CN104982439A - Pesticide combination for preventing and controlling crop powdery mildew - Google Patents
Pesticide combination for preventing and controlling crop powdery mildew Download PDFInfo
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- CN104982439A CN104982439A CN201510402096.9A CN201510402096A CN104982439A CN 104982439 A CN104982439 A CN 104982439A CN 201510402096 A CN201510402096 A CN 201510402096A CN 104982439 A CN104982439 A CN 104982439A
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Abstract
The invention discloses a pesticide combination for preventing and controlling crop powdery mildew. The pesticide combination for preventing and controlling crop powdery mildew consists of an active component a, an active component b and proper pesticide adjuvants, wherein the active component a is fluxapyroxad, the active component b is one of ethirimol and bupirimate; the weight ratio of the active component a to the active component b is 1:10 to 10:1, and the weight percentage of the active component a and the active component b in the combination is 1 to 90 percent. The pesticide combination disclosed by the invention is used for preventing and controlling crop powdery mildew, especially cucumber powdery mildew and grape powdery mildew. The pesticide combination disclosed by the invention has an obvious synergistic effect, the aspects of fast-acting property and long-lasting property are superior to that of a single dose, the use amount of pesticide is reduced, the pesticide cost is reduced and the environmental protection is facilitated.
Description
Technical field
The present invention relates to a kind of composition pesticide for preventing and treating crop powdery mildew, is with fluorine azoles bacterium acid amides and the phonetic phenol of second (or bupirimate) for active ingredient, for preventing and treating cucumber, grape powdery mildew.
Background technology
The resistance problem of agricultural disease is a global problem, is the emphasis problem that agricultural science and technology worker pays close attention to always.Along with the continuity year in year out of disease chemical control, the increase of Pesticide use amount and not scientifical use agricultural chemicals, germ resistance is day by day serious, and the germ kind producing resistance is on the increase.Meanwhile, the use agricultural chemicals of high strength, causes Practice for Pesticide Residue in Agricultural Products to exceed standard, environmental pollution and the increase of peasant's drug cost etc., is unfavorable for agricultural sustainable development.Therefore, the bactericide agricultural chemicals of efficient, the low toxicity of research and development, environmental protection has positive effect to agricultural sustainable development.
Fluorine azoles bacterium acid amides; English name: fluxapyroxad; it is acid amide fungicides; mainly through suppressing mitochondrial succinate acid esters dehydrase, hindering tricarbonic acid cycle, making amino acid, sugar lacks, energy reduces; the division of interference cell and growth; there is protection and therapeutic action, efficient to the gray mold of gourd, fruit and vegetable class crop, powdery mildew, also there is greater activity to fruit tree anthracnose.
The phonetic phenol of second, English name: ethirimol is miazines bactericide, mainly suppress adenosine deaminase, have extremely strong killing effect to mycelium, conidium, trichogyne etc., and the powerful formation suppressing spore of energy, block spore and infect source again, bactericidal effect is comprehensively thorough.For the crop fallen ill, the phonetic phenol of second can play therapeutic action well, can root out the germ in invaded plants body, obviously can suppress the expansion of germ, efficient to crop powdery mildews such as melon, grapes.
Bupirimate, English name: bupirimate, bupirimate is the form that the phonetic phenol of second exists with ester class, and the phonetic phenol of specific activity second is higher.
The mixture of different pesticide species is the common methods of control agricultural pest.Being screened by formulation of pesticide, filter out rational formula, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the drug-fast generation of damage by disease and insect, is the important means that agricultural synthesis is administered.The recipe determination of the present inventor to fluorine azoles bacterium acid amides and miazines conducts in-depth research, and finds that fluorine azoles bacterium acid amides and miazines carry out mixture and have obvious synergistic effect in certain mixed ratio scope to multiple fungi, after further study, completes the present invention.
Composition and the application of fluorine azoles bacterium acid amides and miazines there is no report at present.
Summary of the invention
The object of the present invention is to provide a kind of efficient, low toxicity, low cost, quick-acting are good, the lasting period is long, to crop safety, environment amenable composition pesticide.
The present inventor, by a large amount of indoor bioassay test and field medicine effect test, finds fluorine azoles bacterium acid amides and the phonetic phenol of second or bupirimate, in certain proportion after mixture, has significant synergistic effect to cucumber, grape powdery mildew.
On the basis of above-mentioned discovery, after further study, technical scheme of the present invention is defined:
For preventing and treating a composition pesticide for crop powdery mildew, be made up of active ingredient a and active ingredient b and suitable insecticides adjuvant, wherein active ingredient a is fluorine azoles bacterium acid amides, and active ingredient b is selected from the one in the phonetic phenol of second or bupirimate; The weight ratio of active ingredient a and active ingredient b be 1:10 ~ 10:1, active ingredient a and active ingredient b weight summation in the composition percentage by weight be 1% ~ 90%.
Composition pesticide of the present invention according to well known to a person skilled in the art method, can be processed into the application forms of the applicable agricultural uses such as aqueous emulsion, microemulsion, suspending agent, wetting powder, water dispersible granules.
Composition pesticide of the present invention is also containing the insecticides adjuvant of preparation needed for pesticidal preparations, comprise one or more mixing in emulsifier, wetting agent, stabilizing agent, dispersant, thickener, defoamer, antifreezing agent, disintegrant, binding agent, pH adjusting agent, the agent of transparency temperature range regulation, filler, filler, carrier, medium etc., be known substance, various auxiliary agents conventional in pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
Composition pesticide of the present invention, is applicable to control cucumber, grape powdery mildew.
Composition pesticide described in the invention, can finished product preparation form provide, namely in composition, each material mixes, and the composition of composition also can provide by unit dose form, directly mixes in bucket or tank, be then diluted to desired concn before using.
Composition pesticide provided by the invention, usually adopts spray method to use, also can adopt other operation techniques agriculturally applied as required.
Composition pesticide provided by the invention has following beneficial effect:
1, composition pesticide provided by the invention, obvious synergy or summation action is shown in certain ratio range, the control efficiency of composition to germ is significantly improved than single dose, reduce the using dosage of agricultural chemicals, decrease times for spraying, reduce drug cost, decrease the adverse effect of agricultural chemicals to ecotope.
2, composition pesticide provided by the invention, two kinds of effective ingredient mechanism of action are not quite identical, can overcome the shortcoming that long-term single use easily produces resistance, extend the service life of medicament, to the comprehensive regulation important in inhibiting of germ resistance.
3, composition pesticide provided by the invention, drug effect plays rapidly, and the lasting period is long, and use cost is low, easy to use, time saving and energy saving, and it applies huge economic benefit and social benefit.
Embodiment
In order to make object of the present invention, technical scheme and advantage more short and sweet, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these embodiments.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
The phonetic phenol suspending agent of embodiment 1:18% fluorine azoles bacterium acid amides second.
2% fluorine azoles bacterium acid amides 1%, the phonetic phenol of 16% second, polycarboxylate 4% (dispersant), Nongru-700 #5% (emulsifier), lauryl sodium sulfate 2% (wetting agent), xanthans 0.5% (thickener), organosilicon 0.5% (defoamer), urea 1% (antifreeze), deionized water complements to 100%.Above-mentioned formula is pulverized in proportion in advance, then adds in sand mill and grind, the obtained phonetic phenol suspending agent of 18% fluorine azoles bacterium acid amides second of allotment after high shear mixing.
Embodiment 2:21% fluorine azoles bacterium acid amides bupirimate aqueous emulsion.
3% fluorine azoles bacterium acid amides, 18% bupirimate, 1-METHYLPYRROLIDONE (solvent) 10%, naphthalene (bleeding agent) 2%, calcium dodecyl benzene sulfonate (emulsifier) 6%, agriculture breast 600# phosphate (emulsifier) 5%, organosilicon (defoamer) 3%, xanthans (stabilizing agent) 0.5%, deionized water complements to 100%.By above-mentioned fluorine azoles bacterium acid amides, solvent, bleeding agent, emulsifier, defoamer, stabilizing agent Homogeneous phase mixing, dissolve obtained oil phase; By bupirimate and the obtained aqueous phase of deionized water mixing; Under high velocity agitation, by oil phase and aqueous phase mixing, obtained 21% fluorine azoles bacterium acid amides bupirimate aqueous emulsion.
The phonetic phenol microemulsion of embodiment 3:21% fluorine azoles bacterium acid amides second.
3% fluorine azoles bacterium acid amides, the phonetic phenol of 18% second, 5% ethyl acetate, 6% diethyl phthalate, enters compounding kettle after abundant mixed dissolution, 1% alkylphenol polyoxyethylene is added again to compounding kettle, 4% polyol fatty acid ester and ethylene oxide adduct thereof, 3% disecoctylmaleate sodium sulfonate, 1.5% antioxidant 264, after abundant stirring and dissolving, deionized water complements to 100%.Continue to be stirred to transparent, the obtained phonetic phenol microemulsion of 21% fluorine azoles bacterium acid amides second.
Embodiment 4:24% fluorine azoles bacterium acid amides bupirimate wetting powder.
Fluorine azoles bacterium acid amides 4%, bupirimate 20%, pulls open powder 3% (wetting agent), naphthalenesulfonate formaldehyde condensation compound 6% (dispersant), talcum powder 15% (filler), and surplus is filler kaolin.Mix entering in blender after above-mentioned formula in proportion coarse crushing, more namely obtain 24% fluorine azoles bacterium acid amides bupirimate wetting powder after air-flow crushing.
Embodiment 5:40% fluorine azoles bacterium acid amides ethirimol water dispersible granules.
Fluorine azoles bacterium acid amides 4%, the phonetic phenol 36% of second, sodium lignin sulfonate 5% (dispersant), polycarboxylic acid salt 3% (dispersant), lauryl sodium sulfate 2% (wetting agent), urea 10% (disintegrant), corn starch 3% (binding agent), filler kaolin to 100%.By above-mentioned formula dry pulverization process, granulation, drying, the obtained 40% fluorine azoles bacterium acid amides ethirimol water dispersible granules of screening preparation in proportion.
Embodiment 6: Toxicity Determination is tested.
Test adopts field Cucumis sativus stem leaf spray-on process dispenser (having water membrane to be advisable with blade surface), spraying process is carried out on February 25th, 2015, chemical sprayer tool adopts manual sprayer (liquid capacity is about 2.0L), every 10 days spray medicines once, and continuous spraying 2 times.Often process selects climing 20 blades of uniform melon of falling ill as efficacy of medicine observing object, and each process repeats for 3 times.Grape powdery mildew test method is consistent with powdery mildew of cucumber test method.
Investigation method:
0 grade: without scab;
1 grade: lesion area accounts for less than 5% of whole leaf area;
3 grades: lesion area accounts for the 6%-15% of whole leaf area;
5 grades: lesion area accounts for the 16%-25% of whole leaf area;
7 grades: lesion area accounts for the 26%-50% of whole leaf area;
9 grades: lesion area accounts for more than 50% of whole leaf area.
According to survey data, calculate disease index and the control efficiency of each process.
Disease index presses formulae discovery, and result of calculation retains 2 significant digits:
When carrying out drug combination toxicity test, this test adopts Wadley method to calculate the coefficient of synergism (SR) of mixture, evaluates the synergy type of mixture.
Wadley method: the synergistic effect evaluating pharmacy mix according to coefficient of synergism (SR), namely SR<0.5 is antagonism, and 0.5≤SR≤1.5 are summation action, and SR>1.5 is synergistic function.Coefficient of synergism (SR) calculates by formula (1), (2):
In formula:
X1: mixture EC
50theoretical value, unit is milligrams per liter (mg/L);
P
a: the percentage composition of A in mixture, unit is percentage (%);
P
b: the percentage composition of B in mixture, unit is percentage (%);
A: the EC of A in mixture
50value, unit is milligrams per liter (mg/L);
B: the EC of B in mixture
50value, unit is milligrams per liter (mg/L).
In formula:
SR: the coefficient of synergism of mixture;
X1: the EC of mixture
50theoretical value, unit is milligrams per liter (mg/L);
X2: the EC of mixture
50measured value, unit is milligrams per liter (mg/L).
Table 1, fluorine azoles bacterium acid amides and the phonetic phenol of second are to the synergy result of powdery mildew of cucumber
Table 2, fluorine azoles bacterium acid amides and bupirimate are to the synergy result of powdery mildew of cucumber
Table 3, fluorine azoles bacterium acid amides and the phonetic phenol of second are to the synergy result of grape powdery mildew
Table 4, fluorine azoles bacterium acid amides and bupirimate are to the synergy result of grape powdery mildew
As can be seen from table 1,2,3 and 4, fluorine azoles bacterium acid amides and the phonetic phenol of second (or bupirimate) weight ratio composite in the scope of 1:10-10:1, synergistic effect is shown as to cucumber and grape powdery mildew.
Embodiment 6: prevent and treat powdery mildew of cucumber field trial.
Test site is positioned at Ma An town, Huizhou, adopts spray-on process.Adopt 25% fluorine azoles bacterium amide suspending agents, the phonetic phenol suspending agent of 25% second, 25% bupirimate microemulsion medicament in contrast, 13 chemicals treatment are established in test altogether, each process repeats for 4 times, the sick number of sheets of cucumber is investigated before dispenser, within after dispenser 3 days, 7 days, respectively investigate a control efficiency, record the disease number of sheets, calculate control efficiency, result of the test is as shown in table 5.
The combination of table 5, fluorine azoles bacterium acid amides and miazines prevents and treats powdery mildew of cucumber result of the test
As can be seen from Table 5, the effect that composition pesticide of the present invention prevents and treats powdery mildew of cucumber is better than the process of each contrast single dose.Fluorine azoles bacterium acid amides is described and miazines is composite can improve control efficiency, reduces the using dosage of agricultural chemicals, decrease the impact of agricultural chemicals on environment, reduce drug cost.
Embodiment 7: grape powdery mildew field trial.
Test site is positioned at Huarong County, Hunan Yueyang, adopts spray-on process.Adopt 25% fluorine azoles bacterium amide suspending agents, the phonetic phenol suspending agent of 25% second, 25% bupirimate microemulsion medicament in contrast, 13 chemicals treatment are established in test altogether, each process repeats for 4 times, the sick number of sheets of grape is investigated before dispenser, within after dispenser 3 days, 7 days, respectively investigate a control efficiency, record the disease number of sheets, calculate control efficiency, result of the test is as shown in table 2.
Table 6, fluorine azoles bacterium acid amides and miazines combination control grape powdery mildew result of the test
As can be seen from Table 6, the effect of composition pesticide control grape powdery mildew of the present invention is better than the process of each contrast single dose.Fluorine azoles bacterium acid amides is described and miazines is composite can improve control efficiency, reduces the using dosage of agricultural chemicals, decrease the impact of agricultural chemicals on environment, reduce drug cost.
Claims (4)
1. for preventing and treating a composition pesticide for crop powdery mildew, it is characterized in that: be made up of active ingredient a and active ingredient b and insecticides adjuvant, wherein active ingredient a is fluorine azoles bacterium acid amides, and active ingredient b is selected from the one in the phonetic phenol of second or bupirimate; The weight ratio of active ingredient a and active ingredient b be 1:10 ~ 10:1, active ingredient a and active ingredient b weight summation in the composition percentage by weight be 1% ~ 90%.
2. a kind of composition pesticide for preventing and treating crop powdery mildew according to claim 1, is characterized in that: its formulation is the one in aqueous emulsion, microemulsion, suspending agent, wetting powder, water dispersible granules.
3. the application of a kind of composition pesticide for preventing and treating crop powdery mildew according to claim 1 on control crop powdery mildew.
4. a kind of composition pesticide for preventing and treating crop powdery mildew according to claim 3, is characterized in that: described crops are cucumber, grape.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105831124A (en) * | 2016-04-26 | 2016-08-10 | 南京华洲药业有限公司 | Bactericidal composition containing fluxapyroxad and ethirimol and application thereof |
CN114711240A (en) * | 2022-02-19 | 2022-07-08 | 青岛滕润翔检测评价有限公司 | Bactericidal composition containing indoxacarb and application thereof |
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CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
CN103347389A (en) * | 2010-12-09 | 2013-10-09 | 拜耳知识产权有限责任公司 | Pesticidal mixtures with improved properties |
CN105265443A (en) * | 2014-05-27 | 2016-01-27 | 深圳诺普信农化股份有限公司 | Bactericidal composition containing fluxapyroxad |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
CN103347389A (en) * | 2010-12-09 | 2013-10-09 | 拜耳知识产权有限责任公司 | Pesticidal mixtures with improved properties |
CN105265443A (en) * | 2014-05-27 | 2016-01-27 | 深圳诺普信农化股份有限公司 | Bactericidal composition containing fluxapyroxad |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105831124A (en) * | 2016-04-26 | 2016-08-10 | 南京华洲药业有限公司 | Bactericidal composition containing fluxapyroxad and ethirimol and application thereof |
CN114711240A (en) * | 2022-02-19 | 2022-07-08 | 青岛滕润翔检测评价有限公司 | Bactericidal composition containing indoxacarb and application thereof |
CN114711240B (en) * | 2022-02-19 | 2024-03-15 | 青岛滕润翔检测评价有限公司 | Sterilization composition containing penoxsulam and application thereof |
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Application publication date: 20151021 |