5-OCH 3
Ia.611 CF 3 H The 3-fluorine 4-OCH 3 5-OCF 3
Ia.612 CF 3 H 3-chlorine 4-OCH 3 5-OCF 3
Ia.613 CF 3 H 3-CN 4-OCH 3 5-OCF 3
Ia.614 CF 3 H 3-CH 3 4-OCH 3 5-OCF 3
Ia.615 CF 3 H 3-CF 3 4-OCH 3 5-OCF 3
Ia.616 CF 3 H 3-OCH 3 4-OCH 3 5-OCF 3
Ia.617 CF 3 H 3-OCF 3 4-OCH 3 5-OCF 3
Ia.618 CF 3 H The 3-fluorine 4-OCF 3 The 5-fluorine
Ia.619 CF 3 H 3-chlorine 4-OCF 3 The 5-fluorine
Ia.620 CF 3 H 3-CN 4-OCF 3 The 5-fluorine
Ia.621 CF 3 H 3-CH 3 4-OCF 3 The 5-fluorine
Ia.622 CF 3 H 3-CF 3 4-OCF 3 The 5-fluorine
Ia.623 CF 3 H 3-OCH 3 4-OCF 3 The 5-fluorine
Ia.624 CF 3 H 3-OCF 3 4-OCF 3 The 5-fluorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.625 CF 3 H The 3-fluorine 4-OCF 3 5-chlorine
Ia.626 CF 3 H 3-chlorine 4-OCF 3 5-chlorine
Ia.627 CF 3 H 3-CN 4-OCF 3 5-chlorine
Ia.628 CF 3 H 3-CH 3 4-OCF 3 5-chlorine
Ia.629 CF 3 H 3-CF 3 4-OCF 3 5-chlorine
Ia.630 CF 3 H 3-OCH 3 4-OCF 3 5-chlorine
Ia.631 CF 3 H 3-OCF 3 4-OCF 3 5-chlorine
Ia.632 CF 3 H The 3-fluorine 4-OCF 3 5-CN
Ia.633 CF 3 H 3-chlorine 4-OCF 3 5-CN
Ia.634 CF 3 H 3-CN 4-OCF 3 5-CN
Ia.635 CF 3 H 3-CH 3 4-OCF 3 5-CN
Ia.636 CF 3 H 3-CF 3 4-OCF 3 5-CN
Ia.637 CF 3 H 3-OCH 3 4-OCF 3 5-CN
Ia.638 CF 3 H 3-OCF 3 4-OCF 3 5-CN
Ia.639 CF 3 H The 3-fluorine 4-OCF 3 5-CH 3
Ia.640 CF 3 H 3-chlorine 4-OCF 3 5-CH 3
Ia.641 CF 3 H 3-CN 4-OCF 3 5-CH 3
Ia.642 CF 3 H 3-CH 3 4-OCF 3 5-CH 3
Ia.643 CF 3 H 3-CF3 4-OCF 3 5-CH 3
Ia.644 CF 3 H 3-OCH 3 4-OCF 3 5-CH 3
Ia.645 CF 3 H 3-OCF 3 4-OCF 3 5-CH 3
Ia.646 CF 3 H The 3-fluorine 4-OCF 3 5-CF 3
Ia.647 CF 3 H 3-chlorine 4-OCF 3 5-CF 3
Ia.648 CF 3 H 3-CN 4-OCF 3 5-CF 3
Ia.649 CF 3 H 3-CH 3 4-OCF 3 5-CF 3
Ia.650 CF 3 H 3-CF 3 4-OCF 3 5-CF 3
Ia.651 CF 3 H 3-OCH 3 4-OCF 3 5-CF 3
Ia.652 CF 3 H 3-OCF 3 4-OCF 3 5-CF 3
Ia.653 CF 3 H The 3-fluorine 4-OCF 3 5-OCH 3
Ia.654 CF 3 H 3-chlorine 4-OCF 3 5-OCH 3
Ia.655 CF 3 H 3-CN 4-OCF 3 5-OCH 3
Ia.656 CF 3 H 3-CH 3 4-OCF 3 5-OCH 3
Ia.657 CF 3 H 3-CF 3 4-OCF 3 5-OCH 3
Ia.658 CF 3 H 3-OCH 3 4-OCF 3 5-OCH 3
Ia.659 CF 3 H 3-OCF 3 4-OCF 3 5-OCH 3
Ia.660 CF 3 H The 3-fluorine 4-OCF 3 5-OCF 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.661 CF 3 H 3-chlorine 4-OCF 3 5-OCF 3
Ia.662 CF 3 H 3-CN 4-OCF 3 5-OCF 3
Ia.663 CF 3 H 3-CH 3 4-OCF 3 5-OCF 3
Ia.664 CF 3 H 3-CF 3 4-OCF 3 5-OCF 3
Ia.665 CF 3 H 3-OCH 3 4-OCF 3 5-OCF 3
Ia.666 CF 3 H 3-OCF 3 4-OCF 3 5-OCF 3
Ia.667 CF 3 H The 2-fluorine The 4-fluorine The 5-fluorine 110-113
Ia.668 CF 3 H The 2-fluorine The 4-fluorine 5-chlorine
Ia.669 CF 3 H The 2-fluorine The 4-fluorine 5-CN
Ia.670 CF 3 H The 2-fluorine The 4-fluorine 5-CH 3
Ia.671 CF 3 H The 2-fluorine The 4-fluorine 5-CF 3
Ia.672 CF 3 H The 2-fluorine The 4-fluorine 5-OCH 3
Ia.673 CF 3 H The 2-fluorine The 4-fluorine 5-OCF 3
Ia.674 CF 3 H 2-chlorine The 4-fluorine The 5-fluorine
Ia.675 CF 3 H 2-chlorine The 4-fluorine 5-chlorine
Ia.676 CF 3 H 2-chlorine The 4-fluorine 5-CN
Ia.677 CF 3 H 2-chlorine The 4-fluorine 5-CH 3
Ia.678 CF 3 H 2-chlorine The 4-fluorine 5-CF 3
Ia.679 CF 3 H 2-chlorine The 4-fluorine 5-OCH 3
Ia.680 CF 3 H 2-chlorine The 4-fluorine 5-OCF 3
Ia.681 CF 3 H 2-CN The 4-fluorine The 5-fluorine
Ia.682 CF 3 H 2-CN The 4-fluorine 5-chlorine
Ia.683 CF 3 H 2-CN The 4-fluorine 5-CN
Ia.684 CF 3 H 2-CN The 4-fluorine 5-CH 3
Ia.685 CF 3 H 2-CN The 4-fluorine 5-CF 3
Ia.686 CF 3 H 2-CN The 4-fluorine 5-OCH 3
Ia.687 CF 3 H 2-CN The 4-fluorine 5-OCF 3
Ia.688 CF 3 H The 2-methyl The 4-fluorine The 5-fluorine
Ia.689 CF 3 H The 2-methyl The 4-fluorine 5-chlorine
Ia.690 CF 3 H The 2-methyl The 4-fluorine 5-CN
Ia.691 CF 3 H The 2-methyl The 4-fluorine 5-CH 3
Ia.692 CF 3 H The 2-methyl The 4-fluorine 5-CF 3
Ia.693 CF 3 H The 2-methyl The 4-fluorine 5-OCH 3
Ia.694 CF 3 H The 2-methyl The 4-fluorine 5-OCF 3
Ia.695 CF 3 H 2-CF 3 The 4-fluorine The 5-fluorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.696 CF 3 H 2-CF 3 The 4-fluorine 5-chlorine
Ia.697 CF 3 H 2-CF 3 The 4-fluorine 5-CN
Ia.698 CF 3 H 2-CF 3 The 4-fluorine 5-CH 3
Ia.699 CF 3 H 2-CF 3 The 4-fluorine 5-CF 3
Ia.700 CF 3 H 2-CF 3 The 4-fluorine 5-OCH 3
Ia.701 CF 3 H 2-CF 3 The 4-fluorine 5-OCF 3
Ia.702 CF 3 H 2-OCH 3 The 4-fluorine The 5-fluorine
Ia.703 CF 3 H 2-OCH 3 The 4-fluorine 5-chlorine
Ia.704 CF 3 H 2-OCH 3 The 4-fluorine 5-CN
Ia.705 CF 3 H 2-OCH 3 The 4-fluorine 5-CH 3
Ia.706 CF 3 H 2-OCH 3 The 4-fluorine 5-CF 3
Ia.707 CF 3 H 2-OCH 3 The 4-fluorine 5-OCH 3
Ia.708 CF 3 H 2-OCH 3 The 4-fluorine 5-OCF 3
Ia.709 CF 3 H 2-OCF 3 The 4-fluorine The 5-fluorine
Ia.710 CF 3 H 2-OCF 3 The 4-fluorine 5-chlorine
Ia.711 CF 3 H 2-OCF 3 The 4-fluorine 5-CN
Ia.712 CF 3 H 2-OCF 3 The 4-fluorine 5-CH 3
Ia.713 CF 3 H 2-OCF 3 The 4-fluorine 5-CF 3
Ia.714 CF 3 H 2-OCF 3 The 4-fluorine 5-OCH 3
Ia.715 CF 3 H 2-OCF 3 The 4-fluorine 5-OCF 3
Ia.716 CF 3 H The 2-fluorine 4-chlorine The 5-fluorine
Ia.717 CF 3 H The 2-fluorine 4-chlorine 5-chlorine
Ia.718 CF 3 H The 2-fluorine 4-chlorine 5-CN
Ia.719 CF 3 H The 2-fluorine 4-chlorine 5-CH 3 106-108
Ia.720 CF 3 H The 2-fluorine 4-chlorine 5-CF 3
Ia.721 CF 3 H The 2-fluorine 4-chlorine 5-OCH 3 119-121
Ia.722 CF 3 H The 2-fluorine 4-chlorine 5-OCF 3
Ia.723 CF 3 H 2-chlorine 4-chlorine The 5-fluorine
Ia.724 CF 3 H 2-chlorine 4-chlorine 5-chlorine
Ia.725 CF 3 H 2-chlorine 4-chlorine 5-CN
Ia.726 CF 3 H 2-chlorine 4-chlorine 5-CH 3
Ia.727 CF 3 H 2-chlorine 4-chlorine 5-CF 3
Ia.728 CF 3 H 2-chlorine 4-chlorine 5-OCH 3
Ia.729 CF 3 H 2-chlorine 4-chlorine 5-OCF 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.730 CF 3 H 2-CN 4-chlorine The 5-fluorine
Ia.731 CF 3 H 2-CN 4-chlorine 5-chlorine
Ia.732 CF 3 H 2-CN 4-chlorine 5-CN
Ia.733 CF 3 H 2-CN 4-chlorine 5-CH 3
Ia.734 CF 3 H 2-CN 4-chlorine 5-CF 3
Ia.735 CF 3 H 2-CN 4-chlorine 5-OCH 3
Ia.736 CF 3 H 2-CN 4-chlorine 5-OCF 3
Ia.737 CF 3 H The 2-methyl 4-chlorine The 5-fluorine
Ia.738 CF 3 H The 2-methyl 4-chlorine 5-chlorine
Ia.739 CF 3 H The 2-methyl 4-chlorine 5-CN
Ia.740 CF 3 H The 2-methyl 4-chlorine 5-CH 3
Ia.741 CF 3 H The 2-methyl 4-chlorine 5-CF 3
Ia.742 CF 3 H The 2-methyl 4-chlorine 5-OCH 3
Ia.743 CF 3 H The 2-methyl 4-chlorine 5-OCF 3
Ia.744 CF 3 H 2-CF 3 4-chlorine The 5-fluorine
Ia.745 CF 3 H 2-CF 3 4-chlorine 5-chlorine
Ia.746 CF 3 H 2-CF 3 4-chlorine 5-CN
Ia.747 CF 3 H 2-CF 3 4-chlorine 5-CH 3
Ia.748 CF 3 H 2-CF 3 4-chlorine 5-CF 3
Ia.749 CF 3 H 2-CF 3 4-chlorine 5-OCH 3
Ia.750 CF 3 H 2-CF 3 4-chlorine 5-OCF 3
Ia.751 CF 3 H 2-OCH 3 4-chlorine The 5-fluorine
Ia.752 CF 3 H 2-OCH 3 4-chlorine 5-chlorine
Ia.753 CF 3 H 2-OCH 3 4-chlorine 5-CN
Ia.754 CF 3 H 2-OCH 3 4-chlorine 5-CH 3
Ia.755 CF 3 H 2-OCH 3 4-chlorine 5-CF 3
Ia.756 CF 3 H 2-OCH 3 4-chlorine 5-OCH 3
Ia.757 CF 3 H 2-OCH 3 4-chlorine 5-OCF 3
Ia.758 CF 3 H 2-OCF 3 4-chlorine The 5-fluorine
Ia.759 CF 3 H 2-OCF 3 4-chlorine 5-chlorine
Ia.760 CF 3 H 2-OCF 3 4-chlorine 5-CN
Ia.761 CF 3 H 2-OCF 3 4-chlorine 5-CH 3
Ia.762 CF 3 H 2-OCF 3 4-chlorine 5-CF 3
Ia.763 CF 3 H 2-OCF 3 4-chlorine 5-OCH 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.764 CF 3 H 2-OCF 3 4-chlorine 5-OCF 3
Ia.765 CF 3 H The 2-fluorine 4-CN The 5-fluorine
Ia.766 CF 3 H The 2-fluorine 4-CN 5-chlorine
Ia.767 CF 3 H The 2-fluorine 4-CN 5-CN
Ia.768 CF 3 H The 2-fluorine 4-CN 5-CH 3
Ia.769 CF 3 H The 2-fluorine 4-CN 5-CF 3
Ia.770 CF 3 H The 2-fluorine 4-CN 5-OCH 3
Ia.771 CF 3 H The 2-fluorine 4-CN 5-OCF 3
Ia.772 CF 3 H 2-chlorine 4-CN The 5-fluorine
Ia.773 CF 3 H 2-chlorine 4-CN 5-chlorine
Ia.774 CF 3 H 2-chlorine 4-CN 5-CN
Ia.775 CF 3 H 2-chlorine 4-CN 5-CH 3
Ia.776 CF 3 H 2-chlorine 4-CN 5-CF 3
Ia.777 CF 3 H 2-chlorine 4-CN 5-OCH 3
Ia.778 CF 3 H 2-chlorine 4-CN 5-OCF 3
Ia.779 CF 3 H 2-CN 4-CN The 5-fluorine
Ia.780 CF 3 H 2-CN 4-CN 5-chlorine
Ia.781 CF 3 H 2-CN 4-CN 5-CN
Ia.782 CF 3 H 2-CN 4-CN 5-CH 3
Ia.783 CF 3 H 2-CN 4-CN 5-CF 3
Ia.784 CF 3 H 2-CN 4-CN 5-OCH 3
Ia.785 CF 3 H 2-CN 4-CN 5-OCF 3
Ia.786 CF 3 H The 2-methyl 4-CN The 5-fluorine
Ia.787 CF 3 H The 2-methyl 4-CN 5-chlorine
Ia.788 CF 3 H The 2-methyl 4-CN 5-CN
Ia.789 CF 3 H The 2-methyl 4-CN 5-CH 3
Ia.790 CF 3 H The 2-methyl 4-CN 5-CF 3
Ia.791 CF 3 H The 2-methyl 4-CN 5-OCH 3
Ia.792 CF 3 H The 2-methyl 4-CN 5-OCF 3
Ia.793 CF 3 H 2-CF 3 4-CN The 5-fluorine
Ia.794 CF 3 H 2-CF 3 4-CN 5-chlorine
Ia.795 CF 3 H 2-CF 3 4-CN 5-CN
Ia.796 CF 3 H 2-CF 3 4-CN 5-CH 3
Ia.797 CF 3 H 2-CF 3 4-CN 5-CF 3
Ia.798 CF 3 H 2-CF 3 4-CN 5-OCH 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.799 CF 3 H 2-CF 3 4-CN 5-OCF 3
Ia.800 CF 3 H 2-OCH 3 4-CN The 5-fluorine
Ia.801 CF 3 H 2-OCH 3 4-CN 5-chlorine
Ia.802 CF 3 H 2-OCH 3 4-CN 5-CN
Ia.803 CF 3 H 2-OCH 3 4-CN 5-CH 3
Ia.804 CF 3 H 2-OCH 3 4-CN 5-CF 3
Ia.805 CF 3 H 2-OCH 3 4-CN 5-OCH 3
Ia.806 CF 3 H 2-OCH 3 4-CN 5-OCF 3
Ia.807 CF 3 H 2-OCF 3 4-CN The 5-fluorine
Ia.808 CF 3 H 2-OCF 3 4-CN 5-chlorine
Ia.809 CF 3 H 2-OCF 3 4-CN 5-CN
Ia.810 CF 3 H 2-OCF 3 4-CN 5-CH 3
Ia.811 CF 3 H 2-OCF 3 4-CN 5-CF 3
Ia.812 CF 3 H 2-OCF 3 4-CN 5-OCH 3
Ia.813 CF 3 H 2-OCF 3 4-CN 5-OCF 3
Ia.814 CF 3 H The 2-fluorine 4-CH 3 The 5-fluorine
Ia.815 CF 3 H The 2-fluorine 4-CH 3 5-chlorine
Ia.816 CF 3 H The 2-fluorine 4-CH 3 5-CN
Ia.817 CF 3 H The 2-fluorine 4-CH 3 5-CH 3
Ia.818 CF 3 H The 2-fluorine 4-CH 3 5-CF 3
Ia.819 CF 3 H The 2-fluorine 4-CH 3 5-OCH 3
Ia.820 CF 3 H The 2-fluorine 4-CH 3 5-OCF 3
Ia.821 CF 3 H 2-chlorine 4-CH 3 The 5-fluorine
Ia.822 CF 3 H 2-chlorine 4-CH 3 5-chlorine
Ia.823 CF 3 H 2-chlorine 4-CH 3 5-CN
Ia.824 CF 3 H 2-chlorine 4-CH 3 5-CH 3
Ia.825 CF 3 H 2-chlorine 4-CH 3 5-CF 3
Ia.826 CF 3 H 2-chlorine 4-CH 3 5-OCH 3
Ia.827 CF 3 H 2-chlorine 4-CH 3 5-OCF 3
Ia.828 CF 3 H 2-CN 4-CH 3 The 5-fluorine
Ia.829 CF 3 H 2-CN 4-CH 3 5-chlorine
Ia.830 CF 3 H 2-CN 4-CH 3 5-CN
Ia.831 CF 3 H 2-CN 4-CH 3 5-CH 3
Ia.832 CF 3 H 2-CN 4-CH 3 5-CF 3
Ia.833 CF 3 H 2-CN 4-CH 3 5-OCH 3
Ia.834 CF 3 H 2-CN 4-CH 3 5-OCF 3
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.835 CF 3 H The 2-methyl 4-CH 3 The 5-fluorine
Ia.836 CF 3 H The 2-methyl 4-CH 3 5-chlorine
Ia.837 CF 3 H The 2-methyl 4-CH 3 5-CN
Ia.838 CF 3 H The 2-methyl 4-CH 3 5-CH 3
Ia.839 CF 3 H The 2-methyl 4-CH 3 5-CF 3
Ia.840 CF 3 H The 2-methyl 4-CH 3 5-OCH 3
Ia.841 CF 3 H The 2-methyl 4-CH 3 5-OCF 3
Ia.842 CF 3 H 2-CF 3 4-CH 3 The 5-fluorine
Ia.843 CF 3 H 2-CF 3 4-CH 3 5-chlorine
Ia.844 CF 3 H 2-CF 3 4-CH 3 5-CN
Ia.845 CF 3 H 2-CF 3 4-CH 3 5-CH 3
Ia.846 CF 3 H 2-CF 3 4-CH 3 5-CF 3
Ia.847 CF 3 H 2-CF 3 4-CH 3 5-OCH 3
Ia.848 CF 3 H 2-CF 3 4-CH 3 5-OCF 3
Ia.849 CF 3 H 2-OCH 3 4-CH 3 The 5-fluorine
Ia.850 CF 3 H 2-OCH 3 4-CH 3 5-chlorine
Ia.851 CF 3 H 2-OCH 3 4-CH 3 5-CN
Ia.852 CF 3 H 2-OCH 3 4-CH 3 5-CH 3
Ia.853 CF 3 H 2-OCH 3 4-CH 3 5-CF 3
Ia.854 CF 3 H 2-OCH 3 4-CH 3 5-OCH 3
Ia.855 CF 3 H 2-OCH 3 4-CH 3 5-OCF 3
Ia.856 CF 3 H 2-OCF 3 4-CH 3 The 5-fluorine
Ia.857 CF 3 H 2-OCF 3 4-CH 3 5-chlorine
Ia.858 CF 3 H 2-OCF 3 4-CH 3 5-CN
Ia.859 CF 3 H 2-OCF 3 4-CH 3 5-CH 3
Ia.860 CF 3 H 2-OCF 3 4-CH 3 5-CF 3
Ia.861 CF 3 H 2-OCF 3 4-CH 3 5-OCH 3
Ia.862 CF 3 H 2-OCF 3 4-CH 3 5-OCF 3
Ia.863 CF 3 H The 2-fluorine 4-CF 3 The 5-fluorine
Ia.864 CF 3 H The 2-fluorine 4-CF 3 5-chlorine
Ia.865 CF 3 H The 2-fluorine 4-CF 3 5-CN
Ia.866 CF 3 H The 2-fluorine 4-CF 3 5-CH 3
Ia.867 CF 3 H The 2-fluorine 4-CF 3 5-CF 3
Ia.868 CF 3 H The 2-fluorine 4-CF 3 5-OCH 3
Ia.869 CF 3 H The 2-fluorine 4-CF 3 5-OCF 3
Ia.870 CF 3 H 2-chlorine 4-CF 3 The 5-fluorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.871 CF 3 H 2-chlorine 4-CF 3 5-chlorine
Ia.872 CF 3 H 2-chlorine 4-CF 3 5-CN
Ia.873 CF 3 H 2-chlorine 4-CF 3 5-CH 3
Ia.874 CF 3 H 2-chlorine 4-CF 3 5-CF 3
Ia.875 CF 3 H 2-chlorine 4-CF 3 5-OCH 3
Ia.876 CF 3 H 2-chlorine 4-CF 3 5-OCF 3
Ia.877 CF 3 H 2-CN 4-CF 3 The 5-fluorine
Ia.878 CF 3 H 2-CN 4-CF 3 5-chlorine
Ia.879 CF 3 H 2-CN 4-CF 3 5-CN
Ia.880 CF 3 H 2-CN 4-CF 3 5-CH 3
Ia.881 CF 3 H 2-CN 4-CF 3 5-CF 3
Ia.882 CF 3 H 2-CN 4-CF 3 5-OCH 3
Ia.883 CF 3 H 2-CN 4-CF 3 5-OCF 3
Ia.884 CF 3 H The 2-methyl 4-CF 3 The 5-fluorine
Ia.885 CF 3 H The 2-methyl 4-CF 3 5-chlorine
Ia.886 CF 3 H The 2-methyl 4-CF 3 5-CN
Ia.887 CF 3 H The 2-methyl 4-CF 3 5-CH 3
Ia.888 CF 3 H The 2-methyl 4-CF 3 5-CF 3
Ia.889 CF 3 H The 2-methyl 4-CF 3 5-OCH 3
Ia.890 CF 3 H The 2-methyl 4-CF 3 5-OCF 3
Ia.891 CF 3 H 2-CF 3 4-CF 3 The 5-fluorine
Ia.892 CF 3 H 2-CF 3 4-CF 3 5-chlorine
Ia.893 CF 3 H 2-CF 3 4-CF 3 5-CN
Ia.894 CF 3 H 2-CF 3 4-CF 3 5-CH 3
Ia.895 CF 3 H 2-CF 3 4-CF 3 5-CF 3
Ia.896 CF 3 H 2-CF 3 4-CF 3 5-OCH 3
Ia.897 CF 3 H 2-CF 3 4-CF 3 5-OCF 3
Ia.898 CF 3 H 2-OCH 3 4-CF 3 The 5-fluorine
Ia.899 CF 3 H 2-OCH 3 4-CF 3 5-chlorine
Ia.900 CF 3 H 2-OCH 3 4-CF 3 5-CN
Ia.901 CF 3 H 2-OCH 3 4-CF 3 5-CH 3
Ia.902 CF 3 H 2-OCH 3 4-CF 3 5-CF 3
Ia.903 CF 3 H 2-OCH 3 4-CF 3 5-OCH 3
Ia.904 CF 3 H 2-OCH 3 4-CF 3 5-OCF 3
Ia.905 CF 3 H 2-OCF 3 4-CF 3 The 5-fluorine
Ia.906 CF 3 H 2-OCF 3 4-CF 3 5-chlorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.907 CF 3 H 2-OCF 3 4-CF 3 5-CN
Ia.908 CF 3 H 2-OCF 3 4-CF 3 5-CH 3
Ia.909 CF 3 H 2-OCF 3 4-CF 3 5-CF 3
Ia.910 CF 3 H 2-OCF 3 4-CF 3 5-OCH 3
Ia.911 CF 3 H 2-OCF 3 4-CF 3 5-OCF 3
Ia.912 CF 3 H The 2-fluorine 4-OCH 3 The 5-fluorine
Ia.913 CF 3 H The 2-fluorine 4-OCH 3 5-chlorine
Ia.914 CF 3 H The 2-fluorine 4-OCH 3 5-CN
Ia.915 CF 3 H The 2-fluorine 4-OCH 3 5-CH 3
Ia.916 CF 3 H The 2-fluorine 4-OCH 3 5-CF 3
Ia.917 CF 3 H The 2-fluorine 4-OCH 3 5-OCH 3
Ia.918 CF 3 H The 2-fluorine 4-OCH 3 5-OCF 3
Ia.919 CF 3 H 2-chlorine 4-OCH 3 The 5-fluorine
Ia.920 CF 3 H 2-chlorine 4-OCH 3 5-chlorine
Ia.921 CF 3 H 2-chlorine 4-OCH 3 5-CN
Ia.922 CF 3 H 2-chlorine 4-OCH 3 5-CH 3
Ia.923 CF 3 H 2-chlorine 4-OCH 3 5-CF 3
Ia.924 CF 3 H 2-chlorine 4-OCH 3 5-OCH 3
Ia.925 CF 3 H 2-chlorine 4-OCH 3 5-OCF 3
Ia.926 CF 3 H 2-CN 4-OCH 3 The 5-fluorine
Ia.927 CF 3 H 2-CN 4-OCH 3 5-chlorine
Ia.928 CF 3 H 2-CN 4-OCH 3 5-CN
Ia.929 CF 3 H 2-CN 4-OCH 3 5-CH 3
Ia.930 CF 3 H 2-CN 4-OCH 3 5-CF 3
Ia.931 CF 3 H 2-CN 4-OCH 3 5-OCH 3
Ia.932 CF 3 H 2-CN 4-OCH 3 5-OCF 3
Ia.933 CF 3 H The 2-methyl 4-OCH 3 The 5-fluorine
Ia.934 CF 3 H The 2-methyl 4-OCH 3 5-chlorine
Ia.935 CF 3 H The 2-methyl 4-OCH 3 5-CN
Ia.936 CF 3 H The 2-methyl 4-OCH 3 5-CH 3
Ia.937 CF 3 H The 2-methyl 4-OCH 3 5-CF 3
Ia.938 CF 3 H The 2-methyl 4-OCH 3 5-OCH 3
Ia.939 CF 3 H The 2-methyl 4-OCH 3 5-OCF 3
Ia.940 CF 3 H 2-CF 3 4-OCH 3 The 5-fluorine
Ia.941 CF 3 H 2-CF 3 4-OCH 3 5-chlorine
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.942 CF 3 H 2-CF 3 4-OCH 3 5-CN
Ia.943 CF 3 H 2-CF 3 4-OCH 3 5-CH 3
Ia.944 CF 3 H 2-CF 3 4-OCH 3 5-CF 3
Ia.945 CF 3 H 2-CF 3 4-OCH 3 5-OCH 3
Ia.946 CF 3 H 2-CF 3 4-OCH 3 5-OCF 3
Ia.947 CF 3 H 2-OCH 3 4-OCH 3 The 5-fluorine
Ia.948 CF 3 H 2-OCH 3 4-OCH 3 5-chlorine
Ia.949 CF 3 H 2-OCH 3 4-OCH 3 5-CN
Ia.950 CF 3 H 2-OCH 3 4-OCH 3 5-CH 3
Ia.951 CF 3 H 2-OCH 3 4-OCH 3 5-CF 3
Ia.952 CF 3 H 2-OCH 3 4-OCH 3 5-OCH 3
Ia.953 CF 3 H 2-OCH 3 4-OCH 3 5-OCF 3
Ia.954 CF 3 H 2-OCF 3 4-OCH 3 The 5-fluorine
Ia.955 CF 3 H 2-OCF 3 4-OCH 3 5-chlorine
Ia.956 CF 3 H 2-OCF 3 4-OCH 3 5-CN
Ia.957 CF 3 H 2-OCF 3 4-OCH 3 5-CH 3
Ia.958 CF 3 H 2-OCF 3 4-OCH 3 5-CF 3
Ia.959 CF 3 H 2-OCF 3 4-OCH 3 5-OCH 3
Ia.960 CF 3 H 2-OCF 3 4-OCH 3 5-OCF 3
Ia.961 CF 3 H The 2-fluorine 4-OCF 3 The 5-fluorine
Ia.962 CF 3 H The 2-fluorine 4-OCF 3 5-chlorine
Ia.963 CF 3 H The 2-fluorine 4-OCF 3 5-CN
Ia.964 CF 3 H The 2-fluorine 4-OCF 3 5-CH 3
Ia.965 CF 3 H The 2-fluorine 4-OCF 3 5-CF 3
Ia.966 CF 3 H The 2-fluorine 4-OCF 3 5-OCH 3
Ia.967 CF 3 H The 2-fluorine 4-OCF 3 5-OCF 3
Ia.968 CF 3 H 2-chlorine 4-OCF 3 The 5-fluorine
Ia.969 CF 3 H 2-chlorine 4-OCF 3 5-chlorine
Ia.970 CF 3 H 2-chlorine 4-OCF 3 5-CN
Ia.971 CF 3 H 2-chlorine 4-OCF 3 5-CH 3
Ia.972 CF 3 H 2-chlorine 4-OCF 3 5-CF 3
Ia.973 CF 3 H 2-chlorine 4-OCF 3 5-OCH 3
Ia.974 CF 3 H 2-chlorine 4-OCF 3 5-OCF 3
Ia.975 CF 3 H 2-CN 4-OCF 3 The 5-fluorine
Ia.976 CF 3 H 2-CN 4-OCF 3 5-chlorine
Ia.977 CF 3 H 2-CN 4-OCF 3 5-CN
The compound sequence number R 1 R 2 R 3 R 4 R 5 Fusing point [℃]
Ia.978 CF 3 H 2-CN 4-OCF 3 5-CH 3
Ia.979 CF 3 H 2-CN 4-OCF 3 5-CF 3
Ia.980 CF 3 H 2-CN 4-OCF 3 5-OCH 3
Ia.981 CF 3 H 2-CN 4-OCF 3 5-OCF 3
Ia.982 CF 3 H The 2-methyl 4-OCF 3 The 5-fluorine
Ia.983 CF 3 H The 2-methyl 4-OCF 3 5-chlorine
Ia.984 CF 3 H The 2-methyl 4-OCF 3 5-CN
Ia.985 CF 3 H The 2-methyl 4-OCF 3 5-CH 3
Ia.986 CF 3 H The 2-methyl 4-OCF 3 5-CF 3
Ia.987 CF 3 H The 2-methyl 4-OCF 3 5-OCH 3
Ia.988 CF 3 H The 2-methyl 4-OCF 3 5-OCF 3
Ia.989 CF 3 H 2-CF 3 4-OCF 3 The 5-fluorine
Ia.990 CF 3 H 2-CF 3 4-OCF 3 5-chlorine
Ia.991 CF 3 H 2-CF 3 4-OCF 3 5-CN
Ia.992 CF 3 H 2-CF 3 4-OCF 3 5-CH 3
Ia.993 CF 3 H 2-CF 3 4-OCF 3 5-CF 3
Ia.994 CF 3 H 2-CF 3 4-OCF 3 5-OCH 3
Ia.995 CF 3 H 2-CF 3 4-OCF 3 5-OCF 3
Ia.996 CF 3 H 2-OCH 3 4-OCF 3 The 5-fluorine
Ia.997 CF 3 H 2-OCH 3 4-OCF 3 5-chlorine
Ia.998 CF 3 H 2-OCH 3 4-OCF 3 5-CN
Ia.999 CF 3 H 2-OCH 3 4-OCF 3 5-CH 3
Ia.1000 CF 3 H 2-OCH 3 4-OCF 3 5-CF 3
Ia.1001 CF 3 H 2-OCH 3 4-OCF 3 5-OCH 3
Ia.1002 CF 3 H 2-OCH 3 4-OCF 3 5-OCF 3
Ia.1003 CF 3 H 2-OCF 3 4-OCF 3 The 5-fluorine
Ia.1004 CF 3 H 2-OCF 3 4-OCF 3 5-chlorine
Ia.1005 CF 3 H 2-OCF 3 4-OCF 3 5-CN
Ia.1006 CF 3 H 2-OCF 3 4-OCF 3 5-CH 3
Ia.1007 CF 3 H 2-OCF 3 4-OCF 3 5-CF 3
Ia.1008 CF 3 H 2-OCF 3 4-OCF 3 5-OCH 3
Ia.1009 CF 3 H 2-OCF 3 4-OCF 3 5-OCF 3
In addition, the 1-methyl-pyrazol-4-yl carboxylic acid anilides of special preferred formula Ib-If, especially:
-with the corresponding Compound I different R that only are a.1-Ia.1009 2Compounds ib .1-Ib.1009 for fluorine:
Figure A20068002894400551
-with the corresponding Compound I different R that only are a.1-Ia.1009 2For the Compound I of chlorine c.1-Ic.1009:
-with the corresponding Compound I different R that only are a.1-Ia.1009 1Compound for difluoromethyl
Id.1-Id.1009：
Figure A20068002894400553
Compound sequence number fusing point [℃]
Id.721 150-152
Id.719 120-122
Id.667 122-125
Id.344 156-158
-with the corresponding Compound I different R that only are a.1-Ia.1009 1Be difluoromethyl and R 2For the Compound I of fluorine e.1-Ie.1009:
Figure A20068002894400554
-with the corresponding Compound I different R that only are a.1-Ia.1009 1Be difluoromethyl and R 2For the Compound I of chlorine f.1-If.1009:
Figure A20068002894400561
-with the corresponding Compound I different R that only are a.1-Ia.1009 1For the Compound I of methyl fluoride g.1-Ig.1009:
Figure A20068002894400562
Compound sequence number fusing point [℃]
Ig.344 152-156
Ig.1 126-129
-with the corresponding Compound I different R that only are a.1-Ia.1009 1Be CF 2The Compound I of Cl is h.1-Ih.1009:
Figure A20068002894400563
Compound sequence number fusing point [℃]
Ih.344 158-161
-with the corresponding Compound I different R that only are a.1-Ia.1009 1For the Compound I of chlorine methyl fluoride j.1-Ij.1009:
Figure A20068002894400564
Compound sequence number fusing point [℃]
Ij.344 154-157
Very particularly preferably following compound: N-(2 '-fluoro-4 '-chloro-5 '-methoxyl biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 '-fluoro-4 '-chloro-5 '-methoxyl biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 ', 3 ', 4 '-trifluoro-biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorodifluoramethyl--1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 ', 3 ', 4 '-trifluoro-biphenyl-2-yl)-3-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide and N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide.
Preferred formula I compound and at least a A that is selected from) mixture of reactive compound of azole.
Also preferred formula I compound and at least a B that is selected from) mixture of reactive compound of strobilurins class.
Preferred formula I compound and at least a C that is selected from) mixture of reactive compound of carboxylic acid amides.
In addition, also preferred formula I compound and at least a D that is selected from) mixture of reactive compound of heterocyclic compound.
In addition, also preferred formula I compound and at least a E that is selected from) mixture of reactive compound of Carbamates.
In addition, also preferred formula I compound and at least a F that is selected from) mixture of reactive compound of other fungicides.
In addition, also preferred formula I compound is selected from following A with at least a) mixture of the reactive compound of azole: cyproconazole, Difenoconazole, oxole bacterium, Fluquinconazole, Flusilazole, Flutriafol, ring penta azoles bacterium, nitrile bacterium azoles, penconazole, propiconazole, prothioconazoles, triazolone, triadimenol, Tebuconazole, fluorine ether azoles, triticonazole, Prochloraz, the white azoles of cyanogen, benomyl, carbendazim and Guardian.
Also special preferred formula I compound is selected from following A with at least a) mixture of the reactive compound of azole: cyproconazole, Difenoconazole, oxole bacterium, Fluquinconazole, Flusilazole, Flutriafol, ring penta azoles bacterium, nitrile bacterium azoles, propiconazole, prothioconazoles, triazolone, triadimenol, Tebuconazole, fluorine ether azoles, triticonazole, Prochloraz, the white azoles of cyanogen, benomyl and carbendazim.
Also very particularly preferably formula I compound and at least aly be selected from following A) mixture of the reactive compound of azole: oxole bacterium, Fluquinconazole, Flutriafol, ring penta azoles bacterium, Tebuconazole, triticonazole, Prochloraz and carbendazim.
Also preferred formula I compound and at least aly be selected from following B) mixture of the reactive compound of strobilurins class: nitrile Fluoxastrobin, ether bacterium amine, fluoxastrobin, imines bacterium, orysastrobin, ZEN 90160, pyraclostrobin and oxime bacterium ester.
Also special preferred formula I compound and at least aly be selected from following B) mixture of the reactive compound of strobilurins class: imines bacterium, orysastrobin and pyraclostrobin.
The mixture of formula I compound and pyraclostrobin very particularly preferably also.
Also preferred formula I compound and at least aly be selected from following C) mixture of the reactive compound of carboxylic acid amides: fenhexamid, metalaxyl, Metalaxyl-M, fenfuram, dimethomorph, flumorph, fluorine pyrrole bacterium amine (picobenzamid), zoxamide, carpropamide and mandipropamid amine.
Also special preferred formula I compound and at least aly be selected from following C) mixture of the reactive compound of carboxylic acid amides: fenhexamid, metalaxyl, Metalaxyl-M, fenfuram, dimethomorph, zoxamide and carpropamide.
Also preferred formula I compound and at least aly be selected from following D) mixture of the reactive compound of heterocyclic compound: fluazinam, encircle third pyrimidine, fenarimol, mepanipyrim, pyrimethanil, triforine Fu Evil bacterium, dodemorfe; butadiene morpholine; tridemorph; fenpropidin; different third is fixed; vinclozolin azolactone bacterium; Fenamidone; probenazole; 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2; 4; the 6-trifluorophenyl)-[1; 2; 4] triazols [1; 5-a] pyrimidine; the third oxygen quinoline; thiadiazoles element; difoltan; folpet; zarilamid and quinoxyfen, especially fluazinam; encircle third pyrimidine; fenarimol; mepanipyrim; pyrimethanil; triforine Fu Evil bacterium; dodemorfe; butadiene morpholine; tridemorph; fenpropidin; different third is fixed; vinclozolin azolactone bacterium; Fenamidone; probenazole; the third oxygen quinoline; thiadiazoles element; difoltan; folpet; zarilamid and quinoxyfen.
Also special preferred formula I compound is selected from following D with at least a) mixture of the reactive compound of heterocyclic compound: pyrimethanil, dodemorfe, butadiene morpholine, tridemorph, different third calmly, vinclozolin, 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazol [1,5-a] pyrimidine and quinoxyfen, especially pyrimethanil, dodemorfe, butadiene morpholine, tridemorph, different third fixed, vinclozolin and quinoxyfen.
Also preferred formula I compound and at least aly be selected from following E) mixture of the reactive compound of Carbamates: mancozeb, Carbatene, propineb, tmtd, iprovalicarb, benzene metsulfovax and hundred dimension spirits.
Also special preferred formula I compound and at least aly be selected from following E) mixture of the reactive compound of Carbamates: mancozeb and Carbatene.
Also preferred formula I compound and at least aly be selected from following F) mixture of the reactive compound of other fungicides: the Delan, triphenyltin salt is as fentinacetate, fosetyl, ethyl phosphine aluminium, phosphorous acid and salt thereof, tpn, Euparen, thiophanate methyl, Schweinfurt green, Kocide SD, Cupravit, basic copper sulfate, sulphur, cymoxanil, metrafenone is with the luxuriant amine of Luo Evil.
Also special preferred formula I compound and at least aly be selected from following F) mixture of the reactive compound of other fungicides: phosphorous acid and salt thereof, tpn and metrafenone.
The ternary mixture of also preferred a kind of formula I compound and two kinds of above-mentioned reactive compound II.
Preferred reactive compound combination is listed in the table below among the 3-9:
Table 3
Compound I and A) the reactive compound combination of group reactive compound II:
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
A.1 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.2 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.3 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.4 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.5 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.6 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.7 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.8 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.9 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.10 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.11 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.12 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.13 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
A.14 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.15 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.16 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.17 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.18 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.19 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.20 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.21 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.22 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.23 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.24 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Oxole bacterium
A.25 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.26 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.27 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.28 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.29 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.30 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.31 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.32 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.33 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.34 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.35 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.36 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.37 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.38 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.39 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.40 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.41 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.42 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.43 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.44 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.45 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.46 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.47 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.48 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Encircle penta azoles bacterium
A.49 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
A.50 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.51 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.52 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.53 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.54 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.55 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.56 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.57 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.58 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.59 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.60 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.61 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.62 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.63 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.64 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.65 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.66 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.67 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.68 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.69 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.70 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.71 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.72 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tebuconazole
A.73 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.74 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.75 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.76 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.77 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.78 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.79 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.80 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.81 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.82 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.83 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.84 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.85 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
A.86 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.87 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.88 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.89 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.90 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.91 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.92 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.93 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.94 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.95 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.96 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Fluquinconazole
A.97 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.98 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.99 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.100 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.101 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.102 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.103 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.104 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.105 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.106 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.107 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.108 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Flutriafol
A.109 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.110 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.111 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.112 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.113 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.114 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.115 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.116 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.117 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.118 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.119 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.120 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Flutriafol
A.121 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
A.122 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.123 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.124 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.125 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.126 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.127 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.128 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.129 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.130 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.131 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.132 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Triticonazole
A.133 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.134 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.135 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.136 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.137 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.138 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.139 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.140 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.141 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.142 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.143 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.144 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Triticonazole
A.145 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.146 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.147 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.148 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.149 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.150 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.151 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.152 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.153 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.154 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.155 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.156 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Prochloraz
A.157 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
A.158 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.159 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.160 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.161 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.162 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.163 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.164 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.165 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.166 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.167 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.168 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Prochloraz
A.169 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.170 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.171 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.172 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.173 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.174 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.175 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.176 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.177 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.178 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.179 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.180 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbendazim
A.181 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.182 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.183 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.184 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.185 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.186 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.187 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.188 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.189 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.190 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.191 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
A.192 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbendazim
Table 4
Compound I and B) the reactive compound combination of group reactive compound II:
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
B.1 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.2 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.3 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.4 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.5 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.6 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.7 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.8 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.9 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.10 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.11 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.12 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.13 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.14 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.15 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.16 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.17 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.18 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.19 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.20 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.21 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.22 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.23 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.24 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F The imines bacterium
B.25 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.26 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.27 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.28 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.29 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.30 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.31 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.32 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.33 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.34 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.35 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
B.36 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.37 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.38 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.39 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.40 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.41 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.42 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.43 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.44 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.45 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.46 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.47 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.48 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyraclostrobin
B.49 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.50 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.51 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.52 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.53 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.54 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.55 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.56 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.57 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.58 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.59 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.60 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.61 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.62 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.63 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.64 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.65 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.66 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.67 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.68 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.69 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.70 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
B.71 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
B.72 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Orysastrobin
Table 5
Compound I and C) the reactive compound combination of group reactive compound II:
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
C.1 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.2 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.3 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.4 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.5 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.6 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.7 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.8 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.9 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.10 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.11 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.12 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.13 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.14 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.15 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.16 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.17 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.18 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.19 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.20 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.21 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.22 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.23 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
C.24 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Dimethomorph
Table 6
Compound I and D) the reactive compound combination of group reactive compound II:
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
D.1 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.2 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.3 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.4 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
D.5 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.6 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.7 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.8 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.9 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.10 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.11 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.12 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.13 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.14 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4F；R 5＝5-F Pyrimethanil
D.15 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.16 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.17 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.18 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.19 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.20 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.21 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.22 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.23 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.24 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Pyrimethanil
D.25 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5a] pyrimidine
D.26 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5a] pyrimidine
D.27 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidinyl-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.28 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.29 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
Base)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.30 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.31 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.32 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.33 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.34 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.35 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.36 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.37 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.38 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluoro-benzene
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
Base)-[1,2,4] triazol [1,5-a] pyrimidine
D.39 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.40 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.41 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.42 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.43 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.44 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.45 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.46 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.47 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidines-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a]
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
Pyrimidine
D.48 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F 5-chloro-7-(4-methyl-piperidinyl-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
D.49 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.50 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.51 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.52 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.53 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.54 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.55 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.56 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.57 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.58 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.59 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.60 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.61 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.62 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.63 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.64 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.65 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.66 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.67 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.68 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.69 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.70 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.71 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.72 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Dodemorfe
D.73 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.74 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.75 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.76 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.77 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.78 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.79 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
D.80 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.81 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.82 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.83 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.84 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.85 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.86 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.87 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.88 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.89 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.90 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.91 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.92 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.93 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.94 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.95 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.96 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Butadiene morpholine
D.97 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.98 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.99 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.100 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.101 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.102 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.103 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.104 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.105 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.106 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.107 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.108 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tridemorph
D.109 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.110 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.111 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.112 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.113 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.114 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.115 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
D.116 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.117 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.118 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.119 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.120 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tridemorph
D.121 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.122 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.123 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.124 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.125 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.126 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.127 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.128 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.129 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.130 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.131 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.132 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.133 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.134 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.135 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.136 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.137 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.138 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.139 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.140 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.141 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.142 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.143 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.144 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Different third is fixed
D.145 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.146 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.147 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.148 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.149 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.150 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.151 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
D.152 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.153 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.154 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.155 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.156 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.157 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.158 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.159 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.160 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.161 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.162 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.163 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.164 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.165 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.166 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.167 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
D.168 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Vinclozolin
Table 7
Compound I and E) the reactive compound combination of group reactive compound II:
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
E.1 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.2 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.3 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.4 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.5 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.6 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.7 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.8 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.9 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.10 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.11 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.12 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Mancozeb
E.13 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.14 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.15 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.16 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
E.17 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.18 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.19 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.20 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.21 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.22 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.23 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.24 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Mancozeb
E.25 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.26 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.27 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.28 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.29 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.30 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.31 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.32 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.33 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.34 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.35 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.36 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Carbatene
E.37 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.38 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.39 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.40 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.41 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.42 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.43 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.44 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.45 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.46 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.47 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
E.48 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Carbatene
Table 8
Compound I and F) the reactive compound combination of group reactive compound II:
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
F.1 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
F.2 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.3 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.4 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.5 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.6 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.7 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.8 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.9 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.10 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.11 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.12 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Tpn
F.13 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.14 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.15 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.16 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.17 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.18 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.19 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.20 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.21 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.22 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.23 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.24 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Tpn
F.25 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.26 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.27 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.28 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.29 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.30 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.31 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.32 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.33 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.34 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.35 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.36 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Metrafenone
F.37 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
The mixture sequence number Formula I compound (X=oxygen) Reactive compound II
F.38 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.39 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.40 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.41 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.42 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.43 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.44 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.45 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.46 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.47 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.48 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Metrafenone
F.49 R 1＝CH 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.50 R 1＝CH 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.51 R 1＝CH 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.52 R 1＝CH 2F；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.53 R 1＝CHFCl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.54 R 1＝CHF 2；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.55 R 1＝CHF 2；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.56 R 1＝CHF 2；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.57 R 1＝CF 2Cl；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.58 R 1＝CF 3；R 2＝H；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.59 R 1＝CF 3；R 2＝F；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.60 R 1＝CF 3；R 2＝Cl；R 3＝3-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.61 R 1＝CH 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.62 R 1＝CH 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.63 R 1＝CH 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.64 R 1＝CH 2F；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.65 R 1＝CHFCl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.66 R 1＝CHF 2；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.67 R 1＝CHF 2；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.68 R 1＝CHF 2；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.69 R 1＝CF 2Cl；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.70 R 1＝CF 3；R 2＝H；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.71 R 1＝CF 3；R 2＝F；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
F.72 R 1＝CF 3；R 2＝Cl；R 3＝2-F；R 4＝4-F；R 5＝5-F Phosphorous acid
Table 9
The reactive compound combination of Compound I and two kinds of reactive compound II:
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.1 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Oxole bacterium
I-II-II.2 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Oxole bacterium
I-II-II.3 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Oxole bacterium
I-II-II.4 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Oxole bacterium
I-II-II.5 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Oxole bacterium
I-II-II.6 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Encircle penta azoles bacterium
I-II-II.7 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Encircle penta azoles bacterium
I-II-II.8 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Encircle penta azoles bacterium
I-II-II.9 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Encircle penta azoles bacterium
I-II-II.10 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Encircle penta azoles bacterium
I-II-II.11 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Triticonazole
I-II-II.12 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Triticonazole
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.13 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Triticonazole
I-II-II.14 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Triticonazole
I-II-II.15 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Triticonazole
I-II-II.16 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Fluquinconazole
I-II-II.17 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Fluquinconazole
I-II-II.18 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Fluquinconazole
I-II-II.19 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Fluquinconazole
I-II-II.20 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Fluquinconazole
I-II-II.21 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Prothioconazoles
I-II-II.22 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Prothioconazoles
I-II-II.23 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Prothioconazoles
I-II-II.24 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Prothioconazoles
I-II-II.25 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- Pyraclostrobin Prothioconazoles
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide
I-II-II.26 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Tebuconazole
I-II-II.27 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Tebuconazole
I-II-II.28 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Tebuconazole
I-II-II.29 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Tebuconazole
I-II-II.30 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Tebuconazole
I-II-II.31 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Carbendazim
I-II-II.32 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Carbendazim
I-II-II.33 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Carbendazim
I-II-II.34 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Carbendazim
I-II-II.35 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Carbendazim
I-II-II.36 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Thiophanate methyl
I-II-II.37 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-trifluoromethyl Pyraclostrobin Thiophanate methyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide
I-II-II.38 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Thiophanate methyl
I-II-II.39 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Thiophanate methyl
I-II-II.40 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Thiophanate methyl
I-II-II.41 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Benomyl
I-II-II.42 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Benomyl
I-II-II.43 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Benomyl
I-II-II.44 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Benomyl
I-II-II.45 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Benomyl
I-II-II.46 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Butadiene morpholine
I-II-II.47 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Butadiene morpholine
I-II-II.48 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Butadiene morpholine
I-II-II.49 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Butadiene morpholine
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.50 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Butadiene morpholine
I-II-II.51 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Metrafenone
I-II-II.52 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Pyraclostrobin Metrafenone
I-II-II.53 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Metrafenone
I-II-II.54 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Pyraclostrobin Metrafenone
I-II-II.55 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Pyraclostrobin Metrafenone
I-II-II.56 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Oxole bacterium
I-II-II.57 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Oxole bacterium
I-II-II.58 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Oxole bacterium
I-II-II.59 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Oxole bacterium
I-II-II.60 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Oxole bacterium
I-II-II.61 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Encircle penta azoles bacterium
I-II-II.62 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- The imines bacterium Encircle penta azoles bacterium
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide
I-II-II.63 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Encircle penta azoles bacterium
I-II-II.64 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Encircle penta azoles bacterium
I-II-II.65 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Encircle penta azoles bacterium
I-II-II.66 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Triticonazole
I-II-II.67 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Triticonazole
I-II-II.68 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Triticonazole
I-II-II.69 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Triticonazole
I-II-II.70 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Triticonazole
I-II-II.71 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Fluquinconazole
I-II-II.72 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Fluquinconazole
I-II-II.73 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Fluquinconazole
I-II-II.74 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl The imines bacterium Fluquinconazole
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide
I-II-II.75 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Fluquinconazole
I-II-II.76 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Prothioconazoles
I-II-II.77 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Prothioconazoles
I-II-II.78 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Prothioconazoles
I-II-II.79 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Prothioconazoles
I-II-II.80 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Prothioconazoles
I-II-II.81 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Tebuconazole
I-II-II.82 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Tebuconazole
I-II-II.83 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Tebuconazole
I-II-II.84 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Tebuconazole
I-II-II.85 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Tebuconazole
I-II-II.86 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Carbendazim
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.87 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Carbendazim
I-II-II.88 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Carbendazim
I-II-II.89 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Carbendazim
I-II-II.90 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Carbendazim
I-II-II.91 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Thiophanate methyl
I-II-II.92 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Thiophanate methyl
I-II-II.93 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Thiophanate methyl
I-II-II.94 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Thiophanate methyl
I-II-II.95 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Thiophanate methyl
I-II-II.96 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Benomyl
I-II-II.97 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Benomyl
I-II-II.98 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Benomyl
I-II-II.99 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2- The imines bacterium Benomyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide
I-II-II.100 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Benomyl
I-II-II.101 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Butadiene morpholine
I-II-II.102 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Butadiene morpholine
I-II-II.103 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Butadiene morpholine
I-II-II.104 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Butadiene morpholine
I-II-II.105 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Butadiene morpholine
I-II-II.106 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Metrafenone
I-II-II.107 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide The imines bacterium Metrafenone
I-II-II.108 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Metrafenone
I-II-II.109 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide The imines bacterium Metrafenone
I-II-II.110 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide The imines bacterium Metrafenone
I-II-II.111 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-trifluoro Oxole bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluoro
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Methyl isophthalic acid H-pyrazole-4-carboxamide Phenyl)-[1,2,4] triazol [1,5-a] pyrimidine
I-II-II.112 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.113 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.114 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.115 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.116 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Carbendazim
I-II-II.117 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Carbendazim
I-II-II.118 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Carbendazim
I-II-II.119 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Carbendazim
I-II-II.120 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium Carbendazim
I-II-II.121 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Thiophanate methyl
I-II-II.122 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- Oxole bacterium Thiophanate methyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide
I-II-II.123 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Thiophanate methyl
I-II-II.124 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Thiophanate methyl
I-II-II.125 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium Thiophanate methyl
I-II-II.126 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Benomyl
I-II-II.127 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Benomyl
I-II-II.128 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Benomyl
I-II-II.129 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Benomyl
I-II-II.130 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium Benomyl
I-II-II.131 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Butadiene morpholine
I-II-II.132 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Butadiene morpholine
I-II-II.133 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Butadiene morpholine
I-II-II.134 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl Oxole bacterium Butadiene morpholine
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide
I-II-II.135 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium Butadiene morpholine
I-II-II.136 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Metrafenone
I-II-II.137 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Metrafenone
I-II-II.138 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Metrafenone
I-II-II.139 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Metrafenone
I-II-II.140 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium Metrafenone
I-II-II.141 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Metalaxyl
I-II-II.142 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Metalaxyl
I-II-II.143 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Metalaxyl
I-II-II.144 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Metalaxyl
I-II-II.145 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium Metalaxyl
I-II-II.146 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Different third is fixed
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.147 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Different third is fixed
I-II-II.148 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Different third is fixed
I-II-II.149 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Different third is fixed
I-II-II.150 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium Different third is fixed
I-II-II.151 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Pyrimethanil
I-II-II.152 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Oxole bacterium Pyrimethanil
I-II-II.153 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Pyrimethanil
I-II-II.154 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Oxole bacterium Pyrimethanil
I-II-II.155 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Oxole bacterium Pyrimethanil
I-II-II.156 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.157 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.158 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl Encircle penta azoles bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluoro
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide Phenyl)-[1,2,4] triazol [1,5-a] pyrimidine
I-II-II.159 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.160 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.161 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Carbendazim
I-II-II.162 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Carbendazim
I-II-II.163 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Carbendazim
I-II-II.164 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Carbendazim
I-II-II.165 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium Carbendazim
I-II-II.166 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Thiophanate methyl
I-II-II.167 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Thiophanate methyl
I-II-II.168 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Thiophanate methyl
I-II-II.169 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Thiophanate methyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.170 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium Thiophanate methyl
I-II-II.171 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Benomyl
I-II-II.172 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Benomyl
I-II-II.173 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Benomyl
I-II-II.174 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Benomyl
I-II-II.175 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium Benomyl
I-II-II.176 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Butadiene morpholine
I-II-II.177 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Butadiene morpholine
I-II-II.178 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Butadiene morpholine
I-II-II.179 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Butadiene morpholine
I-II-II.180 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium Butadiene morpholine
I-II-II.181 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metrafenone
I-II-II.182 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- Encircle penta azoles bacterium Metrafenone
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide
I-II-II.183 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metrafenone
I-II-II.184 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metrafenone
I-II-II.185 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metrafenone
I-II-II.186 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metalaxyl
I-II-II.187 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metalaxyl
I-II-II.188 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metalaxyl
I-II-II.189 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metalaxyl
I-II-II.190 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium Metalaxyl
I-II-II.191 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Different third is fixed
I-II-II.192 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Different third is fixed
I-II-II.193 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Different third is fixed
I-II-II.194 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl Encircle penta azoles bacterium Different third is fixed
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide
I-II-II.195 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium Different third is fixed
I-II-II.196 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Pyrimethanil
I-II-II.197 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Encircle penta azoles bacterium Pyrimethanil
I-II-II.198 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Pyrimethanil
I-II-II.199 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Encircle penta azoles bacterium Pyrimethanil
I-II-II.200 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Encircle penta azoles bacterium Pyrimethanil
I-II-II.201 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.202 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.203 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.204 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.205 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl Triticonazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluoro
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide Phenyl)-[1,2,4] triazol [1,5-a] pyrimidine
I-II-II.206 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Carbendazim
I-II-II.207 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Carbendazim
I-II-II.208 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Carbendazim
I-II-II.209 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Carbendazim
I-II-II.210 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Triticonazole Carbendazim
I-II-II.211 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Thiophanate methyl
I-II-II.212 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Thiophanate methyl
I-II-II.213 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Thiophanate methyl
I-II-II.214 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Thiophanate methyl
I-II-II.215 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Triticonazole Thiophanate methyl
I-II-II.216 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Benomyl
I-II-II.217 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-trifluoromethyl Triticonazole Benomyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide
I-II-II.218 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Benomyl
I-II-II.219 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Benomyl
I-II-II.220 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Triticonazole Benomyl
I-II-II.221 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Butadiene morpholine
I-II-II.222 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Butadiene morpholine
I-II-II.223 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Butadiene morpholine
I-II-II.224 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Butadiene morpholine
I-II-II.225 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Triticonazole Butadiene morpholine
I-II-II.226 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Metrafenone
I-II-II.227 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Metrafenone
I-II-II.228 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Metrafenone
I-II-II.229 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Metrafenone
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.230 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Triticonazole Metrafenone
I-II-II.231 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Metalaxyl
I-II-II.232 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Metalaxyl
I-II-II.233 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Metalaxyl
I-II-II.234 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Metalaxyl
I-II-II.235 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Triticonazole Metalaxyl
I-II-II.236 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Different third is fixed
I-II-II.237 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Different third is fixed
I-II-II.238 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Different third is fixed
I-II-II.239 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Different third is fixed
I-II-II.240 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Triticonazole Different third is fixed
I-II-II.241 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Triticonazole Pyrimethanil
I-II-II.242 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- Triticonazole Pyrimethanil
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide
I-II-II.243 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Pyrimethanil
I-II-II.244 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Triticonazole Pyrimethanil
I-II-II.245 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole Pyrimethanil
I-II-II.246 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.247 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.248 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.249 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.250 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.251 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Carbendazim
I-II-II.252 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Carbendazim
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.253 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Carbendazim
I-II-II.254 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Carbendazim
I-II-II.255 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole Carbendazim
I-II-II.256 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Thiophanate methyl
I-II-II.257 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Thiophanate methyl
I-II-II.258 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Thiophanate methyl
I-II-II.259 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Thiophanate methyl
I-II-II.260 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole Thiophanate methyl
I-II-II.261 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Benomyl
I-II-II.262 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Benomyl
I-II-II.263 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Benomyl
I-II-II.264 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Benomyl
I-II-II.265 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- Fluquinconazole Benomyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide
I-II-II.266 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Butadiene morpholine
I-II-II.267 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Butadiene morpholine
I-II-II.268 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Butadiene morpholine
I-II-II.269 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Butadiene morpholine
I-II-II.270 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole Butadiene morpholine
I-II-II.271 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Metrafenone
I-II-II.272 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Metrafenone
I-II-II.273 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Metrafenone
I-II-II.274 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Metrafenone
I-II-II.275 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole Metrafenone
I-II-II.276 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Metalaxyl
I-II-II.277 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-trifluoromethyl Fluquinconazole Metalaxyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide
I-II-II.278 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Metalaxyl
I-II-II.279 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Metalaxyl
I-II-II.280 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole Metalaxyl
I-II-II.281 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Different third is fixed
I-II-II.282 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Different third is fixed
I-II-II.283 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Different third is fixed
I-II-II.284 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Different third is fixed
I-II-II.285 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole Different third is fixed
I-II-II.286 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Pyrimethanil
I-II-II.287 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Fluquinconazole Pyrimethanil
I-II-II.288 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Pyrimethanil
I-II-II.289 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Fluquinconazole Pyrimethanil
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.290 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Fluquinconazole Pyrimethanil
I-II-II.291 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.292 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.293 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.294 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.295 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Prothioconazoles 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.296 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Carbendazim
I-II-II.297 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Carbendazim
I-II-II.298 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Carbendazim
I-II-II.299 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Carbendazim
I-I-II.300 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl Prothioconazoles Carbendazim
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide
I-II-II.301 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Thiophanate methyl
I-II-II.302 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Thiophanate methyl
I-II-II.303 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Thiophanate methyl
I-II-II.304 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Thiophanate methyl
I-II-II.305 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Prothioconazoles Thiophanate methyl
I-II-II.306 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Benomyl
I-II-II.307 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Benomyl
I-II-II.308 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Benomyl
I-II-II.309 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Benomyl
I-II-II.310 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Prothioconazoles Benomyl
I-II-II.311 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Butadiene morpholine
I-II-II.312 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Butadiene morpholine
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.313 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Butadiene morpholine
I-II-II.314 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Butadiene morpholine
I-II-II.315 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Prothioconazoles Butadiene morpholine
I-II-II.316 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Metrafenone
I-II-II.317 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Metrafenone
I-II-II.318 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Metrafenone
I-II-II.319 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Metrafenone
I-II-II.320 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Prothioconazoles Metrafenone
I-II-II.321 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Metalaxyl
I-II-II.322 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Metalaxyl
I-II-II.323 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Metalaxyl
I-II-II.324 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrrole-4-formamide Prothioconazoles Metalaxyl
I-II-II.325 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- Prothioconazoles Metalaxyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide
I-II-II.326 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Different third is fixed
I-II-II.327 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Different third is fixed
I-II-II.328 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Different third is fixed
I-II-II.329 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Different third is fixed
I-II-II.330 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Prothioconazoles Different third is fixed
I-II-II.331 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Pyrimethanil
I-II-II.332 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Prothioconazoles Pyrimethanil
I-II-II.333 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Pyrimethanil
I-II-II.334 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Prothioconazoles Pyrimethanil
I-II-II.335 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Prothioconazoles Pyrimethanil
I-II-II.336 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.337 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- Tebuconazole 5-chloro-7-(4-methyl piperidine
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide -1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.338 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.339 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.340 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Tebuconazole 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.341 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Carbendazim
I-II-II.342 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Carbendazim
I-II-II.343 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Carbendazim
I-II-II.344 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Carbendazim
I-II-II.345 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Tebuconazole Carbendazim
I-II-II.346 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Thiophanate methyl
I-II-II.347 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Thiophanate methyl
I-II-II.348 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2- Tebuconazole Thiophanate methyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide
I-II-II.349 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Thiophanate methyl
I-II-II.350 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Tebuconazole Thiophanate methyl
I-II-II.351 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Benomyl
I-II-II.352 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Benomyl
I-II-II.353 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Benomyl
I-II-II.354 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Benomyl
I-II-II.355 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Tebuconazole Benomyl
I-II-II.356 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Butadiene morpholine
I-II-II.357 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Butadiene morpholine
I-II-II.358 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Butadiene morpholine
I-II-II.359 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Butadiene morpholine
I-II-II.360 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl Tebuconazole Butadiene morpholine
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide
I-II-II.361 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Metrafenone
I-II-II.362 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Metrafenone
I-II-II.363 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Metrafenone
I-II-II.364 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Metrafenone
I-II-II.365 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Tebuconazole Metrafenone
I-II-II.366 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Metalaxyl
I-II-II.367 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Metalaxyl
I-II-II.368 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Metalaxyl
I-II-II.369 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Metalaxyl
I-II-II.370 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Tebuconazole Metalaxyl
I-II-II.371 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Different third is fixed
I-II-II.372 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Different third is fixed
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
I-II-II.373 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Different third is fixed
I-II-II.374 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Different third is fixed
I-II-II.375 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Tebuconazole Different third is fixed
I-II-II.376 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Pyrimethanil
I-II-II.377 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide Tebuconazole Pyrimethanil
I-II-II.378 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Pyrimethanil
I-II-II.379 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Tebuconazole Pyrimethanil
I-II-II.380 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide Tebuconazole Pyrimethanil
I-II-II.381 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Carbendazim
I-II-II.382 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Carbendazim
I-II-II.383 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Carbendazim
I-II-II.384 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2- 5-chloro-7-(4-methyl piperidine-1- Carbendazim
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Base)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide Base)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine
I-II-II.385 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Carbendazim
I-II-II.386 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Thiophanate methyl
I-II-II.387 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Thiophanate methyl
I-II-II.388 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Thiophanate methyl
I-II-II.389 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Thiophanate methyl
I-II-II.390 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Thiophanate methyl
I-II-II.391 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Benomyl
I-II-II.392 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Benomyl
I-II-II.393 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluoro-benzene Benomyl
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
-1H-pyrazole-4-carboxamide Base)-[1,2,4] triazol [1,5-a] pyrimidine
I-II-II.394 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Benomyl
I-II-II.395 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Benomyl
I-II-II.396 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Butadiene morpholine
I-II-II.397 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Butadiene morpholine
I-II-II.398 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Butadiene morpholine
I-II-II.399 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Butadiene morpholine
I-II-II.400 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Butadiene morpholine
I-II-II.401 N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Metrafenone
I-II-II.402 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] Metrafenone
The mixture sequence number Formula I compound Reactive compound II Reactive compound II
Pyrimidine
I-II-II.403 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Metrafenone
I-II-II.404 N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Metrafenone
I-II-II.405 N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine Metrafenone
The mixture of Compound I and at least a reactive compound II, or simultaneously, i.e. associating or at least a Compound I of separately using and at least a reactive compound II are to the plant pathogenic fungi of wide region, and (synonym: fungi Oomycete (Oomycetes)) has excellent activity especially to be selected from Ascomycetes (Ascomycetes), Basidiomycetes (Basidiomycetes), deuteromycetes (Deuteromycetes) and Peronosporomycetes.The interior suction of in them some is effective and can be used as blade face fungicide, seed dressing is used for crop protection with fungicide and soil fungicide.They can also be used to handle seed.
They are even more important to a large amount of fungies of control in the seed of various cultivated plants such as wheat, rye, barley, oat, rice, corn, lawn, banana, cotton, soybean, coffee, sugarcane, grape vine, fruit and ornamental plants and vegetables such as cucumber, beans, tomato, potato and cucurbitaceous plant and these plants.
They especially are fit to prevent and treat the following plants disease:
● the Alternaria on vegetables, oilseed rape, sugar beet, fruit and the rice (Alternaria), for example epidemic disease chain lattice spores morning (A.solani) on potato and the tomato or chain lattice spore (A.alternata);
● the Aphanomyces on sugar beet and the vegetables (Aphanomyces);
● the Ascochyta on cereal class and the vegetables (Ascochyta);
● flat navel Helminthosporium (Bipolaris) in corn, cereal class, rice and the lawn and interior navel Helminthosporium (Drechslera), for example flat navel of the maize on the corn spore (D.maydis) of wriggling;
● the standing grain powdery mildew on the cereal class (Blumeria graminis) (powdery mildew);
● the Botrytis cinerea on strawberry, vegetables, flowers and the grape vine (Botrytis cinerea) (gray mold),
● the lettuce dish stalk mould (Bremia lactucae) on the lettuce,
● the Cercospora on corn, soybean, rice and the sugar beet (Cercospora);
● cochliobolus on corn, cereal class, the rice belongs to (Cochliobolus), the standing grain cochliobolus on the cereal class (Cochliobolus sativus) for example, the palace portion cochliobolus (Cochliobolusmiyabeanus) on the rice;
● the perverse dish spore on soybean and the cotton belongs to (Colletotricum);
● the interior navel Helminthosporium (Drechslera) on corn, cereal class, rice and the lawn, nuclear cavity Pseudomonas (Pyrenophora), for example wriggle D.tritci-repentis on spore (D.teres) or the wheat of navel in the barley filigree on the barley;
● the Eschka (Esca) on the grape vine that causes by Phaeoacremonium chlamydosporium, Ph.Aleophilum and Formitiporapunctata (synonym spot hole Phellinus (Phellinus punctatus));
● the prominent navel Helminthosporium (Exserohilum) on the corn,
● two spore powdery mildews (Erysiphe cichoracearum) on the cucumber and monofilament shell powdery mildew (Sphaerotheca fuliginea),
● Fusarium on each plant species (Fusarium) and Verticillium (Verticillium), for example fusarium graminaria (F.graminearum) on the cereal class or the sharp sickle spore (F.oxysporum) on machete sickle spore (F.culmorum) or various plants such as the tomato;
● the gaeumannomyce on the cereal class (Gaeumanomyces graminis);
● the Gibberella on cereal class and the rice (Gibberella) (for example gibberella fujikuroi on the rice (Gibberellafujikuroi));
● the Grainstaining complex on the rice;
● the Helminthosporium on corn and the rice (Helminthosporium);
● the Michrodochium nivale on the cereal class;
● the mycosphaerella on cereal class, banana and the peanut (Mycosphaerella), for example standing grain green-ball chamber bacterium (M.graminicola) on the wheat or the Fijian ball chamber bacterium (M.fijiensis) on the banana;
● the Peronospora (Peronospora) on cabbage and the bulb plant, for example rape downy mildew (P.brassicae) on the cabbage or the shallot downy mildew (P.destructor) on the onion;
● yam bean layer rest fungus (Phakopsora pachyrhizi) on the soybean and mountain horseleech layer rest fungus (Phakopsara meibomiae);
● the Phomopsis on soybean and the sunflower (Phomopsis);
● the phytophthora infestans on potato and the tomato (Phytophthora infestans);
● the Phytophthora on each plant species (Phytophthora), for example Phytophthora capsici on the green pepper (P.capsici);
● the grape on the grape vine is given birth to single shaft mould (Plasmopara viticola),
● the apple mildew bacterium on the apple (Podosphaera leucotricha),
● the rotten germ (Pseudocercosporella herpotrichoides) of the wheat-based on the cereal class,
● the false Peronospora (Pseudoperonospora) on each plant species, for example the humulus false frost of grass (P.Humili) on false downy mildew (P.Cubensis) of the Cuba on the cucumber or the lupulus;
● the Puccinia on each plant species (Puccinia), for example the wheat handle rest fungus (P.triticina) on the cereal class, bar shaped handle rust (P.striformis), barley handle rust (P.hordei) or puccinia graminis (P.graminis), or the Asparagus handle rust (P.asparagi) on the asparagus);
● the Pyricularia oryzae on the rice (Pyricularia oryzae), Bamboo grass wood photovoltaicing leather bacteria (Corticium sasakii), broom stalk Cylindrocarpon (Sarocladium oryzae), sheath rot of rice plant (S.attenuatum), rice leaf smut (Entyloma oryzae)
● the piricularia oryzae on lawn and the cereal class (Pyricularia grisea),
● the pythium on lawn, rice, corn, cotton, oilseed rape, sunflower, sugar beet, vegetables and the other plant (Pythium), the ultimate pythium spp (P.ultiumum) on each plant species for example, the melon and fruit corruption on the lawn mould (P.aphanidermatum);
● the Rhizoctonia (Rhizoctonia) on cotton, rice, potato, lawn, corn, oilseed rape, sugar beet, vegetables and each plant species, for example the miliary damping-off germ (R.solani) on beet and each plant species;
● the rye beak spore (Rhynchosporium secalis) on barley, rye and the triticale;
● the Sclerotinia on oilseed rape and the sunflower (Sclerotinia);
● wheat septoria on the wheat (Septoria tritici) and the many spores of clever withered shell (Stagonosporanodorum),
● the grape snag shell on the grape vine (Erysiphe (synonym Uncinula) necator),
● the Setospaeria on corn and the lawn belongs to,
● the silk axle smut (Sphacelotheca reilinia) on the corn,
● the Thiclaviopsis on soybean and the cotton (Thievaliopsis),
● the Tilletia on the cereal class (Tilletia),
● the Ustilago on cereal class, corn and the sugarcane (Ustilago), for example Ustilago maydis on the corn (U.maydis);
● the Venturia on apple and the pears (Venturia) (scab), for example apple scab on the apple (V.inaequalis).
Mixture of the present invention also is suitable for preventing and treating the product of harmful fungoid with protective material (as timber, paper, lacquer dispersion, fiber or fabric) and protection storage.In wood protection, should note following harmful fungoid especially: the Ascomycetes fungi, belong to (Ophiostoma spp.) as line mouth shell, long beak shell belongs to (Ceratocystisspp.), Aureobasidium pullulans (Aureobasidium pullulans), Sclerophoma spp., Chaetomium (Chaetomium spp.), Humicola (Humicola spp.), Peter's shell belongs to (Petriella spp.), the mould genus of pieces (Trichurus spp.); The Basidiomycetes fungi; belong to (Coniophoraspp.) as cellar fungus; Coriolus Qu61 (Coriolus spp.); sticking gill fungus belongs to (Gloeophyllum spp.); Lentinus (Lentinus spp.); Pleurotus (Pleurotus spp.); hole genus (Poria spp.) crouches; Merulius (Serpula spp.) and cheese Pseudomonas (Tyromyces spp.); the deuteromycetes fungi; as aspergillus (Aspergillus spp.); Cladosporium (Cladosporium spp.); Penicillium (Penicillium spp.); trichoderma (Trichoderma spp.), Alternaria (Alternaria spp.), paecilomyces (Paecilomyces spp.) and Zygomycetes (Zygomycetes) fungi; as mucor (Mucor spp.), should note following yeast in this external material protection: candida (Candida spp.) and saccharomyces cerevisiae (Saccharomyces cerevisae).
Compound I and at least a reactive compound II can be simultaneously, i.e. associating or separate administration or use successively, under the situation of separate administration order of administration usually to the prophylactico-therapeutic measures result without any influence.
When the preparation mixture, preferably use pure reactive compound I and II, can be to the reactive compound or activity of weeding or growth regulating-activity compound or the fertilizer that wherein add other antagonism harmful fungoids or other insects such as insect, spider or nematode.
Such mixture of three kinds of reactive compounds for example comprises formula I compound, especially N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide or N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide, A) Zu azole, especially oxole bacterium, encircle penta azoles bacterium, triticonazole or Fluquinconazole, and insecticide, especially sharp strength spy of wherein suitable insecticide (fipronil) and anabasine are as pyrrole worm clear (acetamiprid), thiophene worm amine (clothianidin), MTI-446 (dinotefuran), Imidacloprid (imidacloprid), nitenpyram (nitenpyram), thiophene worm quinoline (thiacloprid) and thiophene worm piperazine (thiamethoxam).
Usually use the mixture of at least a Compound I and at least a reactive compound II.Yet the mixture of at least a in some cases Compound I and two kinds or the more kinds of active components of words that need may be particularly advantageous.
Other suitable on above-mentioned meaning active components especially start the reactive compound II that is mentioned, particularly above-mentioned preferred reactive compound II.
Compound I and reactive compound II are usually with 100: 1-1: 100, preferred 20: 1-1: 20, especially 10: 1-1: 10 weight ratio is used.
Need, other active components are with 20: 1-1: 20 ratio adds in the Compound I.
The type and the required effect that depend on Compound I and II, the mixture of the present invention especially rate of application under the situation of agricultural crops zone are 5-2000g/ha, preferred 20-1500g/ha, especially 50-1000g/ha.
Correspondingly, the rate of application of Compound I is generally 1-1000g/ha, preferred 10-900g/ha, especially 20-750g/ha.
Correspondingly, the rate of application of reactive compound II is generally 1-2000g/ha, preferred 10-1500g/ha, especially 40-1000g/ha.
In seed treatment, the rate of application of mixture is generally the 1-1000g/100kg seed, preferred 1-750g/100kg, especially 5-500g/100kg seed.
Methods for fighting harmful mushrooms by before or after the plant seeding or plant emerge before or after by to seed, plant or soil spraying or dusting separates or the mixture of co-administered Compound I and at least a reactive compound II or Compound I and at least a reactive compound II carries out.
Fungicidal mixture of the present invention or Compound I and at least a reactive compound II can be changed into conventional preparaton, for example solution, emulsion, suspension, pulvis, powder, paste or particle.Type of service depends on the specific purpose that is intended to; Should guarantee the meticulous as far as possible and distribution equably of mixture of the present invention in each case.
Preparaton prepares in a manner known way, for example prepares by reactive compound is mixed with solvent and/or carrier, and the words that need are used emulsifier and dispersant.Solvent/the auxiliary agent suitable to this purpose is mainly:
-water, arsol (as
Figure A20068002894401171
Product, dimethylbenzene), paraffin (as mineral oil fractions), alcohols (as methyl alcohol, butanols, amylalcohol, benzylalcohol), ketone (as cyclohexanone, gamma-butyrolacton), pyrrolidones (N-Methyl pyrrolidone, N-octylpyrrolidone), acetic acid esters (ethylene acetate), dihydroxylic alcohols, fatty acid dimethylformamide, fatty acid and fatty acid ester.Can also use solvent mixture in principle.
-carrier is as natural minerals (as kaolin, clay, talcum, chalk) that grinds and the synthetic mineral (as silica, the silicate of high degree of dispersion) that grinds; Emulsifier such as nonionic and anion emulsifier (as polyoxyethylene aliphatic alcohol ether, alkylsulfonate and arylsulphonate) and dispersant such as lignin sulfite waste liquor and methylcellulose.
Used suitable surfactant is a lignosulphonic acid, naphthalene sulfonic acids, phenolsulfonic acid, the alkali metal salt of dibutyl naphthalene sulfonic acids, alkali salt and ammonium salt, alkylaryl sulfonates, alkyl sulfate, alkylsulfonate, aliphatic alcohol sulfate, fatty acid and sulphated fatty alcohol glycol ether, the condensation product of sulfonated naphthalene and naphthalene derivatives and formaldehyde in addition, the condensation product of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde, NONIN HS 240, the ethoxylation isooctylphenol, octyl phenol, nonyl phenol, the alkyl phenyl polyglycol ether, tributyl phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, pure and mild fatty alcohol/ethylene oxide condensation product, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorbitol ester, lignin sulfite waste liquor and methylcellulose.
Being suitable for preparing directly, the material of spray solution, emulsion, paste or oil dispersion is that mid-boiling point arrives high boiling mineral oil fractions, as kerosene or diesel oil, the oil that also has coal tar and plant or animal origin in addition, aliphatic series, ring-type and aromatic hydrocarbon, for example toluene, dimethylbenzene, paraffin, tetrahydronaphthalene, alkylated naphthalene or derivatives thereof, methyl alcohol, ethanol, propyl alcohol, butanols, cyclohexanol, cyclohexanone, isophorone, intensive polar solvent, for example methyl-sulfoxide, N-Methyl pyrrolidone and water.
But powder, broadcast sowing with material and dusting product can by with active substance with at least-kind of a solid carrier mixes or grinds simultaneously and prepare.
Particle such as coated particle, impregnated granules and homogeneous particle can be by preparing reactive compound and the adhesion of at least a solid carrier.The example of solid carrier is that ore deposit soil is as silica gel, silicate, talcum, kaolin, activated clay (attaclay), lime stone, lime, chalk, bole, loess, clay, dolomite, diatomite, calcium sulphate, magnesium sulfate, magnesia; The synthetic material that grinds; Fertilizer such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea; The product of plant origin such as flour, bark powder, wood powder and shuck powder, cellulose powder and other solid carrier.
Preparaton comprises 0.01-95 weight % usually, the Compound I of preferred 0.1-90 weight % and the mixture of at least a reactive compound II or Compound I and at least a reactive compound II.Reactive compound is with 90-100%, and the purity of preferred 95-100% (according to NMR or HPLC spectrum) is used.
Under classify the preparaton example as:
1. the product of dilute with water
A) water-soluble concentrate (SL)
10 weight portions mixture of the present invention is dissolved in 90 weight parts waters or the water-soluble solvent.Perhaps, add wetting agent or other auxiliary agent.Reactive compound is through water dilution dissolving.Obtain the preparaton that the reactive compound total content is 10 weight % in this way.
B) dispersed concentrate (DC)
Be dissolved in 20 weight portions mixture of the present invention in the 70 weight portion cyclohexanone and add 10 weight portion dispersant such as PVP(polyvinyl pyrrolidone).Dilute with water obtains dispersion.Reactive compound content is 20 weight %.
C) emulsible concentrate (EC)
Be dissolved in 15 weight portions mixture of the present invention in the 75 weight portion dimethylbenzene and add calcium dodecyl benzene sulfonate and castor oil ethoxylate (being 5 weight portions in each case).Dilute with water obtains emulsion.The reactive compound content of this preparaton is 15 weight %.
D) emulsion (EW, EO)
Be dissolved in 25 weight portions mixture of the present invention in the 35 weight portion dimethylbenzene and add calcium dodecyl benzene sulfonate and castor oil ethoxylate (being 5 weight portions in each case).Introduce this mixture in 30 weight parts waters and make equal phase emulsion by mulser (Ultraturrax).Dilute with water obtains emulsion.The reactive compound content of this preparaton is 25 weight %.
E) suspension (SC, OD)
In the ball mill that stirs, 20 weight portions mixture of the present invention is pulverized and added 10 weight portion dispersants and wetting agent and 70 weight parts waters or organic solvent, obtain reactive compound suspension in small, broken bits.Dilute with water obtains stable reactive compound suspension.Reactive compound content in this preparaton is 20 weight %.
F) water-dispersible granule and water-soluble granular (WG, SG)
With the grinding in small, broken bits of 50 weight portions mixture of the present invention and add 50 weight portion dispersant and wetting agents, be made into water dispersible or water-soluble granular by commercial plant (as extruder, spray tower, fluid bed).Dilute with water obtains stable active compound dispersion or solution.The reactive compound content of this preparaton is 50 weight %.
G) water dispersible pow-ders and water-soluble powder (WP, SP)
75 weight portions mixture of the present invention ground in the rotor-stator grinding machine and add 25 weight portion dispersants, wetting agent and silica gel.Dilute with water obtains stable active compound dispersion or solution.The reactive compound content of this preparaton is 75 weight %.
2. the product of using without dilution
H) but dusting powder (DP)
Fully mix with the grinding in small, broken bits of 5 weight portions mixture of the present invention and with 95 weight portions kaolin in small, broken bits.But this obtains the dusting product that reactive compound content is 5 weight %.
J) particle (GR, FG, GG, MG)
With the grinding in small, broken bits of 0.5 weight portion mixture of the present invention and in conjunction with 99.5 weight portion carriers.Current methods be extrude, atomized drying or bed process.This obtains the particle of using without dilution that reactive compound content is 0.5 weight %.
K) ULV solution (UL)
10 weight portions mixture of the present invention is dissolved in 90 weight portion organic solvents such as the dimethylbenzene.This obtains the product of using without dilution that reactive compound content is 10 weight %.
Reactive compound can be directly, with its preparaton form or type of service prepared therefrom (but as directly spray solution, powder, suspension or dispersion, emulsion, oil dispersion, paste dusting product, broadcast sowing), by spraying, atomizing, dusting, broadcast sowing or water and use with material or particle.Type of service depends on the purpose that is intended to fully; Be intended to guarantee in each case that the best of reactive compound may distribute.
Moisture type of service can be prepared by emulsion concentrates, paste or wettable powder (sprayable powder, oil dispersion) by adding entry.Be preparation emulsion, paste or oil dispersion, can be with this material directly or be dissolved in back homogenizing in water in oil or the solvent by wetting agent, tackifier, dispersant or emulsifier.Yet, can also prepare concentrate and this concentrate formed by active substance, wetting agent, tackifier, dispersant or emulsifier and suitable solvent or oil and be suitable for dilute with water.
Promptly can in relative broad range, change with the activity compound concentration in the preparation.They are generally 0.0001-10%, preferred 0.01-1%.
Reactive compound also can successfully be used for ultra low volume method (ULV), wherein can use to comprise the preparaton that surpasses 95 weight % reactive compounds, or even use the reactive compound that does not contain additive.
Can in reactive compound, add various types of oil, wetting agent, adjuvant, weed killer herbicide, other pest control agent or bactericide, even the words that need only add (bucket mixes) before being close to use.These reagent usually with mixture of the present invention with 1: 100-100: 1, preferred 1: 10-10: 1 weight ratio mixing.
The polysiloxanes that suitable thus adjuvant is especially organically-modified, for example Break ThruS
Figure A20068002894401201
Alcohol alkoxylates, for example Atplus
Figure A20068002894401202
Atplus MBA
Figure A20068002894401203
PlurafacLF
Figure A20068002894401204
With
Figure A20068002894401205
ON 30; The EO/PO block polymer, for example
Figure A20068002894401206
RPE 2035 Hes
Figure A20068002894401207
B; Alcohol ethoxylate, for example
Figure A20068002894401208
XP 80; And sulfosuccinic acid dioctyl ester sodium, for example
Figure A20068002894401209
RA.
Compound I and II or mixture or corresponding preparaton need maybe to prevent that by handle harmful fungoid, its habitat with the mixture of antifungal effective dose or the Compound I under the separate administration situation and II their plant, seed, soil, zone, material or space from using.Use and before or after harmful fungoid infects, to carry out.
Application Example
The fungicidal action of each compound of the present invention and mixture is confirmed by following test:
Use solvent/emulsifier volume ratio is 99: 1 acetone and/or methyl-sulfoxide and an emulsifier
Figure A200680028944012010
The mixture of EL (wetting agent based on ethoxylated alkylphenol with emulsification and peptizaiton) with reactive compound separately or unite and make the stock solution that comprises the 25mg reactive compound and be made into 10ml.Then this mixture water is made into 100ml.Dilute this stock solution to following activity compound concentration with described solvent/emulsifier/aqueous mixtures.
Perhaps promptly use reactive compound oxole bacterium, triticonazole and pyraclostrobin and they are diluted with water to following activity compound concentration with preparaton with commercially available.
The leaf area percentage that infects that naked eyes are measured changes into the effectiveness of representing with the % with respect to untreated control.
Use the Abbot formula to render a service (E) by following calculating:
E＝(1-α/β)·100
α corresponding to the fungal infection percentage of handling plant and
β is corresponding to the fungal infection percentage of (contrast) plant of being untreated.
Effectiveness is that 0 infecting of plant of expression processing is on close level in untreated check plant; Effectiveness is that 100 expression processing plants are infected.
The expection effectiveness use Colby formula (Colby S.R., " Synergistic and the antagonism that calculate combinations of herbicides are corresponding ", Weeds (weeds) 15, the 20-22 pages or leaves, 1967) of reactive compound combination is determined and is compared with the effectiveness of observing.
Colby formula: E=x+y-xy/100
Expection when the E working concentration is the mixture of the reactive compound A of a and b and B is renderd a service, represents with % with respect to untreated control,
Effectiveness when the x working concentration is the reactive compound A of a is represented with the % with respect to untreated control,
Effectiveness when the y working concentration is the reactive compound B of b is represented with the % with respect to untreated control.
Application Example 1-is to the activity of the tomato early blight that caused by epidemic disease chain lattice spore morning (Alternaria solani)
The leaf of potted plant tomato plant is sprayed to the drip point with activity compound concentration aqueous suspension as described below.Leaf infected with the moisture spore suspension of epidemic disease chain lattice spore in 2% biological malt solution early in second day, this suspension has 0.17 * 10 6The density of individual spore/ml.Then plant being placed temperature is 20-22 ℃ steam-laden chamber.After 5 days, the disease on the check plant that is untreated but infects has developed into and can measure the degree that infects with percentage by naked eyes.
Reactive compound/active compound combinations Concentration [mg/l] Ratio Observed activity (% infects) According to Colby activity calculated (%)
(contrast) --- --- 0 (90% infects) ---
Reactive compound/active compound combinations Concentration [mg/l] Ratio Observed activity (% infects) According to Colby activity calculated (%)
The Ia.719 compound 4 --- 0 ---
Prochloraz 16 --- 30 ---
Pyraclostrobin 4 --- 50 ---
Carbatene 63 --- 0 ---
Tpn 63 --- 0 ---
Ia.719 compound+Prochloraz 4+16 1∶4 60 30
Ia.719 compound+pyraclostrobin 4+4 1∶1 93 50
Ia.719 compound+Carbatene 4+63 1∶4 70 0
Ia.179 compound+tpn 4+63 1∶4 70 0
Application Example 2-is to the activity of the green pepper leaf gray mold that caused by Botrytis cinerea (Botrytis cinerea), and protectiveness was used in 1 day
Cultivar is sprayed to drip point with activity compound concentration aqueous suspension as described below for the green pepper rice shoot of " Neusiedler Ideal Elite " behind the 2-3 sheet leaf that reaches full growth out.To handle plant in second day, to be used in concentration be to contain 1.7 * 10 in 2% the biological malt water solution 6The spore suspension inoculation of the Botrytis cinerea of individual spore/ml.Then test plant is placed the dark climate regulation chamber of 22-24 ℃ and high atmospheric humidity.Can the percentage naked eyes after 5 days measure the fungal infection degree on the leaf.
Reactive compound/active compound combinations Concentration [mg/l] Ratio Observed activity (% infects) According to Colby activity calculated (%)
(contrast) --- --- 0 (100% infects) ---
The Id.344 compound 1 --- 40 ---
The Ia.344 compound 16 --- 60 ---
The Ij.344 compound 4 1 --- --- 22 0 --- ---
Triticonazole 4 --- 0 ---
Prochloraz 4 --- 11 ---
Dimethomorph 63 16 4 --- --- --- 0 0 0 --- --- ---
Carbatene 16 --- 0 ---
Metrafenone 63 16 4 --- --- --- 0 0 0 --- --- ---
Id.344 compound+dimethomorph 1+4 1∶4 80 40
Id.344 compound+Carbatene 1+16 1∶ 16 70 40
Reactive compound/active compound combinations Concentration [mg/l] Ratio Observed activity (% infects) According to Colby activity calculated (%)
Id.344 compound+metrafenone 1+4 1∶4 60 40
Ia.344 compound+dimethomorph 16+63 1∶4 85 60
Ia.344 compound+metrafenone 16+63 1∶4 90 60
Ij.344 compound+triticonazole 4+4 1∶1 78 22
Ij.344 compound+Prochloraz 1+4 1∶4 92 11
Ij.344 compound+dimethomorph 4+16 1∶4 78 22
Ij.344 compound+metrafenone 4+16 1∶4 100 22
The therapeutic activity of the wheat leaf rust that Application Example 3-Puccinia recondita f. sp. tritici (Puccinia recondita) causes
The leaf of potted plant wheat rice shoot that with cultivar is " Kanzler " is with the spore suspension inoculation of wheat leaf rust bacterium (Puccinia recondita f. sp. tritici).Under 20-22 ℃, basin was placed on then in the chamber of high atmospheric humidity (90-95%) 24 hours.Spore germination and germ tube are penetrated in the leaf texture during this period.The plant that to infect in second day is sprayed to the drip point with activity compound concentration above-mentioned active compounds solution as described below.After the spray-painting drying, it is cultivation 7 days in the greenhouse of 65-70% with relative atmospheric humidity that test plant is 20-22 ℃ in temperature.Measure the development degree of rust fungi on leaf then.
Reactive compound/active compound combinations Concentration [mg/l] Ratio Observed activity (% infects) According to Colby activity calculated (%)
(contrast) --- --- 0 (90% infects) ---
The Id.344 compound 1 --- 0 ---
The Ij.344 compound 1 --- 0 ---
The Ia.719 compound 0.25 --- 0 ---
Oxole bacterium 0.063 --- 0 ---
Triticonazole 1 --- 0 ---
Pyraclostrobin 1 --- 0 ---
Tpn 16 --- 0 ---
5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine 4 --- 40 ---
Id.344 compound+triticonazole 1+1 1∶1 56 0
Id.344 compound+pyraclostrobin 1+1 1∶1 83 0
Id.344 compound+tpn 1+16 1∶16 78 0
Ij.344 compound+5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluoro-benzene 1+4 1∶4 100 40
Reactive compound/active compound combinations Concentration [mg/l] Ratio Observed activity (% infects) According to Colby activity calculated (%)
Base)-[1,2,4] triazol [1,5-a] pyrimidine
Ia.719 compound+oxole bacterium 0.25+0.063 4∶1 30 0
Application Example 4-is to the activity of the net blotch of barley that caused by net blotch (Pyrenophora teres), and protectiveness was used in 1 day
The leaf of potted plant barley rice shoot is sprayed to the drip point with activity compound concentration aqueous suspension as described below.Dry back 24 hours of spray-painting is with the moisture spore suspension inoculation of test plant with net blotch (Pyrenophora[synonym Drechslera] teres)-net blotch pathogene.Then test plant is put into temperature and is 20-24 ℃ and relatively atmospheric humidity be the greenhouse of 95-100%.The % naked eyes that infect with whole leaf area after 6 days are measured the development of disease degree.
Reactive compound/active compound combinations Concentration [mg/l] Ratio Observed activity (% infects) According to Colby activity calculated (%)
(contrast) --- --- 0 (90% infects) ---
The Id.344 compound 0.25 --- 67 ---
Oxole bacterium 0.063 --- 0 ---
Id.344 compound+oxole bacterium 0.25+0.063 4∶1 83 67
Result of the test shows that owing to the Synergistic phenomenon mixture of the present invention will significantly have more activity with using comparing of Colby formula expection.

Claims (11)

1. Fungicidal mixture that is used to prevent and treat the plant-pathogenic harmful fungoid, this mixture comprises following compound with the Synergistic effective dose:
1) the 1-methyl-pyrazol-4-yl carboxylic acid anilides of at least a formula I:
Figure A20068002894400021
Wherein each substituting group is following defines:
X is an oxygen;
R 1Be C 1-C 4Alkyl or C 1-C 4Haloalkyl;
R 2Be hydrogen or halogen;
R 3, R 4R 5Be cyano group, nitro, halogen, C independently of each other 1-C 4Alkyl, C 1-C 4Haloalkyl, C 1-C 4Alkoxyl, C 1-C 4Halogenated alkoxy or C 1-C 4Alkylthio group;
With
2) Zu the reactive compound II at least a A that is selected from)-F):
A) be selected from following azole: Bitertanol, bromuconazole, cyproconazole Difenoconazole, alkene azoles alcohol, IMAZALIL, oxole bacterium, Fluquinconazole, RH-7592, Flusilazole, Flutriafol, own azoles alcohol, the acid amides azoles, cycltebuconazole, encircle penta azoles bacterium, nitrile bacterium azoles, penconazole, propiconazole, prothioconazoles, simeconazoles, triazolone, triadimenol, Tebuconazole, fluorine ether azoles, triticonazole, Prochloraz, pefurazoate, IMAZALIL, fluorine bacterium azoles, cyanogen frost azoles, benomyl, carbendazim, thiabendazole, furidazol, Guardian, kobam and hydroxyisoxazole;
B) be selected from following strobilurins class: nitrile Fluoxastrobin, ether bacterium amine, Enestroburin, fluoxastrobin, imines bacterium, fork phenalgin acid amides, orysastrobin, ZEN 90160, pyraclostrobin, oxime bacterium ester, (2-chloro-5-[1-(3-methyl benzyloxy imino) ethyl] benzyl) methyl carbamate, (2-chloro-5-[1-(6-picoline-2-base methoxyimino) ethyl] benzyl) methyl carbamate and 2-(neighbour-(2,5-dimethyl phenoxy methylene) phenyl)-3-methoxy-methyl acrylate;
C) be selected from following carboxylic acid amides: carboxin, M 9834, Boscalid, fenhexamid, flutolanil, the spirit of furan pyrazoles, third oxygen embroidery amine that goes out, metalaxyl, Metalaxyl-M, the spirit of fenfuram Evil frost, oxycarboxin, the pyrrole metsulfovax, thifluzamide, tiadinil, 3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide, dimethomorph, flumorph, fluorine biphenyl bacterium, fluorine pyrrole bacterium amine, zoxamide, carpropamide, two chlorine zarilamids, mandipropamid amine, N-(2-{4-[3-(4-chlorphenyl) third-2-alkynyloxy group]-the 3-anisyl } ethyl)-2-methanesulfonamido-3-methylbutyryl amine, N-(2-{4-[3-(4-chlorphenyl)-third-2-alkynyloxy group]-the 3-anisyl } ethyl)-2-second sulfonamido-3-methylbutyryl amine, 3-(4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) methyl propionate, the formula III compound:
Figure A20068002894400031
R wherein 4Be methyl or ethyl,
N-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide, N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-and 3-difluoromethyl-1-methylpyrazole-4-formamide and N-(2-cyano-phenyl)-3,4-two chloroisothiazoles-5-formamide;
D) be selected from following heterocyclic compound: fluazinam, pyrifenox, the phonetic bacterium spirit of sulphur, encircle third pyrimidine, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil, triforine, fenpiclonil Fu Evil bacterium, 4-dodecyl-2, the 6-thebaine, dodemorfe; butadiene morpholine; tridemorph; fenpropidin; different third is fixed; sterilization profit; vinclozolin; azolactone bacterium; Fenamidone; different thiophene bacterium ketone; probenazole; 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2; 4; the 6-trifluorophenyl)-[1; 2; 4] triazols [1,5-a] pyrimidine; anilazine; diclomezine; pyroquilon; the third oxygen quinoline; tricyclazole; formula IV compound (2-butoxy-6-iodo-3-propyl group chromene-4-ketone):
Figure A20068002894400032
The N of thiadiazoles element, difoltan, captan, dazomet, folpet, zarilamid, quinoxyfen and formula V, N-dimethyl-3-(3-bromo-6-fluoro-2 methyl indole-1-sulfonyl)-[1,2,4] triazole-1-sulfonamide:
E) be selected from following Carbamates: 3-(4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) propionic acid of mancozeb, maneb, metham-sodium, Carbatene, ferbam, propineb, tmtd, zineb, ziram, the mould prestige of second, iprovalicarb, benzene metsulfovax, hundred dimension spirits, N-(1-(1-(4-cyano-phenyl) ethylsulfonyl) fourth-2-yl) carbamic acid 4-fluorophenyl ester, formula VI
Methyl esters:
Figure A20068002894400042
Carbamic acid lactazone ether with formula VII:
Figure A20068002894400043
Wherein Z is N or CH;
F) be selected from other following fungicides: guanidine class: dodine, biguanide spicy acid salt, guazatine, antibiotic class: spring thunder element, streptomycin, Polyoxin, jinggangmeisu, nitrophenyl derivative: binapacryl, karathane, dinobuton, sulfur heterocyclic ring based compound: Delan, Isoprothiolane, organo-metallic compound: triphenyltin salt, organic phosphorus compound: Hinosan, iprobenfos, fosetyl, ethyl phosphine aluminium, phosphorous acid and salt thereof, Ppyrazophos, tolelofos-methyl, organochlorine compound: tpn, Euparen, flusulfamide, hexachloro-benzene, Rabcide, Pencycuron, pcnb, thiophanate methyl, tolyfluanid, inorganic active compound: bordeaux mixture, Schweinfurt green, Kocide SD, Cupravit, basic copper sulfate, sulphur, other: cyflufenamid, cymoxanil, Milcurb, Milstem, Furalaxyl, metrafenone is with the luxuriant amine of Luo Evil.
2. according to the Fungicidal mixture of claim 1, comprise as component 1) the 1-methyl-pyrazol-4-yl carboxylic acid anilides of formula I, R wherein 1Be methyl or halogenated methyl, R 2Be hydrogen, fluorine or chlorine and R 3, R 4And R 5The halogen of respectively doing for oneself.
3. according to the Fungicidal mixture of claim 1, comprise as component 1) at least a be selected from down the group Compound I: N-(2 '-fluoro-4 '-chloro-5 '-methoxyl biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 '-fluoro-4 '-chloro-5 '-methoxyl biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 ', 3 ', 4 '-trifluoro-biphenyl-2-yl)-3-Trifluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-one chlorodifluoramethyl--1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(2 ', 3 ', 4 '-trifluoro-biphenyl-2-yl)-3-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide and N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide.
4. according to each Fungicidal mixture among the claim 1-3, with 100: 1-1: 100 weight ratio comprises component 1) and 2).
5. composition comprises at least a liquid or solid carrier and according to each mixture among the claim 1-3.
6. method of preventing and treating the plant-pathogenic harmful fungoid is wherein handled the maybe needs plant, soil, seed, zone, material or the space that prevent fungal attack of fungi, its habitat with effective dose according to each at least a Compound I and at least a Compound I I among the claim 1-3.
7. according to the method for claim 6, wherein simultaneously, i.e. associating or separate administration or use successively according to each component 1 among the claim 1-3) and 2).
8. according to the method for claim 6 or 7, wherein use according to each component 1 among the claim 1-3 with the amount of 5-2000g/ha) and 2).
9. according to the method for claim 6 or 7, wherein use according to each component 1 among the claim 1-3 with the amount of 1-1000g/100kg seed) and 2).
10. seed comprises according to each mixture among the claim 1-3 with the amount of 1-1000g/100kg seed.
11. be suitable for preventing and treating purposes in the composition of harmful fungoid in preparation according to each Compound I and II among the claim 1-3.
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