CN106900716A - A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fluazinam - Google Patents
A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fluazinam Download PDFInfo
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- CN106900716A CN106900716A CN201710140068.3A CN201710140068A CN106900716A CN 106900716 A CN106900716 A CN 106900716A CN 201710140068 A CN201710140068 A CN 201710140068A CN 106900716 A CN106900716 A CN 106900716A
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- China
- Prior art keywords
- fluazinam
- hexanaphthene flusulfamide
- bactericidal composition
- hexanaphthene
- flusulfamide
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
Abstract
The invention discloses a kind of bactericidal composition containing Hexanaphthene flusulfamide and fluazinam and its application.With Hexanaphthene flusulfamide and fluazinam as principle active component, wherein Hexanaphthene flusulfamide and the mass ratio of fluazinam is 1 to the bactericidal composition:50~70:1.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, with synergistic function higher, overcome and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as downy mildew, late blight, phytophthora root rot, scab, sclerotiniose, gray mold, effect is better than single dose and uses.
Description
Technical field：
The present invention relates to a kind of bactericidal composition and application thereof, especially it is a kind of with Hexanaphthene flusulfamide and fluazinam be main
The bactericidal composition of active component and its application.
Background technology
Hexanaphthene flusulfamide molecular formula：C13H13CIF3NO3S.Chemical name：N- (2- trifluoromethyl-4-chlorophenyls)-alpha-oxo
Cyclohexyl sulfonamide.It has stronger prevention, treatment and osmotically active, there is lasting effect higher.Through table of field test results
It is bright effectively to prevent and treat gray mold, sclerotinia rot of colza, Cucumber Target Leaf Spot and scab.
Fluazinam (fluazinam), molecular formula：C13H4Cl2F6N4O4.Chemical name：The chloro- N- of 3- (the chloro- 5- fluoroforms of 3-
Base -2- pyridine radicals)-a, the fluoro- 2,6- dinitros-p-toluidine of a, a- tri-.Fluazinam is developed by Japanese Shi Yuan industry companies
New substituted phenyl amines wide-spectrum bactericide, the various gray molds caused to Botrytis cinerea have special efficacy.To interlink spore genus, Phytophthora,
The germ disease such as Plasmopara, Sclerotinia and Venturia also has good activity..
The difficulty of prevention and cure of current phytopathogen is increasing, and main cause has：One is with the change of pattern of farming, melon
The industrial crops cultivated area such as fruits and vegetables progressively expands, and disease occurrence degree, generation quantity increase, difficult in preventing and treating
Degree is increased；Two is current climate exception, and the outburst to disease provides certain condition；Three is the selection of long-term chemical medication
Property influence so that the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality.
In sum, current control of plant disease work faces big challenge emphatically.
The content of the invention：
The purpose of the present invention be directed to above-mentioned technical problem provide a kind of applied widely, low cost, effect it is good containing ring
The bactericidal composition of own flusulfamide and fluazinam.
It is a still further object of the present invention to provide the bactericidal composition on the fungal disease that preventing and treating plant epiphyte causes
Using the especially purposes on the fungal diseases such as downy mildew, late blight, phytophthora root rot, scab, sclerotiniose, gray mold are prevented and treated.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing Hexanaphthene flusulfamide and fluazinam, the bactericidal composition is with Hexanaphthene flusulfamide and fluazinam
It is principle active component, wherein Hexanaphthene flusulfamide and the mass ratio of fluazinam is 1:50~70:1, wherein have in bactericidal composition
Effect composition is present in composition with enhancing effective amount.
Described bactericidal composition, wherein Hexanaphthene flusulfamide are preferably 1 with the mass ratio of fluazinam:10~30:1, enter one
Step is preferably 1:7~20:1.In some preferred technical schemes：Hexanaphthene flusulfamide can be 70 with the mass ratio of fluazinam：
1、50:1、30:1、20:1、10:1、5:1、2.5:1、1:1、1:2、1:4、1:7、1:10、1:15、1:20、1:30、1:Selected in 50
Select.
In bactericidal composition of the present invention, the weight/mass percentage composition that both Hexanaphthene flusulfamide and fluazinam account for composition is
2%~80%.It is preferred that 10%~70%.
Described bactericidal composition, wherein with Hexanaphthene flusulfamide and fluazinam as principle active component and known auxiliary agent and
Excipient is re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, disappear
Infusion, wetting agent, disintegrant etc., can use calcium dodecyl benzene sulfonate, APES, benzyl phenol polyethenoxy
Ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Warm series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more combinations in lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc., excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other
Auxiliary material can be with alone or be used in combination.
Described bactericidal composition, its formulation is that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the described bactericidal composition on preventing and treating fungal diseases of plants medicine, especially in preventing and treating Cereal, fruit
Application in terms of tree, vegetable crop disease.
Described fungal diseases of plants is downy mildew, late blight, phytophthora root rot, scab, sclerotiniose, gray mold etc..
Beneficial effects of the present invention：
1st, the Hexanaphthene flusulfamide used by the present invention is different with the fluazinam mechanism of action, mutual mixture will not produce it is low tactile, can
Synergistic, reduces dosage, reduces cost.
2nd, the present composition scope of application increases, it is adaptable to prevent and treat the fungal disease of Cereal, fruit tree, vegetables, special
It is not that application on downy mildew, late blight, phytophthora root rot, scab, sclerotiniose, gray mold etc. is prevented and treated has significant effect.
Bactericidal composition of the present invention has good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And press down
The drug-fast generation of insect processed or fungi to unitary agent (Hexanaphthene flusulfamide and fluazinam are any).Bactericidal composite of the invention
Thing can produce synergistic function higher, and the consumption of the amount ratio independent reactive compound of the mixture to substantially reduce,
I.e. the activity of mixture is more than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as downy mildew, late blight, phytophthora root rot, scab, sclerotiniose, gray mold have obvious synergistic function, overcome and
Delay the resistance to the action of a drug, expand preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) it is alternative
Agricultural chemicals that is conventional and being also easy to produce resistance；(4) compared with single dose, production and use cost are reduced；(5) the drug-fast product of fungi is suppressed
Raw, its effect is used apparently higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, determines EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows：
A certain single dose (generally selects EC as standard agent with mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
According to active ingredient Hexanaphthene flusulfamide (A)：Fluazinam (B) quality proportioning is：70：1、50：1、30：1、20：1、10：
1、5：1、2.5：1、1：1、1：2、1：4、1：7、1：10、1：20、1：30、1：50 are tested, and determine it to tomato late blight
Co-toxicity coefficient.
Table 1：Indoor biometricses result of the Hexanaphthene flusulfamide+fluazinam different ratio to tomato late blight
Field control effectiveness test：
Tomato late blight is prevented and treated with pesticidal preparations obtained in following examples to test.
1st, test process：This test medicine consumption sets two concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is respectively the fluazinam SC of agricultural chemicals single dose 50% and 50% Hexanaphthene flusulfamide WP and blank clean water experiment.
2nd, test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates anti-
Effect.Result of the test is shown in Table 2：
The field efficacy experiment of table 2
Shown by indoor biometricses and field efficacy result, Hexanaphthene flusulfamide and fluazinam composition have and significantly cooperate with
Synergistic effect, the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application valency in agricultural application
Value.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds with specific embodiment below
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% Hexanaphthene flusulfamide fluazinam wettable powder (1:2)
By Hexanaphthene flusulfamide 5g, fluazinam 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, are obtained effective
Ingredient percent is 15% Hexanaphthene flusulfamide fluazinam wettable powder.
Embodiment 2：15% Hexanaphthene flusulfamide fluazinam wettable powder (1:4)
By Hexanaphthene flusulfamide 3g, fluazinam 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is obtained for 15% Hexanaphthene flusulfamide fluazinam can
WP.
Embodiment 3：16% Hexanaphthene flusulfamide fluazinam wettable powder (1:7)
By Hexanaphthene flusulfamide 2g, fluazinam 14g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is obtained for 16% Hexanaphthene flusulfamide fluazinam can
WP.
Embodiment 4：20% Hexanaphthene flusulfamide fluazinam suspending agent (1:1)
10g Hexanaphthene flusulfamides, 10g fluazinams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the effect of sand mill with water
Under be made effective Ingredient percent for 20% Hexanaphthene flusulfamide fluazinam suspending agent.
Embodiment 5：55% Hexanaphthene flusulfamide fluazinam aqueous emulsion (1:10)
Weigh 5g Hexanaphthene flusulfamides, 50g fluazinams, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing
Kettle high speed mixes, and is made effective Ingredient percent for 55% Hexanaphthene flusulfamide fluazinam aqueous emulsion.
Embodiment 6：42% Hexanaphthene flusulfamide fluazinam missible oil (1:20)
Weigh 2g Hexanaphthene flusulfamides, 40g fluazinams, it is calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 42% Hexanaphthene flusulfamide fluazinam missible oil.
Embodiment 7：70% Hexanaphthene flusulfamide fluazinam missible oil (2.5:1)
Weigh 50g Hexanaphthene flusulfamides, 20g fluazinams, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared missible oil
Close, be made effective Ingredient percent for 70% Hexanaphthene flusulfamide fluazinam missible oil.
Embodiment 8：18% Hexanaphthene flusulfamide fluazinam water dispersion granule (5：1)
15g Hexanaphthene flusulfamides, 3g fluazinams are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and above raw material is formed with by water dispersible granular agent method to imitate composition
Mass percent is 18% Hexanaphthene flusulfamide fluazinam water dispersion granule.
Embodiment 9：11% Hexanaphthene flusulfamide fluazinam missible oil (10:1)
Weigh 10g Hexanaphthene flusulfamides, 1g fluazinams, it is calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 11% Hexanaphthene flusulfamide fluazinam missible oil.
Embodiment 10：31.5% Hexanaphthene flusulfamide fluazinam microemulsion (20:1)
Weigh 30g Hexanaphthene flusulfamides, 1.5g fluazinams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mix in the method input mixing kettle of microemulsion, be made effective Ingredient percent for 31.5% Hexanaphthene flusulfamide fluazinam
Microemulsion.
Embodiment 11：31% Hexanaphthene flusulfamide fluazinam missible oil (30:1)
Weigh 30g Hexanaphthene flusulfamides, 1g fluazinams, it is calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 31% Hexanaphthene flusulfamide fluazinam missible oil.
Embodiment 12：51% Hexanaphthene flusulfamide fluazinam suspending agent (50:1)
50g Hexanaphthene flusulfamides, 1g fluazinams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 51% Hexanaphthene flusulfamide fluazinam suspending agent.
Embodiment 13：32% Hexanaphthene flusulfamide fluazinam microemulsion (1:15)
Weigh 2g Hexanaphthene flusulfamides, 30g fluazinams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared micro-
Mix in the method input mixing kettle of emulsion, be made effective Ingredient percent for 32% Hexanaphthene flusulfamide fluazinam micro emulsion
Agent.
Embodiment 14：6% Hexanaphthene flusulfamide fluazinam aqueous emulsion (1:5)
Weigh 1g Hexanaphthene flusulfamides, 5g fluazinams, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
APEO 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing kettle
High speed mixes, and is made effective Ingredient percent for 6% Hexanaphthene flusulfamide fluazinam aqueous emulsion.
Embodiment 15：62% Hexanaphthene flusulfamide fluazinam microemulsion (1:30)
Weigh 2g Hexanaphthene flusulfamides, 60g fluazinams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared micro-
Mix in the method input mixing kettle of emulsion, be made effective Ingredient percent for 62% Hexanaphthene flusulfamide fluazinam micro emulsion
Agent.
Embodiment 16：51% Hexanaphthene flusulfamide fluazinam suspending agent (1:50)
1g Hexanaphthene flusulfamides, 50g fluazinams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 51% Hexanaphthene flusulfamide fluazinam suspending agent.
Embodiment 17：7% Hexanaphthene flusulfamide fluazinam water dispersion granule (1：2.5)
Weigh 2g Hexanaphthene flusulfamides, 5g fluazinams, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with into effect by water dispersible granular agent method
Ingredient percent is 7% Hexanaphthene flusulfamide fluazinam water dispersion granule.
Claims (9)
1. a kind of bactericidal composition containing Hexanaphthene flusulfamide and fluazinam, it is characterised in that the bactericidal composition is with Hexanaphthene flusulfamide
With the main active principle of fluazinam, wherein Hexanaphthene flusulfamide and the mass ratio of fluazinam is 1:50~70:1.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the Hexanaphthene flusulfamide and fluazinam
It is 1:10~30:1.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the Hexanaphthene flusulfamide and fluazinam
It is 1:7~20:1.
4. bactericidal composition according to claim 1, it is characterised in that both described Hexanaphthene flusulfamide and fluazinam are accounted for
The weight/mass percentage composition of composition is 2%~80%.
5. bactericidal composition according to claim 4, it is characterised in that both described Hexanaphthene flusulfamide and fluazinam are accounted for
The weight/mass percentage composition of composition is 10%~70%.
6. bactericidal composition according to claim 1, it is characterised in that with Hexanaphthene flusulfamide and fluazinam as it is main effectively
Composition and insecticides adjuvant, excipients are configured to any one formulation allowed on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition described in claim 1 on preventing and treating fungal diseases of plants medicine is prepared.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is downy mildew, late blight, epidemic disease
At least one in mildew, scab, sclerotiniose, gray mold.
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2017
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| CN1900059A (en) * | 2005-07-20 | 2007-01-24 | 中国农业大学 | 2-keto naphthene sulfamide, its preparing method and use as germicide |
| CN101720764A (en) * | 2008-10-13 | 2010-06-09 | 中国农业大学 | New application of N-(2-trifluoromethyl-4-chlorphenyl)-alpha-oxocyclohexyl sulfamide as sterilizing agent |
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