CN106472525A - A kind of bactericidal composition and its application containing fluoxastrobin and fludioxonil - Google Patents
A kind of bactericidal composition and its application containing fluoxastrobin and fludioxonil Download PDFInfo
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- CN106472525A CN106472525A CN201610766090.4A CN201610766090A CN106472525A CN 106472525 A CN106472525 A CN 106472525A CN 201610766090 A CN201610766090 A CN 201610766090A CN 106472525 A CN106472525 A CN 106472525A
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- Prior art keywords
- fludioxonil
- fluoxastrobin
- bactericidal composition
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- blight
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition and its application containing fluoxastrobin and fludioxonil.With fluoxastrobin and fludioxonil as principle active component, wherein fluoxastrobin is 1～70 with the weight ratio of fludioxonil to the bactericidal composition：1～50.The bactericidal composition can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to for fungal diseases such as control rust, glume blight, net blotch, powdery mildew, downy mildew, early blight, late blight, anthracnose, gray molds, and effect is better than single dose use.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, especially one kind are lived with fluoxastrobin and fludioxonil as main
The bactericidal composition of property composition and its application.
Background technology
Fluoxastrobin (Fluoxastrobin), molecular formula：C21H16ClFN4O5, chemical name：{ 2- [6- (2- chlorobenzene oxygen
Base) -5-FU -4- base oxygen] phenyl } (5,6- dihydros-Isosorbide-5-Nitrae, 2- diazine -3- base) ketone O- methyloxime, structural formula：
Fluoxastrobin has the bactericidal activity of wide spectrum, to nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete
And Fungi Imperfecti) the tens of kinds of diseases such as disease such as rust, clever blessing disease, net blotch, powdery mildew, downy mildew all have good activity.
Fludioxonil (Fludioxonil), molecular formula：C12H6F2N2O2, chemical name：4- (the fluoro- 1,3- benzo two of 2,2- bis-
Oxygen -4- base) pyrroles's -3- nitrile, chemical structural formula：
Fludioxonil derives from natural products pyrrolnitrin, new pyrrole class, non-internal-absorting, wide-spectrum bactericide.Main use
In wheat, barley, corn, pea, rape, paddy rice, ornamental crops, hard fruits and vegetables, grape and lawn etc., sterilized as blade face
Agent is used for preventing and treating the rotten Fusariumsp of snow, wheat net raw meat black rot, rhizoctonia solani etc., has special efficacy to gray mold.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty is increased；Separately
On the one hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
Content of the invention
The purpose of the present invention is to provide a kind of applied widely, low cost, effect good fluorine-containing for above-mentioned technical problem
Fluoxastrobin and the plant bactericidal composition of fludioxonil.
It is a still further object of the present invention to provide the bactericidal composition causes answering on fungal disease in preventing and treating plant epiphyte
With especially in control rust, glume blight, net blotch, powdery mildew, downy mildew, early blight, late blight, anthracnose, gray mold etc.
Purposes on fungal disease.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing fluoxastrobin and fludioxonil, it is with fluoxastrobin and fludioxonil as mainly effectively becoming
Point, wherein fluoxastrobin is 1～70 with fludioxonil weight ratio：1～50.In bactericidal composition, effective ingredient is deposited with enhancing effective amount
It is in composition.
In the present invention, in bactericidal composition fluoxastrobin and fludioxonil can be in weight than 1～70：In the range of 1～50
Arbitrarily adjust, the such as weight ratio of the two is 5～50：10～50,5～40：10～30,1～5：1～20,1～2：0.5～
151：1～9 etc..In another kind of scheme, fluoxastrobin and fludioxonil can select following weight than in any one or many
Kind：1:50、1:49、1:48、1:47、1:46、1:45、1:44、1:43、1:42、1:41、1:40、1:39、1:38、1:37、1:
36、1:35、1:34、1:33、1:32、1:31、1:30、1:29、1:28、1:27、1:26、1:25、1:24、1:23、1:22、1:
21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:
5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、
15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、28:1、29:1、
30:1、31:1、32:1、33:1、34:1、35:1、36:1、37:1、38:1、39:1、40:1、41:1、42:1、43:1、44:1、
45:1、46:1、47:1、48:1、49:1、50:1、51:1、52:1、53:1、54:1、55:1、56:1、57:1、58:1、59:1、
60:1、61:1、62:1、63:1、64:1、65:1、66:1、67:1、68:1、69:1、70:1、2:3、2:5、3:4、3:5、3:2、4:
3、5:2、5:3 etc..
In the compositions of the present invention, the percentage by weight for accounting for composition both fluoxastrobin and fludioxonil is 1～95%, excellent
Select 2～80%, further preferred 10～40%.
Described bactericidal composition, wherein with fluoxastrobin and fludioxonil as principle active component, with insecticides adjuvant and/or
Excipient is re-dubbed any one formulation that allow on agricultural chemicals.Auxiliary agent, excipients known to these including but not limited to have dispersion
Agent, diffusant, defoamer, wetting agent, disintegrant etc., can adopt calcium dodecyl benzene sulfonate, APES, benzyl
Base phenol polyethenoxy ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene
Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, nonyl phenol gather
Oxygen vinethene, TWEEN Series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphoric acid
One or more groups in salt, phosphite, lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc.
Close, excipient includes cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water etc..More than help
Agent, excipient and other auxiliary materials can be alone or be used in combination.
Described bactericidal composition, its formulation are that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
In terms of this bactericidal composition can be applicable to prevent and treat resistance plant fungal disease, Cereal, fruit tree, vegetable is particularly prevented and treated
Application in terms of dish crop pest.
The present composition scope of application increases, it is adaptable to prevents and treats the disease of Cereal, fruit tree, vegetables, particularly prevents and treats
Rust, glume blight, net blotch, powdery mildew, downy mildew, early blight, late blight, anthracnose, gray mold.Bactericidal composition of the present invention
There is good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti fungal disease；And suppress insect or fungi to unitary agent
The drug-fast generation of (fluoxastrobin and fludioxonil arbitrary).
Application of the bactericidal composition of the present invention on preventing and treating refractory fungal is prepared, especially in control rust, glume blight, net
Pinta, powdery mildew, downy mildew, early blight, late blight, anthracnose, the application of gray mold all have significant effect.Above-mentioned sterilization group
Compound can produce higher synergistic function, and the consumption of the amount ratio independent reactive compound of the mixture drops significantly
Low, i.e. the activity of mixture is more than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease has
Substantially synergistic function, overcomes and has delayed the resistance to the action of a drug, and expanding prevention is composed, hence it is evident that improve prevention effect；(2) reduce preventing and treating
Recruitment, drug cost；(3) alternative routine and the agricultural chemicals for being also easy to produce resistance；(4) compared with single dose, production and use cost drop
Low；(5) the drug-fast generation of suppression fungi, its effect are used apparently higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, and in embodiment, the preparation method of formulation is conventional side
Method, " % " of the present invention are mass percent.
Indoor biometricses are tested：
Adopt mycelial growth rate method indoors, different agents are determined to graw mold of tomato bacterial strain (Botrytis
Cinerea Pers.) EC50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture, determines mixture
Building performance, circular is as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single dose × A single dose proportion+B single dose in mixture
× B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
Table 1：Indoor biometricses result of the fluoxastrobin+fludioxonil different ratio to graw mold of tomato bacterial strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| Fluoxastrobin (A) | Y=1.11X+4.53 | 2.635 | - |
| Fludioxonil (B) | Y=2.90X+5.91 | 0.485 | - |
| A:B=70:1 | Y=2.57X+3.97 | 2.509 | 98.86 |
| A:B=10:1 | Y=3.53X+5.02 | 0.988 | 190.12 |
| A:B=1:1 | Y=2.52X+5.66 | 0.546 | 150.08 |
| A:B=1:3 | Y=1.46X+5.68 | 0.342 | 178.16 |
| A:B=1:6 | Y=2.40X+6.28 | 0.292 | 188.32 |
| A:B=1:10 | Y=1.91X+5.84 | 0.364 | 144.01 |
| A:B=1:20 | Y=1.22X+5.65 | 0.292 | 172.58 |
| A:B=1:70 | Y=1.76X+5.68 | 0.409 | 119.96 |
Field control effectiveness test：
With pesticidal preparations preventing and treating graw mold of tomato test obtained in following embodiments.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is 10% fluoxastrobin EC of agricultural chemicals single dose and 2.5% fludioxonil WP and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in the test process area (takes 5M per2), disease is carried out according to national field test relevant criterion
Mutual affection level, calculates preventive effect.
3rd, result of the test see the table below：
Shown by indoor biometricses and field efficacy result, fluoxastrobin has significantly collaboration with fludioxonil composition and increases
Effect is acted on, and the prevention effect of composition is excellent, and prevention effect is all better than single dose kind, with using value in agricultural application.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds with specific embodiment below
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to set forth below.
Embodiment 1：
By fluoxastrobin 5g, fludioxonil 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusant
NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixture and carry out air-flow crushing, are obtained effectively to become
It is 15% fluoxastrobin-fludioxonil wettable powder to divide weight percentage.
Embodiment 2：
Fluoxastrobin 3g, fludioxonil 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin are added
Air-flow crushing is carried out to 100g mixture, it is 15% fluoxastrobin-fludioxonil wettable that active ingredient weight percentage is obtained
Pulvis.
Embodiment 3：
Fluoxastrobin 2g, fludioxonil 14g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin are added
Air-flow crushing is carried out to 100g mixture, it is 16% fluoxastrobin-fludioxonil wettable that active ingredient weight percentage is obtained
Pulvis.
Embodiment 4：
Weigh 5g fluoxastrobin, 50g fludioxonil, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
APEO 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared aqueous emulsion puts into mixed
The mixing of kettle high speed is closed, and effective Ingredients Weight percentage composition is made for 55% fluoxastrobin-fludioxonil aqueous emulsion.
Embodiment 5：
Weigh 2g fluoxastrobin, 30g fludioxonil, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared micro emulsion
The method of agent puts in mixing kettle and mixes, and makes effective Ingredients Weight percentage composition for 32% fluoxastrobin-fludioxonil micro emulsion
Agent.
Embodiment 6：
Weigh 1g fluoxastrobin, 5g fludioxonil, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol to gather
Oxygen vinethene 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared aqueous emulsion puts into mixing
Kettle high speed mixes, and makes effective Ingredients Weight percentage composition for 6% fluoxastrobin-fludioxonil aqueous emulsion.
Embodiment 7：
Weigh 50g fluoxastrobin, 20g fludioxonil, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Sesame oil APEO 2g, 150# solvent naphtha is to 100g.The method that above raw material is routinely prepared missible oil is put in mixing kettle
Mixing, makes effective Ingredients Weight percentage composition for 70% fluoxastrobin-fludioxonil missible oil.
Embodiment 8：
Weigh 2g fluoxastrobin, 40g fludioxonil, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, 150#
Solvent naphtha is to 100g.The method that above raw material is routinely prepared missible oil puts in mixing kettle and mixes, and makes effective Ingredients Weight
Percentage composition is 42% fluoxastrobin-fludioxonil missible oil.
Embodiment 9：
Weigh 5g fluoxastrobin, 20g fludioxonil, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared micro emulsion
The method of agent puts in mixing kettle and mixes, and makes effective Ingredients Weight percentage composition for 25% fluoxastrobin-fludioxonil micro emulsion
Agent.
Embodiment 10：
Weigh 5g fluoxastrobin, 0.5g fludioxonil, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
150# solvent naphtha is to 100g.The method that above raw material is routinely prepared missible oil puts in mixing kettle and mixes, and makes active ingredient
Weight percentage is 5.5% fluoxastrobin-fludioxonil missible oil.
Embodiment 11：
Weigh 5g fluoxastrobin, 30g fludioxonil, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150#
Solvent naphtha is to 100g.The method that above raw material is routinely prepared missible oil puts in mixing kettle and mixes, and makes effective Ingredients Weight
Percentage composition is 35% fluoxastrobin-fludioxonil missible oil.
Embodiment 12：
10g fluoxastrobin, 10g fludioxonil, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g is weighed, yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, 100g is complemented to water, in the presence of sand mill
Effective Ingredients Weight percentage composition is made for 20% fluoxastrobin-fludioxonil suspending agent.
Embodiment 13：
30g fluoxastrobin, 12g fludioxonil, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g is weighed, yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, 100g is complemented to water, in the presence of sand mill
Effective Ingredients Weight percentage composition is made for 42% fluoxastrobin-fludioxonil suspending agent.
Embodiment 14：
Weigh 2g fluoxastrobin, 5g fludioxonil, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyethylene
Alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with imitating into by water dispersible granular agent method
It is 7% fluoxastrobin-fludioxonil water dispersion granule to divide weight percentage.
Embodiment 15：
Weigh 4g fluoxastrobin, 13g fludioxonil, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, diatomite 28g complement to 100g, and above raw material is formed with imitating composition weight by water dispersible granular agent method
Amount percentage composition is 17% fluoxastrobin-fludioxonil water dispersion granule.
Embodiment 16：
Weigh 5g fluoxastrobin, 15g fludioxonil, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, 100g is complemented to water, make in the presence of sand mill
Become active ingredient weight percentage for 20% fluoxastrobin-fludioxonil suspending agent.
Claims (10)
1. a kind of bactericidal composition containing fluoxastrobin and fludioxonil, it is characterised in that said composition is with fluoxastrobin and fludioxonil
For principle active component, wherein fluoxastrobin is 1～70 with the weight ratio of fludioxonil：1～50.
2. bactericidal composition according to claim 1, it is characterised in that the fluoxastrobin is 1 with the weight ratio of fludioxonil
～5：1～20.
3. bactericidal composition according to claim 2, it is characterised in that the weight ratio of the fluoxastrobin and fludioxonil is 1
～2：1～15.
4. bactericidal composition according to claim 3, it is characterised in that the weight ratio of described fluoxastrobin and fludioxonil
For 1：1～10.
5. bactericidal composition according to claim 1, it is characterised in that both fluoxastrobin and fludioxonil account for composition
Weight percentage is 2～80%.
6. bactericidal composition according to claim 5, it is characterised in that both fluoxastrobin and fludioxonil account for composition
Weight percentage is 10～40%.
7. bactericidal composition according to claim 1, it is characterised in that said composition is based on fluoxastrobin and fludioxonil
Active ingredient is wanted, and insecticides adjuvant and/or excipients are configured to any one formulation of permission on agricultural chemicals.
8. bactericidal composition according to claim 7, it is characterised in that the formulation be missible oil, suspending agent, aqueous emulsion, can
WP, microemulsion or water dispersion granule.
9. the bactericidal composition containing fluoxastrobin and fludioxonil described in claim 1 is on preventing and treating resistance plant fungal disease
Application.
10. the bactericidal composition containing fluoxastrobin and fludioxonil described in claim 1 control rust, glume blight, net blotch,
Application on powdery mildew, downy mildew, early blight, late blight, anthracnose or gray mold class fungal disease.
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| CN201610766090.4A CN106472525A (en) | 2016-08-29 | 2016-08-29 | A kind of bactericidal composition and its application containing fluoxastrobin and fludioxonil |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107094766A (en) * | 2017-05-11 | 2017-08-29 | 深圳诺普信农化股份有限公司 | A kind of seed treatment |
| WO2023023815A1 (en) * | 2021-08-25 | 2023-03-02 | Adama Australia Pty Limited | Highly loaded fludioxonil formulations |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004049761A1 (en) * | 2004-10-12 | 2006-04-13 | Bayer Cropscience Ag | Fungicidal drug combinations |
| CN102763659A (en) * | 2012-07-13 | 2012-11-07 | 王学权 | Tridemorph-containing fungicide |
-
2016
- 2016-08-29 CN CN201610766090.4A patent/CN106472525A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004049761A1 (en) * | 2004-10-12 | 2006-04-13 | Bayer Cropscience Ag | Fungicidal drug combinations |
| CN101039578A (en) * | 2004-10-12 | 2007-09-19 | 拜尔农作物科学股份公司 | Fungicidal active ingredient combinations containing fluoxastrobin |
| CN102763659A (en) * | 2012-07-13 | 2012-11-07 | 王学权 | Tridemorph-containing fungicide |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107094766A (en) * | 2017-05-11 | 2017-08-29 | 深圳诺普信农化股份有限公司 | A kind of seed treatment |
| WO2023023815A1 (en) * | 2021-08-25 | 2023-03-02 | Adama Australia Pty Limited | Highly loaded fludioxonil formulations |
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