CN107047566A - A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and volution bacterium amine - Google Patents
A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and volution bacterium amine Download PDFInfo
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- CN107047566A CN107047566A CN201710136268.1A CN201710136268A CN107047566A CN 107047566 A CN107047566 A CN 107047566A CN 201710136268 A CN201710136268 A CN 201710136268A CN 107047566 A CN107047566 A CN 107047566A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
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- Pest Control & Pesticides (AREA)
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Abstract
The invention discloses a kind of bactericidal composition containing Hexanaphthene flusulfamide and volution bacterium amine and its application.The bactericidal composition is using Hexanaphthene flusulfamide and volution bacterium amine as principle active component, and wherein the mass ratio of Hexanaphthene flusulfamide and volution bacterium amine is 1:50~70:1.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and used.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as gray mold, scab, brown spot, sclerotiniose, banded sclerotial blight, effect is better than single dose and used.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, especially one kind is based on Hexanaphthene flusulfamide and volution bacterium amine
Want bactericidal composition and its application of active component.
Background technology
Hexanaphthene flusulfamide molecular formula：C13H13CIF3NO3S.Chemical name：N- (2- trifluoromethyl-4-chlorophenyls)-alpha-oxo
Cyclohexyl sulfonamide.It has stronger prevention, treatment and osmotically active, there is higher lasting effect.Through table of field test results
It is bright effectively to prevent and treat gray mold, sclerotinia sclerotiorum, Cucumber Target Leaf Spot and scab.
Volution bacterium amine (Spiroxamine), molecular formula：C18H35NO2.Chemical name is：The tertiary fourths of N- ethyl-N- propyl group -8-
Base -1,4- dioxo spiros [4.5] decane -2- methylamines.Volution bacterium amine is a kind of foliage fungicide of absorbability, has spy to powdery mildew
Effect, the work fast and lasting period is long has protection therapeutic action concurrently, both can be used alone, again can be mixed with other bactericide
It is equipped with expansion fungicidal spectrum, controlling object wheat powdery mildew and various rust, barley leaf blotch and stripe disease.
The difficulty of prevention and cure of current phytopathogen is increasing, and main cause has：One is the change with pattern of farming, melon
The industrial crops cultivated area such as fruits and vegetables progressively expands, and disease occurrence degree, generation quantity increase, difficult in preventing and treating
Degree is increased；Two be that current climate is abnormal, and the outburst to disease provides certain condition；Three be the selection of long-term chemical medication
Property influence so that the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality.
In summary, current control of plant disease work faces big challenge emphatically.
The content of the invention
The purpose of the present invention be provide that a kind of applied widely, cost is low for above-mentioned technical problem, effect is good contains ring
The bactericidal composition of own flusulfamide and volution bacterium amine.
Prevented and treated it is a still further object of the present invention to provide the bactericidal composition caused by plant epiphyte on fungal disease
Using the especially purposes on the fungal diseases such as gray mold, scab, brown spot, sclerotiniose, banded sclerotial blight are prevented and treated.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing Hexanaphthene flusulfamide and volution bacterium amine, the bactericidal composition is with Hexanaphthene flusulfamide and loop coil
Bacterium amine is principle active component, and wherein the mass ratio of Hexanaphthene flusulfamide and volution bacterium amine is 1:50~70:1, wherein Bactericidal composite
Effective ingredient is present in composition with enhancing effective amount in thing.
The mass ratio of described bactericidal composition, wherein Hexanaphthene flusulfamide and volution bacterium amine is preferably 50：1~1:7 or 1:
20~1:30；More preferably 30:1~1:2 or 1:20；Still more preferably it is 30:1 or 10:1~1:1, invention human hair
Existing, within this range, not only the bactericidal composition has more preferable synergy, and the lasting period is longer.
In bactericidal composition of the present invention, the weight/mass percentage composition that both Hexanaphthene flusulfamide and volution bacterium amine account for composition is
2%~80%.It is preferred that 10%~70%, more preferably 10%~40%.
Described bactericidal composition, wherein using Hexanaphthene flusulfamide and volution bacterium amine as principle active component and known auxiliary agent
Any one formulation allowed on agricultural chemicals is re-dubbed with excipient.These known auxiliary agents, excipients have dispersant, diffusant,
Defoamer, wetting agent, disintegrant etc., can use calcium dodecyl benzene sulfonate, APES, benzylphenol polyoxy second
Alkene ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid
Ethylene oxide adduct, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE,
TWEEN Series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphorous acid
One or more of salt, lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. are combined, excipient
Including cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and
Other auxiliary materials can be with alone or be used in combination.
Described bactericidal composition, its formulation is that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the described bactericidal composition on preventing and treating fungal diseases of plants medicine, especially in preventing and treating Cereal, fruit
Application in terms of tree, vegetable crop disease.
Described fungal diseases of plants is gray mold, scab, brown spot, sclerotiniose, banded sclerotial blight etc..
Beneficial effects of the present invention：
1st, the Hexanaphthene flusulfamide used in the present invention is different with the volution bacterium amine mechanism of action, mutual mixture will not produce it is low tactile,
Can Synergistic, reduce dosage, reduce cost.
2nd, present composition scope of application increase, it is adaptable to prevent and treat Cereal, fruit tree, the fungal disease of vegetables, it is special
It is not that application on gray mold, scab, brown spot, sclerotiniose, banded sclerotial blight etc. is prevented and treated has significant effect.The present invention is killed
Bacteria composition has good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And suppress insect or
Drug-fast generation of the fungi to unitary agent (Hexanaphthene flusulfamide and volution bacterium amine are any).The bactericidal composition of the present invention can be produced
Higher synergistic function is given birth to, and the consumption of the amount ratio independent reactive compound of the mixture is substantially reduced, that is, is mixed
The activity of thing is more than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as gray mold, scab, brown spot, sclerotiniose, banded sclerotial blight have obvious synergistic function, overcome and have delayed anti-
The property of medicine, expands preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and easily
Produce the agricultural chemicals of resistance；(4) compared with single dose, production and use cost reduction；(5) the drug-fast generation of fungi is suppressed, it is imitated
Fruit uses apparently higher than its single dose.
Embodiment
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Embodiment 1：15% Hexanaphthene flusulfamide volution bacterium amine wettable powder (1:2)
By Hexanaphthene flusulfamide 5g, volution bacterium amine 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, expansion
Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, and being made has
Effect Ingredient percent is 15% Hexanaphthene flusulfamide volution bacterium amine wettable powder.
Embodiment 2：15% Hexanaphthene flusulfamide volution bacterium amine wettable powder (1:4)
It is high by Hexanaphthene flusulfamide 3g, volution bacterium amine 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g
Ridge soil adds to 100g mixtures and carries out air-flow crushing, and it is 15% Hexanaphthene flusulfamide loop coil bacterium that active ingredient mass percent, which is made,
Amine wettable powder.
Embodiment 3：16% Hexanaphthene flusulfamide volution bacterium amine wettable powder (1:7)
It is high by Hexanaphthene flusulfamide 2g, volution bacterium amine 14g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g
Ridge soil adds to 100g mixtures and carries out air-flow crushing, and it is 16% Hexanaphthene flusulfamide loop coil bacterium that active ingredient mass percent, which is made,
Amine wettable powder.
Embodiment 4：20% Hexanaphthene flusulfamide volution bacterium amine suspending agent (1:1)
Weigh 10g Hexanaphthene flusulfamides, 10g volution bacterium amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in sand mill with water
Effective Ingredient percent is made under effect for 20% Hexanaphthene flusulfamide volution bacterium amine suspending agent.
Embodiment 5：55% Hexanaphthene flusulfamide volution bacterium amine aqueous emulsion (1:10)
Weigh 5g Hexanaphthene flusulfamides, 50g volution bacterium amines, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkane
Base phenol polyethenoxy ether 1g, solvent naphtha 13g, add water to 100g.The method input that above raw material is routinely prepared into aqueous emulsion is mixed
The mixing of kettle high speed is closed, effective Ingredient percent is made for 55% Hexanaphthene flusulfamide volution bacterium amine aqueous emulsion.
Embodiment 6：42% Hexanaphthene flusulfamide volution bacterium amine missible oil (1:20)
Weigh 2g Hexanaphthene flusulfamides, 40g volution bacterium amines, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality is made
Percentage is 42% Hexanaphthene flusulfamide volution bacterium amine missible oil.
Embodiment 7：70% Hexanaphthene flusulfamide volution bacterium amine missible oil (2.5:1)
Weigh 50g Hexanaphthene flusulfamides, 20g volution bacterium amines, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether
2g, castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.In the method input mixing kettle that above raw material is routinely prepared to missible oil
Mixing, is made effective Ingredient percent for 70% Hexanaphthene flusulfamide volution bacterium amine missible oil.
Embodiment 8：18% Hexanaphthene flusulfamide volution bacterium amine water dispersion granule (5：1)
Weigh 15g Hexanaphthene flusulfamides, 3g volution bacterium amines, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and above raw material is formed with imitating into by water dispersible granular agent method
It is 18% Hexanaphthene flusulfamide volution bacterium amine water dispersion granule to divide mass percent.
Embodiment 9：11% Hexanaphthene flusulfamide volution bacterium amine missible oil (10:1)
Weigh 10g Hexanaphthene flusulfamides, 1g volution bacterium amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality is made
Percentage is 11% Hexanaphthene flusulfamide volution bacterium amine missible oil.
Embodiment 10：31.5% Hexanaphthene flusulfamide volution bacterium amine microemulsion (20:1)
Weigh 30g Hexanaphthene flusulfamides, 1.5g volution bacterium amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether
Phosphate 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely matched somebody with somebody
Mixed in the method input mixing kettle of microemulsion processed, effective Ingredient percent is made for 31.5% Hexanaphthene flusulfamide loop coil
Bacterium amine microemulsion.
Embodiment 11：31% Hexanaphthene flusulfamide volution bacterium amine missible oil (30:1)
Weigh 30g Hexanaphthene flusulfamides, 1g volution bacterium amines, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g,
Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality is made
Percentage is 31% Hexanaphthene flusulfamide volution bacterium amine missible oil.
Embodiment 12：51% Hexanaphthene flusulfamide volution bacterium amine suspending agent (50:1)
50g Hexanaphthene flusulfamides, 1g volution bacterium amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the effect of sand mill with water
Under effective Ingredient percent is made for 51% Hexanaphthene flusulfamide volution bacterium amine suspending agent.
Embodiment 13：32% Hexanaphthene flusulfamide volution bacterium amine microemulsion (1:15)
Weigh 2g Hexanaphthene flusulfamides, 30g volution bacterium amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mixed in the method input mixing kettle of microemulsion, effective Ingredient percent is made for 32% Hexanaphthene flusulfamide volution bacterium amine
Microemulsion.
Embodiment 14：6% Hexanaphthene flusulfamide volution bacterium amine aqueous emulsion (1:5)
Weigh 1g Hexanaphthene flusulfamides, 5g volution bacterium amines, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared into aqueous emulsion puts into mixing
Kettle high speed is mixed, and effective Ingredient percent is made for 6% Hexanaphthene flusulfamide volution bacterium amine aqueous emulsion.Embodiment 15：
62% Hexanaphthene flusulfamide volution bacterium amine microemulsion (1:30)
Weigh 2g Hexanaphthene flusulfamides, 60g volution bacterium amines, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mixed in the method input mixing kettle of microemulsion, effective Ingredient percent is made for 62% Hexanaphthene flusulfamide volution bacterium amine
Microemulsion.
Embodiment 16：51% Hexanaphthene flusulfamide volution bacterium amine suspending agent (1:50)
1g Hexanaphthene flusulfamides, 50g volution bacterium amines, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the effect of sand mill with water
Under effective Ingredient percent is made for 51% Hexanaphthene flusulfamide volution bacterium amine suspending agent.
Embodiment 17：7% Hexanaphthene flusulfamide volution bacterium amine water dispersion granule (1：2.5)
2g Hexanaphthene flusulfamides, 5g volution bacterium amines are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with by water dispersible granular agent method
Effect Ingredient percent is 7% Hexanaphthene flusulfamide volution bacterium amine water dispersion granule.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, determines EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows：
A certain single dose (generally selects EC as standard agent using in mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The virulence of the toxicity index of theoretical toxicity index (TTI)=A single doses × A single doses proportion+B single doses in mixture
Index × B single doses proportion in mixture
Survey the EC of toxicity index (ATI)=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, and CTC exists when being less than 80 for antagonism, CTC
It is summation action between 80-120.
According to active ingredient Hexanaphthene flusulfamide (A)：Volution bacterium amine (B) quality proportioning is：70：1、50：1、30：1、20：1、
10：1、5：1、2.5：1、1：1、1：2、1：4、1：7、1：10、1：20、1：30、1：50 are tested, and determine it to wheat sharp eyespot
Co-toxicity coefficient.
Table 1：Indoor biometricses result of the Hexanaphthene flusulfamide+volution bacterium amine different ratio to wheat sharp eyespot
| Medicament | Virulence regression equation | EC50(mg/L) | ATI | TTI | Co-toxicity coefficient |
| Hexanaphthene flusulfamide | Y=1.4514X+4.1122 | 4.0896 | 100.00 | - | - |
| Volution bacterium amine | Y=1.0895X+3.8461 | 11.4570 | 35.6952 | - | - |
| A:B=70:1 | Y=2.0555X+3.9731 | 3.1593 | 129.447 | 99.094 | 130.63 |
| A:B=50:1 | Y=2.0639X+4.0632 | 2.8437 | 143.814 | 98.739 | 145.65 |
| A:B=30:1 | Y=2.4947X+4.0189 | 2.4733 | 165.347 | 97.926 | 168.85 |
| A:B=20:1 | Y=1.3908X+4.4131 | 2.6425 | 154.761 | 96.938 | 159.65 |
| A:B=10:1 | Y=2.0184X+4.2282 | 2.4120 | 169.553 | 94.154 | 180.08 |
| A:B=5:1 | Y=1.8987X+4.1558 | 2.7837 | 146.914 | 89.283 | 164.55 |
| A:B=2.5:1 | Y=2.1098X+4.0172 | 2.9229 | 139.917 | 81.627 | 171.41 |
| A:B=1:1 | Y=2.8792X+3.4675 | 3.4062 | 120.063 | 67.848 | 176.96 |
| A:B=1:2 | Y=2.0569X+3.6182 | 4.6965 | 87.078 | 57.130 | 152.42 |
| A:B=1:4 | Y=2.4512X+3.1234 | 5.8287 | 70.164 | 48.556 | 144.50 |
| A:B=1:7 | Y=2.5698X+2.9565 | 6.2404 | 65.534 | 43.733 | 149.85 |
| A:B=1:10 | Y=2.2145X+3.1170 | 7.0846 | 57.726 | 41.541 | 138.96 |
| A:B=1:20 | Y=2.9077X+2.5979 | 6.7004 | 61.035 | 38.757 | 157.48 |
| A:B=1:30 | Y=1.8874X+3.3355 | 7.6188 | 53.678 | 37.770 | 142.12 |
| A:B=1:50 | Y=2.2678X+2.8814 | 8.5944 | 47.585 | 36.956 | 128.76 |
Field control effectiveness test：
Tested with pesticidal preparations preventing and treating wheat sharp eyespot made from following examples.
1st, test process：This test medicine consumption sets two concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is the volution bacterium amine EC of agricultural chemicals single dose 25% and 50% Hexanaphthene flusulfamide WP and blank clean water experiment respectively.
2nd, test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates anti-
Effect.Result of the test is shown in Table 2：
The field efficacy experiment of table 2
Shown by indoor biometricses and field efficacy result, Hexanaphthene flusulfamide has obvious association with volution bacterium amine composition
Same synergistic effect, the prevention effect of composition is excellent, and prevention effect is better than single dose kind, and preventive effect phase is long, in agricultural application
In have application value.
Claims (9)
1. a kind of bactericidal composition containing Hexanaphthene flusulfamide and volution bacterium amine, it is characterised in that the bactericidal composition is with hexamethylene sulphur bacterium
Amine and the main active principle of volution bacterium amine, the wherein mass ratio of Hexanaphthene flusulfamide and volution bacterium amine are 1:50~70:1.
2. bactericidal composition according to claim 1, it is characterised in that the quality of the Hexanaphthene flusulfamide and volution bacterium amine
Than for 50：1~1:7 or 1:20~1:30.
3. bactericidal composition according to claim 2, it is characterised in that the quality of the Hexanaphthene flusulfamide and volution bacterium amine
Than for 30:1~1:2 or 1:20.
4. bactericidal composition according to claim 1, it is characterised in that both described Hexanaphthene flusulfamide and volution bacterium amine
The weight/mass percentage composition for accounting for composition is 2% ~ 80%.
5. bactericidal composition according to claim 4, it is characterised in that both described Hexanaphthene flusulfamide and volution bacterium amine
The weight/mass percentage composition for accounting for composition is 10% ~ 70%.
6. bactericidal composition according to claim 1, it is characterised in that using Hexanaphthene flusulfamide and volution bacterium amine mainly to have
Effect composition and insecticides adjuvant, excipients are configured to any one formulation allowed on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared described in claim 1.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is gray mold, scab, brown
At least one of pinta, sclerotiniose, banded sclerotial blight.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0281842A1 (en) * | 1987-03-07 | 1988-09-14 | Bayer Ag | Aminomethyl-heterocycles |
| CN1900059A (en) * | 2005-07-20 | 2007-01-24 | 中国农业大学 | 2-keto naphthene sulfamide, its preparing method and use as germicide |
| CN101720764A (en) * | 2008-10-13 | 2010-06-09 | 中国农业大学 | New application of N-(2-trifluoromethyl-4-chlorphenyl)-alpha-oxocyclohexyl sulfamide as sterilizing agent |
| CN104322501A (en) * | 2012-08-15 | 2015-02-04 | 陕西美邦农药有限公司 | Chesulfamide-containing efficient sterilization composition |
-
2017
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0281842A1 (en) * | 1987-03-07 | 1988-09-14 | Bayer Ag | Aminomethyl-heterocycles |
| CN1900059A (en) * | 2005-07-20 | 2007-01-24 | 中国农业大学 | 2-keto naphthene sulfamide, its preparing method and use as germicide |
| CN101720764A (en) * | 2008-10-13 | 2010-06-09 | 中国农业大学 | New application of N-(2-trifluoromethyl-4-chlorphenyl)-alpha-oxocyclohexyl sulfamide as sterilizing agent |
| CN104322501A (en) * | 2012-08-15 | 2015-02-04 | 陕西美邦农药有限公司 | Chesulfamide-containing efficient sterilization composition |
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Application publication date: 20170818 |