CN103907614B - A kind of composite synergistic bactericidal composition and application thereof containing biphenyl pyrrole bacterium amine and Difenoconazole - Google Patents
A kind of composite synergistic bactericidal composition and application thereof containing biphenyl pyrrole bacterium amine and Difenoconazole Download PDFInfo
- Publication number
- CN103907614B CN103907614B CN201210593288.9A CN201210593288A CN103907614B CN 103907614 B CN103907614 B CN 103907614B CN 201210593288 A CN201210593288 A CN 201210593288A CN 103907614 B CN103907614 B CN 103907614B
- Authority
- CN
- China
- Prior art keywords
- difenoconazole
- bacterium amine
- pyrrole bacterium
- biphenyl pyrrole
- bactericidal composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of the composite synergistic bactericidal composition and the application thereof that contain biphenyl pyrrole bacterium amine and Difenoconazole.This bactericidal composition is with biphenyl pyrrole bacterium amine and Difenoconazole for principle active component, and wherein the weight ratio of biphenyl pyrrole bacterium amine and Difenoconazole is 1 ~ 60:1 ~ 80.This bactericidal composition can be applicable to control cereal crop and vegetables fruit diseases, there is higher synergistic function, overcome and delayed the pesticide resistance of germ, sterilization speed is fast, the lasting period is longer, reducing application cost, control efficiency is obviously better than its single dose and uses.The present invention may be used for preventing and treating the fungal disease on crops, especially may be used for the fungal diseases such as control rust, powdery mildew, leaf spot, brown spot, head blight, gray mold, and effect is better than single dose and uses.<!--1-->
Description
Technical field:
The present invention relates to a kind of bactericidal composition and uses thereof, especially a kind of be main active bactericidal composition and the application thereof of biphenyl pyrrole bacterium amine and Difenoconazole.
Background technology
Biphenyl pyrrole bacterium amine (Bixafen), the chloro-5-fluorine of chemical name: N-(3', 4'-bis-[1,1'-biphenyl]-2-base)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, molecular formula: C
18h
12cl
2f
3n
3o, chemical structural formula is as follows:
Biphenyl pyrrole bacterium amine is a kind of novel SDI pyrazoles bactericide, Bixafen is developed by Beyer Co., Ltd, this medicine is succinate dehydrogenase inhibitors, the mechanism of action is novel, main exploitation is used for the control of leaf spot and leaf rust, but is shown by research, and this new compound all has excellent activity to multiple germ, as powdery mildew, gray mold, downy mildew etc., this medicine is expected to the emphasis kind becoming bactericide resistance management.It is reported biphenyl pyrrole bacterium amine in listing in 2011, obtain registration in Australia, Chile, Estonia, Germany, Ireland, Lithuania, Ukraine and Britain at present,
Difenoconazole (Difenoconazole), chemical name: suitable, the chloro-4-of trans-3-[4-methyl-2-1H-1,2,4-triazol-1-yl methyl)-1,3-bis-mute pentane-2-base) phenyl 4-chlorphenyl ether.Structural formula:
Difenoconazole has protection, treatment and systemic activity, is sterol demethylation inhibitors, and the biosynthesis of T suppression cell wall sterol stops the growth of fungi.Fungicidal spectrum is wide, and leaf surface treatment or seed treatment can improve output and the guaranteed quality of crop.Be widely used in the crop such as fruit tree, vegetables, effectively prevent and treat scab, anthrachose of grape, white rot, spot defoliation, powdery mildew, brown spot, rust, yellow rust, head blight etc.
Triazole bactericidal agent is the longer bactericide kind of China's applicating history, the control of crop pest as powdery mildew, rust etc. plays an important role, although triazole type medicament is still in large-area use at present, but there is decline by a relatively large margin to the susceptibility of such medicament in bacterial strain, the using dosage in field improves gradually, larger pressure is created to environment and resistance, therefore should carry out correlative study to slow down the generation of resistance, and adopt the pharmacy mix of different mechanism to be namely main direction of studying.
At present, along with the change of pattern of farming, disease occurrence degree, the generation quantity of melon and fruit, vegetables, cereal crop all increase, and are are objectively preventing and treating difficulty increasing; On the other hand, SM, under the medicament selection pressure continued, cause the resistance of pathogen to rise year by year, the control efficiency of single dose is had a greatly reduced quality; 3rd, the speed to introduce of current new varieties of pesticides obviously declines, and lacks new action target medicament; 4th, strict gradually due to environmental requirement, portioned product is limited to use, and causes medication selectivity to become less.In a word, how effective control plant disease is the important topic that vast plant protection work person faces.
Summary of the invention:
The object of the invention is for above-mentioned technical problem provide a kind of applied widely, cost is low, the effective plant bactericidal composition containing biphenyl pyrrole bacterium amine and Difenoconazole.
A further object of the invention is to provide this bactericidal composition and causes application on fungal disease at control sac fungi, basidiomycetes, imperfect fungus and Oomycete fungal, especially on the fungal diseases such as control rust, powdery mildew, leaf spot, brown spot, head blight, gray mold purposes.
The object of the invention is to be realized by following measures:
A kind of composite synergistic bactericidal composition containing biphenyl pyrrole bacterium amine and Difenoconazole, it contains biphenyl pyrrole bacterium amine and Difenoconazole, wherein biphenyl pyrrole bacterium amine and Difenoconazole weight ratio are 1 ~ 60:1 ~ 80, and wherein in bactericidal composition, effective ingredient is present in composition with enhancing effective amount.
Described bactericidal composition, wherein biphenyl pyrrole bacterium amine and Difenoconazole weight ratio are preferably 5 ~ 30:10 ~ 60, more preferably 8 ~ 20:15 ~ 30.
In the compositions of the present invention, the percentage by weight accounting for composition both biphenyl pyrrole bacterium amine and Difenoconazole is 2% ~ 90%.Be preferably 5% ~ 60%, most preferably 8% ~ 50%.
Described bactericidal composition, wherein with biphenyl pyrrole bacterium amine and Difenoconazole for principle active component and known auxiliary agent and excipient are re-dubbed any one formulation that agricultural chemicals allows, the preferred missible oil of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
These known auxiliary agents, excipients have emulsifier, wetting dispersing agent, suspending agent, defoamer, disintegrant, binding agent etc.
The aforementioned emulsifier that can be applicable in insecticides adjuvant of the present invention includes, but are not limited to calcium dodecyl benzene sulfonate, the rare block compound of polyoxyethylene polyoxy third, castor oil polyoxyethylene ether, alkylphenol polyoxyethylene polyethenoxy ether, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether, phenethyl phenol polyethenoxy ether polyethenoxy ether, alkylphenol polyoxyethylene formaldehyde condensation products etc., and the phosphate of above-mentioned wherein moieties and in and salt.Concrete kind as: agriculture breast 500# series, 600# is serial, 400# is serial, 1600# is serial, NP is serial, OP is serial, AEO is serial, By is serial, these dish series, TWEEN Series etc.
The aforementioned wetting dispersing agent that can be applicable in insecticides adjuvant of the present invention include, but are not limited in sodium lignin sulfonate, calcium lignosulfonate, alkylnaphthalene sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products, Abietyl quaternary ammonium salt, alkylphenol polyoxyethylene phosphate, saponin, the withered powder of tea, fatty alcohol polyoxyethylene ether sulfate, lauryl sodium sulfate, neopelex, polycarboxylic acid salt and high molecular comb shape compound etc. one or more.
It is aforementioned that to can be applicable to excipient of the present invention be one or more in water, solvent or filler.
Described solvent includes, but are not limited to one or more of toluene, dimethylbenzene, solvent naphtha series, mixed methylnaphthalene, turpentine oil, vegetable oil, methyl oleate, carrene, chloroform, methyl alcohol, ethanol, isopropyl alcohol, n-butanol, cyclohexanone, isophorone, pyrrolidones, tetrahydrofurfuryl alcohol, acetic acid dimethyl ester, acetophenone, ethyl acetate, DMF, dimethyl sulfoxide (DMSO) etc.
Described filler is selected from one or more of white carbon, kaolin, precipitated calcium carbonate, diatomite, corn starch, quartz sand, talcum powder, ammonium sulfate, sodium sulphate, sodium chloride, potassium chloride etc.
As required, also the functional aids such as antifreezing agent, thickener, stabilizing agent, defoamer can be added.
Described antifreezing agent is selected from one or more of ethylene glycol, propane diols, urea, diethylene glycol (DEG), glycerine etc.
Described thickener be selected from xanthans, polyvinyl alcohol, bentonite, CMC, aluminium-magnesium silicate one or more.
Described bactericidal composition, its formulation is missible oil, suspending agent, suspension emulsion, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
The application of described bactericidal composition in preparation control cereal diseases germ killing drugs.Especially the application on control rust, powdery mildew, leaf spot, brown spot, head blight, gray mold fungal disease germ killing drugs is being prepared.
Beneficial effect of the present invention:
1, the biphenyl pyrrole bacterium amine that the present invention is used is novel pyrazole series bactericidal agent, and Difenoconazole is wide spectrum triazole bactericidal agent, and mutual mixture can not produce low touching, can Synergistic, reduces dosage, slows down resistance and reduce costs.
2, the present composition scope of application increases, be applicable to the crop pest of preventing and treating Cereal, various melon and fruit, vegetables, particularly prevent and treat the crop pests such as paddy rice, wheat, barley, capsicum, rape, peanut, paddy rice, tomato, as wheat rust, wheat powdery mildew, large wheat rust, wheat net blotch, capsicum brown spot, the cercospora brown spot of peanut, grape powdery mildew etc.
Bactericidal composition of the present invention has good control efficiency to sac fungi, basidiomycetes, imperfect fungus and Oomycete fungal disease; Because Synergistic causes consumption to reduce, can unitary agent (biphenyl pyrrole bacterium amine and Difenoconazole arbitrary) be developed immunity to drugs Antifungi.
The application of bactericidal composition of the present invention on preparation control refractory fungal, especially all has significant effect in the application of control rust, powdery mildew, leaf spot, brown spot, head blight, gray mold.Above-mentioned bactericidal composition can produce higher synergistic function, and the consumption of the independent reactive compound of the amount ratio of this mixture reduces greatly, and namely the activity of mixture is greater than the activity of independent component.
Compared with prior art beneficial effect of the present invention: (1) is compared with single dose, said composition antagonism fungal disease such as the fungal diseases such as rust, powdery mildew, leaf spot, brown spot, head blight, gray mold have obvious synergistic function, overcome and delayed pesticide resistance, expanding prevention is composed, and significantly improves control efficiency; (2) control recruitment, drug cost is reduced; (3) alternative routine and the easy agricultural chemicals producing resistance; (4) compared with single dose, produce and use cost reduction; (5) the drug-fast generation of Antifungi, its successful uses higher than its single dose.
" % " of the present invention is all weight percentage.
Embodiment
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of formulation is conventional laboratory's formulation method.
Indoor biometrics is tested:
In indoor with wheat rust (PucciniastriiformisWest) for test strain, adopt mycelial growth rate method, measure different agents to concentration EC in the suppression of bacterial strain
50value, adopt the abundant co-toxicity coefficient computational methods of Sun Yun, calculate the co-toxicity coefficient (CTC) of mixture, determine the building performance of mixture, computational methods are as follows:
1. with single dose a certain in mixture for standard agent (selects EC usually
50junior), calculate:
2. single dose toxicity index=standard agent EC
50/ certain single dose EC in addition
50× 100
3. toxicity index × B single dose proportion in mixture of toxicity index × A single dose proportion+B single dose in mixture of theoretical toxicity index=A single dose.
4. survey the EC of toxicity index=standard single dose
50the EC of value/mixture
50value × 100
5. co-toxicity coefficient CTC=surveys toxicity index/theoretical toxicity index × 100
The value of mixture is evaluated according to the numerical value of CTC, CTC shows that mixture has synergetic when being greater than 120, CTC shows that mixture has Antagonism when being less than 80, CTC shows that between 80-120 mixture has summation action, generally speaking, the CTC>120 of mixture is the basic demand of agriculture chemical compounding research and development.
Indoor biometrics result is as follows:
Table 1: biphenyl pyrrole bacterium amine+Difenoconazole different ratio is to the indoor biometrics result of wheat rust
| Medicament | Virulence regression equation | EC 50（mg/L） | Co-toxicity coefficient |
| 5% biphenyl pyrrole bacterium amine EC | Y= 1.9477X+ 4.0077 | 3.2322 | --- |
| 10% Difenoconazole WDG | Y= 2.4580X+ 2.7341 | 8.3526 | --- |
| Embodiment 1(1:10) | Y= 3.123X+ 2.9441 | 4.5532 | 161.3 |
| Embodiment 2(1:5) | Y= 3.4916X+ 3.2726 | 3.1241 | 211.1 |
| Embodiment 3(1:2) | Y= 2.9462X+ 3.4897 | 3.2555 | 168.2 |
| Embodiment 4(1:1) | Y= 3.1761X+ 3.4296 | 3.1221 | 150.0 |
| Embodiment 5(2:1) | Y= 3.0243X+ 3.5566 | 3.0010 | 134.6 |
Field control effectiveness test:
Indoor biometrics shows good Pesticidal composition, actual field medicine effect test must be carried out, field medicine effect test is the important means that whether final evaluation Pesticidal composition has using value under the impact of field integrated environment, therefore, the field medicine effect test preventing and treating wheat rust has been carried out with the pesticide mixed preparation that embodiment obtains in the basis of indoor biometrics.
1. test process: this test medicine consumption establishes three concentration for the treatment of respectively according to the difference of each composition, contrast medicament is 10% Difenoconazole WDG and 5% biphenyl pyrrole bacterium amine EC and blank clean water experiment respectively.
2. each plot area of test method is 66.7m
2, repeat 3 times; Inspection drug effect method before dispenser after Investigation and Prevention is: in test treatment region, adopt accidental sampling, sample 5 points, 0.5 square metre often, check wheat rust occurrence degree.
Table 2: the field control effectiveness test of biphenyl pyrrole bacterium amine+Difenoconazole difference pairing wheat rust:
Shown by the result of indoor biometrics and field medicine effect test, biphenyl pyrrole bacterium amine and Difenoconazole composition have obvious synergistic function, the control efficiency of composition is excellent, and control efficiency is all better than single dose kind, in agricultural application, have good using value.
Two kinds of reactive compounds can be processed into any one formulation of permission, with specific embodiment, the preparation that two kinds of active ingredients are processed into are described below, but the preparation that these two kinds of active components can be processed be not limited only to following listed by.
Embodiment 1:
By biphenyl pyrrole bacterium amine 3g, Difenoconazole 30g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and obtained principle active component weight percentage is 33% wetting powder.
Embodiment 2:
By biphenyl pyrrole bacterium amine 5g, Difenoconazole 25g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and obtained principle active component weight percentage is 30% wetting powder.
Embodiment 3:
By biphenyl pyrrole bacterium amine 10g, Difenoconazole 20g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and obtained principle active component weight percentage is 30% wetting powder.
Embodiment 4:
Take biphenyl pyrrole bacterium amine 15g, Difenoconazole 15g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and obtained principle active component weight percentage is 30% wetting powder.
Embodiment 5:
Take biphenyl pyrrole bacterium amine 20g, Difenoconazole 10g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and obtained principle active component weight percentage is 30% wetting powder.
Embodiment 6:
Take 1g biphenyl pyrrole bacterium amine, 5g Difenoconazole, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, C5 ~ C8 solvent 13g, add water to 100g.The method above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, and making principle active component weight percentage is 6% biphenyl pyrrole bacterium amine-difenoconazole water emulsion.
Embodiment 7:
Take 50g biphenyl pyrrole bacterium amine, 20g Difenoconazole, sodium lignin sulfonate 8g, polycarboxylate salt dispersant 2g, lauryl sodium sulfate 1g, ammonium sulfate 5g, corn starch complement to 100g.The method above raw material being prepared routinely water dispersion granule first mixes, rear cross air-flow crushing, finally mediate granulation, making principle active component weight percentage is 70% biphenyl pyrrole bacterium amine-Difenoconazole water dispersion granule.
Embodiment 8:
Take 2g biphenyl pyrrole bacterium amine, 40g Difenoconazole, sodium lignin sulfonate 8g, polycarboxylate salt dispersant 2g, lauryl sodium sulfate 1g, ammonium sulfate 5g, corn starch complement to 100g.The method above raw material being prepared routinely water dispersion granule first mixes, rear cross air-flow crushing, finally mediate granulation, making principle active component weight percentage is 42% biphenyl pyrrole bacterium amine-Difenoconazole water dispersion granule.
Embodiment 9:
Take 5g biphenyl pyrrole bacterium amine, 20g Difenoconazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method above raw material being prepared routinely microemulsion drops in mixing kettle and mixes, and making principle active component weight percentage is 25% biphenyl pyrrole bacterium amine-micro-emulsion of phenyl ether methyl cyclic-azole.
Embodiment 10:
Take 5g biphenyl pyrrole bacterium amine, 0.5g Difenoconazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, add vegetable oil to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and making principle active component weight percentage is 5.5% biphenyl pyrrole bacterium amine-Difenoconazole missible oil.
Embodiment 11:
Take 5g biphenyl pyrrole bacterium amine, 30g Difenoconazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill, make principle active component weight percentage is 35% biphenyl pyrrole bacterium amine-difenoconazole suspending agent.
Embodiment 12:
Take 10g biphenyl pyrrole bacterium amine, 10g Difenoconazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill, make principle active component weight percentage is 20% biphenyl pyrrole bacterium amine-difenoconazole suspending agent.
Embodiment 13:
Take 30g biphenyl pyrrole bacterium amine, 12g Difenoconazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill, make principle active component weight percentage is 42% biphenyl pyrrole bacterium amine-difenoconazole suspending agent.
Embodiment 14:
Take 2g biphenyl pyrrole bacterium amine, 5g Difenoconazole, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite complements to 100g, and it is 7% biphenyl pyrrole bacterium amine-Difenoconazole water dispersion granule that above raw material is made principle active component weight percentage by water dispersible granular agent method.
Embodiment 15:
Take 4g biphenyl pyrrole bacterium amine, 13g Difenoconazole, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite complements to 100g, and it is 17% biphenyl pyrrole bacterium amine-Difenoconazole water dispersion granule that above raw material is made principle active component weight percentage by water dispersible granular agent method.
Embodiment 16:
Take 5g biphenyl pyrrole bacterium amine, 15g Difenoconazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill, make principle active component weight percentage is 20% biphenyl pyrrole bacterium amine-difenoconazole suspending agent.
Claims (8)
1., containing a composite synergistic bactericidal composition for biphenyl pyrrole bacterium amine and Difenoconazole, it is characterized in that wherein the weight ratio of biphenyl pyrrole bacterium amine and Difenoconazole is 1:5 with biphenyl pyrrole bacterium amine and Difenoconazole for active ingredient.
2. the composite synergistic bactericidal composition containing biphenyl pyrrole bacterium amine and Difenoconazole according to claim 1, is characterized in that the weight percentage that both biphenyl pyrrole bacterium amine and Difenoconazole account for composition is 2% ~ 90%.
3. the composite synergistic bactericidal composition containing biphenyl pyrrole bacterium amine and Difenoconazole according to claim 2, is characterized in that the weight percentage that both biphenyl pyrrole bacterium amine and Difenoconazole account for composition is 5% ~ 60%.
4. the composite synergistic bactericidal composition containing biphenyl pyrrole bacterium amine and Difenoconazole according to claim 3, is characterized in that the weight percentage that both biphenyl pyrrole bacterium amine and Difenoconazole account for composition is 8% ~ 50%.
5. the composite synergistic bactericidal composition containing biphenyl pyrrole bacterium amine and Difenoconazole according to claim 1, is characterized in that with biphenyl pyrrole bacterium amine and Difenoconazole for active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that agricultural chemicals allows.
6. the composite synergistic bactericidal composition containing biphenyl pyrrole bacterium amine and Difenoconazole according to claim 5, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
7. the composite synergistic bactericidal composition containing biphenyl pyrrole bacterium amine and Difenoconazole according to claim 1 is preparing the application on control resistance plant fungal disease germ killing drugs.
8. application according to claim 7, is characterized in that the compound biocide composite containing biphenyl pyrrole bacterium amine and Difenoconazole is preparing the application on control rust, powdery mildew, leaf spot, brown spot, head blight, gray mold fungal disease germ killing drugs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210593288.9A CN103907614B (en) | 2012-12-31 | 2012-12-31 | A kind of composite synergistic bactericidal composition and application thereof containing biphenyl pyrrole bacterium amine and Difenoconazole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210593288.9A CN103907614B (en) | 2012-12-31 | 2012-12-31 | A kind of composite synergistic bactericidal composition and application thereof containing biphenyl pyrrole bacterium amine and Difenoconazole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103907614A CN103907614A (en) | 2014-07-09 |
| CN103907614B true CN103907614B (en) | 2016-03-16 |
Family
ID=51033888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210593288.9A Active CN103907614B (en) | 2012-12-31 | 2012-12-31 | A kind of composite synergistic bactericidal composition and application thereof containing biphenyl pyrrole bacterium amine and Difenoconazole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103907614B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104713977B (en) * | 2015-01-09 | 2016-05-11 | 韩超 | SPE-the liquid chromatography-tandem mass of multiple pyrazoles bactericide in grape wine |
| CN106538546A (en) * | 2016-10-11 | 2017-03-29 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition of the bacterium of pyrrole containing biphenyl amine and its application |
| CN106857540A (en) * | 2017-04-17 | 2017-06-20 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol and triazole bactericidal agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
| CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10347090A1 (en) * | 2003-10-10 | 2005-05-04 | Bayer Cropscience Ag | Synergistic fungicidal drug combinations |
-
2012
- 2012-12-31 CN CN201210593288.9A patent/CN103907614B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101257798A (en) * | 2005-08-05 | 2008-09-03 | 巴斯福股份公司 | Fungicidal mixtures containing substituted 1-methyl pyrazol-4-yl carboxylic acid anilides |
| CN102014628A (en) * | 2008-02-05 | 2011-04-13 | 巴斯夫欧洲公司 | Plant health composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103907614A (en) | 2014-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105766952B (en) | The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and folpet | |
| CN103583537A (en) | Sterilization composition containing metconazole and pyraclostrobin and application of sterilization composition | |
| CN103563949B (en) | A kind of bactericidal composition and application thereof containing metconazole and tmtd | |
| CN103907614B (en) | A kind of composite synergistic bactericidal composition and application thereof containing biphenyl pyrrole bacterium amine and Difenoconazole | |
| CN104621126A (en) | Sterilization composition containing prothioconazole and difenoconazole and application thereof | |
| CN103563910B (en) | Bactericidal composition containing prothioconazole and validamycin and application thereof | |
| CN103907615B (en) | A kind of composite synergistic bactericidal composition and application thereof containing isopyrazam and Tebuconazole | |
| CN103907616B (en) | A kind of composite synergistic bactericidal composition and application thereof containing biphenyl pyrrole bacterium amine and Flutriafol | |
| CN103907604A (en) | Composite synergistic bactericidal composition containing isopyrazam and azoxystrobin and application thereof | |
| CN104621168A (en) | Sterilization composition containing prothioconazole and prochloraz-manganese chloride and application thereof | |
| CN104621125A (en) | Sterilization composition containing prothioconazole and trifloxystrobin and application thereof | |
| CN103891725B (en) | A kind of bactericidal composition and application thereof containing isopyrazam and kresoxim-methyl | |
| CN103229771A (en) | Fluoxastrobin-containing fungicide combination | |
| CN103891729A (en) | Bactericidal composition containing isopyrazam and prothioconazole and application thereof | |
| CN103891731B (en) | Bactericidal composition containing isopyrazam and propiconazole and application thereof | |
| CN103891723A (en) | Bactericidal composition containing isopyrazam and picoxystrobin and application thereof | |
| CN103563909A (en) | Bactericidal composition containing prothioconazole and fenoxanil and application of bactericidal composition | |
| CN105941416B (en) | A kind of bactericidal composition and its application of the bacterium amine of pyrrole containing biphenyl and Tebuconazole | |
| CN103563926B (en) | A kind of bactericidal composition and application thereof containing metconazole and dimethomorph | |
| CN103891733A (en) | Composite synergistic bactericidal composition containing bixafen and hexaconazole and application thereof | |
| CN103891724B (en) | A kind of composite synergistic bactericidal composition and application thereof containing isopyrazam and oxime bacterium ester | |
| CN103891732B (en) | Bactericidal composition containing isopyrazam and hexaconazole and application thereof | |
| CN103891743B (en) | Bactericidal composition containing isopyrazam and pyraclostrobin and application thereof | |
| CN104430389A (en) | Bactericidal composition comprising famoxadone and boscalid and application thereof | |
| CN104542648A (en) | Sterilization composition and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 213200 Jintan, Jiangsu Province, Dan Jing Road, No. F5, No. 10 Applicant after: JIANGSU FENGDENG CROP SCIENCE CO., LTD. Address before: 213200 Jintan, Jiangsu Province, Dan Jing Road, No. F5, No. 10 Applicant before: Fengdeng Pesticide Co., Ltd., Jiangsu |
|
| COR | Change of bibliographic data | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Composite synergic sterilization composition containing bixafen and difenoconazole and application thereof Effective date of registration: 20191012 Granted publication date: 20160316 Pledgee: Jiangsu Jiangnan Rural Commercial Bank Limited by Share Ltd Pledgor: JIANGSU FENGDENG CROP SCIENCE CO., LTD. Registration number: Y2019320010015 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |