CN106922672A - A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fluopyram - Google Patents
A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fluopyram Download PDFInfo
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- CN106922672A CN106922672A CN201710140096.5A CN201710140096A CN106922672A CN 106922672 A CN106922672 A CN 106922672A CN 201710140096 A CN201710140096 A CN 201710140096A CN 106922672 A CN106922672 A CN 106922672A
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- Prior art keywords
- fluopyram
- hexanaphthene flusulfamide
- bactericidal composition
- hexanaphthene
- flusulfamide
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
Abstract
The invention discloses a kind of bactericidal composition containing Hexanaphthene flusulfamide and fluopyram and its application.With Hexanaphthene flusulfamide and fluopyram as principle active component, wherein Hexanaphthene flusulfamide and the mass ratio of fluopyram is 1 to the bactericidal composition:50~70:1.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, with synergistic function higher, overcome and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as downy mildew, powdery mildew, scab, sclerotiniose, gray mold, brown spot, effect is better than single dose and uses.
Description
Technical field：
It is with Hexanaphthene flusulfamide and fluopyram the present invention relates to a kind of bactericidal composition and application thereof, especially one kind
The bactericidal composition of main active and its application.
Background technology
Hexanaphthene flusulfamide molecular formula：C13H13CIF3NO3S.Chemical name：N- (2- trifluoromethyl-4-chlorophenyls)-alpha-oxo
Cyclohexyl sulfonamide.It has stronger prevention, treatment and osmotically active, there is lasting effect higher.Through table of field test results
It is bright effectively to prevent and treat gray mold, sclerotinia rot of colza, Cucumber Target Leaf Spot and scab.
Fluopyram (fluopyram), molecular formula：C16H11ClF6N2O.Chemical name：N- { 2- [chloro- 5- (the trifluoros of 3-
Methyl) -2- pyridine radicals] the fluoro- O- toluamides of ethyl-α, α, α-three }, by the electronics for hindering succinate dehydrogenase in respiratory chain
Shift and suppress mitochondrial respiratory, be mainly used in preventing and treating the microbial disease of capsule on broad leaf crop, to vegetables such as cucumber, cucurbita pepos
On downy mildew, powdery mildew, the germ multiple diseases such as the downy mildew of fruit tree have favorable effect.
The difficulty of prevention and cure of current phytopathogen is increasing, and main cause has：One is with the change of pattern of farming, melon
The industrial crops cultivated area such as fruits and vegetables progressively expands, and disease occurrence degree, generation quantity increase, difficult in preventing and treating
Degree is increased；Two is current climate exception, and the outburst to disease provides certain condition；Three is the selection of long-term chemical medication
Property influence so that the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality.
In sum, current control of plant disease work faces big challenge emphatically.
The content of the invention：
The purpose of the present invention be directed to above-mentioned technical problem provide a kind of applied widely, low cost, effect it is good containing ring
The bactericidal composition of own flusulfamide and fluopyram.
It is a still further object of the present invention to provide the bactericidal composition on the fungal disease that preventing and treating plant epiphyte causes
Using the especially purposes on the fungal diseases such as downy mildew, powdery mildew, scab, sclerotiniose, gray mold, brown spot are prevented and treated.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing Hexanaphthene flusulfamide and fluopyram, the bactericidal composition is with Hexanaphthene flusulfamide and fluorine
Pyrrole bacterium acid amides is principle active component, and wherein Hexanaphthene flusulfamide and the mass ratio of fluopyram is 1:50~70:1, wherein killing
Effective ingredient is present in composition with enhancing effective amount in bacteria composition.
Described bactericidal composition, wherein Hexanaphthene flusulfamide are preferably 1 with the mass ratio of fluopyram:20~50:1,
More preferably 1:20~1:4、30:1~1:1.In some preferred technical schemes：Hexanaphthene flusulfamide and fluopyram
Mass ratio can be 70：1、50:1、30:1、20:1、10:1、5:1、2.5:1、1:1、1:2、1:4、1:7、1:10、1:15、1:
20、1:30、1:Selected in 50.
In bactericidal composition of the present invention, both Hexanaphthene flusulfamide and fluopyram account for the weight/mass percentage composition of composition
It is 2%~80%.It is preferred that 10%~70%.
Described bactericidal composition, wherein being helped with known as principle active component with Hexanaphthene flusulfamide and fluopyram
Agent and excipient are re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusion
Agent, defoamer, wetting agent, disintegrant etc., can be gathered using calcium dodecyl benzene sulfonate, APES, benzylphenol
Oxygen vinethene, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, fat
Fat acid ethylene oxide adduct, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, Nonyl pheno
Ether, TWEEN Series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphorous
One or more combinations, figuration in hydrochlorate, lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc.
Agent includes cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient
And other auxiliary materials can be with alone or be used in combination.
Described bactericidal composition, its formulation is that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the described bactericidal composition on preventing and treating fungal diseases of plants medicine, especially in preventing and treating Cereal, fruit
Application in terms of tree, vegetable crop disease.
Described fungal diseases of plants is downy mildew, powdery mildew, scab, sclerotiniose, gray mold, brown spot etc..
Beneficial effects of the present invention：
1st, the Hexanaphthene flusulfamide used by the present invention is different with the fluopyram mechanism of action, and mutual mixture will not produce low
Touch, can Synergistic, reduction dosage, reduces cost.
2nd, the present composition scope of application increases, it is adaptable to prevent and treat the fungal disease of Cereal, fruit tree, vegetables, special
It is not that application on downy mildew, powdery mildew, scab, sclerotiniose, gray mold, brown spot etc. is prevented and treated has significant effect.
Bactericidal composition of the present invention has good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And press down
The drug-fast generation of insect processed or fungi to unitary agent (Hexanaphthene flusulfamide and fluopyram are any).Sterilization of the invention
Composition can produce synergistic function higher, and the consumption of the amount ratio independent reactive compound of the mixture to drop significantly
Low, i.e., the activity of mixture is more than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as downy mildew, powdery mildew, scab, sclerotiniose, gray mold, brown spot have obvious synergistic function, overcome and
Delay the resistance to the action of a drug, expand preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) it is alternative
Agricultural chemicals that is conventional and being also easy to produce resistance；(4) compared with single dose, production and use cost are reduced；(5) the drug-fast product of fungi is suppressed
Raw, its effect is used apparently higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, determines EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows：
A certain single dose (generally selects EC as standard agent with mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
According to active ingredient Hexanaphthene flusulfamide (A)：Fluopyram (B) quality proportioning is：70：1、50：1、30：1、20：
1、10：1、5：1、2.5：1、1：1、1：2、1：4、1：7、1：10、1：20、1：30、1：50 are tested, and determine it to cucumber downy mildew
The co-toxicity coefficient of disease.
Table 1：Indoor biometricses result of the Hexanaphthene flusulfamide+fluopyram different ratio to cucumber downy mildew
Field control effectiveness test：
Cucumber downy mildew is prevented and treated with pesticidal preparations obtained in following examples to test.
1st, test process：This test medicine consumption sets two concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is respectively the fluopyram SC of agricultural chemicals single dose 50% and 50% Hexanaphthene flusulfamide WP and blank clean water experiment.
2nd, test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates anti-
Effect.Result of the test is shown in Table 2：
The field efficacy experiment of table 2
Shown by indoor biometricses and field efficacy result, Hexanaphthene flusulfamide has obvious with fluopyram composition
Synergistic function, the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application in agricultural application
Value.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds with specific embodiment below
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% Hexanaphthene flusulfamide fluopyram wettable powder (1:2)
By Hexanaphthene flusulfamide 5g, fluopyram 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g,
Dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, are obtained
Active ingredient mass percent is 15% Hexanaphthene flusulfamide fluopyram wettable powder.
Embodiment 2：15% Hexanaphthene flusulfamide fluopyram wettable powder (1:4)
By Hexanaphthene flusulfamide 3g, fluopyram 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g,
Kaolin adds to 100g mixtures and carries out air-flow crushing, and it is 15% Hexanaphthene flusulfamide fluorine pyrrole that active ingredient mass percent is obtained
Bacterium acid amides wettable powder.
Embodiment 3：16% Hexanaphthene flusulfamide fluopyram wettable powder (1:7)
By Hexanaphthene flusulfamide 2g, fluopyram 14g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g,
Kaolin adds to 100g mixtures and carries out air-flow crushing, and it is 16% Hexanaphthene flusulfamide fluorine pyrrole that active ingredient mass percent is obtained
Bacterium acid amides wettable powder.
Embodiment 4：20% Hexanaphthene flusulfamide fluopyram suspending agent (1:1)
Weigh 10g Hexanaphthene flusulfamides, 10g fluopyrams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
Effective Ingredient percent is made under effect for 20% Hexanaphthene flusulfamide fluopyram suspending agent.
Embodiment 5：55% Hexanaphthene flusulfamide fluopyram aqueous emulsion (1:10)
Weigh 5g Hexanaphthene flusulfamides, 50g fluopyrams, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g,
APES 1g, solvent naphtha 13g, adds water to 100g.Above raw material is routinely prepared the method input of aqueous emulsion
Mixing kettle high speed mixes, and is made effective Ingredient percent for 55% Hexanaphthene flusulfamide fluopyram aqueous emulsion.
Embodiment 6：42% Hexanaphthene flusulfamide fluopyram missible oil (1:20)
Weigh 2g Hexanaphthene flusulfamides, 40g fluopyrams, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether
5g, solvent naphtha are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made active ingredient matter
Amount percentage is 42% Hexanaphthene flusulfamide fluopyram missible oil.
Embodiment 7：70% Hexanaphthene flusulfamide fluopyram missible oil (2.5:1)
Weigh 50g Hexanaphthene flusulfamides, 20g fluopyrams, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether
2g, castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.By above raw material routinely prepare missible oil method input mixing kettle in
Mixing, is made effective Ingredient percent for 70% Hexanaphthene flusulfamide fluopyram missible oil.
Embodiment 8：18% Hexanaphthene flusulfamide fluopyram water dispersion granule (5：1)
Weigh 15g Hexanaphthene flusulfamides, 3g fluopyrams, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and above raw material is formed with into effect by water dispersible granular agent method
Ingredient percent is 18% Hexanaphthene flusulfamide fluopyram water dispersion granule.
Embodiment 9：11% Hexanaphthene flusulfamide fluopyram missible oil (10:1)
Weigh 10g Hexanaphthene flusulfamides, 1g fluopyrams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether
7g, solvent naphtha are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made active ingredient matter
Amount percentage is 11% Hexanaphthene flusulfamide fluopyram missible oil.
Embodiment 10：31.5% Hexanaphthene flusulfamide fluopyram microemulsion (20:1)
Weigh 30g Hexanaphthene flusulfamides, 1.5g fluopyrams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyoxyethylene
Ether phosphate 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.By above raw material routinely
Mix in the method input mixing kettle for preparing microemulsion, be made effective Ingredient percent for 31.5% Hexanaphthene flusulfamide fluorine
Pyrrole bacterium acid amides microemulsion.
Embodiment 11：31% Hexanaphthene flusulfamide fluopyram missible oil (30:1)
Weigh 30g Hexanaphthene flusulfamides, 1g fluopyrams, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether
4g, solvent naphtha are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made active ingredient matter
Amount percentage is 31% Hexanaphthene flusulfamide fluopyram missible oil.
Embodiment 12：51% Hexanaphthene flusulfamide fluopyram suspending agent (50:1)
Weigh 50g Hexanaphthene flusulfamides, 1g fluopyrams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
Effective Ingredient percent is made under effect for 51% Hexanaphthene flusulfamide fluopyram suspending agent.
Embodiment 13：32% Hexanaphthene flusulfamide fluopyram microemulsion (1:15)
Weigh 2g Hexanaphthene flusulfamides, 30g fluopyrams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether
Phosphate 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, be made effective Ingredient percent for 32% Hexanaphthene flusulfamide fluorine pyrrole bacterium
Acid amides microemulsion.
Embodiment 14：6% Hexanaphthene flusulfamide fluopyram aqueous emulsion (1:5)
Weigh 1g Hexanaphthene flusulfamides, 5g fluopyrams, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkane
Base phenol polyethenoxy ether 1g, solvent naphtha 13g, add water to 100g.The method input that above raw material is routinely prepared into aqueous emulsion is mixed
The mixing of kettle high speed is closed, effective Ingredient percent is made for 6% Hexanaphthene flusulfamide fluopyram aqueous emulsion.
Embodiment 15：62% Hexanaphthene flusulfamide fluopyram microemulsion (1:30)
Weigh 2g Hexanaphthene flusulfamides, 60g fluopyrams, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether
Phosphate 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, be made effective Ingredient percent for 62% Hexanaphthene flusulfamide fluorine pyrrole bacterium
Acid amides microemulsion.
Embodiment 16：51% Hexanaphthene flusulfamide fluopyram suspending agent (1:50)
Weigh 1g Hexanaphthene flusulfamides, 50g fluopyrams, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
Effective Ingredient percent is made under effect for 51% Hexanaphthene flusulfamide fluopyram suspending agent.
Embodiment 17：7% Hexanaphthene flusulfamide fluopyram water dispersion granule (1：2.5)
Weigh 2g Hexanaphthene flusulfamides, 5g fluopyrams, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is made by water dispersible granular agent method
Active ingredient mass percent is 7% Hexanaphthene flusulfamide fluopyram water dispersion granule.
Claims (9)
1. a kind of bactericidal composition containing Hexanaphthene flusulfamide and fluopyram, it is characterised in that the bactericidal composition is with hexamethylene sulphur
Bacterium amine and the main active principle of fluopyram, wherein Hexanaphthene flusulfamide are 1 with the mass ratio of fluopyram:50~70:1.
2. bactericidal composition according to claim 1, it is characterised in that the matter of the Hexanaphthene flusulfamide and fluopyram
Amount is than being 1:20~50:1.
3. bactericidal composition according to claim 2, it is characterised in that the matter of the Hexanaphthene flusulfamide and fluopyram
Amount is than being 1:20~1:4、30:1~1:1.
4. bactericidal composition according to claim 1, it is characterised in that described Hexanaphthene flusulfamide and fluopyram two
The weight/mass percentage composition that person accounts for composition is 2%~80%.
5. bactericidal composition according to claim 4, it is characterised in that described Hexanaphthene flusulfamide and fluopyram two
The weight/mass percentage composition that person accounts for composition is 10%~70%.
6. bactericidal composition according to claim 1, it is characterised in that with Hexanaphthene flusulfamide and fluopyram be main
Active ingredient and insecticides adjuvant, excipients are configured to any one formulation allowed on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition described in claim 1 on preventing and treating fungal diseases of plants medicine is prepared.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is downy mildew, powdery mildew, black
At least one in star disease, sclerotiniose, gray mold, brown spot.
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| CN201710140096.5A CN106922672A (en) | 2017-03-10 | 2017-03-10 | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fluopyram |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651467A (en) * | 2012-08-31 | 2014-03-26 | 陕西美邦农药有限公司 | Cyclohexyl flusulfamide-containing bactericidal composition |
-
2017
- 2017-03-10 CN CN201710140096.5A patent/CN106922672A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651467A (en) * | 2012-08-31 | 2014-03-26 | 陕西美邦农药有限公司 | Cyclohexyl flusulfamide-containing bactericidal composition |
Non-Patent Citations (1)
| Title |
|---|
| 刘安昌 等: "新型杀菌剂氟吡菌酰胺的合成", 《农药》 * |
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Application publication date: 20170707 |