CN104604883A - Sterilizing composition containing fluxapyroxad and ipconazole as well as application of sterilizing composition - Google Patents
Sterilizing composition containing fluxapyroxad and ipconazole as well as application of sterilizing composition Download PDFInfo
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- CN104604883A CN104604883A CN201510031122.1A CN201510031122A CN104604883A CN 104604883 A CN104604883 A CN 104604883A CN 201510031122 A CN201510031122 A CN 201510031122A CN 104604883 A CN104604883 A CN 104604883A
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- azoles
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- acid amides
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Abstract
The invention discloses sterilizing composition containing fluxapyroxad and ipconazole. The sterilizing composition comprises active components which include fluxapyroxad and ipconazole, wherein the weight ratio of fluxapyroxad to ipconazole ranges from 1:8 to 80:1. The pesticide composition is good in sterilizing effect and remarkable in synergistic effect, and can increase the yield of crops and reduce the labor cost of farmers. The pesticide composition can be used for various crops such as wheat, barley, oats, rye, triticale, corns, vegetables, fruits, lawn, soybeans, cotton and sunflowers.
Description
Technical field
The present invention relates to a kind of fluorine azoles bacterium acid amides and bactericidal composition of planting bacterium azoles and uses thereof, belong to the composition pesticide that technical field of pesticide has synergistic effect, its active component is fluorine azoles bacterium acid amides and plants bacterium azoles.
Background technology
Fluorine azoles bacterium acid amides, english common name: fluxapyroxad, molecular formula: C
18h
12f
5n
3o, chemical name: 3-(difluoro)-1-methyl-N-(3', 4', 5'-trifluoro [1,1'-biphenyl]-2-base)-1-H-pyrazoles-4-acid amides, CAS:907204-31-3.Fluorine azoles bacterium acid amides hinders fungus grown by suppressing succinate dehydrogenase effect.Can be used for foliage-spray and the seed treatment of the various crop such as cereal (wheat, barley, oat, rye, triticale), veterinary antibiotics, lawn, have stronger control efficiency to fungus-caused diseases such as Septoria, Botrytis, powdery mildew, Cercospora, handle rest fungus, rhizoctonia and chamber Pseudomonas.
Plant bacterium azoles, english common name: Ipconazole, molecular formula: C
18h
24clN
3o; chemical name: 2-((4-chlorobenzyl) methyl-5-(1-isopropyl)-1-(1H-1; 2; 4-triazole-1-methyl) cyclopentanol; CAS:125225-28-7, has systemic activity, protection and therapeutic activity, can effectively prevent and treat disease caused by sac fungi, basidiomycetes and imperfect fungus; conducted to cauline leaf by root by seed treatment, have good preventive effect to head blight, leaf spot, fusarium wilt.
In the process of growth of crops, inevitably there will be some diseases, if control can have a strong impact on the output of crop not in time, but use these diseases of same pesticide-treated frequently, these germs can develop immunity to drugs, and for addressing this problem, are undertaken composite by the agricultural chemicals of different activities composition, the generation of energy effectively preventing resistance germ, the agricultural chemicals of different activities composition carries out the composite effect can also playing synergy.Inventor is found by test; fluorine azoles bacterium acid amides different for the mechanism of action is composite with kind bacterium azoles; it is unexpected that discovery said composition have synergistic effect significantly; the control efficiency for the treatment of, protection can be improved significantly; decrease usage amount and the spraying times of agricultural chemicals simultaneously; effectively slow down the generation of resistance, reduce cost accounting.
Summary of the invention
The object of the present invention is to provide that a kind of mixture is reasonable, control efficiency is good, not easily produce the low fluorine azoles bacterium acid amides of resistance, drug cost and the bactericidal composition, preparation and uses thereof of planting bacterium azoles.Another object of the present invention is to provide above-mentioned composition pesticide preventing and treating the diseases such as powdery mildew, banded sclerotial blight, downy mildew, scab, spot defoliation, leaf spot, anthracnose.
For achieving the above object, technical scheme of the present invention is:
A bactericidal composition for fluorine azoles bacterium acid amides and kind bacterium azoles, comprises active component, and wherein said active component comprises fluorine azoles bacterium acid amides and plants bacterium azoles, and the weight ratio of described fluorine azoles bacterium acid amides and kind bacterium azoles is 1:80 ~ 80:1.
The weight ratio of described fluorine azoles bacterium acid amides and kind bacterium azoles is 1:40 ~ 40:1.
The composition pesticide preparation that auxiliary agent is made into any formulation agriculturally allowed is added in described bactericidal composition.
Auxiliary agent in composition pesticide preparation of the present invention includes but not limited to one or more the mixture in emulsifier, solvent, dispersant, film forming agent, thickener, stabilizing agent, defoamer, preservative, antifreezing agent, filler, disintegrant, warning colouration.
Described emulsifier, can make immiscible two-phase liquid form the auxiliary agent of opaque or translucent missible oil liquid, as sulfated castor oil, turkey red oil, polyoxyethylene alkyl amine, aralkyl phenol polyethenoxy ether formaldehyde condensation products, sucrose fatty ester; In pesticidal preparations of the present invention, emulsifier adopts one or more the mixture in agriculture breast 500#, 602#, 700-2#, 700#, 400#, styrene polyoxyethylene ether ammonium sulfate salt, and mentioned emulsifier is purchased from Jiangsu Hai'an Petrochemical Plant.
Described solvent is solvent conventional on market, and pesticidal preparations of the present invention adopts one or more the mixture in toluene, dimethylbenzene, methyl alcohol, ethanol, n-butanol, acetone, cyclohexanone, dimethyl formamide, benzinum.Above-mentioned solvent is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Pesticide dispersion can be become colloid granule by described dispersant, promote wetting and dispersing between active ingredients particles, in pesticidal preparations of the present invention, dispersant of the present invention adopts one or more mixtures in polyacrylic acid, polycarboxylate, phosphoric acid ester, neopelex, aryl alkyl APEO, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, lauryl sodium sulfate and lignin sodium iodate.Above-mentioned dispersant is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Described film forming agent is Customary film formers on market, and as preferably, in pesticidal preparations of the present invention, film forming agent adopts the one or more kinds of mixtures in starch, polyvinyl alcohol, gum Arabic, polyvinyl acetate, xanthans and gelatin.Above-mentioned film forming agent is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Described thickener is used for improving the viscosity of dispersion medium, reduces the settling velocity of particle, and improve the stability of preparation, in pesticidal preparations of the present invention, thickener is Magnesiumaluminumsilicate or xanthans.Above-mentioned thickener is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Described stabilizing agent can prevent preparation physical property from degenerating in storage, and in pesticidal preparations of the present invention, stabilizing agent adopts one or more the mixture in bentonite, Sodium Benzoate, linseed oil, benzenediol, borax, ethylene glycol amine, monoethanolamine, triethanolamine, oleic acid triethanolamine.Aforementioned stable agent is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Described defoamer is defoamer conventional on market, and in pesticidal preparations of the present invention, defoamer adopts one or more the mixture in alcohols (methyl alcohol, ethanol etc.), fatty acid (caproic acid, sad, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid etc.), silicone based (silicone oil, silicon rubber, silicones and silane coupler etc.), polyethers (PPG, oxirane, expoxy propane etc.).Above-mentioned defoamer is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Described preservative is preservative conventional on market, and in pesticidal preparations of the present invention, preservative adopts one or more the mixture in formaldehyde, Sodium Benzoate, phenmethylol, sorbierite.Foregoing preservatives is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Described antifreezing agent is antifreezing agent conventional on market, and in pesticidal preparations of the present invention, antifreezing agent adopts one or more the mixture in glycerine, ethylene glycol.Above-mentioned antifreezing agent is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Described filler adopts one or more the mixture in kaolin, diatomite, bentonite, white carbon, starch, precipitated calcium carbonate.Above-mentioned filler is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Described disintegrant can accelerate particle disintegration in water of water dispersible granules, and in pesticidal preparations of the present invention, disintegrant adopts one or more the mixture in sodium chloride, sodium sulphate, sodium carboxymethyl starch, ammonium sulfate, urea, polyvinylpyrrolidone, sodium alginate.Above-mentioned disintegrant is purchased from Shanghai Xue Zhuo Fine Chemical Co., Ltd.
Composition pesticide preparation of the present invention utilizes warning colouration that medicament is dyed the pesticidal preparations of shades of colour, and in pesticidal preparations of the present invention, warning colouration adopts bright red, purple, blueness.
Described composition pesticide preparation can be made into the one in suspending agent, wetting powder, water dispersible granules, aqueous emulsion, seed treatment.
In described composition pesticide preparation, the weight percentage of fluorine azoles bacterium acid amides and kind bacterium azoles is 0.1% ~ 90% of described composition pesticide total formulation weight amount.
The weight percentage of described fluorine azoles bacterium acid amides and kind bacterium azoles is 2% ~ 70% of described composition pesticide total formulation weight amount.
A purposes for the bactericidal composition of fluorine azoles bacterium acid amides and kind bacterium azoles, described fluorine-containing azoles bacterium acid amides and kind bacterium azoles bactericidal composition can for preventing and treating the disease on grass family class crop, cotton, peanut, vegetables, soybean and fruit tree.
Described disease is specially powdery mildew, banded sclerotial blight, downy mildew, scab, spot defoliation, leaf spot, anthracnose.
Fluorine azoles bacterium acid amides and the purposes of bactericidal composition of planting bacterium azoles, the composition pesticide preparation that described bactericidal composition or described bactericidal composition are mixed with for seed treatment, by the method treatment of plant propagation material of seed soaking, seed dressing or seed pelleting.
Beneficial effect of the present invention is: 1, composition pesticide broad-spectrum of the present invention, by expanding application target and effect to the combination of fluorine azoles bacterium acid amides and kind bacterium azoles, and there is special interior absorption, there is control efficiency significantly when the cauline leaf of plant is processed.When said composition is used for seed treatment, not only protects seed self, but also protect the infringement from disease before and after seed sprouting, well treatment and protective effect are served to crop.
2, composition pesticide of the present invention shows extraordinary synergistic effect in certain ratio range, improves control germ effect, reduces the usage amount of agricultural chemicals, thus reduce cost, decrease environmental pollution.
3, the mechanism of action due to active component in composition pesticide is different, and its application can delay the resistance development of germ to medicament, helps and extends single dose service life.
Embodiment
Below by specific embodiment, the invention will be further described, but the present invention not limited by following examples, and adding of each component is measured by weight.
Embodiment 1
26% kind of bacterium azoles fluorine azoles bacterium amide suspending agents
A kind bacterium azoles of the present embodiment and the composition pesticide suspending agent of fluorine azoles bacterium acid amides, comprise active component and auxiliary agent, wherein said active component is made up of kind of bacterium azoles and fluorine azoles bacterium acid amides, the percentage by weight of component is: 14% kind of former medicine of bacterium azoles, the former medicine of 12% fluorine azoles bacterium acid amides, 5% lignin sodium iodate, 4% agriculture breast 400#, 3% xanthans, 4% ethylene glycol, all the other water are supplied, join in sand mill and grind, filter and obtain suspending agent.From table 1, the obtained suspending agent indices of embodiment 1 all meets Pesticidal products specification requirement, and properties of product are stablized, suspension is good, fineness is high, heat storage stability and low-temperature stability strong.
The composition pesticide preparation broad-spectrum of the present embodiment, by expanding application target and effect to fluorine azoles bacterium acid amides and the combination of kind bacterium azoles, and having absorption especially, having control efficiency significantly when processing the cauline leaf of plant.
Embodiment 2
28% kind of bacterium azoles fluorine azoles bacterium acid amides wetting powder
A kind bacterium azoles of the present embodiment and the composition pesticide wetting powder of fluorine azoles bacterium acid amides, comprise active component and auxiliary agent, wherein said active component is made up of kind of bacterium azoles and fluorine azoles bacterium acid amides, the percentage by weight of component is: 14% kind of former medicine of bacterium azoles, the former medicine of 14% fluorine azoles bacterium acid amides, 5% aryl alkyl APEO, 3% lauryl sodium sulfate, 6% white carbon, all the other precipitated calcium carbonates are supplied, abundant mixing, after cracker is pulverized, obtain 28% kind of bacterium azoles fluorine azoles bacterium acid amides wetting powder.From table 2, the wetting powder indices that embodiment 2 obtains all meets Pesticidal products specification requirement, and properties of product are stablized, and good dispersion, suspensibility are high, fineness is excellent, water content is low, MEBO ribbon gauze is short.
The composition pesticide preparation broad-spectrum of the present embodiment, by expanding application target and effect to kind of bacterium azoles and the combination of fluorine azoles bacterium acid amides, and having special interior absorption, having control efficiency significantly when processing the cauline leaf of plant.
Embodiment 3
40% kind of bacterium azoles fluorine azoles bacterium acid amides water dispersible granules
A kind bacterium azoles of the present embodiment and the composition pesticide water dispersible granules of fluorine azoles bacterium acid amides; comprise active component and auxiliary agent; wherein said active component is made up of kind of bacterium azoles and fluorine azoles bacterium acid amides; the percentage by weight of component is: 20% kind of former medicine of bacterium azoles, the former medicine of 20% fluorine azoles bacterium acid amides, 8% lignin sodium iodate, 5% methyl naphthalene sulfonate formaldehyde condensate, 5% epoxidized polyether, 12% sodium sulphate, 30% kaolin etc. carry out co-grinding; add water kneading; add in the comminutor that certain specification screen cloth is housed and carry out granulation; drying, screening obtains granular product.From table 3, the water dispersible granules indices that embodiment 3 obtains all meets Pesticidal products specification requirement, and properties of product are stablized, and good dispersion, suspensibility are high, fineness is excellent, water content is low, MEBO ribbon gauze is short.
The composition pesticide preparation broad-spectrum of the present embodiment, by expanding application target and effect to fluorine azoles bacterium acid amides and the combination of kind bacterium azoles, and having absorption especially, having control efficiency significantly when processing the cauline leaf of plant.
Embodiment 4
30% kind of bacterium azoles fluorine azoles bacterium acid amides aqueous emulsion
A kind bacterium azoles of the present embodiment and the composition pesticide aqueous emulsion of fluorine azoles bacterium acid amides, comprise active component and auxiliary agent, wherein said active component is made up of kind of bacterium azoles and fluorine azoles bacterium acid amides, the percentage by weight of component is: 15% kind of former medicine of bacterium azoles, the former medicine of 15% fluorine azoles bacterium acid amides, 5% polyoxyethylene phenethyl phenol ether through reaction oleate, 5% neopelex, 8% cyclohexanone, 5% sorbierite mix, be dissolved into homogeneous oil phase, supply with water under high-speed stirred, form the aqueous emulsion of favorable dispersibility.The aqueous emulsion the key technical indexes of the present embodiment is shown in Table 4.From table 4, the aqueous emulsion indices that embodiment 4 obtains all meets Pesticidal products specification requirement, and properties of product are stablized, and heat storage stability is good, low-temperature stability is good.
The composition pesticide preparation broad-spectrum of the present embodiment, by expanding application target and effect to kind of bacterium azoles and the combination of fluorine azoles bacterium acid amides, and having special interior absorption, having control efficiency significantly when processing the cauline leaf of plant.
Embodiment 5
15% kind of bacterium azoles fluorine azoles bacterium acid amides suspension seed-coating agent
A kind bacterium azoles of the present embodiment and the composition pesticide suspension seed-coating agent of fluorine azoles bacterium acid amides, comprise active component and auxiliary agent, wherein said active component is made up of kind of bacterium azoles and fluorine azoles bacterium acid amides, the percentage by weight of component is: 10% kind of former medicine of bacterium azoles, the former medicine of 5% fluorine azoles bacterium acid amides, 7% agriculture breast 602#, 2% lignin sodium iodate, 3% oleic acid triethanolamine, 2% xanthans, 3% n-octyl alcohol, 3% glycerine, 1% rhodamine toner, add water and supply.After the water first kind of bacterium azoles and fluorine azoles bacterium acid amides being converted 20kg grinds 2h in sand mill, emulsifier, dispersant are added in sand mill and grinds 1.5h, then add film forming agent, stabilizing agent, defoamer and other auxiliary agent grinding 1h, filter and obtain suspension seed-coating agent.From table 5 result, the suspension seed-coating agent indices that embodiment 5 obtains all meets the requirement of suspension seed-coating agent, and properties of product are stablized, less by low temperature effect, and expulsion rate is low.
The composition pesticide preparation broad-spectrum of the present embodiment, by expanding application target and effect to kind of bacterium azoles and the combination of fluorine azoles bacterium acid amides, and having special interior absorption, having control efficiency significantly when processing the cauline leaf of plant.When said composition is used for seed treatment, not only protects seed self, but also protect the infringement from germ before and after seed sprouting, well treatment and protective effect are served to crop; Secondly the composition pesticide of the present embodiment shows extraordinary synergistic effect, improves protection effect, reduces the usage amount of agricultural chemicals, thus reduce cost, decrease environmental pollution.Be that its application can delay the resistance development of disease to medicament because the mechanism of action of active component in composition pesticide is different again, help and extend single dose service life.
Embodiment 6
40% kind of bacterium azoles fluorine azoles bacterium acid amides suspension seed-coating agent
A kind bacterium azoles of the present embodiment and the composition pesticide suspension seed-coating agent of fluorine azoles bacterium acid amides, comprise active component and auxiliary agent, wherein said active component is made up of kind of bacterium azoles and fluorine azoles bacterium acid amides, the percentage by weight of component is: 20% kind of former medicine of bacterium azoles, the former medicine of 20% fluorine azoles bacterium acid amides, 5% agriculture breast 400#, 3% lauryl sodium sulfate, 2% polyvinyl alcohol, 2% silicone oil, 1% Magnesiumaluminumsilicate, 3% glycerine, 1% rhodamine toner, add water and supply.After the water first kind of bacterium azoles and fluorine azoles bacterium acid amides being converted 10kg grinds 2h in sand mill, emulsifier, dispersant are added in sand mill and grinds 0.5h, then add film forming agent, stabilizing agent, defoamer and other auxiliary agent grinding 1h, filter and obtain suspension seed-coating agent.From table 5 result, the suspension seed-coating agent indices that embodiment 6 obtains all meets the requirement of suspension seed-coating agent, and properties of product are stablized, less by low temperature effect, and expulsion rate is low.
The composition pesticide preparation broad-spectrum of the present embodiment, by expanding application target and effect to kind of bacterium azoles and the combination of fluorine azoles bacterium acid amides, and having special interior absorption, having control efficiency significantly when processing the cauline leaf of plant.When said composition is used for seed treatment, not only protects seed self, but also protect the infringement from germ before and after seed sprouting, well treatment and protective effect are served to crop; Secondly the composition pesticide of the present embodiment shows extraordinary synergistic effect, improves protection effect, reduces the usage amount of agricultural chemicals, thus reduce cost, decrease environmental pollution.Be that its application can delay the resistance development of disease to medicament because the mechanism of action of active component in composition pesticide is different again, help and extend single dose service life.
Embodiment 7
The present embodiment is the method adopting Toxicity Determination and field trial to combine.
Toxicity Determination
Kind of bacterium azoles and fluorine azoles bacterium acid amides composite to target fungus Toxicity Determination.
Test medicine provides by Zhejiang Tide Crop Technology Co., Ltd..
Determine after the effective inhibition concentration scope of each medicament through prerun, each medicament establishes 5 to measure process by active component content respectively, if clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt mycelial growth rate method to measure medicament to the virulence of target fungus.Measure colony diameter by right-angled intersection method after 72h, calculate net production, mycelial growth inhibition rate everywhere.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probability value (y), liquor strength (μ g/ml) converts logarithm value (x) to, try to achieve virulence regression equation (y=a+bx) with method of least squares, and calculate the EC of often kind of medicament thus
50value.Calculate two medicament different ratio synergies ratio (SR) according to Wadley method, SR < 0.5 is antagonism, and 0.5≤SR≤1.5 are summation action simultaneously, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively kind of bacterium azoles and fluorine azoles bacterium acid amides ratio shared in the composition:
A is kind of a bacterium azoles.
B is fluorine azoles bacterium acid amides.
Result of the test is as shown in the table:
Toxicity test the results are shown in Table 6, and table 6 is kind of bacterium azoles and the composite toxicity test analysis of results table to wheat powdery mildew of fluorine azoles bacterium acid amides.As shown in Table 6, bacterium azoles, fluorine azoles bacterium acid amides is planted to the EC of wheat powdery mildew
50be respectively 0.36mg/L and 1.27mg/L.Kind bacterium azoles, both fluorine azoles bacterium acid amides mixture within the scope of 60:1 ~ 1:60 all show obvious synergistic effect.Wherein, both mixed synergies within the scope of 30:1 ~ 1:30 are ideal, and within the scope of 10:1 ~ 1:10, mixed synergies is particularly outstanding.
Embodiment 8
Field control effectiveness test
1,25% kind of bacterium azoles fluorine azoles bacterium amide suspending agents control wheat sharp eyespot test of pesticide effectiveness.
Kind bacterium azoles 10%, fluorine azoles bacterium acid amides 15%, polycarboxylate 2%, lignosulfonates 3%, neopelex 3%, polyoxyethylene nonylphenol ether modified phosphate 3%, acetone 3%, xanthans 1%, propane diols 3%, deionized water are supplied, the obtained 25% kind of bacterium azoles fluorine azoles bacterium amide suspending agents of mixing.This proportioning, by 4000 times of dilution sprayings, in their early stage dispenser, adds up control efficiency in after medicine 5 days, 10 days, 15 days; 25% fluorine azoles bacterium amide suspending agents and 28% kind of bacterium azoles pulvis, according to same method, are used by 3500 times and 2000 times of dilutions respectively, and 15 days statistics control efficiency after medicine, concrete control efficiency is in table 7.
2,15% kind of bacterium azoles fluorine azoles bacterium acid amides seed treatment process wheat seed test.
Kind bacterium azoles 5%, fluorine azoles bacterium acid amides 10%, polycarboxylate 3%, lignosulfonates 2%, neopelex 3%, xanthans 3%, polyvinyl acetate 4%, sodium dichlorophenol indophenol 2%, alkyl benzene sulfonate calcium salt 3%, deionized water are supplied, the obtained 15% kind of bacterium azoles fluorine azoles bacterium acid amides seed treatment of mixing.This proportioning presses the seed dressing of 30g/100kg seed, in closed container, seed dressing is mixed 1 minute with seed jolting, then by planting seed to experimental field, and in one day laggard row man-made irrigation.Within after planting 28 days, calculate control efficiency, do not observe wheat powdery mildew and infect.Contrast medicament 25% fluorine azoles bacterium amide suspending agents and 28% kind of bacterium azoles pulvis are used according to same method, and within after planting 28 days, calculate control efficiency, concrete control efficiency is in table 8.
Above-described embodiment only illustrates inventive concept of the present invention for explaining, but not the restriction to rights protection of the present invention, all changes utilizing this design the present invention to be carried out to unsubstantiality, all should fall into protection scope of the present invention.
Table 1
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7
* in table, data are added up through duncan's new multiple range method, are that extreme difference is not remarkable containing same letter person
Table 8
Claims (9)
1. a bactericidal composition for fluorine azoles bacterium acid amides and kind bacterium azoles, is characterized in that: comprise active component, and wherein said active component comprises fluorine azoles bacterium acid amides and plants bacterium azoles, and the weight ratio of described fluorine azoles bacterium acid amides and kind bacterium azoles is 1:80 ~ 80:1.
2. a kind of fluorine azoles bacterium acid amides according to claim 1 and the bactericidal composition of planting bacterium azoles, is characterized in that: the weight ratio of described fluorine azoles bacterium acid amides and kind bacterium azoles is 1:40 ~ 40:1.
3. a kind of fluorine azoles bacterium acid amides according to claim 1 and the bactericidal composition of planting bacterium azoles, is characterized in that: add the composition pesticide preparation that auxiliary agent is made into any formulation agriculturally allowed in described bactericidal composition.
4. a kind of fluorine azoles bacterium acid amides according to claim 3 and the bactericidal composition of planting bacterium azoles, is characterized in that: described composition pesticide preparation can be made into the one in suspending agent, wetting powder, water dispersible granules, aqueous emulsion, seed treatment.
5. a kind of fluorine azoles bacterium acid amides according to claim 4 and the bactericidal composition of planting bacterium azoles, is characterized in that: in described composition pesticide preparation, the weight percentage of fluorine azoles bacterium acid amides and kind bacterium azoles is 0.1% ~ 90% of described composition pesticide total formulation weight amount.
6. a kind of fluorine azoles bacterium acid amides according to claim 5 and the bactericidal composition of planting bacterium azoles, is characterized in that: the weight percentage of described fluorine azoles bacterium acid amides and kind bacterium azoles is 2% ~ 70% of described composition pesticide total formulation weight amount.
7. a purposes for fluorine-containing azoles bacterium acid amides and kind bacterium azoles composition pesticide, is characterized in that: described fluorine-containing azoles bacterium acid amides and kind bacterium azoles bactericidal composition can for preventing and treating the disease on grass family class crop, cotton, peanut, vegetables, soybean and fruit tree.
8. the purposes of a kind of fluorine-containing azoles bacterium acid amides according to claim 7 and kind bacterium azoles composition pesticide, is characterized in that: described disease is specially powdery mildew, banded sclerotial blight, downy mildew, scab, spot defoliation, leaf spot, anthracnose.
9. the purposes of a fluorine-containing azoles bacterium acid amides and kind bacterium azoles composition pesticide, it is characterized in that: the composition pesticide preparation that described bactericidal composition or bactericidal composition are mixed with for seed treatment, by seed soaking, seed dressing or the method treatment of plant propagation material of seed pelleting.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2906042A4 (en) * | 2012-10-15 | 2016-04-13 | Kureha Corp | Plant disease controlling agent, plant disease controlling method, and plant disease controlling product |
CN106070237A (en) * | 2016-07-12 | 2016-11-09 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of Fluxapyroxad-containsterilization and the bactericidal composition of nitrile bacterium azoles and application thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
US20140200140A1 (en) * | 2013-12-30 | 2014-07-17 | Sumitomo Chemical Company, Limited | Method of controlling pests |
-
2015
- 2015-01-21 CN CN201510031122.1A patent/CN104604883A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
US20140200140A1 (en) * | 2013-12-30 | 2014-07-17 | Sumitomo Chemical Company, Limited | Method of controlling pests |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2906042A4 (en) * | 2012-10-15 | 2016-04-13 | Kureha Corp | Plant disease controlling agent, plant disease controlling method, and plant disease controlling product |
CN106070237A (en) * | 2016-07-12 | 2016-11-09 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of Fluxapyroxad-containsterilization and the bactericidal composition of nitrile bacterium azoles and application thereof |
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