CN106857591A - A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and benzene metsulfovax - Google Patents
A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and benzene metsulfovax Download PDFInfo
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- CN106857591A CN106857591A CN201710140091.2A CN201710140091A CN106857591A CN 106857591 A CN106857591 A CN 106857591A CN 201710140091 A CN201710140091 A CN 201710140091A CN 106857591 A CN106857591 A CN 106857591A
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- Prior art keywords
- benzene metsulfovax
- hexanaphthene flusulfamide
- bactericidal composition
- hexanaphthene
- benzene
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
Abstract
The invention discloses a kind of bactericidal composition containing Hexanaphthene flusulfamide and benzene metsulfovax and its application.With Hexanaphthene flusulfamide and benzene metsulfovax as principle active component, wherein Hexanaphthene flusulfamide and the mass ratio of benzene metsulfovax is 1 to the bactericidal composition:50~70:1.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, with synergistic function higher, overcome and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as late blight, downy mildew, scab, sclerotiniose, gray mold, brown spot, effect is better than single dose and uses.
Description
Technical field：
The present invention relates to a kind of bactericidal composition and application thereof, especially one kind is based on Hexanaphthene flusulfamide and benzene metsulfovax
Want bactericidal composition and its application of active component.
Background technology
Hexanaphthene flusulfamide molecular formula：C13H13CIF3NO3S.Chemical name：N- (2- trifluoromethyl-4-chlorophenyls)-alpha-oxo
Cyclohexyl sulfonamide.It has stronger prevention, treatment and osmotically active, there is lasting effect higher.Through table of field test results
It is bright effectively to prevent and treat gray mold, sclerotinia rot of colza, Cucumber Target Leaf Spot and scab.
Benzene metsulfovax (benthiavalicarb-isopropyl), chemical name：[[(6- fluoro benzothiazole -2- bases)-second
Base carbamoyl] -2- methyl-propyls] carbamic acid isopropyl ester.Benzene metsulfovax are by combinatorial chemistry industrial group and Ihara companies
New type bactericide-the benzene metsulfovax of joint development, have good activity to Oomycete fungal disease.In field test, benzene metsulfovax
The downy mildew of late blight, grape and other crops of potato and tomato can be effectively controlled with relatively low dosage.
The difficulty of prevention and cure of current phytopathogen is increasing, and main cause has：One is with the change of pattern of farming, melon
The industrial crops cultivated area such as fruits and vegetables progressively expands, and disease occurrence degree, generation quantity increase, difficult in preventing and treating
Degree is increased；Two is current climate exception, and the outburst to disease provides certain condition；Three is the selection of long-term chemical medication
Property influence so that the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality.
In sum, current control of plant disease work faces big challenge emphatically.
The content of the invention：
The purpose of the present invention be directed to above-mentioned technical problem provide a kind of applied widely, low cost, effect it is good containing ring
The bactericidal composition of own flusulfamide and benzene metsulfovax.
It is a still further object of the present invention to provide the bactericidal composition on the fungal disease that preventing and treating plant epiphyte causes
Using the especially purposes on the fungal diseases such as late blight, downy mildew, scab, sclerotiniose, gray mold, brown spot are prevented and treated.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing Hexanaphthene flusulfamide and benzene metsulfovax, the bactericidal composition is with Hexanaphthene flusulfamide and benzene thiophene
Bacterium amine is principle active component, and wherein Hexanaphthene flusulfamide and the mass ratio of benzene metsulfovax is 1:50~70:1, wherein Bactericidal composite
Effective ingredient is present in composition with enhancing effective amount in thing.
Described bactericidal composition, wherein Hexanaphthene flusulfamide are preferably 1 with the mass ratio of benzene metsulfovax:10~30:1, enter
One step is preferably 1:10~10:1.In some preferred technical schemes：The mass ratio of Hexanaphthene flusulfamide and benzene metsulfovax can be with
70：1、50:1、30:1、20:1、10:1、5:1、2.5:1、1:1、1:2、1:4、1:7、1:10、1:15、1:20、1:30、1:50
Middle selection.
In bactericidal composition of the present invention, the weight/mass percentage composition that both Hexanaphthene flusulfamide and benzene metsulfovax account for composition is
2%~80%.It is preferred that 10%~20% or 70%.
Described bactericidal composition, wherein with Hexanaphthene flusulfamide and benzene metsulfovax be principle active component and known auxiliary agent
Any one formulation allowed on agricultural chemicals is re-dubbed with excipient.These known auxiliary agents, excipients have dispersant, diffusant,
Defoamer, wetting agent, disintegrant etc., can use calcium dodecyl benzene sulfonate, APES, benzylphenol polyoxy second
Alkene ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid
Ethylene oxide adduct, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE,
TWEEN Series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphorous acid
One or more combinations, excipient in salt, lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc.
Including cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and
Other auxiliary materials can be with alone or be used in combination.
Described bactericidal composition, its formulation is that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the described bactericidal composition on preventing and treating fungal diseases of plants medicine, especially in preventing and treating Cereal, fruit
Application in terms of tree, vegetable crop disease.
Described fungal diseases of plants is late blight, downy mildew, scab, sclerotiniose, gray mold, brown spot etc..
Beneficial effects of the present invention：
1st, the Hexanaphthene flusulfamide used by the present invention is different with the benzene metsulfovax mechanism of action, mutual mixture will not produce it is low tactile,
Can Synergistic, reduction dosage, reduces cost.
2nd, the present composition scope of application increases, it is adaptable to prevent and treat the fungal disease of Cereal, fruit tree, vegetables, special
It is not that application on late blight, downy mildew, scab, sclerotiniose, gray mold, brown spot etc. is prevented and treated has significant effect.
Bactericidal composition of the present invention has good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And press down
The drug-fast generation of insect processed or fungi to unitary agent (Hexanaphthene flusulfamide and benzene metsulfovax are any).Sterilized group of the invention
Compound can produce synergistic function higher, and the consumption of the amount ratio independent reactive compound of the mixture to drop significantly
Low, i.e., the activity of mixture is more than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as late blight, downy mildew, scab, sclerotiniose, gray mold, brown spot have obvious synergistic function, overcome and
Delay the resistance to the action of a drug, expand preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) it is alternative
Agricultural chemicals that is conventional and being also easy to produce resistance；(4) compared with single dose, production and use cost are reduced；(5) the drug-fast product of fungi is suppressed
Raw, its effect is used apparently higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, determines EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows：
A certain single dose (generally selects EC as standard agent with mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
According to active ingredient Hexanaphthene flusulfamide (A)：Benzene metsulfovax (B) quality proportioning is：70：1、50：1、30：1、20：1、
10：1、5：1、2.5：1、1：1、1：2、1：4、1：7、1：10、1：20、1：30、1：50 are tested, and determine it to tomato late blight
Co-toxicity coefficient.
Table 1：Indoor biometricses result of the Hexanaphthene flusulfamide+benzene metsulfovax different ratio to tomato late blight
Field control effectiveness test：
Tomato late blight is prevented and treated with pesticidal preparations obtained in following examples to test.
1st, test process：This test medicine consumption sets two concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is respectively the benzene metsulfovax WDG of agricultural chemicals single dose 20% and 50% Hexanaphthene flusulfamide WP and blank clean water experiment.
2nd, test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates anti-
Effect.Result of the test is shown in Table 2：
The field efficacy experiment of table 2
Shown by indoor biometricses and field efficacy result, Hexanaphthene flusulfamide has obvious association with benzene metsulfovax composition
Same synergistic effect, the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application valency in agricultural application
Value.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds with specific embodiment below
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% Hexanaphthene flusulfamide benzene metsulfovax wettable powder (1:2)
By Hexanaphthene flusulfamide 5g, benzene metsulfovax 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, expansion
Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, and being obtained has
Effect Ingredient percent is 15% Hexanaphthene flusulfamide benzene metsulfovax wettable powder.
Embodiment 2：15% Hexanaphthene flusulfamide benzene metsulfovax wettable powder (1:4)
It is high by Hexanaphthene flusulfamide 3g, benzene metsulfovax 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g
Ridge soil adds to 100g mixtures and carries out air-flow crushing, and it is 15% Hexanaphthene flusulfamide benzene thiophene bacterium that active ingredient mass percent is obtained
Amine wettable powder.
Embodiment 3：16% Hexanaphthene flusulfamide benzene metsulfovax wettable powder (1:7)
It is high by Hexanaphthene flusulfamide 2g, benzene metsulfovax 14g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g
Ridge soil adds to 100g mixtures and carries out air-flow crushing, and it is 16% Hexanaphthene flusulfamide benzene thiophene bacterium that active ingredient mass percent is obtained
Amine wettable powder.
Embodiment 4：20% Hexanaphthene flusulfamide benzene metsulfovax suspending agent (1:1)
Weigh 10g Hexanaphthene flusulfamides, 10g benzene metsulfovax, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
Effective Ingredient percent is made under effect for 20% Hexanaphthene flusulfamide benzene metsulfovax suspending agent.
Embodiment 5：55% Hexanaphthene flusulfamide benzene metsulfovax aqueous emulsion (1:10)
Weigh 5g Hexanaphthene flusulfamides, 50g benzene metsulfovax, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkane
Base phenol polyethenoxy ether 1g, solvent naphtha 13g, add water to 100g.The method input that above raw material is routinely prepared into aqueous emulsion is mixed
The mixing of kettle high speed is closed, effective Ingredient percent is made for 55% Hexanaphthene flusulfamide benzene metsulfovax aqueous emulsion.
Embodiment 6：42% Hexanaphthene flusulfamide benzene metsulfovax missible oil (1:20)
Weigh 2g Hexanaphthene flusulfamides, 40g benzene metsulfovax, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality
Percentage is 42% Hexanaphthene flusulfamide benzene metsulfovax missible oil.
Embodiment 7：70% Hexanaphthene flusulfamide benzene metsulfovax missible oil (2.5:1)
Weigh 50g Hexanaphthene flusulfamides, 20g benzene metsulfovax, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether
2g, castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.By above raw material routinely prepare missible oil method input mixing kettle in
Mixing, is made effective Ingredient percent for 70% Hexanaphthene flusulfamide benzene metsulfovax missible oil.
Embodiment 8：18% Hexanaphthene flusulfamide benzene metsulfovax water dispersion granule (5：1)
Weigh 15g Hexanaphthene flusulfamides, 3g benzene metsulfovax, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and above raw material is formed with imitating into by water dispersible granular agent method
Mass percent is divided to be 18% Hexanaphthene flusulfamide benzene metsulfovax water dispersion granule.
Embodiment 9：11% Hexanaphthene flusulfamide benzene metsulfovax missible oil (10:1)
Weigh 10g Hexanaphthene flusulfamides, 1g benzene metsulfovax, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality
Percentage is 11% Hexanaphthene flusulfamide benzene metsulfovax missible oil.
Embodiment 10：31.5% Hexanaphthene flusulfamide benzene metsulfovax microemulsion (20:1)
Weigh 30g Hexanaphthene flusulfamides, 1.5g benzene metsulfovax, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether
Phosphate 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, be made effective Ingredient percent for 31.5% Hexanaphthene flusulfamide benzene thiophene
Bacterium amine microemulsion.
Embodiment 11：31% Hexanaphthene flusulfamide benzene metsulfovax missible oil (30:1)
Weigh 30g Hexanaphthene flusulfamides, 1g benzene metsulfovax, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g,
Solvent naphtha is to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality
Percentage is 31% Hexanaphthene flusulfamide benzene metsulfovax missible oil.
Embodiment 12：51% Hexanaphthene flusulfamide benzene metsulfovax suspending agent (50:1)
50g Hexanaphthene flusulfamides, 1g benzene metsulfovax, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the effect of sand mill with water
Under be made effective Ingredient percent for 51% Hexanaphthene flusulfamide benzene metsulfovax suspending agent.
Embodiment 13：32% Hexanaphthene flusulfamide benzene metsulfovax microemulsion (1:15)
Weigh 2g Hexanaphthene flusulfamides, 30g benzene metsulfovax, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mix in the method input mixing kettle of microemulsion, be made effective Ingredient percent for 32% Hexanaphthene flusulfamide benzene metsulfovax
Microemulsion.
Embodiment 14：6% Hexanaphthene flusulfamide benzene metsulfovax aqueous emulsion (1:5)
Weigh 1g Hexanaphthene flusulfamides, 5g benzene metsulfovax, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing
Kettle high speed mixes, and is made effective Ingredient percent for 6% Hexanaphthene flusulfamide benzene metsulfovax aqueous emulsion.
Embodiment 15：62% Hexanaphthene flusulfamide benzene metsulfovax microemulsion (1:30)
Weigh 2g Hexanaphthene flusulfamides, 60g benzene metsulfovax, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mix in the method input mixing kettle of microemulsion, be made effective Ingredient percent for 62% Hexanaphthene flusulfamide benzene metsulfovax
Microemulsion.
Embodiment 16：51% Hexanaphthene flusulfamide benzene metsulfovax suspending agent (1:50)
1g Hexanaphthene flusulfamides, 50g benzene metsulfovax, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the effect of sand mill with water
Under be made effective Ingredient percent for 51% Hexanaphthene flusulfamide benzene metsulfovax suspending agent.
Embodiment 17：7% Hexanaphthene flusulfamide benzene metsulfovax water dispersion granule (1：2.5)
2g Hexanaphthene flusulfamides, 5g benzene metsulfovax are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with by water dispersible granular agent method
Effect Ingredient percent is 7% Hexanaphthene flusulfamide benzene metsulfovax water dispersion granule.
Claims (9)
1. a kind of bactericidal composition containing Hexanaphthene flusulfamide and benzene metsulfovax, it is characterised in that the bactericidal composition is with hexamethylene sulphur bacterium
Amine and the main active principle of benzene metsulfovax, wherein Hexanaphthene flusulfamide are 1 with the mass ratio of benzene metsulfovax:50~70:1.
2. bactericidal composition according to claim 1, it is characterised in that the quality of the Hexanaphthene flusulfamide and benzene metsulfovax
Than being 1:10~30:1.
3. bactericidal composition according to claim 2, it is characterised in that the quality of the Hexanaphthene flusulfamide and benzene metsulfovax
Than being 1:10~10:1.
4. bactericidal composition according to claim 1, it is characterised in that both described Hexanaphthene flusulfamide and benzene metsulfovax
The weight/mass percentage composition for accounting for composition is 2%~80%.
5. bactericidal composition according to claim 4, it is characterised in that both described Hexanaphthene flusulfamide and benzene metsulfovax
The weight/mass percentage composition for accounting for composition is 10%~20% or 70%.
6. bactericidal composition according to claim 1, it is characterised in that with Hexanaphthene flusulfamide and benzene metsulfovax mainly to have
Effect composition and insecticides adjuvant, excipients are configured to any one formulation allowed on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition described in claim 1 on preventing and treating fungal diseases of plants medicine is prepared.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is late blight, downy mildew, black
At least one in star disease, sclerotiniose, gray mold, brown spot.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB857383A (en) * | 1957-10-26 | 1960-12-29 | Merck Ag E | New dithia-anthracene derivatives and fungicidal compositions containing them |
| CN1900059A (en) * | 2005-07-20 | 2007-01-24 | 中国农业大学 | 2-keto naphthene sulfamide, its preparing method and use as germicide |
| CN101720764A (en) * | 2008-10-13 | 2010-06-09 | 中国农业大学 | New application of N-(2-trifluoromethyl-4-chlorphenyl)-alpha-oxocyclohexyl sulfamide as sterilizing agent |
| CN102823593A (en) * | 2012-09-18 | 2012-12-19 | 南通江山农药化工股份有限公司 | Hexanaphthene flusulfamide water dispersible granule and preparation method thereof |
| CN103081930A (en) * | 2013-01-17 | 2013-05-08 | 湖南农大海特农化有限公司 | Benthiavalicarb isopropyl/chlorothalonil bactericidal composition |
-
2017
- 2017-03-10 CN CN201710140091.2A patent/CN106857591A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB857383A (en) * | 1957-10-26 | 1960-12-29 | Merck Ag E | New dithia-anthracene derivatives and fungicidal compositions containing them |
| CN1900059A (en) * | 2005-07-20 | 2007-01-24 | 中国农业大学 | 2-keto naphthene sulfamide, its preparing method and use as germicide |
| CN101720764A (en) * | 2008-10-13 | 2010-06-09 | 中国农业大学 | New application of N-(2-trifluoromethyl-4-chlorphenyl)-alpha-oxocyclohexyl sulfamide as sterilizing agent |
| CN102823593A (en) * | 2012-09-18 | 2012-12-19 | 南通江山农药化工股份有限公司 | Hexanaphthene flusulfamide water dispersible granule and preparation method thereof |
| CN103081930A (en) * | 2013-01-17 | 2013-05-08 | 湖南农大海特农化有限公司 | Benthiavalicarb isopropyl/chlorothalonil bactericidal composition |
Non-Patent Citations (1)
| Title |
|---|
| 张海滨 等: "创制杀菌剂—环己磺菌胺", 《农药》 * |
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