CN103371184A - Fungicidal composition containing prochloraz manganese complex - Google Patents
Fungicidal composition containing prochloraz manganese complex Download PDFInfo
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- CN103371184A CN103371184A CN2013102746680A CN201310274668A CN103371184A CN 103371184 A CN103371184 A CN 103371184A CN 2013102746680 A CN2013102746680 A CN 2013102746680A CN 201310274668 A CN201310274668 A CN 201310274668A CN 103371184 A CN103371184 A CN 103371184A
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- manganese chloride
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Abstract
The invention relates to a fungicidal composition containing a prochloraz manganese complex, belonging to the technical field of pesticides. The fungicidal composition comprises a raw pesticide compounded by a fungicide A and a fungicide B, wherein the mixture ratio of the fungicide A to the fungicide B is (1-90): (90:1); the fungicide A is the prochloraz manganese complex; and the fungicide B is any one type of the following fungicides: copper preparations, strobilurins, triazoles, amides, pyrimidinamines, benzimidazoles, thiocarbamates, dimethyl imides, imidazoles, morpholines, oxazoles, ureas, pyridines, pyrimidines, pyrroles, phthalimides, carbamates, antibiotics, heterocycles and others. The fungicidal composition disclosed by the invention contains the raw pesticide compounded by the prochloraz manganese complex and the fungicide B, and can expand the fungicidal spectrum, slow down the drug resistance of pathogenic bacteria and realize an obvious sustained synergistic effect.
Description
Technical field
The present invention relates to technical field of pesticide, specifically, relate to a kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound.
Background technology
Bactericide is for a class agricultural chemicals of preventing and treating the plant disease that is caused by various pathogenic microorganisms, refers generally to fungicide.But in the world, normally as the general name of medicament of all kinds of pathogenic microorganisms of control.Along with the development of bactericide, distinguish again the subclass such as bactericide, virucide, algicide.According to investigations, the whole world pathogenic microorganism (fungi, strong bacterium, rickettsia, mycoplasma, virus, algae etc.) harmful to plant has more than 80,000 kinds.Using bactericide is a kind of cost-effective method of controlling plant diseases.
Early stage bactericide all is inorganic compound, is wherein still using so far such as Cosan and copper agent (such as bordeaux mixture).Twentieth century four the fifties, developed the organosulfureous fungicides that three main series are arranged: the U.S. class of good fortune, generation gloomy class (such as zineb) and trichloro-methylthio diformazan carboxylic acid imide, organochlorine, organic mercury, organoarsenic fungicide also have development in addition.These bactericide are protectant mostly, and limitation is arranged in the application.Since the sixties, more the bactericide of polyvoltine type constantly occurs, and wherein most important progress is the appearance of systemic fungicide.Meanwhile, farm antibiotics also has faster development.Organic mercury, organo-arsenic and some organochlorine bactericide are because toxicity or problem of environmental pollution gradually are eliminated.The systemics bactericide of a new generation further enlarges the market of bactericide owing to control efficiency improves.To the eighties, the kind of bactericide is above 200 kinds.
Yet, in the real process of agricultural production, prevent and treat disease the problem of easy generation be the drug-fast generation of germ.The different cultivars composition carries out composite, is to prevent and treat the very common method of resistance germ.
Summary of the invention
The objective of the invention is to overcome the defective of prior art, a kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound is provided.
For addressing the above problem, the technical solution adopted in the present invention is:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-90:90-1 by bactericide A and the composite former medicine that forms of bactericide B;
Described bactericide A is the prochloraz-manganese chloride complex complex compound;
In the bactericide that described bactericide B is following classification any one: copper agent, methoxy acrylic, triazole type, amide-type, aminopyrimidine, benzimidazole, thiocarbamates, dicarboximide class, imidazoles, morpholine class, oxazole class, ureas, pyridines, miazines, pyroles, phthalimide class, carbamates, antibiotics, heterocyclic, and other classes.
Say further:
Described copper agent bactericide is any one in the following bactericide: Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper.
Described methoxy acrylic bactericide is any one in the following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Described triazole bactericidal agent is any one in the following bactericide: penta ring bacterium, bromuconazole, ether azoles, smart alkene azoles alcohol, oxole bacterium, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, acid amides azoles, cycltebuconazole, ring penta azoles mattress, nitrile bacterium azoles, imidazoles, paclobutrazol, penconazole, propiconazole, prothioconazoles, simeconazoles, Tebuconazole, fluorine ether azoles, triazolone, triadimenol, triticonazole, uniconazole P.
Described acid amide fungicides is any one in the following bactericide: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, isotianil, the third oxygen go out and embroider amine, metalaxyl, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil, ring propionamide, furan pyrrole acid amides, thiazole acid amides, silicon tisocromide, zarilamid.
Described imidazoles bactericide is any one in the following bactericide: Prochloraz, cyazofamid, imazalil, efficient imazalil, fluorine bacterium azoles, pefurazoate, Fenamidone, cyanogen azoles flusulfamide, allyl isothiazole.
Described morpholine series bactericidal agent is any one in the following bactericide: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine.
Described ureas bactericide is any one in the following bactericide: sodium dichloro cyanurate, sodium trichloro-isocyanurate, chlorobromide isocyanuric acid;
Described pyridines bactericide is any one in the following bactericide: pyrifenox, ring pyridine bacterium amine, Boscalid, fluopicolide, pyridine bacterium amine;
Described miazines bactericide is any one in the following bactericide: cyprodinil, fluorine mepanipyrim, ferimzone, phonetic mould amine, Fenarimol, nuarimol;
Described carbamate bactericide is any one in the following bactericide: the mould prestige of second, iprovalicarb, benzene metsulfovax, methasulfocarb;
Described antibiotics bactericide is any one in the following bactericide: pesticide corrosion 120, polyoxin, agricultural streptomycin, blasticidin-S, Polyoxin;
Described aminopyrimidine bactericide is any one in the following bactericide: methyl mepanipyrim, mepanipyrim, fluorine mepanipyrim, ring the third mepanipyrim;
Described thiocarbamates bactericide is any one in the following bactericide: zineb, Carbatene, tmtd, Isoprothiolane;
Described oxazole series bactericidal agent is any one in the following bactericide: Famoxate, SYP-Zo48, the mould spirit of evil, Wakil.
Described benzimidazole germicide is thiophanate methyl;
Described dicarboximide fungicide is iprodione, dimethachlon or procymidone;
Described pyroles bactericide is fenpiclonil or coughs up the mattress nitrile;
Described phthalimide series bactericidal agent is folpet;
Described heterocyclic nitrogen-group fungicide is the phonetic phenol of second or bupirimate.
Described other series bactericidal agents are Rabcide or Yekuzuo.
Furtherly, the proportioning of described bactericide A and bactericide B is: 2:1.
Again furtherly, described bactericide be missible oil, micro emulsion, water and milk, suspending agent (comprising: do outstanding, water is outstanding and oil outstanding), all formulations such as fumicants, pulvis, soluble liquid, wetting powder, granula, soluble powder, water dispersible granules or suspension emulsion.
Owing to adopted technique scheme, compared with prior art, include among the present invention by prochloraz-manganese chloride complex complex compound and the composite former medicine that forms of bactericide B, not only enlarged fungicidal spectrum, also slowed down the pesticide resistance of germ, have significantly lasting synergistic effect.
Embodiment
The present invention will be further described below in conjunction with embodiment.
The bactericidal composition that contains the prochloraz-manganese chloride complex complex compound of the present invention comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-90:90-1 by bactericide A and the composite former medicine that forms of bactericide B;
Described bactericide A is the prochloraz-manganese chloride complex complex compound;
In the bactericide that described bactericide B is following classification any one: copper agent, methoxy acrylic, triazole type, amide-type, aminopyrimidine, benzimidazole, thiocarbamates, dicarboximide class, imidazoles, morpholine class, oxazole class, ureas, pyridines, miazines, pyroles, phthalimide class, carbamates, antibiotics, heterocyclic, and other classes.
One of preferred as technique scheme, the proportioning of described bactericide A and bactericide B is: 2:1.
The prochloraz-manganese chloride complex complex compound has protection and eradicant action, and without systemic action, but the certain conductive performance of tool has special efficacy to the microbial plurality of plant diseases of ascus.Be applicable to crop and the fruit trees such as oranges and tangerines, mango such as mushroom, cucumber, Kidney bean, eggplant, pimento, garlic, watermelon, tobacco, can effectively prevent and treat: the diseases such as brown spot, white rot, dark green mildew, blossom-end rot, anthracnose, gray mold, fusarium wilt, early blight, leaf blight, leaf spot, stem wilt, purple spot.
Copper agent, all effective to fungi, bacterium, and do not have resistance, there is not volatility.Its sterilizing mechanisms is: moisture copper is to have bioactive copper, moisture copper discharges copper ion, act on a plurality of sites after copper ion is absorbed, cause nonspecific protein denaturation, and then cause three results: 1, the sprouting of the brood body of Antifungi and bacterium; 2, the growth of anti-bacteria; 3, stop the growth of mycelia.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper.
Methoxy acrylic bactericide (claiming Strobilurin abroad) is a kind of bionic fungicide, is a landmark disinfectant use in agriculture after benzimidazole and triazole type, at present, has become the very important bactericide of a class.It has very widely fungicidal spectrum, almost all known fungies are had control efficiency, and using dosage is low.Its mechanism of action all is to suppress mitochondrial respiration by the electronics transmission of blocking between cytochrome b and the cl, can effectively prevent and treat the pathogen series that other bactericide is produced resistance.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: Enestroburin, alkene oxime amine, azoles mattress ester, azoles amine bacterium ester, pyraclostrobin, fluoxastrobin, nitrile Fluoxastrobin, ether mattress ester, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Triazole bactericidal agent, common feature is on its chemical constitution, contains hydroxyl (ketone group), substituted-phenyl and 1,2,4-triazole group compound on the main chain.Triazole bactericidal agent is except to Mastigomycotina, the middle oomycetes non-activity, and the pathogen of Ascomycotina, Basidiomycotina and Deuteromycotina is all had activity, and its mechanism of action is damaged somatic cells film function for to affect the sterols biosynthesis.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: penta ring bacterium, bromuconazole, ether azoles, smart alkene azoles alcohol, oxole bacterium, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, nitrile bacterium azoles, imidazoles, paclobutrazol, penconazole, propiconazole, prothioconazoles, simeconazoles, Tebuconazole, fluorine ether azoles, triazolone, triadimenol, triticonazole, uniconazole P.
Acid amide fungicides is the organic compound that contains amide structure in the chemical constitution.Rust pathogen Uromyces, Puccinia and black rust pathogen Ustilago, Tilletia to the wheat class, and cause that crops such as tomato, eggplant, cucumber the soil fungis such as Rhizoctonia of root rot, fusarium wilt are effectively, effective especially to Basidiomycetes.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, isotianil, the third oxygen go out and embroider amine, metalaxyl, fenfuram, white spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil, ring propionamide, furan pyrrole acid amides, thiazole acid amides, silicon tisocromide, zarilamid.
The imidazoles bactericide is a class broad-spectrum germicide.This series bactericidal agent adopts is in the following bactericide any one: Prochloraz, cyazofamid, imazalil, efficient imazalil, fluorine bacterium azoles, pefurazoate, Fenamidone, cyanogen azoles flusulfamide, allyl isothiazole.
The morpholine series bactericidal agent is a series bactericidal agent that contains the morpholine ring structure, is the broad spectrum activity systemic fungicide with protection and therapeutic action.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine.
The ureas bactericide is extremely strong oxidant and chlorinating agent, has efficient, wide spectrum, safer disinfective action.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: sodium dichloro cyanurate, sodium trichloro-isocyanurate, chlorobromide isocyanuric acid.
The pyridines bactericide, among the present invention, this series bactericidal agent adopts is in the following bactericide any one: pyrifenox, ring pyridine bacterium amine, Boscalid, fluopicolide, pyridine bacterium amine.
The miazines bactericide is a kind of systemic fungicide, has the characteristics such as wide spectrum, efficient, low toxicity, low-residual; and with existing bactericide without cross resistance; sensitivity or resistance pathogen all there are excellent activity, have protection and result for the treatment of, the various diseases due to the Botrytis cinerea are had special efficacy.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: cyprodinil, fluorine mepanipyrim, ferimzone, phonetic mould amine, Fenarimol, nuarimol.
Carbamate fungicide belongs to the low toxicity bactericide, medicament enter behind the somatic cells with somatic cells in tubulin binding, thereby affect the division of cell.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: the mould prestige of second, iprovalicarb, benzene metsulfovax, methasulfocarb.
The antibiotics bactericide, deriving from the secondary metabolite of microorganisms and the bioactivator of generation is model, manually synthesizes or structure of modification, becomes artificial semisynthetic product.This series bactericidal agent have interior absorption energy, efficient, selectivity by force, effectively treatment and protective effect, and biological degradation is fast, and is nuisanceless, to advantages such as person poultry safeties.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: pesticide corrosion 120, polyoxin, agricultural streptomycin, blasticidin-S, Polyoxin.
The aminopyrimidine bactericide, this series bactericidal agent is very weak to the antibiotic property of germ in vitro, be used in the control efficiency of but doing well on the host plant, such medicament can suppress the biosynthesis of germ methionine and the secretion of cell wall degrading enzyme, invades parasitic plant thereby affect germ.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: methyl mepanipyrim, mepanipyrim, fluorine mepanipyrim, ring the third mepanipyrim.
Benzimidazole germicide, the class organic bactericide take benzimidazole ring that bactericidal activity is arranged as parent, nearly all this compounds all shows interior suction bactericidal activity.Among the present invention, what this series bactericidal agent adopted is thiophanate methyl.
The thiocarbamates bactericide, its main mechanism: (1) destroys COASH, thereby affects the oxidation of fatty acid; (2) activity of the enzyme of inhibition take copper, iron etc. as prothetic group.Among the present invention, this series bactericidal agent adopts is in the following bactericide any one: zineb, Carbatene, tmtd, Isoprothiolane.
Dicarboximide fungicide is a class broad-spectrum germicide, and spore germination, the mycelial growth of fungi all had inhibitory action, causes thalli morphology to change, and the mycelia top has produced abnormal branch and swelling.Among the present invention, what this series bactericidal agent adopted is iprodione, dimethachlon or procymidone.
The oxazole series bactericidal agent, among the present invention, this series bactericidal agent adopts is in the following bactericide any one: Famoxate, SYP-Zo48, the mould spirit of evil, Wakil.
The pyroles bactericide, the wide-spectrum bactericide of genus non-internal-absorting, by the relevant transfer of inhibition glucose phosphorylated, and the mycelial growth of Antifungi, finally cause germ dead.The mechanism of action is unique, with existing biocide agent without cross resistance.Among the present invention, what this series bactericidal agent adopted is fenpiclonil or fludioxonil.
The phthalimide series bactericidal agent, broad spectrum activity low toxicity bactericide take protective effect as main, has certain therapeutic action concurrently.Among the present invention, what this series bactericidal agent adopted is folpet.
Heterocyclic nitrogen-group fungicide, among the present invention, what this series bactericidal agent adopted is the phonetic phenol of second or bupirimate.The phonetic phenol of second is to the actual preventive effect of many crop powdery mildews such as strawberry, watermelon, cucumber, grape, safe in other imports or domestic like product to crop; Bupirimate, systemic fungicide, the powdery mildew that is mainly used in preventing and treating the crops such as apple, greenhouse rose and strawberry.
Other series bactericidal agents have adopted Rabcide or Yekuzuo among the present invention.
Embodiment 1:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of prochloraz-manganese chloride complex complex compound;
The former medicine 10% of Thiodiazole-copper;
Wetting agent 4%;
Dispersant 6%;
White carbon 4%;
Kaolin 56%.
Present embodiment is used for the control Cucumber Target Leaf Spot.The wetting powder of present embodiment is pressed 4000 extraordinarily water dilution sprayings, and 3 days control efficiency is 92.7% behind the medicine.By 2500 times, with the same method use, 3 days preventive effect is respectively 81.3% and 78.7% to 25% prochloraz-manganese chloride complex complex compound suspending agent behind the medicine by 1000 times and 50% Thiodiazole-copper wetting powder.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and Thiodiazole-copper is obvious, and significantly better than single dose, and because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces to the preventive effect of Cucumber Target Leaf Spot, thereby has alleviated the pollution to environment.
Embodiment 2:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 400% of prochloraz-manganese chloride complex complex compound;
The former medicine 3% of SYP-3375;
Wetting agent 4%;
Dispersant 4%;
White carbon 5%;
Emulsifier 10%.
Water 34%
Present embodiment is used for the control citrus anthracnose.The suspending agent of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 3 days control efficiency is 91.9% behind the medicine.25% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with 255g/L SYP-3375 suspending agent, uses with same method, and 3 days preventive effect is respectively 83.3% and 82.7% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and SYP-3375 is obvious, to the preventive effect of citrus anthracnose significantly better than single dose, and, because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 3:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 30% of prochloraz-manganese chloride complex complex compound;
Difenoconazole technical material 10%;
Emulsifier 12%;
Methyl alcohol 10%;
Dimethylbenzene 5%;
Water 33%.
Present embodiment is used for the control angular leaf spot.The aqueous emulsion of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 3 days control efficiency is 93.2% behind the medicine.40% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with the 255g/L Paclobutrazol suspension concentrate, uses with same method, and 3 days preventive effect is respectively 82.5% and 83.8% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and Difenoconazole is obvious, to the preventive effect of cucumber leaf rot significantly better than single dose, and, because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 4:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 40% of prochloraz-manganese chloride complex complex compound;
The former medicine 5% of pyraclostrobin;
Emulsifier 15%;
Methyl alcohol 8%;
Dimethylbenzene 5%;
Water 23%.
Present embodiment is used for the control rice blast.The aqueous emulsion of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 7 days control efficiency is 91.2% behind the medicine.By 2500 times, with the same method use, 7 days preventive effect is respectively 78.5% and 79.8% to 40% prochloraz-manganese chloride complex complex compound suspending agent behind the medicine by 1000 times and 25% pyraclostrobin suspending agent.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and pyraclostrobin is obvious, to the preventive effect of rice blast significantly better than single dose, and, because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 5:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of prochloraz-manganese chloride complex complex compound;
The former medicine 40% of imazalil;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 20%.
Present embodiment is used for control oranges and tangerines leaf spot.2500 extraordinarily water dilution sprayings are pressed in the wetting powder agent of present embodiment, and 7 days control efficiency is 93.2% behind the medicine.25% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with 255g/L imazalil suspending agent, uses with same method, and 7 days preventive effect is respectively 83.3% and 80.7% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and imazalil is obvious, and significantly better than single dose, and because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces to the preventive effect of oranges and tangerines leaf spot, thereby has alleviated the pollution to environment.
Embodiment 6:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of prochloraz-manganese chloride complex complex compound;
The former medicine 38% of tridemorph;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 22%.
Present embodiment is used for preventing and treating powdery mildew of cucumber.The wetting powder of present embodiment is pressed 2000 extraordinarily water dilution sprayings, and 7 days control efficiency is 93.7% behind the medicine.By 2500 times, with the same method use, 7 days preventive effect is respectively 81.3% and 83.2% to 25% prochloraz-manganese chloride complex complex compound suspending agent behind the medicine by 1000 times and 50% tridemorph wetting powder.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and tridemorph is obvious, to the preventive effect of Cucumber Target Leaf Spot significantly better than single dose, and, because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 7:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of prochloraz-manganese chloride complex complex compound;
The former medicine 42% of sodium dichloro cyanurate;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 18%.
It is sick that present embodiment is used for the control cucumber fusarium axysporum.The wetting powder of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 7 days control efficiency is 92.2% behind the medicine.40% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with 255g/L sodium dichloro cyanurate suspending agent, uses with same method, and 7 days preventive effect is respectively 82.5% and 79.6% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and sodium dichloro cyanurate is obvious, to the preventive effect of cucumber fusarium axysporum significantly better than single dose, and, because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 8:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of prochloraz-manganese chloride complex complex compound;
The former medicine 45% of pyridine bacterium amine;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 15%.
Present embodiment is used for control eggplant leaf spot.The wetting powder of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 7 days control efficiency is 90.2% behind the medicine.40% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with 255fL pyridine bacterium amine suspending agent, uses with same method, and 7 days preventive effect is respectively 78.5% and 81.8% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and pyridine bacterium amine is obvious, and significantly better than single dose, and because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces to the preventive effect of eggplant leaf spot, thereby has alleviated the pollution to environment.
Embodiment 9:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of prochloraz-manganese chloride complex complex compound;
The former medicine 15% of cyprodinil;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 45%.
Present embodiment is used for the control gray mold of cucumber.The wetting powder of present embodiment is pressed 2000 extraordinarily water dilution sprayings, and 7 days control efficiency is 93.9% behind the medicine.By 2500 times, with the same method use, 7 days preventive effect is respectively 81.3% and 80.9% to 25% prochloraz-manganese chloride complex complex compound suspending agent behind the medicine by 1000 times and 50% cyprodinil wetting powder.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and cyprodinil is obvious, to the preventive effect of gray mold of cucumber significantly better than single dose, and, because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 10:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of prochloraz-manganese chloride complex complex compound;
The former medicine 20% of polyoxin;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 40%.
Present embodiment is used for the control rice blast.The suspending agent of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 7 days control efficiency is 95.3% behind the medicine.25% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with 255g/L polyoxin suspending agent, uses with same method, and 7 days preventive effect is respectively 83.3% and 82.7% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and polyoxin is obvious, to the preventive effect of rice blast significantly better than single dose, and, because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 11:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of prochloraz-manganese chloride complex complex compound;
The former medicine 10% of thiophanate methyl;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 50%.
Present embodiment is used for the control angular leaf spot.The wetting powder of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 7 days control efficiency is 91.2% behind the medicine.40% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with 255g/L thiophanate methyl suspending agent, uses with same method, and 7 days preventive effect is respectively 82.5% and 78.9% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and thiophanate methyl is obvious, to the preventive effect of angular leaf spot significantly better than single dose, and, because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 12:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 22% of prochloraz-manganese chloride complex complex compound;
Isoprothiolane 20%;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 38%.
Present embodiment is used for the control rice blast.The wetting powder of present embodiment is pressed 1500 extraordinarily water dilution sprayings, and 7 days control efficiency is 91.9% behind the medicine.By 1000 times, with the same method use, 7 days preventive effect is respectively 81.3% and 79.2% to 25% prochloraz-manganese chloride complex complex compound suspending agent behind the medicine by 1000 times and 50% Isoprothiolane wetting powder.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and Isoprothiolane is obvious, and the preventive effect of rice blast is significantly better than single dose, and because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces, thereby has alleviated the pollution to environment.
Embodiment 13:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 32% of prochloraz-manganese chloride complex complex compound;
The former medicine 20% of dimethachlon;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 28%.
It is sick that present embodiment is used for the control sclerotinia rot of colza.The wetting powder of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 7 days control efficiency is 91.2% behind the medicine.40% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with 255g/L dimethachlon suspending agent, uses with same method, and 7 days preventive effect is respectively 78.5% and 80.8% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and dimethachlon is obvious, and significantly better than single dose, and because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces to the preventive effect of sclerotinia rot of colza, thereby has alleviated the pollution to environment.
Embodiment 14:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 32% of prochloraz-manganese chloride complex complex compound;
The former medicine 20% of the phonetic phenol of second;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 28%.
Present embodiment is used for control watermelon powdery mildew.The wetting powder of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 3 days control efficiency is 94.1% behind the medicine.25% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with the phonetic phenol suspending agent of 255g/L second, uses with same method, and 3 days preventive effect is respectively 83.3% and 81.7% behind the medicine.The composite rear synergistic effect of the phonetic phenol of prochloraz-manganese chloride complex complex compound and second is obvious, and significantly better than single dose, and because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces to the preventive effect of watermelon powdery mildew, thereby has alleviated the pollution to environment.
Embodiment 15:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 32% of prochloraz-manganese chloride complex complex compound;
The former medicine 10% of fludioxonil;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 38%.
Present embodiment is used for the control gray mold of cucumber.The wetting powder of present embodiment is pressed 4000 extraordinarily water dilution sprayings, and 7 days control efficiency is 92.9% behind the medicine.By 2500 times, with the same method use, 7 days preventive effect is respectively 81.3% and 77.5% to 25% prochloraz-manganese chloride complex complex compound suspending agent behind the medicine by 1000 times and 50% fludioxonil wetting powder.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and fludioxonil is obvious, and significantly better than single dose, and because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces to the preventive effect of gray mold of cucumber, thereby has alleviated the pollution to environment.
Embodiment 16:
A kind of bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 32% of prochloraz-manganese chloride complex complex compound;
The former medicine 10% of Yekuzuo;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 38%.
Present embodiment is used for control cucumber leaf rot.The aqueous emulsion of present embodiment is pressed 2500 extraordinarily water dilution sprayings, and 7 days control efficiency is 94.7% behind the medicine.40% prochloraz-manganese chloride complex complex compound suspending agent is pressed 1000 times by 1000 times with 255g/L Yekuzuo suspending agent, uses with same method, and 7 days preventive effect is respectively 82.5% and 83.2% behind the medicine.The composite rear synergistic effect of prochloraz-manganese chloride complex complex compound and Yekuzuo is obvious, and significantly better than single dose, and because pharmacy control efficacy improves, the amount ratio of compound drug active ingredient uses obviously separately and reduces to the preventive effect of cucumber leaf rot, thereby has alleviated the pollution to environment.
Claims (10)
1. bactericidal composition that contains the prochloraz-manganese chloride complex complex compound, it is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-90:90-1 by bactericide A and the composite former medicine that forms of bactericide B;
Described bactericide A is the prochloraz-manganese chloride complex complex compound;
In the bactericide that described bactericide B is following classification any one: copper agent, methoxy acrylic, triazole type, amide-type, aminopyrimidine, benzimidazole, thiocarbamates, dicarboximide class, imidazoles, morpholine class, oxazole class, ureas, pyridines, miazines, pyroles, phthalimide class, carbamates, antibiotics, heterocyclic, and other classes.
2. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1, it is characterized in that: described copper agent bactericide is any one in the following bactericide: Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper.
3. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1, it is characterized in that: described methoxy acrylic bactericide is any one in the following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
4. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1, it is characterized in that: described triazole bactericidal agent is any one in the following bactericide: penta ring bacterium, bromuconazole, ether azoles, smart alkene azoles alcohol, oxole bacterium, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, nitrile bacterium azoles, imidazoles, paclobutrazol, penconazole, propiconazole, prothioconazoles, simeconazoles, Tebuconazole, fluorine ether azoles, triazolone, triadimenol, triticonazole, uniconazole P.
5. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1, it is characterized in that: described acid amide fungicides is any one in the following bactericide: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, isotianil, the third oxygen go out and embroider amine, metalaxyl, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil, ring propionamide, furan pyrrole acid amides, thiazole acid amides, silicon tisocromide, zarilamid.
6. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1, it is characterized in that: described imidazoles bactericide is any one in the following bactericide: Prochloraz, cyazofamid, imazalil, efficient imazalil, fluorine bacterium azoles, pefurazoate, Fenamidone, cyanogen azoles flusulfamide, allyl isothiazole.
7. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1, it is characterized in that: described morpholine series bactericidal agent is any one in the following bactericide: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine.
8. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1 is characterized in that:
Described ureas bactericide is any one in the following bactericide: sodium dichloro cyanurate, sodium trichloro-isocyanurate, chlorobromide isocyanuric acid;
Described pyridines bactericide is any one in the following bactericide: pyrifenox, ring pyridine bacterium amine, Boscalid, fluopicolide, pyridine bacterium amine;
Described miazines bactericide is any one in the following bactericide: cyprodinil, fluorine mepanipyrim, ferimzone, phonetic mould amine, Fenarimol, nuarimol;
Described carbamate bactericide is any one in the following bactericide: the mould prestige of second, iprovalicarb, benzene metsulfovax, methasulfocarb;
Described antibiotics bactericide is any one in the following bactericide: pesticide corrosion 120, polyoxin, agricultural streptomycin, blasticidin-S, Polyoxin;
Described aminopyrimidine bactericide is any one in the following bactericide: methyl mepanipyrim, mepanipyrim, fluorine mepanipyrim, ring the third mepanipyrim;
Described thiocarbamates bactericide is any one in the following bactericide: zineb, Carbatene, tmtd, Isoprothiolane;
Described oxazole series bactericidal agent is any one in the following bactericide: Famoxate, SYP-Zo48, the mould spirit of evil, Wakil.
9. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1 is characterized in that:
Described benzimidazole germicide is thiophanate methyl;
Described dicarboximide fungicide is iprodione, dimethachlon or procymidone;
Described pyroles bactericide is fenpiclonil or fludioxonil;
Described phthalimide series bactericidal agent is folpet;
Described heterocyclic nitrogen-group fungicide is the phonetic phenol of second or bupirimate.
10. the bactericidal composition that contains the prochloraz-manganese chloride complex complex compound according to claim 1, it is characterized in that: described other series bactericidal agents are Rabcide or Yekuzuo.
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