CN105831131A - Bactericidal composition containing fluxapyroxad and thiabendazole and application thereof - Google Patents
Bactericidal composition containing fluxapyroxad and thiabendazole and application thereof Download PDFInfo
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- CN105831131A CN105831131A CN201610266240.5A CN201610266240A CN105831131A CN 105831131 A CN105831131 A CN 105831131A CN 201610266240 A CN201610266240 A CN 201610266240A CN 105831131 A CN105831131 A CN 105831131A
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- fluxapyroxad
- probenazole
- bactericidal composition
- thiabendazole
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses a bactericidal composition containing fluxapyroxad and thiabendazole and an application thereof. The bactericidal composition takes fluxapyroxad and thiabendazole as main active ingredients, wherein the mass ratio of fluxapyroxad to thiabendazole is (1-70) to (1-50). The bactericidal composition can be used for controlling cereal, fruit tree and vegetable diseases, has higher synergistic effects, has the effects of overcoming and delaying the drug resistance of germs, has a high bactericidal speed and a long lasting period, has the effect of reducing the application cost and has obviously better control effects than single agents. The bactericidal composition can be used for controlling fungal diseases on crops, especially fungal diseases, such as sheath blight, gray mold, rice bakanae diseases, pear powdery mildew, anthracnose, and the like, and has obviously better effects than single agents.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially one live with fluxapyroxad and probenazole for main
The bactericidal composition of property composition and application thereof.
Background technology
Fluxapyroxad (fluxapyroxad), chemical formula: C18H12F5N3O, chemical name: 3-(difluoromethyl)-1-
Methyl-N-(3', 4', 5'-trifluoro-biphenyl-2-base) pyrazole-4-carboxamide.
Fluxapyroxad belongs to benzamide type antibacterial, for succinate dehydrogenase inhibitors, is a kind of broad-spectrum germicide,
There is the treatment of excellence, systemic activity, all kinds of crop banded sclerotial blights, gray mold etc. are respectively provided with good control effect.
Probenazole (thiabendazole), molecular formula: C10H7N3S, chemical name: 2-(4-thiazolyl)-1H-benzo miaow
Azoles.Structural formula:
Probenazole is a kind of efficient, wide-spectrum bactericide, is drawn to push up conductive performance, but can not conduct to base in tool.Holding effect
Phase is long, has cross resistance with benzimidazole germicide.Ascomycetes, basidiomycetes and Fungi Imperfecti there are is inhibitory activity, is used for
Prevent and treat various crop fungal disease and antiseptic preservation of fruits and vegetables.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, along with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty strengthens;
On the other hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality,
Control of plant disease is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, low cost, effective fluorine-containing azoles for above-mentioned technical problem
Bacterium amide and the plant bactericidal composition of probenazole.
It is a still further object of the present invention to provide this bactericidal composition and cause the application on fungal disease at preventing and treating plant epiphyte,
Especially in the purposes prevented and treated on the fungal diseases such as banded sclerotial blight, gray mold, bakanae disease of rice, pears powdery mildew, anthrax.
It is an object of the invention to be achieved through the following technical solutions:
A kind of Fluxapyroxad-containsterilization and the bactericidal composition of probenazole, this bactericidal composition with fluxapyroxad with probenazole is
Principle active component, wherein fluxapyroxad is 1~70:1~50 with the mass ratio of probenazole, wherein in bactericidal composition
Active ingredient is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein fluxapyroxad is preferably 10~70:1~50 with the mass ratio of probenazole, enters one
Step is preferably 20~70:1~10, the most preferably 20~70:1~4.
Fluxapyroxad with the preferred mass proportioning of probenazole can also be: 70:1,50:1,30:1,20:1,10:
1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50.
In the compositions of the present invention, the weight/mass percentage composition accounting for compositions both fluxapyroxad and probenazole is 2~80%.
Preferably 5~70%.
Described bactericidal composition, wherein with fluxapyroxad and probenazole for principle active component and known auxiliary agent and tax
Shape agent is re-dubbed on pesticide any one dosage form allowed.Auxiliary agent known to these, excipient have dispersant, diffusant,
Defoamer, wetting agent, disintegrating agent etc., can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, benzylphenol
Polyoxyethylene ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products, aliphatic amine polyoxyethylene
Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, nonyl
Phenol polyethenoxy ether, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfur
Hydrochlorate, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc.
In one or more combinations, excipient includes that Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent are (such as the third two
Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.Especially preventing and treating Cereal,
Application in terms of fruit tree, vegetable crop disease has remarkable result.
Above-mentioned application, described fungal diseases of plants is banded sclerotial blight, gray mold, bakanae disease of rice, pears powdery mildew, charcoal
At least one in cellulitis disease.
The feature of bactericidal composition of the present invention:
1, the fluxapyroxad used by the present invention and probenazole, the mechanism of action is different, and mutual mixture will not produce low touching,
Can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating Cereal, fruit tree, the refractory fungal disease of vegetable,
Particularly prevent and treat banded sclerotial blight, gray mold, bakanae disease of rice, pears powdery mildew, anthrax etc. and all have significant effect.This
Bright bactericidal composition has good prevention effect to ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease;And press down
Insect processed or the fungus drug-fast generation to unitary agent (fluxapyroxad and probenazole are arbitrary).Sterilization group of the present invention
Compound can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture drops significantly
Low, i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as banded sclerotial blight, gray mold, bakanae disease of rice, pears powdery mildew, anthrax have obvious synergistic function, gram
Taking and delayed Drug resistance, expanding prevention is composed, hence it is evident that improve prevention effect;(2) preventing and treating recruitment, drug cost are reduced;
(3) alternative routine and the pesticide being easily generated resistance;(4) compared with single dose, produce and use cost reduces;(5)
The suppression drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is conventional method,
" % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A the single dose of theoretical toxicity index=A single dose in mixture the toxicity index of proportion+B single dose ×
B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, CTC
It it is summation action between 80-120.
According to effective ingredient fluxapyroxad (A): probenazole (B) quality proportioning is: 80:1,70:1,50:1,
30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:
30,1:50,1:60 test, and measure it to pears anthrax bacteria (Colletotrichum gloeosporioides Penz.)
Co-toxicity coefficient.
Table 1: the fluxapyroxad+probenazole different ratio indoor biometrics result to pears anthrax bacteria
Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
12.5% fluxapyroxad SC | Y=4.514+1.201X | 2.540 | - |
60% probenazole WP | Y=4.247+2.524X | 1.987 | - |
A:B=80:1 | Y=3.771+3.556X | 2.216 | 114.21 |
A:B=70:1 | Y=4.552+2.598X | 1.488 | 170.04 |
A:B=50:1 | Y=4.654+1.874X | 1.529 | 165.23 |
A:B=30:1 | Y=4.484+2.365X | 1.652 | 152.41 |
A:B=20:1 | Y=4.624+2.635X | 1.389 | 180.45 |
A:B=10:1 | Y=4.787+1.209X | 1.499 | 165.23 |
A:B=5:1 | Y=4.111+3.051X | 1.956 | 124.08 |
A:B=2.5:1 | Y=4.459+2.350X | 1.699 | 138.49 |
A:B=1:1 | Y=4.603+2.630X | 1.416 | 157.48 |
A:B=1:2 | Y=4.806+1.547X | 1.335 | 160.53 |
A:B=1:4 | Y=4.888+2.635X | 1.103 | 188.29 |
A:B=1:6 | Y=4.296+4.451X | 1.439 | 142.54 |
A:B=1:10 | Y=4.630+3.625X | 1.265 | 160.25 |
A:B=1:20 | Y=4.583+2.045X | 1.600 | 125.48 |
A:B=1:30 | Y=4.744+1.205X | 1.632 | 122.63 |
A:B=1:50 | Y=4.783+2.301X | 1.243 | 160.54 |
A:B=1:60 | Y=4.520+1.447X | 2.148 | 92.82 |
Field control effectiveness test:
The pesticidal preparations preventing and treating pears anthrax test prepared with above-described embodiment.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, compares medicine
Agent is pesticide single dose 12.5% fluxapyroxad SC and 60% probenazole WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times;Investigation drug effect after investigating before dispenser and preventing and treating
Method is: randomization 5 point in test treatment region, carries out severity Scaling according to country's field test relevant criterion, meter
Calculate preventive effect.Result of the test is shown in Table 2:
Table 2 field test effect
Being shown by indoor biometrics and field efficacy result, fluxapyroxad and probenazole compositions have the most collaborative increasing
Effect effect, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has application valency in agricultural is applied
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates that two kinds have with specific embodiment below
The preparation that effect composition is processed into, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% fluxapyroxad probenazole wettable powder (1:2)
By fluxapyroxad 5g, probenazole 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g,
Dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out air-flow powder
Broken, preparing effective ingredient mass percent is 15% fluxapyroxad probenazole wettable powder.
Embodiment 2:15% fluxapyroxad probenazole wettable powder (1:4)
By fluxapyroxad 3g, probenazole 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g,
Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 15% fluxapyroxad thiophene
Bacterium spirit wettable powder.
Embodiment 3:14% fluxapyroxad probenazole wettable powder (1:6)
By fluxapyroxad 2g, probenazole 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g,
Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 14% fluxapyroxad thiophene
Bacterium spirit wettable powder.
Embodiment 4:20% fluxapyroxad probenazole suspending agent (1:1)
Weigh 10g fluxapyroxad, 10g probenazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof,
Xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand milling
Making effective Ingredient percent under the effect of machine is 20% fluxapyroxad probenazole suspending agent.
Embodiment 5:55% fluxapyroxad probenazole aqueous emulsion (1:10)
Weigh 5g fluxapyroxad, 50g probenazole, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g,
Alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely
Putting into the mixing of mixing kettle high speed, making effective Ingredient percent is 55% fluxapyroxad probenazole aqueous emulsion.
Embodiment 6:42% fluxapyroxad probenazole cream (1:20)
Weigh 2g fluxapyroxad, 40g probenazole, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
Solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient matter
Amount percentage ratio is 42% fluxapyroxad probenazole cream.
Embodiment 7:70% fluxapyroxad probenazole cream (2.5:1)
Weigh 50g fluxapyroxad, 20g probenazole, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing kettle
Middle mixing, making effective Ingredient percent is 70% fluxapyroxad probenazole cream.
Embodiment 8:18% fluxapyroxad probenazole water dispersion granule (5:1)
Weigh 15g fluxapyroxad, 3g probenazole, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, kieselguhr 28g complement to 100g, are made by water dispersible granular agent method by above raw material
Effective ingredient mass percent is 17% fluxapyroxad probenazole water dispersion granule.
Embodiment 9:11% fluxapyroxad probenazole cream (10:1)
Weigh 10g fluxapyroxad, 1g probenazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
Solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient matter
Amount percentage ratio is 11% fluxapyroxad probenazole cream.
Embodiment 10:31.5% fluxapyroxad probenazole microemulsion (20:1)
Weigh 30g fluxapyroxad, 1.5g probenazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material
The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 31.5% fluorine azoles bacterium
Amide probenazole microemulsion.
Embodiment 11:31% fluxapyroxad probenazole cream (30:1)
Weigh 30g fluxapyroxad, 1g probenazole, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g,
Solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient matter
Amount percentage ratio is 31% fluxapyroxad probenazole cream.
Embodiment 12:51% fluxapyroxad probenazole suspending agent (50:1)
Weigh 50g fluxapyroxad, 1g probenazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof,
Xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand milling
Making effective Ingredient percent under the effect of machine is 51% fluxapyroxad probenazole suspending agent.
Embodiment 13:32% fluxapyroxad probenazole microemulsion (1:15)
Weigh 2g fluxapyroxad, 30g probenazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material
The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 32% fluorine azoles bacterium acyl
Amine probenazole microemulsion.
Embodiment 14:6% fluxapyroxad probenazole aqueous emulsion (1:5)
Weigh 1g fluxapyroxad, 5g probenazole, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkane
Base phenol polyethenoxy ether 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely is thrown
Entering the mixing of mixing kettle high speed, making effective Ingredient percent is 6% fluxapyroxad probenazole aqueous emulsion.
Embodiment 15:62% fluxapyroxad probenazole microemulsion (1:30)
Weigh 2g fluxapyroxad, 60g probenazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material
The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 62% fluorine azoles bacterium acyl
Amine probenazole microemulsion.
Embodiment 16:51% fluxapyroxad probenazole suspending agent (1:50)
Weigh 1g fluxapyroxad, 50g probenazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof,
Xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand milling
Making effective Ingredient percent under the effect of machine is 51% fluxapyroxad probenazole suspending agent.
Embodiment 17:7% fluxapyroxad probenazole water dispersion granule (1:2.5)
Weigh 2g fluxapyroxad, 5g probenazole, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, above raw material are pressed water dispersion granule side
It is 7% fluxapyroxad probenazole water dispersion granule that method makes effective ingredient mass percent.
Claims (10)
1. a Fluxapyroxad-containsterilization and the bactericidal composition of probenazole, it is characterised in that this bactericidal composition is with fluorine azoles bacterium
Amide and probenazole are principle active component, and wherein fluxapyroxad is 1~70:1~50 with the mass ratio of probenazole.
Bactericidal composition the most according to claim 1, it is characterised in that described fluxapyroxad and the matter of probenazole
Amount ratio is 10~70:1~50.
Bactericidal composition the most according to claim 2, it is characterised in that described fluxapyroxad and the matter of probenazole
Amount ratio is 20~70:1~10.
Bactericidal composition the most according to claim 3, it is characterised in that described fluxapyroxad and the matter of probenazole
Amount ratio is 20~70:1~4.
Bactericidal composition the most according to claim 1, it is characterised in that described fluxapyroxad and probenazole two
It is 2-80% that person accounts for the weight/mass percentage composition of compositions.
Bactericidal composition the most according to claim 5, it is characterised in that described fluxapyroxad and probenazole two
It is 5-70% that person accounts for the weight/mass percentage composition of compositions.
Bactericidal composition the most according to claim 1, it is characterised in that be main with fluxapyroxad and probenazole
Effective ingredient and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.
Bactericidal composition the most according to claim 7, it is characterised in that described dosage form is cream, suspending agent, water
Emulsion, wettable powder or water dispersion granule.
9. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
Application the most according to claim 9, it is characterised in that described fungal diseases of plants is banded sclerotial blight, grey mold
At least one in disease, bakanae disease of rice, pears powdery mildew, anthrax.
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CN106172431A (en) * | 2016-07-12 | 2016-12-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of Fluxapyroxad-containsterilization and the bactericidal composition of probenazole |
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US20080293786A1 (en) * | 2007-05-23 | 2008-11-27 | Korea Institute Of Science And Technology | Novel 2-imino-1,3-thiazoline-based compounds and t-type calcium channel inhibitors containing the same |
CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
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CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
US20080293786A1 (en) * | 2007-05-23 | 2008-11-27 | Korea Institute Of Science And Technology | Novel 2-imino-1,3-thiazoline-based compounds and t-type calcium channel inhibitors containing the same |
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CN106172431A (en) * | 2016-07-12 | 2016-12-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of Fluxapyroxad-containsterilization and the bactericidal composition of probenazole |
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