CN105831139A - Bactericidal composition containing fluxapyroxad and benomyl and application thereof - Google Patents
Bactericidal composition containing fluxapyroxad and benomyl and application thereof Download PDFInfo
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- CN105831139A CN105831139A CN201610265876.8A CN201610265876A CN105831139A CN 105831139 A CN105831139 A CN 105831139A CN 201610265876 A CN201610265876 A CN 201610265876A CN 105831139 A CN105831139 A CN 105831139A
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- Prior art keywords
- benomyl
- fluxapyroxad
- bactericidal composition
- composition
- bactericidal
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The invention discloses a bactericidal composition containing fluxapyroxad and benomyl and an application thereof. The bactericidal composition takes fluxapyroxad and benomyl as main active ingredients, wherein the mass ratio of fluxapyroxad to benomyl is (1-70) to (1-50). The bactericidal composition can be used for controlling cereal, fruit tree and vegetable diseases, has higher synergistic effects, has the effects of overcoming and delaying the drug resistance of germs, has a high bactericidal speed and a long lasting period, has the effect of reducing the application cost and has obviously better control effects than single agents. The bactericidal composition can be used for controlling fungal diseases on crops, especially fungal diseases, such as sheath blight, gray mold, fusarium wilt of cucumber, pepper anthracnose, and the like, and has better effects than single agents.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially one is main with fluxapyroxad and benomyl
The bactericidal composition of active component and application thereof.
Background technology
Fluxapyroxad (fluxapyroxad), chemical formula: C18H12F5N3O, chemical name: 3-(difluoromethyl)-1-first
Base-N-(3', 4', 5'-trifluoro-biphenyl-2-base) pyrazole-4-carboxamide.
Fluxapyroxad belongs to benzamide type antibacterial, for succinate dehydrogenase inhibitors, is a kind of broad-spectrum germicide,
There is the treatment of excellence, systemic activity, all kinds of crop banded sclerotial blights, gray mold etc. are respectively provided with good control effect.
Benomyl (Benomyl), molecular formula: C14H18N4O3, chemical name: 1-n-butylamine-based formyl-benzimidazolyl-2 radicals-ammonia
Base methyl formate.Structural formula:
Benomyl is systemic fungicide, is carbendazim and another kind has volatility Carbimide. fourth at plant intracellular metabolite
Ester, is its major antibacterial material.Benomyl can be used for preventing and treating the multiple diseases of the crops such as vegetable, fruit tree, rice wheat, is commonly used for mixing
Kind, spraying and soil treatment, in addition to protected and therapeutical effect, also there is acaricidal action.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, along with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty strengthens；Separately
On the one hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, low cost, effective fluorine-containing for above-mentioned technical problem
Azoles bacterium amide and the plant bactericidal composition of benomyl.
It is a still further object of the present invention to provide this bactericidal composition and cause answering on fungal disease at preventing and treating plant epiphyte
With, especially in the purposes prevented and treated on the fungal diseases such as banded sclerotial blight, gray mold, cucumber fusarium axysporum, pepper anthracnose.
It is an object of the invention to be achieved through the following technical solutions:
A kind of Fluxapyroxad-containsterilization and the bactericidal composition of benomyl, this bactericidal composition is with fluxapyroxad and benomyl
For principle active component, wherein fluxapyroxad is 1～70:1～50 with the mass ratio of benomyl, wherein has in bactericidal composition
Effective constituent is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein fluxapyroxad is preferably 1～30:10～50 with the mass ratio of benomyl, enters
One step is preferably 1～20:1～30, the most preferably 1～10:1～6.
Fluxapyroxad with the preferred mass proportioning of benomyl can also be: 70:1,50:1,30:1,20:1,10:1,5:
1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50.
In the compositions of the present invention, account for both fluxapyroxad and benomyl the weight/mass percentage composition of compositions be 2～
80%.Preferably 5～70%.
Described bactericidal composition, wherein with fluxapyroxad and benomyl for principle active component and known auxiliary agent and
Excipient is re-dubbed on pesticide any one dosage form allowed.Known to these, auxiliary agent, excipient have dispersant, diffusant, disappear
Infusion, wetting agent, disintegrating agent etc., can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, benzylphenol polyoxyethylene
Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products thereof, aliphatic amine polyoxyethylene ether, fatty acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Temperature series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more combinations in lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., excipient includes
Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other
Adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.Especially preventing and treating cereal
Application in terms of class, fruit tree, vegetable crop disease has remarkable result.
Above-mentioned application, described fungal diseases of plants is in banded sclerotial blight, gray mold, cucumber fusarium axysporum, pepper anthracnose
At least one.
The feature of bactericidal composition of the present invention:
1, the fluxapyroxad used by the present invention and benomyl, the mechanism of action is different, and mutual mixture will not produce low touching, can
Synergistic, reduces dosage, reduces cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating Cereal, fruit tree, the refractory fungal disease of vegetable,
Particularly prevent and treat banded sclerotial blight, gray mold, cucumber fusarium axysporum, pepper anthracnose etc. and all have significant effect.Bactericidal composite of the present invention
Thing has good prevention effect to ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And suppress insect or fungus pair
The drug-fast generation of unitary agent (fluxapyroxad and benomyl are arbitrary).Bactericidal composition of the present invention can produce higher association
Same potentiation, and the consumption of the independent reactive compound of amount ratio of this mixture is substantially reduced, i.e. and the activity of mixture is big
Activity in independent component.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as banded sclerotial blight, gray mold, cucumber fusarium axysporum, pepper anthracnose have obvious synergistic function, overcome and delay
Drug resistance, expanding prevention is composed, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and
It is easily generated the pesticide of resistance；(4) compared with single dose, produce and use cost reduces；(5) the suppression drug-fast generation of fungus, its
Effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is routine side
Method, " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A single dose toxicity index of proportion+B single dose in mixture of theoretical toxicity index=A single dose
× B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, and CTC exists
It it is summation action between 80-120.
According to effective ingredient fluxapyroxad (A): benomyl (B) quality proportioning is: 80:1,70:1,50:1,30:1,20:
1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50,1:60 test, and measure it to Portugal
The co-toxicity coefficient of grape ash arrhizus bacteria (Botrytis cinerea.).
Table 1: the fluxapyroxad+benomyl different ratio indoor biometrics result to Botrytis cinerea
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% fluxapyroxad SC | Y=4.817+2.201X | 1.211 | - |
| 50% benomyl WP | Y=3.166+3.574X | 3.260 | - |
| A:B=80:1 | Y=3.461+2.987X | 3.276 | 100.28 |
| A:B=70:1 | Y=4.483+1.270X | 2.554 | 128.79 |
| A:B=50:1 | Y=3.700+3.625X | 2.284 | 144.52 |
| A:B=30:1 | Y=4.386+2.078X | 1.975 | 168.49 |
| A:B=20:1 | Y=3.816+4.087X | 1.949 | 172.43 |
| A:B=10:1 | Y=4.205+2.347X | 2.182 | 158.49 |
| A:B=5:1 | Y=4.360+1.503X | 2.667 | 136.56 |
| A:B=2.5:1 | Y=4.151+2.651X | 2.090 | 190.08 |
| A:B=1:1 | Y=4.105+2.005X | 2.794 | 170.15 |
| A:B=1:2 | Y=4.218+1.489X | 3.350 | 167.48 |
| A:B=1:4 | Y=3.235+2.963X | 3.942 | 166.32 |
| A:B=1:6 | Y=4.190+1.247X | 4.459 | 158.49 |
| A:B=1:10 | Y=2.487+3.202X | 6.091 | 124.87 |
| A:B=1:20 | Y=1.772+4.151X | 5.994 | 135.49 |
| A:B=1:30 | Y=3.300+2.333X | 5.352 | 155.48 |
| A:B=1:50 | Y=3.494+2.078X | 5.303 | 160.18 |
| A:B=1:60 | Y=3.53+1.669X | 7.600 | 112.36 |
Field control effectiveness test:
The pesticidal preparations preventing and treating grape grey mould test prepared with above-described embodiment.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, compares medicine
Agent is pesticide single dose 25% fluxapyroxad SC and 50% benomyl WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating before dispenser and preventing and treating
Method is: randomization 5 point in test treatment region, carries out severity Scaling according to country's field test relevant criterion, calculates preventive effect.
Result of the test is shown in Table 2:
Table 2 field test effect
Being shown by indoor biometrics and field efficacy result, fluxapyroxad and benomyl compositions have the most collaborative
Potentiation, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has application valency in agricultural is applied
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates two kinds with specific embodiment below
The preparation that effective ingredient is processed into, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% fluxapyroxad benomyl wettable powder (1:2)
By fluxapyroxad 5g, benomyl 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, prepares effectively
Ingredient percent is 15% fluxapyroxad benomyl wettable powder.
Embodiment 2:15% fluxapyroxad benomyl wettable powder (1:4)
By fluxapyroxad 3g, benomyl 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is that 15% fluxapyroxad benomyl can
WP.
Embodiment 3:14% fluxapyroxad benomyl wettable powder (1:6)
By fluxapyroxad 2g, benomyl 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is that 14% fluxapyroxad benomyl can
WP.
Embodiment 4:20% fluxapyroxad benomyl suspending agent (1:1)
Weigh 10g fluxapyroxad, 10g benomyl, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof,
Xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, in the effect of sand mill
Under to make effective Ingredient percent be 20% fluxapyroxad benomyl suspending agent.
Embodiment 5:55% fluxapyroxad benomyl aqueous emulsion (1:10)
Weigh 5g fluxapyroxad, 50g benomyl, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into mixing
Still high speed mixes, and making effective Ingredient percent is 55% fluxapyroxad benomyl aqueous emulsion.
Embodiment 6:42% fluxapyroxad benomyl cream (1:20)
Weigh 2g fluxapyroxad, 40g benomyl, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent is oily to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective composition quality hundred
Proportion by subtraction is 42% fluxapyroxad benomyl cream.
Embodiment 7:70% fluxapyroxad benomyl cream (2.5:1)
Weigh 50g fluxapyroxad, 20g benomyl, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts in mixing kettle mixed
Closing, making effective Ingredient percent is 70% fluxapyroxad benomyl cream.
Embodiment 8:18% fluxapyroxad benomyl water dispersion granule (5:1)
Weigh 15g fluxapyroxad, 3g benomyl, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, gather
Vinyl alcohol 5g, Borax 2g, kieselguhr 28g complement to 100g, are formed with imitating composition by water dispersible granular agent method by above raw material
Mass percent is 17% fluxapyroxad benomyl water dispersion granule.
Embodiment 9:11% fluxapyroxad benomyl cream (10:1)
Weigh 10g fluxapyroxad, 1g benomyl, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent is oily to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective composition quality hundred
Proportion by subtraction is 11% fluxapyroxad benomyl cream.
Embodiment 10:32% fluxapyroxad benomyl microemulsion (20:1)
Weigh 30g fluxapyroxad, 2g benomyl, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is prepared micro-routinely
The method of Emulsion puts in mixing kettle and mixes, and making effective Ingredient percent is 32% fluxapyroxad benomyl microemulsion
Agent.
Embodiment 11:31% fluxapyroxad benomyl cream (30:1)
Weigh 30g fluxapyroxad, 1g benomyl, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent is oily to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective composition quality hundred
Proportion by subtraction is 31% fluxapyroxad benomyl cream.
Embodiment 12:51% fluxapyroxad benomyl suspending agent (50:1)
Weigh 50g fluxapyroxad, 1g benomyl, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill
Making effective Ingredient percent is 51% fluxapyroxad benomyl suspending agent.
Embodiment 13:32% fluxapyroxad benomyl microemulsion (1:15)
Weigh 2g fluxapyroxad, 30g benomyl, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is prepared micro-routinely
The method of Emulsion puts in mixing kettle and mixes, and making effective Ingredient percent is 32% fluxapyroxad benomyl microemulsion
Agent.
Embodiment 14:6% fluxapyroxad benomyl aqueous emulsion (1:5)
Weigh 1g fluxapyroxad, 5g benomyl, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into mixing kettle
High speed mixes, and making effective Ingredient percent is 6% fluxapyroxad benomyl aqueous emulsion.
Embodiment 15:62% fluxapyroxad benomyl microemulsion (1:30)
Weigh 2g fluxapyroxad, 60g benomyl, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is prepared micro-routinely
The method of Emulsion puts in mixing kettle and mixes, and making effective Ingredient percent is 62% fluxapyroxad benomyl microemulsion
Agent.
Embodiment 16:51% fluxapyroxad benomyl suspending agent (1:50)
Weigh 1g fluxapyroxad, 50g benomyl, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill
Making effective Ingredient percent is 51% fluxapyroxad benomyl suspending agent.
Embodiment 17:7% fluxapyroxad benomyl water dispersion granule (1:2.5)
Weigh 2g fluxapyroxad, 5g benomyl, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, poly-second
Enol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, by water dispersible granular agent method, above raw material are formed with effect
Ingredient percent is 7% fluxapyroxad benomyl water dispersion granule.
Claims (10)
1. a Fluxapyroxad-containsterilization and the bactericidal composition of benomyl, it is characterised in that this bactericidal composition is with fluxapyroxad
Being principle active component with benomyl, wherein fluxapyroxad is 1～70:1～50 with the mass ratio of benomyl.
Bactericidal composition the most according to claim 1, it is characterised in that described fluxapyroxad and the mass ratio of benomyl
It is 1～30:1～50.
Bactericidal composition the most according to claim 2, it is characterised in that described fluxapyroxad and the mass ratio of benomyl
It is 1～20:1～30.
Bactericidal composition the most according to claim 3, it is characterised in that described fluxapyroxad and the mass ratio of benomyl
It is 1～10:1～6.
Bactericidal composition the most according to claim 1, it is characterised in that both described fluxapyroxad and benomyl account for
The weight/mass percentage composition of compositions is 2-80%.
Bactericidal composition the most according to claim 5, it is characterised in that both described fluxapyroxad and benomyl account for
The weight/mass percentage composition of compositions is 5-70%.
Bactericidal composition the most according to claim 1, it is characterised in that with fluxapyroxad and benomyl for main effectively
Composition and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.
Bactericidal composition the most according to claim 7, it is characterised in that described dosage form be cream, suspending agent, aqueous emulsion,
Wettable powder or water dispersion granule.
9. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
Application the most according to claim 9, it is characterised in that described fungal diseases of plants is banded sclerotial blight, gray mold, Huang
At least one in cucurbit wilt, pepper anthracnose.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
| CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
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2016
- 2016-04-26 CN CN201610265876.8A patent/CN105831139A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
| CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
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Application publication date: 20160810 |