CN105941403A - Bactericidal composition containing spiroxamine and coumoxystrobin and application of bactericidal composition - Google Patents
Bactericidal composition containing spiroxamine and coumoxystrobin and application of bactericidal composition Download PDFInfo
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- CN105941403A CN105941403A CN201610340255.1A CN201610340255A CN105941403A CN 105941403 A CN105941403 A CN 105941403A CN 201610340255 A CN201610340255 A CN 201610340255A CN 105941403 A CN105941403 A CN 105941403A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
Abstract
The invention discloses a bactericidal composition containing spiroxamine and coumoxystrobin and an application of the bactericidal composition. The spiroxamine and the coumoxystrobin are used as main effective constituents of the bactericidal composition, and the mass ratio of the spiroxamine to the coumoxystrobin is 1-90:1-90. The bactericidal composition can be used for preventing and treating diseases of cereals, fruit trees and vegetables, has high synergism, overcomes and delays pesticide resistance of germs, and is high in bactericidal speed and long in lasting period; application cost is reduced; and the preventing and treating effect is obviously higher than that of a single agent. The bactericidal composition can be used for preventing and treating fungal diseases of crops, and can be particularly used for preventing and treating fungal diseases such as powdery mildew, rust diseases, downy mildew, late blight, scab, leaf mold, anthracnose and apple valsa canker, and the effect of the bactericidal composition is greater than that of the single agent.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, a kind of bactericidal composition with volution bacterium amine and SYP-3375 as main active and application thereof.
Background technology
Volution bacterium amine (Spiroxamine), chemical formula: C18H35NO2, chemical name: the N-ethyl-N-propyl group-8-tert-butyl group-Isosorbide-5-Nitrae-dioxo spiro [4.5] decane-2-methylamine.Structural formula:
Volution bacterium amine is substitutional amine-group antibacterial, sterol biosynthesis inhibitor, the main synthesis suppressing the hydroxymethylated enzyme of pathogenic bacteria C-14.Controlling object is wheat powdery mildew and various rust, barley leaf blotch and stripe disease.Volution bacterium amine is a kind of novel, foliage fungicide of interior absorption, and powdery mildew is had specially good effect.Speed of action is fast and the lasting period is long, has protection and therapeutical effect concurrently.
SYP-3375 (coumoxystrobin), molecular formula: C14H13N3, chemical name: N-(4-methyl-6-acrylate-acetylenic-2-base) aniline.
SYP-3375 belongs to methoxy acrylic, is a kind of protective fungicide, has certain therapeutical effect simultaneously concurrently.It has wide spectrum, low toxicity, efficient, safe feature, have immunity, prevent, treat, increasing both production and income effect.To apple tree canker specially good effect, it it is the whole nation medicament of preventing and treating canker most authority.Fungicidal spectrum is wide, effective to melon fruits and vegetables, fruit tree downy mildew, late blight, scab, anthrax, leaf mold；Simultaneously to ring spot, anthrax, cotton wilt, Oryza sativa L. pestilence, banded sclerotial blight, root rotof flax, corn southern leaf blight is the most effective.
The industrial crops cultivated areas the such as at present difficulty of prevention and cure of phytopathogen is increasing, on the one hand, along with the change of pattern of farming, melon fruits and vegetables progressively expand, and disease occurrence degree, occur quantity all to increase, and in preventing and treating, difficulty strengthens；On the other hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, and control of plant disease is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, low cost, the effective plant bactericidal composition containing volution bacterium amine Yu SYP-3375 for above-mentioned technical problem.
It is a still further object of the present invention to provide this bactericidal composition and cause the application on fungal disease, especially in the purposes prevented and treated on the fungal diseases such as powdery mildew, rust, downy mildew, late blight, scab, leaf mold, anthrax, apple tree canker at preventing and treating plant epiphyte.
It is an object of the invention to be achieved through the following technical solutions:
A kind of containing volution bacterium amine and the bactericidal composition of SYP-3375, this bactericidal composition is with volution bacterium amine and SYP-3375 as principle active component, wherein volution bacterium amine is 1～90:1～90 with the mass ratio of SYP-3375, and wherein in bactericidal composition, active ingredient is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein volution bacterium amine is preferably 1～70:1～50 with the mass ratio of SYP-3375, more preferably 70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50.
Described bactericidal composition, wherein volution bacterium amine is most preferably 1:1 with the mass ratio of SYP-3375.
In the compositions of the present invention, the weight/mass percentage composition accounting for compositions both volution bacterium amine and SYP-3375 is 2～80%.Preferably 10～40%.
Described bactericidal composition, is wherein re-dubbed on pesticide, with known auxiliary agent and excipient, any one dosage form allowed for principle active component with volution bacterium amine and SYP-3375.Auxiliary agent known to these, excipient has dispersant, diffusant, defoamer, wetting agent, disintegrating agent etc., calcium dodecyl benzene sulfonate can be used, alkylphenol polyoxyethylene, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products thereof, aliphatic amine polyoxyethylene ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, one or more combinations in quaternary etc., excipient includes Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.The especially application in terms of preventing and treating Cereal, fruit tree, vegetable crop disease.
Above-mentioned application, described fungal diseases of plants is at least one in powdery mildew, rust, downy mildew, late blight, scab, leaf mold, anthrax, apple tree canker.
Beneficial effects of the present invention:
1, the volution bacterium amine used by the present invention and SYP-3375, the mechanism of action is different, and mutual mixture will not produce low touching, can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, being applicable to prevent and treat Cereal, fruit tree, the refractory fungal disease of vegetable, particularly preventing and treating powdery mildew, rust, downy mildew, late blight, scab, leaf mold, anthrax, apple tree canker etc. all has significant effect.Bactericidal composition of the present invention has good prevention effect to ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And suppress the drug-fast generation to unitary agent (volution bacterium amine and SYP-3375 are arbitrary) of insect or fungus.Bactericidal composition of the present invention can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture is substantially reduced, and i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1) is compared with single dose, the said composition antagonism fungal disease such as fungal disease such as powdery mildew, rust, downy mildew, late blight, scab, leaf mold, anthrax, apple tree canker has obvious synergistic function, overcome and delayed Drug resistance, expanding prevention is composed, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and the pesticide being easily generated resistance；(4) compared with single dose, produce and use cost reduces；(5) the suppression drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is conventional method, and " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture, determine the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A single dose the toxicity index of proportion+B single dose × B single dose proportion in mixture in mixture of theoretical toxicity index=A single dose
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, and CTC is summation action between 80-120.
According to effective ingredient volution bacterium amine (A): SYP-3375 (B) quality proportioning is: 70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50 test, measure its co-toxicity coefficient to apple rot pathogen (Valsa mali Miyabe et Yamada.).
Table 1: the volution bacterium amine+SYP-3375 different ratio indoor biometrics result to apple tree canker
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% volution bacterium amine EC | Y=4.102+1.245X | 5.267 | - |
| 10% SYP-3375 SC | Y=4.178+2.635X | 2.051 | - |
| A:B=70:1 | Y=4.039+2.005X | 3.015 | 170.90 |
| A:B=50:1 | Y=3.114+3.659X | 3.276 | 155.96 |
| A:B=30:1 | Y=4.640+0.745X | 3.042 | 164.83 |
| A:B=20:1 | Y=4.155+1.441X | 3.860 | 126.97 |
| A:B=10:1 | Y=3.648+2.550X | 3.391 | 135.93 |
| A:B=5:1 | Y=3.339+3.628X | 2.870 | 145.48 |
| A:B=2.5:1 | Y=3.933+2.225X | 3.016 | 120.61 |
| A:B=1:1 | Y=4.357+3.625X | 1.504 | 196.34 |
| A:B=1:2 | Y=4.400+2.754X | 1.651 | 155.93 |
| A:B=1:4 | Y=4.647+3.020X | 1.309 | 178.53 |
| A:B=1:6 | Y=4.426+5.021X | 1.301 | 172.65 |
| A:B=1:10 | Y=4.337+3.214X | 1.608 | 135.07 |
| A:B=1:20 | Y=4.631+2.548X | 1.396 | 151.34 |
| A:B=1:30 | Y=4.723+1.222X | 1.684 | 124.26 |
| A:B=1:50 | Y=4.476+3.658X | 1.575 | 131.78 |
Field control effectiveness test:
The pesticidal preparations prepared with above-described embodiment prevents and treats the test of apple tree canker mildew.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, and comparison medicament is pesticide single dose 25% volution bacterium amine EC and 10% SYP-3375 SC and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect method after investigating before dispenser and preventing and treating is: randomization 5 point in test treatment region, carries out severity Scaling according to country's field test relevant criterion, calculates preventive effect.Result of the test is shown in Table 2:
Table 2 field test effect
Being shown by indoor biometrics and field efficacy result, volution bacterium amine and SYP-3375 compositions have obvious synergistic function, and the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, have using value in agricultural is applied.
Two kinds of reactive compounds can be processed into any one dosage form of permission, with specific embodiment, the preparation that two kinds of effective ingredient are processed into is described below, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% volution bacterium amine SYP-3375 wettable powder (1:2)
By volution bacterium amine 5g, SYP-3375 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 15% volution bacterium amine SYP-3375 wettable powder.
Embodiment 2:15% volution bacterium amine SYP-3375 wettable powder (1:4)
By volution bacterium amine 3g, SYP-3375 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 15% volution bacterium amine SYP-3375 wettable powder.
Embodiment 3:14% volution bacterium amine SYP-3375 wettable powder (1:6)
By volution bacterium amine 2g, SYP-3375 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 14% volution bacterium amine SYP-3375 wettable powder.
Embodiment 4:20% volution bacterium amine SYP-3375 suspending agent (1:1)
Weigh 10g volution bacterium amine, 10g SYP-3375, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredient percent under the effect of sand mill is 20% volution bacterium amine SYP-3375 suspending agent.
Embodiment 5:55% volution bacterium amine SYP-3375 aqueous emulsion (1:10)
Weigh 5g volution bacterium amine, 50g SYP-3375, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 55% volution bacterium amine SYP-3375 aqueous emulsion.
Embodiment 6:42% volution bacterium amine SYP-3375 cream (1:20)
Weigh 2g volution bacterium amine, 40g SYP-3375, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 42% volution bacterium amine SYP-3375 cream.
Embodiment 7:70% volution bacterium amine SYP-3375 cream (2.5:1)
Weigh 50g volution bacterium amine, 20g SYP-3375, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 70% volution bacterium amine SYP-3375 cream.
Embodiment 8:18% volution bacterium amine SYP-3375 water dispersion granule (5:1)
Weigh 15g volution bacterium amine, 3g SYP-3375, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, kieselguhr 28g complements to 100g, and being formed with imitating Ingredient percent by water dispersible granular agent method by above raw material is 17% volution bacterium amine SYP-3375 water dispersion granule.
Embodiment 9:11% volution bacterium amine SYP-3375 cream (10:1)
Weigh 10g volution bacterium amine, 1g SYP-3375, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 11% volution bacterium amine SYP-3375 cream.
Embodiment 10:31.5% volution bacterium amine SYP-3375 microemulsion (20:1)
Weigh 30g volution bacterium amine, 1.5g SYP-3375, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 32% volution bacterium amine SYP-3375 microemulsion.
Embodiment 11:31% volution bacterium amine SYP-3375 cream (30:1)
Weigh 30g volution bacterium amine, 1g SYP-3375, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 31% volution bacterium amine SYP-3375 cream.
Embodiment 12:51% volution bacterium amine SYP-3375 suspending agent (50:1)
Weigh 50g volution bacterium amine, 1g SYP-3375, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredient percent under the effect of sand mill is 51% volution bacterium amine SYP-3375 suspending agent.
Embodiment 13:32% volution bacterium amine SYP-3375 microemulsion (1:15)
Weigh 2g volution bacterium amine, 30g SYP-3375, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 32% volution bacterium amine SYP-3375 microemulsion.
Embodiment 14:6% volution bacterium amine SYP-3375 aqueous emulsion (1:5)
Weigh 1g volution bacterium amine, 5g SYP-3375, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 6% volution bacterium amine SYP-3375 aqueous emulsion.
Embodiment 15:62% volution bacterium amine SYP-3375 microemulsion (1:30)
Weigh 2g volution bacterium amine, 60g SYP-3375, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material
The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 62% volution bacterium amine SYP-3375 microemulsion.
Embodiment 16:51% volution bacterium amine SYP-3375 suspending agent (1:50)
Weigh 1g volution bacterium amine, 50g SYP-3375, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredient percent under the effect of sand mill is 51% volution bacterium amine SYP-3375 suspending agent.
Embodiment 17:7% volution bacterium amine SYP-3375 water dispersion granule (1:2.5)
Weigh 2g volution bacterium amine, 5g SYP-3375, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and being formed with imitating Ingredient percent by water dispersible granular agent method by above raw material is 7% volution bacterium amine SYP-3375 water dispersion granule.
Claims (9)
1. one kind contains volution bacterium amine and the bactericidal composition of SYP-3375, it is characterised in that this bactericidal composition is with volution bacterium
Amine and SYP-3375 are principle active component, and wherein volution bacterium amine is 1～90:1～90 with the mass ratio of SYP-3375.
Bactericidal composition the most according to claim 1, it is characterised in that described volution bacterium amine and the matter of SYP-3375
Amount ratio is 1～70:1～50.
Bactericidal composition the most according to claim 2, it is characterised in that described volution bacterium amine and the matter of SYP-3375
Amount ratio is 1:1.
Bactericidal composition the most according to claim 1, it is characterised in that described volution bacterium amine and SYP-3375 two
It is 2-80% that person accounts for the weight/mass percentage composition of compositions.
Bactericidal composition the most according to claim 4, it is characterised in that described volution bacterium amine and SYP-3375 two
It is 10-40% that person accounts for the weight/mass percentage composition of compositions.
Bactericidal composition the most according to claim 1, it is characterised in that be main with volution bacterium amine and SYP-3375
Effective ingredient and insecticides adjuvant are configured on pesticide any one dosage form allowed.
Bactericidal composition the most according to claim 6, it is characterised in that described dosage form is cream, suspending agent, water
Emulsion, wettable powder or water dispersion granule.
8. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
Application the most according to claim 8, it is characterised in that described fungal diseases of plants be powdery mildew, rust,
At least one in downy mildew, late blight, scab, leaf mold, anthrax, apple tree canker.
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|---|---|---|---|---|
| US4851405A (en) * | 1987-03-07 | 1989-07-25 | Bayer Aktiengesellschaft | Aminomethyl heterocyclic compounds |
| CN101822251A (en) * | 2010-01-27 | 2010-09-08 | 深圳诺普信农化股份有限公司 | Sterilization compound containing ZJ0712 |
| CN102308824A (en) * | 2011-04-26 | 2012-01-11 | 陕西韦尔奇作物保护有限公司 | Bactericide composition containing spiroxamine and methoxyl acrylate |
| CN102657188A (en) * | 2012-04-24 | 2012-09-12 | 陕西韦尔奇作物保护有限公司 | Efficient sterilization composition |
| CN102885033A (en) * | 2012-09-28 | 2013-01-23 | 王龙华 | Water emulsion pesticide and production technology thereof |
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2016
- 2016-05-20 CN CN201610340255.1A patent/CN105941403B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4851405A (en) * | 1987-03-07 | 1989-07-25 | Bayer Aktiengesellschaft | Aminomethyl heterocyclic compounds |
| CN101822251A (en) * | 2010-01-27 | 2010-09-08 | 深圳诺普信农化股份有限公司 | Sterilization compound containing ZJ0712 |
| CN102308824A (en) * | 2011-04-26 | 2012-01-11 | 陕西韦尔奇作物保护有限公司 | Bactericide composition containing spiroxamine and methoxyl acrylate |
| CN102657188A (en) * | 2012-04-24 | 2012-09-12 | 陕西韦尔奇作物保护有限公司 | Efficient sterilization composition |
| CN102885033A (en) * | 2012-09-28 | 2013-01-23 | 王龙华 | Water emulsion pesticide and production technology thereof |
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Effective date of registration: 20200827 Address after: 243100 Anhui city of Ma'anshan province Dangtu Economic Development Zone Red Sun Life Science Industrial Park Patentee after: ANHUI REDPONT BIOTECHNOLOGY Co.,Ltd. Address before: Dongfeng Road, Sam town Gaochun District of Nanjing City, Jiangsu Province, No. 8 211318 Patentee before: Nanjing Huazhou Parmaceutical Co.,Ltd. |