CN106900711A - A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and M 9834 - Google Patents
A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and M 9834 Download PDFInfo
- Publication number
- CN106900711A CN106900711A CN201710136255.4A CN201710136255A CN106900711A CN 106900711 A CN106900711 A CN 106900711A CN 201710136255 A CN201710136255 A CN 201710136255A CN 106900711 A CN106900711 A CN 106900711A
- Authority
- CN
- China
- Prior art keywords
- hexanaphthene flusulfamide
- bactericidal composition
- hexanaphthene
- flusulfamide
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
Abstract
The invention discloses a kind of bactericidal composition containing Hexanaphthene flusulfamide and M 9834 and its application.With Hexanaphthene flusulfamide and M 9834 as principle active component, wherein Hexanaphthene flusulfamide and the mass ratio of M 9834 is 1 to the bactericidal composition:50~70:1.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, with synergistic function higher, overcome and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as gray mold, scab, brown spot, sclerotiniose, downy mildew, epidemic disease, effect is better than single dose and uses.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, especially it is a kind of with Hexanaphthene flusulfamide and M 9834 be main
The bactericidal composition of active component and its application.
Background technology
Hexanaphthene flusulfamide molecular formula：C13H13CIF3NO3S.Chemical name：N- (2- trifluoromethyl-4-chlorophenyls)-alpha-oxo
Cyclohexyl sulfonamide.It has stronger prevention, treatment and osmotically active, there is lasting effect higher.Through table of field test results
It is bright effectively to prevent and treat gray mold, sclerotinia rot of colza, Cucumber Target Leaf Spot and scab.
M 9834 (Benalaxyl), molecular formula：C20H28NO3.Chemical name is：N- phenylacetyl groups-N-2,6- dimethylbenzene
Base-DL-Alanine methyl esters.M 9834 is the systemic fungicide for preventing and treating oomycetes diseases.For prevent and treat grape, tobacco, it is melon,
The downy mildew of the crop such as soybean and round onions, the epidemic disease on potato, tomato, grass poison, ornamental plant.
The difficulty of prevention and cure of current phytopathogen is increasing, and main cause has：One is with the change of pattern of farming, melon
The industrial crops cultivated area such as fruits and vegetables progressively expands, and disease occurrence degree, generation quantity increase, difficult in preventing and treating
Degree is increased；Two is current climate exception, and the outburst to disease provides certain condition；Three is the selection of long-term chemical medication
Property influence so that the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality.
In sum, current control of plant disease work faces big challenge emphatically.
The content of the invention
The purpose of the present invention be directed to above-mentioned technical problem provide a kind of applied widely, low cost, effect it is good containing ring
The bactericidal composition of own flusulfamide and M 9834.
It is a still further object of the present invention to provide the bactericidal composition on the fungal disease that preventing and treating plant epiphyte causes
Using the especially purposes on the fungal diseases such as gray mold, scab, brown spot, sclerotiniose, downy mildew, epidemic disease are prevented and treated.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing Hexanaphthene flusulfamide and M 9834, the bactericidal composition is with Hexanaphthene flusulfamide and M 9834
It is principle active component, wherein Hexanaphthene flusulfamide and the mass ratio of M 9834 is 1:50~70:1, wherein have in bactericidal composition
Effect composition is present in composition with enhancing effective amount.
Described bactericidal composition, wherein Hexanaphthene flusulfamide are preferably 50 with the mass ratio of M 9834:1~1:20；Enter one
Step is preferably 50:1~30:1 or 5:1~1:10；Still more preferably it is 1:1~1:7、5:1、30:1, inventor has found, herein
In the range of, not only the bactericidal composition has preferably synergy, and the lasting period is longer.
In bactericidal composition of the present invention, the weight/mass percentage composition that both Hexanaphthene flusulfamide and M 9834 account for composition is
2%~80%.It is preferred that 10%~70%, more preferably 10%~40%.
Described bactericidal composition, wherein with Hexanaphthene flusulfamide and M 9834 as principle active component and known auxiliary agent and
Excipient is re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, disappear
Infusion, wetting agent, disintegrant etc., can use calcium dodecyl benzene sulfonate, APES, benzyl phenol polyethenoxy
Ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Warm series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more combinations in lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc., excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other
Auxiliary material can be with alone or be used in combination.
Described bactericidal composition, its formulation is that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the described bactericidal composition on preventing and treating fungal diseases of plants medicine, especially in preventing and treating Cereal, fruit
Application in terms of tree, vegetable crop disease.
Described fungal diseases of plants is gray mold, scab, brown spot, sclerotiniose, downy mildew, epidemic disease etc..
Beneficial effects of the present invention：
1st, the Hexanaphthene flusulfamide used by the present invention is different with the M 9834 mechanism of action, mutual mixture will not produce it is low tactile, can
Synergistic, reduces dosage, reduces cost.
2nd, the present composition scope of application increases, it is adaptable to prevent and treat the fungal disease of Cereal, fruit tree, vegetables, special
It is not that application on gray mold, scab, brown spot, sclerotiniose, downy mildew, epidemic disease etc. is prevented and treated has significant effect.This
Invention bactericidal composition has good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And suppress
The drug-fast generation of insect or fungi to unitary agent (Hexanaphthene flusulfamide and M 9834 are any).Bactericidal composition of the invention
Synergistic function higher, and the consumption of the amount ratio independent reactive compound of the mixture can be produced to substantially reduce, i.e.,
Activity of the activity of mixture more than independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as gray mold, scab, brown spot, sclerotiniose, downy mildew, epidemic disease have obvious synergistic function, overcome and prolong
Delay the resistance to the action of a drug, expand preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) it is alternative normal
Advise and be also easy to produce the agricultural chemicals of resistance；(4) compared with single dose, production and use cost are reduced；(5) the drug-fast product of fungi is suppressed
Raw, its effect is used apparently higher than its single dose.
Specific embodiment
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds with specific embodiment below
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Embodiment 1：15% Hexanaphthene flusulfamide M 9834 wettable powder (1:2)
By Hexanaphthene flusulfamide 5g, M 9834 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, are obtained effective
Ingredient percent is 15% Hexanaphthene flusulfamide M 9834 wettable powder.
Embodiment 2：15% Hexanaphthene flusulfamide M 9834 wettable powder (1:4)
By Hexanaphthene flusulfamide 3g, M 9834 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is obtained for 15% Hexanaphthene flusulfamide M 9834 can
WP.
Embodiment 3：16% Hexanaphthene flusulfamide M 9834 wettable powder (1:7)
By Hexanaphthene flusulfamide 2g, M 9834 14g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g mixtures and carries out air-flow crushing, and active ingredient mass percent is obtained for 16% Hexanaphthene flusulfamide M 9834 can
WP.
Embodiment 4：20% Hexanaphthene flusulfamide M 9834 suspending agent (1:1)
10g Hexanaphthene flusulfamides, 10g M 9834s, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the effect of sand mill with water
Under be made effective Ingredient percent for 20% Hexanaphthene flusulfamide M 9834 suspending agent.
Embodiment 5：55% Hexanaphthene flusulfamide M 9834 aqueous emulsion (1:10)
Weigh 5g Hexanaphthene flusulfamides, 50g M 9834s, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing
Kettle high speed mixes, and is made effective Ingredient percent for 55% Hexanaphthene flusulfamide M 9834 aqueous emulsion.
Embodiment 6：42% Hexanaphthene flusulfamide M 9834 missible oil (1:20)
Weigh 2g Hexanaphthene flusulfamides, 40g M 9834s, it is calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 42% Hexanaphthene flusulfamide M 9834 missible oil.
Embodiment 7：70% Hexanaphthene flusulfamide M 9834 missible oil (2.5:1)
Weigh 50g Hexanaphthene flusulfamides, 20g M 9834s, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, solvent naphtha are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared missible oil
Close, be made effective Ingredient percent for 70% Hexanaphthene flusulfamide M 9834 missible oil.
Embodiment 8：18% Hexanaphthene flusulfamide M 9834 water dispersion granule (5：1)
15g Hexanaphthene flusulfamides, 3g M 9834s are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and above raw material is formed with by water dispersible granular agent method to imitate composition
Mass percent is 18% Hexanaphthene flusulfamide M 9834 water dispersion granule.
Embodiment 9：11% Hexanaphthene flusulfamide M 9834 missible oil (10:1)
Weigh 10g Hexanaphthene flusulfamides, 1g M 9834s, it is calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 11% Hexanaphthene flusulfamide M 9834 missible oil.
Embodiment 10：31.5% Hexanaphthene flusulfamide M 9834 microemulsion (20:1)
Weigh 30g Hexanaphthene flusulfamides, 1.5g M 9834s, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mix in the method input mixing kettle of microemulsion, be made effective Ingredient percent for 31.5% Hexanaphthene flusulfamide M 9834
Microemulsion.
Embodiment 11：31% Hexanaphthene flusulfamide M 9834 missible oil (30:1)
Weigh 30g Hexanaphthene flusulfamides, 1g M 9834s, it is calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, molten
Agent is oily to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, be made effective composition quality hundred
Divide than being 31% Hexanaphthene flusulfamide M 9834 missible oil.
Embodiment 12：51% Hexanaphthene flusulfamide M 9834 suspending agent (50:1)
50g Hexanaphthene flusulfamides, 1g M 9834s, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 51% Hexanaphthene flusulfamide M 9834 suspending agent.
Embodiment 13：32% Hexanaphthene flusulfamide M 9834 microemulsion (1:15)
Weigh 2g Hexanaphthene flusulfamides, 30g M 9834s, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared micro-
Mix in the method input mixing kettle of emulsion, be made effective Ingredient percent for 32% Hexanaphthene flusulfamide M 9834 micro emulsion
Agent.
Embodiment 14：6% Hexanaphthene flusulfamide M 9834 aqueous emulsion (1:5)
Weigh 1g Hexanaphthene flusulfamides, 5g M 9834s, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
APEO 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is put into mixing kettle
High speed mixes, and is made effective Ingredient percent for 6% Hexanaphthene flusulfamide M 9834 aqueous emulsion.
Embodiment 15：62% Hexanaphthene flusulfamide M 9834 microemulsion (1:30)
Weigh 2g Hexanaphthene flusulfamides, 60g M 9834s, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared micro-
Mix in the method input mixing kettle of emulsion, be made effective Ingredient percent for 62% Hexanaphthene flusulfamide M 9834 micro emulsion
Agent.
Embodiment 16：51% Hexanaphthene flusulfamide M 9834 suspending agent (1:50)
1g Hexanaphthene flusulfamides, 50g M 9834s, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 51% Hexanaphthene flusulfamide M 9834 suspending agent.
Embodiment 17：7% Hexanaphthene flusulfamide M 9834 water dispersion granule (1：2.5)
Weigh 2g Hexanaphthene flusulfamides, 5g M 9834s, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with into effect by water dispersible granular agent method
Ingredient percent is 7% Hexanaphthene flusulfamide M 9834 water dispersion granule.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, determines EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows：
A certain single dose (generally selects EC as standard agent with mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The virulence of the toxicity index of theoretical toxicity index (TTI)=A single doses × A single doses proportion+B single doses in mixture
Index × B single doses proportion in mixture
The EC of actual measurement toxicity index (ATI)=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC exists
It is summation action between 80-120.
According to active ingredient Hexanaphthene flusulfamide (A)：M 9834 (B) quality proportioning is：70：1、50：1、30：1、20：1、10：
1、5：1、2.5：1、1：1、1：2、1：4、1：7、1：10、1：20、1：30、1：50 are tested, and determine it to grape grey mould
Co-toxicity coefficient.
Table 1：Indoor biometricses result of the Hexanaphthene flusulfamide+M 9834 different ratio to grape grey mould
| Medicament | Virulence regression equation | EC50(mg/L) | ATI | TTI | Co-toxicity coefficient |
| Hexanaphthene flusulfamide | Y=2.2258X+3.7475 | 3.6535 | 100.00 | - | - |
| M 9834 | Y=2.0923X+3.3574 | 6.0963 | 59.9298 | - | - |
| A:B=70:1 | Y=2.6393X+3.8944 | 2.6235 | 139.260 | 99.436 | 140.05 |
| A:B=50:1 | Y=2.0142X+4.2982 | 2.2306 | 163.793 | 99.214 | 165.09 |
| A:B=30:1 | Y=2.3359X+4.2616 | 2.0706 | 176.449 | 98.707 | 178.76 |
| A:B=20:1 | Y=2.8755X+3.9206 | 2.3734 | 153.936 | 98.092 | 156.93 |
| A:B=10:1 | Y=1.1974X+4.5451 | 2.3985 | 152.322 | 96.357 | 158.08 |
| A:B=5:1 | Y=2.3696X+4.2754 | 2.0221 | 180.680 | 93.322 | 193.61 |
| A:B=2.5:1 | Y=3.0231X+3.8279 | 2.4419 | 149.616 | 88.551 | 168.96 |
| A:B=1:1 | Y=2.0587X+4.1597 | 2.5597 | 142.729 | 79.965 | 178.49 |
| A:B=1:2 | Y=2.4747X+3.9625 | 2.6256 | 139.149 | 73.287 | 189.87 |
| A:B=1:4 | Y=1.6395X+4.2961 | 2.6875 | 135.942 | 67.944 | 200.08 |
| A:B=1:7 | Y=2.0985X+3.9531 | 3.1543 | 115.824 | 64.939 | 178.36 |
| A:B=1:10 | Y=2.1654X+3.8537 | 3.3836 | 107.978 | 63.573 | 169.85 |
| A:B=1:20 | Y=2.8745X+3.2890 | 3.9377 | 92.782 | 61.838 | 150.04 |
| A:B=1:30 | Y=2.0636X+3.7016 | 4.2580 | 85.803 | 61.222 | 140.15 |
| A:B=1:50 | Y=2.7968X+3.1994 | 4.4035 | 82.968 | 60.715 | 136.65 |
Field control effectiveness test：
Grape grey mould is prevented and treated with pesticidal preparations obtained in following examples to test.
1st, test process：This test medicine consumption sets two concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is respectively the M 9834 WP of agricultural chemicals single dose 25% and 50% Hexanaphthene flusulfamide WP and blank clean water experiment.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates preventive effect.
Result of the test is shown in Table 2：
The field efficacy experiment of table 2
Shown by indoor biometricses and field efficacy result, Hexanaphthene flusulfamide and M 9834 composition have and significantly cooperate with
Synergistic effect, the prevention effect of composition is excellent, and prevention effect is better than single dose kind, and preventive effect phase is long, in agricultural application
With application value.
Claims (9)
1. a kind of bactericidal composition containing Hexanaphthene flusulfamide and M 9834, it is characterised in that the bactericidal composition is with Hexanaphthene flusulfamide
It is active principle with M 9834, wherein Hexanaphthene flusulfamide and the mass ratio of M 9834 is 1:50~70:1.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the Hexanaphthene flusulfamide and M 9834
It is 50:1~1:20.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the Hexanaphthene flusulfamide and M 9834
It is 50:1~30:1 or 5:1~1:10.
4. bactericidal composition according to claim 1, it is characterised in that both described Hexanaphthene flusulfamide and M 9834 are accounted for
The weight/mass percentage composition of composition is 2% ~ 80%.
5. bactericidal composition according to claim 4, it is characterised in that both described Hexanaphthene flusulfamide and M 9834 are accounted for
The weight/mass percentage composition of composition is 10% ~ 70%.
6. bactericidal composition according to claim 1, it is characterised in that with Hexanaphthene flusulfamide and M 9834 as it is main effectively
Composition and insecticides adjuvant, excipients are configured to any one formulation allowed on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder, microemulsion or water dispersion granule.
8. application of the bactericidal composition described in claim 1 on preventing and treating fungal diseases of plants medicine is prepared.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is gray mold, scab, brown
At least one in pinta, sclerotiniose, downy mildew, epidemic disease.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710136255.4A CN106900711A (en) | 2017-03-08 | 2017-03-08 | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and M 9834 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710136255.4A CN106900711A (en) | 2017-03-08 | 2017-03-08 | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and M 9834 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106900711A true CN106900711A (en) | 2017-06-30 |
Family
ID=59186938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710136255.4A Pending CN106900711A (en) | 2017-03-08 | 2017-03-08 | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and M 9834 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106900711A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651467A (en) * | 2012-08-31 | 2014-03-26 | 陕西美邦农药有限公司 | Cyclohexyl flusulfamide-containing bactericidal composition |
-
2017
- 2017-03-08 CN CN201710136255.4A patent/CN106900711A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651467A (en) * | 2012-08-31 | 2014-03-26 | 陕西美邦农药有限公司 | Cyclohexyl flusulfamide-containing bactericidal composition |
Non-Patent Citations (1)
| Title |
|---|
| 盛书祥 等: "苯霜灵与茶皂素对黄瓜灰霉病菌的联合作用研究", 《农药科学与管理》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105941416B (en) | A kind of bactericidal composition and its application of the bacterium amine of pyrrole containing biphenyl and Tebuconazole | |
| CN106472525A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and fludioxonil | |
| CN105994318A (en) | Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite | |
| CN106508943A (en) | Bactericidal composition containing benthiavalicarb-isopropyl and prochloraz, and applications thereof | |
| CN106889074A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fluxapyroxad | |
| CN106922668A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and alkene oxime amine | |
| CN106900711A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and M 9834 | |
| CN105994281A (en) | Antibacterial composition containing C15H8ClF7N2O2 and bupirimate as well as application of antibacterial composition | |
| CN105941407A (en) | {0><}0{>Sterilization composition containing fluoride ether bacteria amide and fludioxonil and application of sterilization composition<0} | |
| CN105831140B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and thiram | |
| CN106900713A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fludioxonil | |
| CN105961400B (en) | A kind of bactericidal composition and its application of Fluxapyroxad-containsterilization and olefin conversion | |
| CN105941403B (en) | A kind of bactericidal composition and its application containing volution bacterium amine and coumoxystrobin | |
| CN106973908A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and mepanipyrim | |
| CN106900716A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fluazinam | |
| CN106889075A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and RH-7592 | |
| CN107079911A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and olefin conversion | |
| CN105994285A (en) | Antibacterial composition containing bixafen and metrafenone as well as application of antibacterial composition | |
| CN106889086A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and thifluzamide | |
| CN106973920A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and fenoxanil | |
| CN106035340A (en) | Spiroxamine and cyprodinil containing fungicidal composition and application thereof | |
| CN105941418A (en) | Sterilization composition containing fluoride ether bacteria amide and tebuconazole and application thereof | |
| CN106922672A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fluopyram | |
| CN107027756A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and fenhexamid | |
| CN106900718A (en) | A kind of bactericidal composition and its application containing Hexanaphthene flusulfamide and pyrrole metsulfovax |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170630 |