CN106135252A - A kind of containing Boscalid and the bactericidal composition of prochloraz-manganese chloride complex and application - Google Patents
A kind of containing Boscalid and the bactericidal composition of prochloraz-manganese chloride complex and application Download PDFInfo
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- CN106135252A CN106135252A CN201510171881.8A CN201510171881A CN106135252A CN 106135252 A CN106135252 A CN 106135252A CN 201510171881 A CN201510171881 A CN 201510171881A CN 106135252 A CN106135252 A CN 106135252A
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- prochloraz
- boscalid
- manganese chloride
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Abstract
The invention discloses a kind of containing Boscalid and the bactericidal composition of prochloraz-manganese chloride complex and application.This bactericidal composition is with Boscalid and prochloraz-manganese chloride complex as principle active component, and wherein Boscalid is 1～70:1～50 with the weight ratio of prochloraz-manganese chloride complex.This bactericidal composition can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the Drug resistance of pathogenic bacteria, and sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention may be used for preventing and treating the fungal disease on crops, being particularly useful for preventing and treating the fungal diseases such as powdery mildew, gray mold, sclerotinia rot of colza and canker, garlic leaf blight, Alternaria alternate, Botrytis cinerea, watermelon blight, mushroom wet bubble disease, grapevine anthracnose, Penicillium italicum, green mould, mango anthracnose, effect is better than single dose and uses.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, especially a kind of with Boscalid and prochloraz-manganese chloride complex
Bactericidal composition and application thereof for main active.
Background technology
Boscalid (Boscalid), is the novel nicotine acid amide fungicides of BASF Aktiengesellschaft's exploitation, changes
Formal name used at school claims: the chloro-N-of 2-(4'-chlordiphenyl-2-base) nicotiamide, molecular formula: C18H12Cl2N2O.Structural formula is such as
Under:
This antibacterial fungicidal spectrum is relatively wide, almost the most active to all types of fungal diseases, to prevent and treat powdery mildew,
Gray mold, sclerotiniose and various cankers etc. are highly effective, and also effective to the resistance bacterium of other medicaments, use
In Brassica campestris L, beans, corm vegetable, Caulis et Folium Brassicae junceae, Radix Dauci Sativae, Fructus Mali pumilae, Caulis et Folium Lactucae sativae, Semen arachidis hypogaeae, Rhizoma Solani tuber osi, drupe,
Fructus Fragariae Ananssae, nut, Caulis et Folium Brassicae capitatae, Fructus Cucumidis sativi, Herba Menthae, Semen Pisi sativi, roots vegetable, Helianthi, Fructus Vitis viniferae, lawn, other
The preventing and treating of the diseases such as fruit tree, vegetable, field crop；Owing to its distinctive mechanism of action is not likely to produce cross resistance,
In addition to crop safety and favourable toxicity data and ecological effect, it is the Novel tobacco amide-type sterilization of significant
Agent.
Prochloraz-manganese chloride complex (Prochloraz manganese), molecular formula: [C15H16Cl3N3O2]4MnCl2。
Chemical name: N-propyl group-N-[2-(2,4,6-Trichlorophenoxy) ethyl]-1H imidazoles-1-first
Amide-manganese chloride.Structural formula:
Imidazoles antibacterial, is worked by the biosynthesis of suppression sterol, has interior suction and pass in plant
Leading effect, the multiple diseases preventive effect caused for ascomycetes and Fungi Imperfecti is splendid.Fusing point 141-142.5 DEG C, water
Middle dissolubility is 40mg/L, is 7g/L in acetone, and vapour pressure is 0.02Pa (20 DEG C), in aqueous or outstanding
In supernatant liquid, this complex separates soon, and at 25 DEG C, its separating degree reached 55% in 4 hours.
But powdery mildew of cereals, gray mold, sclerotinia rot of colza and canker, garlic leaf blight, Alternaria alternate,
Botrytis cinerea, watermelon blight, mushroom wet bubble disease, grapevine anthracnose, Penicillium italicum, green mould, awns
Really the morbidity such as anthrax is more serious, causes catastrophic loss to agricultural production, although Boscalid, Prochloraz
Manganese salt single dose has an ideal prevention effect to Some Disease, but in actual applications, it has been found that phytopathy
The difficulty of prevention and cure of bacterium is increasing, and main cause has: one is as the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, difficult in preventing and treating
Degree strengthens；Two is that current climate is abnormal, provides certain condition to the outburst of disease；Three is chemical over a long time
The selectivity impact of medication so that the resistance of pathogen rises under lasting medicament selection pressure year by year, single dose
Prevention effect have a greatly reduced quality.In sum, current control of plant disease work faces challenges the most greatly.
Summary of the invention
It is an object of the invention to provide a kind of applied widely, low cost, effective for above-mentioned technical problem
Plant bactericidal composition containing Boscalid Yu prochloraz-manganese chloride complex.
It is a still further object of the present invention to provide this bactericidal composition to cause on fungal disease at preventing and treating plant epiphyte
Application, especially preventing and treating powdery mildew, gray mold, sclerotinia rot of colza and canker, garlic leaf blight, cigarette
Grass rust, Botrytis cinerea, watermelon blight, mushroom wet bubble disease, grapevine anthracnose, Penicillium italicum,
On the fungal disease such as green mould, mango anthracnose purposes.
It is an object of the invention to be realized by following measures:
A kind of bactericidal composition, with Boscalid with prochloraz-manganese chloride complex as effective ingredient, wherein Boscalid and miaow
Fresh amine manganese salt weight ratio is 1～70:1～50, and wherein in bactericidal composition, active ingredient exists with enhancing effective amount
In compositions.
Described bactericidal composition, wherein Boscalid and prochloraz-manganese chloride complex weight ratio are preferably 2～50:10～50,
Further preferred 2～5:10～50, further preferably 1:2～15, most preferably Boscalid and prochloraz-manganese chloride complex
Weight ratio is 1:2,1:4,1:6,1:10,1:15.
In some embodiments of the invention, the invention provides one and comprise Boscalid with Prochloraz as work
Property composition agrochemical composition, wherein the weight ratio of Boscalid and Prochloraz independent of each other for 1:5,
2.5:1、1:20、10:1、1:1、5:2、2:5、4:13、1:3.Through indoor biometrics experiment and field control effectiveness test,
These compositionss can produce synergistic function than Boscalid and Prochloraz single dose to fungal diseases of plants is equal.
In the compositions of the present invention, the percentage by weight accounting for compositions both Boscalid and prochloraz-manganese chloride complex is
2～80%.Preferably 14～55%.
Described bactericidal composition, wherein Boscalid becomes on pesticide with known additive compound with prochloraz-manganese chloride complex
Any one dosage form allowed.Auxiliary agent known to these has dispersant, diffusant, defoamer, wetting agent, collapses
Solve agent, excipient etc..Dispersant, diffusant, defoamer, wetting agent, disintegrating agent can use dodecyl
Benzenesulfonic acid calcium, alkylphenol polyoxyethylene, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fat
Polyoxyethylenated alcohol and similar products, aliphatic amine polyoxyethylene ether, fatty acid ethylene oxide addition product, polyoxy
Ethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, TWEEN Series,
Fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphorous
In hydrochlorate, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc. one or many
Individual combination.Excipient be selected from Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent (such as propylene glycol),
Deionized water etc..Above auxiliary agent and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion
Or water dispersion granule.
The application in terms of preventing and treating Cereal, fruit tree, vegetable crop disease of the described bactericidal composition.
Beneficial effects of the present invention:
1, the Boscalid used by the present invention is pyridines antibacterial, and prochloraz-manganese chloride complex is imidazoles antibacterial,
The mechanism of action is different, and mutual mixture will not produce low touching, can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating Cereal, fruit tree, the disease of vegetable,
Particularly prevent and treat powdery mildew, gray mold, sclerotinia rot of colza and canker, garlic leaf blight, Alternaria alternate,
Botrytis cinerea, watermelon blight, mushroom wet bubble disease, grapevine anthracnose, Penicillium italicum, green mould, awns
Really anthrax.Ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease are had by bactericidal composition of the present invention
Well prevention effect；And suppress insect or fungus to unitary agent (Boscalid and prochloraz-manganese chloride complex are arbitrary)
Drug-fast generation.
The bactericidal composition of the present invention application on preparation preventing and treating refractory fungal, is especially preventing and treating powdery mildew, ash
Mildew, sclerotinia rot of colza and canker, garlic leaf blight, Alternaria alternate, Botrytis cinerea, watermelon blight, mushroom are wet
Bubble disease, grapevine anthracnose, Penicillium italicum, green mould, the application of mango anthracnose all have significant effect.Above-mentioned kill
Bacteria composition can produce higher synergistic function, and the independent reactive compound of amount ratio of this mixture
Consumption is substantially reduced, and i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1) compared with single dose, said composition antagonism fungus
Disease such as powdery mildew, gray mold, sclerotinia rot of colza and canker, garlic leaf blight, Alternaria alternate, Fructus Capsici
Gray mold, watermelon blight, mushroom wet bubble disease, grapevine anthracnose, Penicillium italicum, green mould, Fructus Mangifera Indicae charcoal
The fungal diseases such as cellulitis is sick have obvious synergistic function, overcome and delayed Drug resistance, and expanding prevention is composed, hence it is evident that
Improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and be easily generated resistance
Pesticide；(4) compared with single dose, produce and use cost reduces；(5) the suppression drug-fast generation of fungus,
Its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is routine
Method, " % " of the present invention is mass percent.
Embodiment 1:
By Boscalid 5g, prochloraz-manganese chloride complex 10g, detergent LS (to methoxyl group fatty acid anilinesulfonic acid
Sodium) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g
Mixture carries out comminution by gas stream, and preparing effective ingredient weight percentage is 15% wettable powder.
Embodiment 2:
By Boscalid 3g, prochloraz-manganese chloride complex 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white
White carbon black 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, prepares effective ingredient weight percentage and is
15% wettable powder.
Embodiment 3:
By Boscalid 2g, prochloraz-manganese chloride complex 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white
White carbon black 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, prepares effective ingredient weight percentage and is
14% wettable powder.
Embodiment 4:
Weigh 5g Boscalid, 50g prochloraz-manganese chloride complex, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast
33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.By above raw material routinely
The method of preparation aqueous emulsion puts into the mixing of mixing kettle high speed, and making effective Ingredients Weight percentage composition is 55%
Boscalid-prochloraz-manganese chloride complex aqueous emulsion.
Embodiment 5:
Weigh 2g Boscalid, 30g prochloraz-manganese chloride complex, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyoxy
Vinyl Ether phosphate ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.
The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, makes effective Ingredients Weight percentage
Content is 32% Boscalid-prochloraz-manganese chloride complex microemulsion.
Embodiment 6:
Weigh 1g Boscalid, 5g prochloraz-manganese chloride complex, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast
33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.By above raw material routinely
The method of preparation aqueous emulsion puts into the mixing of mixing kettle high speed, and making effective Ingredients Weight percentage composition is 6% pyridine
Acyl bacterium amine-prochloraz-manganese chloride complex aqueous emulsion.
Embodiment 7:
Weigh 50g Boscalid, 20g prochloraz-manganese chloride complex, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyoxy
Vinyl Ether 2g, castor oil polyoxyethylene ether 2g, solvent naphtha to 100g.Above raw material is prepared cream routinely
Method put in mixing kettle and mix, making effective Ingredients Weight percentage composition is that 70% Boscalid-miaow is fresh
Amine manganese salt cream.
Embodiment 8:
Weigh 2g Boscalid, 40g prochloraz-manganese chloride complex, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyoxy
Vinyl Ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts in mixing kettle mixed
Closing, making effective Ingredients Weight percentage composition is 42% Boscalid-prochloraz-manganese chloride complex cream.
Embodiment 9:
Weigh 5g Boscalid, 20g prochloraz-manganese chloride complex, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyoxy
Vinyl Ether phosphate ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.
The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, makes effective Ingredients Weight percentage
Content is 25% Boscalid-prochloraz-manganese chloride complex microemulsion.
Embodiment 10:
Weigh 5g Boscalid, 0.5g prochloraz-manganese chloride complex, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyoxy
Vinyl Ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts in mixing kettle mixed
Closing, making effective Ingredients Weight percentage composition is 5.5% Boscalid-prochloraz-manganese chloride complex cream.
Embodiment 11:
Weigh 5g Boscalid, 30g prochloraz-manganese chloride complex, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyoxy
Vinyl Ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts in mixing kettle mixed
Closing, making effective Ingredients Weight percentage composition is 35% Boscalid-prochloraz-manganese chloride complex cream.
Embodiment 12:
Weigh 10g Boscalid, 10g prochloraz-manganese chloride complex, lignin 2g, polyoxyethylene poly-oxygen propylene aether and
Sulfate 4g, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, mend with water
Foot is to 100g, and making effective Ingredients Weight percentage composition under the effect of sand mill is 20% Boscalid-miaow
Fresh amine manganese salt suspension agent.
Embodiment 13:
Weigh 30g Boscalid, 12g prochloraz-manganese chloride complex, lignin 2g, polyoxyethylene poly-oxygen propylene aether and
Sulfate 4g, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, mend with water
Foot is to 100g, and making effective Ingredients Weight percentage composition under the effect of sand mill is 42% Boscalid-miaow
Fresh amine manganese salt suspension agent.
Embodiment 14:
Weigh 2g Boscalid, 5g prochloraz-manganese chloride complex, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g,
Ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, will be the most former
Expect that being formed with imitating Ingredients Weight percentage composition by water dispersible granular agent method is 7% Boscalid-prochloraz-manganese chloride complex
Brine dispersion granule.
Embodiment 15:
Weigh 4g Boscalid, 13g prochloraz-manganese chloride complex, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g,
Ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, kieselguhr 28g complement to 100g, and above raw material is pressed water
It is 17% Boscalid-prochloraz-manganese chloride complex moisture that discrete particles agent method is formed with imitating Ingredients Weight percentage composition
Scattered seed agent.
Embodiment 16:
Weigh 5g Boscalid, 15g prochloraz-manganese chloride complex, lignin 2g, polyoxyethylene poly-oxygen propylene aether and
Sulfate 4g, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, mend with water
Foot is to 100g, and making effective Ingredients Weight percentage composition under the effect of sand mill is 20% Boscalid-miaow
Fresh amine manganese salt suspension agent.
Embodiment 17:
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure different agents to bacterial strain (Sclerotinia
Sclerotiorum) EC50Value, uses co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture,
Determining the building performance of mixture, circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A single dose poison of proportion+B single dose in mixture of theoretical toxicity index=A single dose
Power index × B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is short of money when CTC is less than 80
Anti-, CTC is summation action between 80-120.
Table 1: the Boscalid+prochloraz-manganese chloride complex different ratio indoor biometrics result to sclerotinia rot of colza
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% Boscalid SC (A) | Y=2.1523X+3.4764 | 5.1036 | - |
| 50% prochloraz-manganese chloride complex WP (B) | Y=2.0047X+3.1773 | 8.1140 | - |
| A:B=1:2 | Y=1.5264X+3.6938 | 7.1731 | 150.29 |
| A:B=1:4 | Y=2.0020X+3.1807 | 8.1048 | 142.37 |
| A:B=1:6 | Y=1.4258X+3.7873 | 7.0882 | 167.85 |
| A:B=1:10 | Y=1.2215X+3.9081 | 7.832 | 156.32 |
| A:B=1:15 | Y=2.3021X+3.1077 | 6.637 | 187.45 |
Field control effectiveness test:
The pesticidal preparations preventing and treating sclerotinia rot of colza test prepared with above-described embodiment.
1, test processes: it is dense that this test medicine consumption sets three process respectively according to the difference of each composition
Degree, comparison medicament is pesticide single dose 50% prochloraz-manganese chloride complex WP and 25% Boscalid respectively
SC and blank clean water experiment.
2, test method: each plot area is 66.7m2, is repeated 3 times；Investigate before dispenser and prevent and treat
After investigation drug effect method be: test treatment region in randomization 5 point, according to country field
Between test relevant criterion and carry out severity Scaling, calculate preventive effect.
3, result of the test see table:
Being shown by indoor biometrics and field efficacy result, Boscalid and prochloraz-manganese chloride complex salt composite have substantially
Synergistic function, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, agricultural should
There is in using value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates with specific embodiment above
The preparation that two kinds of effective ingredient are processed into, but the preparation that these two kinds of active component can be processed is not limited only to above
Listed.
Claims (9)
1. a bactericidal composition, it is characterised in that with Boscalid and prochloraz-manganese chloride complex as effective ingredient, wherein Boscalid with
The weight ratio of prochloraz-manganese chloride complex is 1～70:1～50.
Bactericidal composition the most according to claim 1, it is characterised in that Boscalid with the weight ratio of prochloraz-manganese chloride complex is
2～50:10～50.
Bactericidal composition the most according to claim 2, is characterized in that the weight ratio of described Boscalid and prochloraz-manganese chloride complex
It is 2～5:10～50, preferably 1:2～15.
The most according to claim 1 containing Boscalid with the bactericidal composition of prochloraz-manganese chloride complex, it is characterized in that Boscalid
The weight percentage accounting for compositions with both prochloraz-manganese chloride complexes is 2-80%.
The most according to claim 4 containing Boscalid with the bactericidal composition of prochloraz-manganese chloride complex, it is characterized in that Boscalid
The weight percentage accounting for compositions with both prochloraz-manganese chloride complexes is 14-55%.
The most according to claim 1 containing Boscalid with the Synergistic bactericidal composition of prochloraz-manganese chloride complex, it is characterized in that with pyridine acyl
Bacterium amine and prochloraz-manganese chloride complex are any one dosage form that effective ingredient and insecticides adjuvant are configured on pesticide permission.
The most according to claim 6 containing Boscalid with the compound biocide composite of prochloraz-manganese chloride complex, it is characterized in that described dose
Type is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
8. the compound biocide composite containing Boscalid and prochloraz-manganese chloride complex described in claim 1 is true at preparation preventing and treating resistance plant
Application on fungus diseases.
Compound biocide composite containing Boscalid and prochloraz-manganese chloride complex the most according to claim 8 preparation prevent and treat powdery mildew,
Gray mold, sclerotinia rot of colza and canker, garlic leaf blight, Alternaria alternate, Botrytis cinerea, watermelon blight, mushroom are wet
Application on the fungal disease germ killing drugs such as bubble disease, grapevine anthracnose, Penicillium italicum, green mould, mango anthracnose.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510171881.8A CN106135252A (en) | 2015-04-13 | 2015-04-13 | A kind of containing Boscalid and the bactericidal composition of prochloraz-manganese chloride complex and application |
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| CN201510171881.8A CN106135252A (en) | 2015-04-13 | 2015-04-13 | A kind of containing Boscalid and the bactericidal composition of prochloraz-manganese chloride complex and application |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108552202A (en) * | 2018-05-23 | 2018-09-21 | 安徽国星生物化学有限公司 | A kind of bactericidal composition and its fungicide of prochloraz-manganese chloride complex and zoxamide |
| CN108703159A (en) * | 2018-07-23 | 2018-10-26 | 安徽华星化工有限公司 | A kind of composition pesticide containing nicosulfuron and Prochloraz |
| CN114128718A (en) * | 2021-11-09 | 2022-03-04 | 黑龙江八一农垦大学 | Pharmaceutical composition for preventing and treating sunflower sclerotinia rot |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007134778A2 (en) * | 2006-05-18 | 2007-11-29 | Bayer Cropscience Ag | Synergistic active ingredient combinations |
| CN101653139A (en) * | 2009-07-22 | 2010-02-24 | 深圳诺普信农化股份有限公司 | Compound bactericidal composition containing boscalid |
| CN103371184A (en) * | 2013-06-27 | 2013-10-30 | 王学权 | Fungicidal composition containing prochloraz manganese complex |
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2015
- 2015-04-13 CN CN201510171881.8A patent/CN106135252A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007134778A2 (en) * | 2006-05-18 | 2007-11-29 | Bayer Cropscience Ag | Synergistic active ingredient combinations |
| CN101653139A (en) * | 2009-07-22 | 2010-02-24 | 深圳诺普信农化股份有限公司 | Compound bactericidal composition containing boscalid |
| CN103371184A (en) * | 2013-06-27 | 2013-10-30 | 王学权 | Fungicidal composition containing prochloraz manganese complex |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108552202A (en) * | 2018-05-23 | 2018-09-21 | 安徽国星生物化学有限公司 | A kind of bactericidal composition and its fungicide of prochloraz-manganese chloride complex and zoxamide |
| CN108703159A (en) * | 2018-07-23 | 2018-10-26 | 安徽华星化工有限公司 | A kind of composition pesticide containing nicosulfuron and Prochloraz |
| CN114128718A (en) * | 2021-11-09 | 2022-03-04 | 黑龙江八一农垦大学 | Pharmaceutical composition for preventing and treating sunflower sclerotinia rot |
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