CN106135223A - A kind of containing Boscalid and the bactericidal composition of prothioconazoles and application - Google Patents
A kind of containing Boscalid and the bactericidal composition of prothioconazoles and application Download PDFInfo
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- CN106135223A CN106135223A CN201510172709.4A CN201510172709A CN106135223A CN 106135223 A CN106135223 A CN 106135223A CN 201510172709 A CN201510172709 A CN 201510172709A CN 106135223 A CN106135223 A CN 106135223A
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Abstract
The invention discloses a kind of containing Boscalid and the bactericidal composition of prothioconazoles and application.This bactericidal composition is with Boscalid and prothioconazoles as principle active component, and wherein Boscalid is 1～70:1～50 with the weight ratio of prothioconazoles.This bactericidal composition can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the Drug resistance of pathogenic bacteria, and sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, a kind of bactericidal composition with Boscalid and prothioconazoles as main active and application thereof.
Background technology
Boscalid (Boscalid), is the novel nicotine acid amide fungicides of BASF Aktiengesellschaft's exploitation, the chloro-N-of chemical name: 2-(4'-chlordiphenyl-2-base) nicotiamide, molecular formula: C18H12Cl2N2O.Structural formula is as follows:
This antibacterial fungicidal spectrum is wider, almost the most active to all types of fungal diseases, to preventing and treating, powdery mildew, gray mold, sclerotiniose and various cankers etc. are highly effective, and it is the most effective to the resistance bacterium of other medicaments, for Brassica campestris L, beans, corm vegetable, Caulis et Folium Brassicae junceae, Radix Dauci Sativae, Fructus Mali pumilae, Caulis et Folium Lactucae sativae, Semen arachidis hypogaeae, Rhizoma Solani tuber osi, drupe, Fructus Fragariae Ananssae, nut, Caulis et Folium Brassicae capitatae, Fructus Cucumidis sativi, Herba Menthae, Semen Pisi sativi, roots vegetable, Helianthi, Fructus Vitis viniferae, lawn, the preventing and treating of the diseases such as other fruit trees, vegetable, field crop；Owing to its distinctive mechanism of action is not likely to produce cross resistance, in addition to crop safety and favourable toxicity data and ecological effect, it is the Novel tobacco acid amide fungicides of significant.
Prothioconazoles (prothioconazole), chemical name: 2-(2-(1-chlorine cyclopropyl)-3-(2-chlorphenyl)-2-hydroxypropyl-1-2-dihydro-3-1,2,4-triazole-3-sulfur generations, molecular formula: C14H15Cl2N3OS.Structural formula:
Prothioconazoles is the one novel spectrum triazolinthione insecticides that Beyer Co., Ltd develops, and is mainly used in preventing and treating numerous diseases such as frumentum, wheat and barley legume crop, and prothioconazoles toxicity is low, and without teratogenesis, mutagenesis type, to embryo's avirulence, to human and environment safety.
The mechanism of action is the demethylation effect in suppression fungus on the precursor lanosterol one by one of sterol or 24-methylene dihydro Mi hair liquor-saturated l4 position, i.e. demethylation inhibitors (DMIs).Not only there is good systemic activity, excellent protection, treat and root out activity, and the lasting period is long.By substantial amounts of field control effectiveness test, result shows that prothioconazoles not only has good safety to crop, and preventing disease theraping effect is good, and increases production substantially, compared with triazole type biocide agent.Prothioconazoles has broader spectrum of bactericidal activity, and prothioconazoles is mainly used in preventing and treating numerous diseases such as cereal crop such as Semen Tritici aestivi, Fructus Hordei Vulgaris, Brassica campestris L, Semen arachidis hypogaeae, Oryza sativa L. and legume crop.Almost all wheat and barley diseases there is good prevention effect, such as Semen Tritici aestivi and the powdery mildew of Fructus Hordei Vulgaris, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, net blotch, moire disease etc..Oil Lay and the soil-borne disease of Semen arachidis hypogaeae can also be prevented and treated, such as sclerotiniose, and main foliage disease, such as gray mold, melasma, brown spot, balck shank, sclerotiniose and rust etc..
But wheat and barley leaf blight, leaf rust, glume blight, brown spot, powdery mildew, leaf spot, droop, sclerotiniose, net blotch and moire disease, rice sheath blight disease, rice green smut, Brassica campestris L and Semen arachidis hypogaeae gray mold, melasma, brown spot, balck shank, the morbidity such as sclerotiniose and rust is more serious, catastrophic loss is caused to agricultural production, although Boscalid, prothioconazoles single dose has ideal prevention effect to Some Disease, but in actual applications, have been found that the difficulty of prevention and cure of phytopathogen is increasing, main cause has: one is as the change of pattern of farming, melon and fruit, the industrial crops cultivated areas such as vegetable progressively expand, disease occurrence degree, quantity is occurred all to increase, in preventing and treating, difficulty strengthens；Two is that current climate is abnormal, provides certain condition to the outburst of disease；Three is the selectivity impact of chemistry medication over a long time so that the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality.In sum, current control of plant disease work faces challenges the most greatly.
Summary of the invention
It is an object of the invention to provide a kind of applied widely, low cost, the effective plant bactericidal composition containing Boscalid Yu prothioconazoles for above-mentioned technical problem.
It is a still further object of the present invention to provide this bactericidal composition and cause the application on fungal disease at preventing and treating plant epiphyte.
It is an object of the invention to be realized by following measures:
A kind of bactericidal composition, it contains Boscalid and prothioconazoles, and wherein Boscalid and prothioconazoles weight ratio are 1～70:1～50, and wherein in bactericidal composition, active ingredient is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein Boscalid and prothioconazoles weight ratio are preferably 5～50:10～50, and more preferably 5～40:10～30, further preferably 1:2～15, most preferably Boscalid and prothioconazoles weight ratio are 1:2,1:4,1:6,1:10,1:15.
In some embodiments of the invention, the invention provides a kind of Boscalid and prothioconazoles agrochemical composition as active component that comprises, wherein Boscalid is independent of each other for 1:5,2.5:1,1:20,10:1,1:1,5:2,2:5,4:13,1:3 with the weight ratio of prothioconazoles.Through indoor biometrics experiment and field control effectiveness test, these compositionss can produce synergistic function than Boscalid and prothioconazoles single dose to fungal diseases of plants is equal.
In the compositions of the present invention, it is 2～80% that both Boscalid and prothioconazoles account for the percentage by weight of compositions, preferably 10～40%, further preferred 10～20%.
Described bactericidal composition, wherein Boscalid becomes, with prothioconazoles, any one dosage form allowed on pesticide with known additive compound.Auxiliary agent known to these has dispersant, diffusant, defoamer, wetting agent, disintegrating agent, excipient etc..Described dispersant, diffusant, defoamer, wetting agent, disintegrating agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products thereof, aliphatic amine polyoxyethylene ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, one or more combinations in quaternary etc., excipient is selected from Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water etc..Above dispersant, diffusant, defoamer, wetting agent, disintegrating agent, excipient and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
The application in preparation prevents and treats the medicine of Cereal, fruit tree, vegetable crop fungal disease of the described bactericidal composition.
Described fungus preferred wheat and barley leaf blight, leaf rust, glume blight, brown spot, powdery mildew, leaf spot, droop, sclerotiniose, net blotch and moire disease, rice sheath blight disease, rice green smut, Brassica campestris L or Semen arachidis hypogaeae gray mold, melasma, brown spot, balck shank, sclerotiniose and rust.
A kind of method preventing and treating fungal diseases of plants, including co-administered Boscalid and prothioconazoles, preferably uses compositions of the present invention.
Described co-administered Boscalid and prothioconazoles are interpreted as separately, sequentially or simultaneously use Boscalid and prothioconazoles.
Described fungal disease is wheat and barley leaf blight, leaf rust, glume blight, brown spot, powdery mildew, leaf spot, droop, sclerotiniose, net blotch and moire disease, rice sheath blight disease, rice green smut, Brassica campestris L or Semen arachidis hypogaeae gray mold, melasma, brown spot, balck shank, sclerotiniose and rust.
Beneficial effects of the present invention:
1, the Boscalid used by the present invention is pyridines antibacterial, and prothioconazoles is triazole bactericidal agent, and the mechanism of action is different, and mutual mixture will not produce low touching, can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, it is applicable to prevent and treat Cereal, fruit tree, the disease of vegetable, particularly preventing and treating wheat and barley leaf blight, leaf rust, glume blight, brown spot, powdery mildew, leaf spot, droop, sclerotiniose, net blotch and moire disease, rice sheath blight disease, rice green smut, Brassica campestris L and Semen arachidis hypogaeae gray mold, melasma, brown spot, balck shank, sclerotiniose and rust.Bactericidal composition of the present invention has good prevention effect to ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And suppress the drug-fast generation to unitary agent (Boscalid and prothioconazoles are arbitrary) of insect or fungus.
The bactericidal composition of the present invention application on preparation preventing and treating refractory fungal, especially at preventing and treating wheat and barley leaf blight, leaf rust, glume blight, brown spot, powdery mildew, leaf spot, droop, sclerotiniose, net blotch and moire disease, rice sheath blight disease, rice green smut, the application of Brassica campestris L and Semen arachidis hypogaeae gray mold, melasma, brown spot, balck shank, sclerotiniose and rust all has significant effect.Above-mentioned bactericidal composition can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture is substantially reduced, and i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1) is compared with single dose, said composition antagonism fungal disease such as wheat and barley leaf blight, leaf rust, glume blight, brown spot, powdery mildew, leaf spot, droop, sclerotiniose, net blotch and moire disease, rice sheath blight disease, rice green smut, the fungal diseases such as Brassica campestris L and Semen arachidis hypogaeae gray mold, melasma, brown spot, balck shank, sclerotiniose and rust have obvious synergistic function, overcome and delayed Drug resistance, expanding prevention is composed, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and the pesticide being easily generated resistance；(4) compared with single dose, produce and use cost reduces；(5) the suppression drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is conventional method, and " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture, determine the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A single dose the toxicity index of proportion+B single dose × B single dose proportion in mixture in mixture of theoretical toxicity index=A single dose
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, and CTC is summation action between 80-120.
Table 1: the Boscalid+prothioconazoles different ratio indoor biometrics result to Sclerotinia sclerotiorum (Sclerotinia sclerotiorum)
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% Boscalid SC (A) | Y=1.2458X+3.9952 | 6.4055 | - |
| 5% prothioconazoles ME (B) | Y=1.6523X+3.1913 | 12.4253 | - |
| A:B=1:2 | Y=2.0036X+2.7885 | 12.6993 | 144.52 |
| A:B=1:4 | Y=1.4221X+3.4512 | 12.2770 | 165.26 |
| A:B=1:6 | Y=2.0014X+2.6962 | 14.1607 | 150.06 |
| A:B=1:10 | Y=1.5472X+3.3830 | 11.095 | 200.14 |
| A:B=1:15 | Y=2.6350X+1.9433 | 14.456 | 157.48 |
Field control effectiveness test:
The pesticidal preparations preventing and treating sclerotinia rot of colza test prepared with above-described embodiment.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, and comparison medicament is pesticide single dose 5% prothioconazoles ME and 25% Boscalid SC and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, is repeated 3 times；Investigation drug effect method after investigating before dispenser and preventing and treating is: randomization 5 point in test treatment region, carries out severity Scaling according to country's field test relevant criterion, calculates preventive effect.
3, result of the test see table:
Being shown by indoor biometrics and field efficacy result, Boscalid and prothioconazoles compositions have obvious synergistic function, and the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, have using value in agricultural is applied.
Two kinds of reactive compounds can be processed into any one dosage form of permission, with specific embodiment, the preparation that two kinds of effective ingredient are processed into is described below, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:
By Boscalid 5g, prothioconazoles 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 15% wettable powder.
Embodiment 2:
By Boscalid 3g, prothioconazoles 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 15% wettable powder.
Embodiment 3:
By Boscalid 2g, prothioconazoles 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient weight percentage is 14% wettable powder.
Embodiment 4:
Weigh 5g Boscalid, 50g prothioconazoles, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into the mixing of mixing kettle high speed, and making effective Ingredients Weight percentage composition is 55% Boscalid-prothioconazoles aqueous emulsion.
Embodiment 5:
Weigh 2g Boscalid, 30g prothioconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 32% Boscalid-prothioconazoles microemulsion.
Embodiment 6:
Weigh 1g Boscalid, 5g prothioconazoles, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into the mixing of mixing kettle high speed, and making effective Ingredients Weight percentage composition is 6% Boscalid-prothioconazoles aqueous emulsion.
Embodiment 7:
Weigh 50g Boscalid, 20g prothioconazoles, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 70% Boscalid-prothioconazoles cream.
Embodiment 8:
Weigh 2g Boscalid, 40g prothioconazoles, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 42% Boscalid-prothioconazoles cream.
Embodiment 9:
Weigh 5g Boscalid, 20g prothioconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 25% Boscalid-prothioconazoles microemulsion.
Embodiment 10:
Weigh 5g Boscalid, 0.5g prothioconazoles, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 5.5% Boscalid-prothioconazoles cream.
Embodiment 11:
Weigh 5g Boscalid, 30g prothioconazoles, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredients Weight percentage composition is 35% Boscalid-prothioconazoles cream.
Embodiment 12:
Weigh 10g Boscalid, 10g prothioconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredients Weight percentage composition under the effect of sand mill is 20% Boscalid-prothioconazoles suspending agent.
Embodiment 13:
Weigh 30g Boscalid, 12g prothioconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredients Weight percentage composition under the effect of sand mill is 42% Boscalid-prothioconazoles suspending agent.
Embodiment 13:
Weigh 2g Boscalid, 5g prothioconazoles, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and being formed with imitating Ingredients Weight percentage composition by water dispersible granular agent method by above raw material is 7% Boscalid-prothioconazoles water dispersion granule.
Embodiment 14:
Weigh 4g Boscalid, 13g prothioconazoles, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, kieselguhr 28g complements to 100g, and being formed with imitating Ingredients Weight percentage composition by water dispersible granular agent method by above raw material is 17% Boscalid-prothioconazoles water dispersion granule.
Embodiment 15:
Weigh 5g Boscalid, 15g prothioconazoles, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredients Weight percentage composition under the effect of sand mill is 20% Boscalid-prothioconazoles suspending agent.
Claims (10)
1. one kind contains Boscalid and the bactericidal composition of prothioconazoles, it is characterised in that containing Boscalid
With prothioconazoles, wherein Boscalid is 1～70:1～50 with the weight ratio of prothioconazoles.
The most according to claim 1 containing Boscalid with the bactericidal composition of prothioconazoles, its feature
It is that Boscalid is 5～50:10～50 with the weight ratio of prothioconazoles, preferably 5～40:10～30, further
Preferably 1:2～15.
The most according to claim 2 containing Boscalid with the bactericidal composition of prothioconazoles, its feature
It is that to account for the weight percentage of compositions be 2 80% for both Boscalid and prothioconazoles, preferably 10 40%, enter
One step preferably 10～20%.
The most according to claim 1 containing Boscalid with the bactericidal composition of prothioconazoles, its feature
With Boscalid and prothioconazoles as principle active component and insecticides adjuvant be configured on pesticide to allow any
A kind of dosage form.
The most according to claim 4 containing Boscalid with the bactericidal composition of prothioconazoles, its feature
Be described dosage form be cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule etc..
The most according to claim 4 containing Boscalid with the bactericidal composition of Difenoconazole, it is special
Levy is also to comprise one or more other active component.
7. described in claim 1 containing Boscalid and the bactericidal composition of prothioconazoles, in preparation preventing and treating
Application in the medicine of fungal diseases of plants.
Application the most according to claim 7, it is characterised in that described in claim 1 containing pyridine acyl bacterium
The bactericidal composition of amine and prothioconazoles preparation preventing and treating wheat and barley leaf blight, leaf rust, glume blight, brown spot,
Powdery mildew, leaf spot, droop, sclerotiniose, net blotch and moire disease, rice sheath blight disease, rice green smut,
Application in the medicine of Brassica campestris L or Semen arachidis hypogaeae gray mold, melasma, brown spot, balck shank, sclerotiniose and rust.
9. the method preventing and treating fungal diseases of plants, it is characterised in that include co-administered Boscalid and third
Sulfur bacterium azoles, preferably uses the compositions according to any one of claim 1～6.
Method the most according to claim 9, wherein said fungal disease is powdery mildew, gray mold, sclerotium
Disease, canker, scab, anthrachose of grape, white rot, spot defoliation, brown spot, rust or head blight.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024009138A1 (en) * | 2022-07-04 | 2024-01-11 | Upl Limited | Fungicide composition |
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| CN1642423A (en) * | 2002-03-21 | 2005-07-20 | 巴斯福股份公司 | Fungicidal mixtures |
| WO2007134777A2 (en) * | 2006-05-24 | 2007-11-29 | Bayer Cropscience Ag | Fungicidal active ingredient combinations |
| CN102428931A (en) * | 2011-12-23 | 2012-05-02 | 江阴苏利化学有限公司 | Bacteriocidal composition containing Boscalid and triazole bactericide |
| CN103355308A (en) * | 2013-07-08 | 2013-10-23 | 海利尔药业集团股份有限公司 | Sterilization composition containing prothioconazole and boscalid |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1642423A (en) * | 2002-03-21 | 2005-07-20 | 巴斯福股份公司 | Fungicidal mixtures |
| WO2007134777A2 (en) * | 2006-05-24 | 2007-11-29 | Bayer Cropscience Ag | Fungicidal active ingredient combinations |
| CN102428931A (en) * | 2011-12-23 | 2012-05-02 | 江阴苏利化学有限公司 | Bacteriocidal composition containing Boscalid and triazole bactericide |
| CN103355308A (en) * | 2013-07-08 | 2013-10-23 | 海利尔药业集团股份有限公司 | Sterilization composition containing prothioconazole and boscalid |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024009138A1 (en) * | 2022-07-04 | 2024-01-11 | Upl Limited | Fungicide composition |
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