CN105766957A - Sterilization composition containing triazoles fungicide and mancozeb - Google Patents

Sterilization composition containing triazoles fungicide and mancozeb Download PDF

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Publication number
CN105766957A
CN105766957A CN201610194974.7A CN201610194974A CN105766957A CN 105766957 A CN105766957 A CN 105766957A CN 201610194974 A CN201610194974 A CN 201610194974A CN 105766957 A CN105766957 A CN 105766957A
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CN
China
Prior art keywords
mancozeb
agent
bactericidal
bactericidal composition
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610194974.7A
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Chinese (zh)
Inventor
夏建国
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Taicang Dongjing Farm Professional Cooperatives
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Taicang Dongjing Farm Professional Cooperatives
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Priority to CN201610194974.7A priority Critical patent/CN105766957A/en
Publication of CN105766957A publication Critical patent/CN105766957A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14Di-thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a sterilization composition containing a triazoles fungicide and mancozeb. The sterilization composition is characterized in that active ingredients comprise triazoles fungicide and mancozeb, wherein the triazoles fungicide is selected from at least one of tetraconazole, tebuconazole, cyproconazole, diniconazole, flutriafol, hexakonazol and imibenconazole; and the weight ratio of triazoles fungicide to mancozeb ranges from (50:1) to (1:100). According to the sterilization composition, two types of the effective ingredients are combined so that the bactericidal spectrum is expanded and the resistance of bacteria is alleviated; the sterilization effect is remarkable and diseases of crops can be effectively prevented and treated; and compared with single dosages of the triazoles fungicide and the mancozeb, the production cost and the utilization cost are reduced, and the pesticide utilization cost of farmers is saved.

Description

A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb
Technical field
The present invention relates to technical field of pesticide, particularly to one containing triazole bactericidal agent and Mancozeb Bactericidal composition.
Background technology
Chemical agent is the important means of preventing and treating corps diseases, and along with the change of environment, crops The degree that virosis occurs increases the weight of, and must imitate by sterilizing pesticide although pesticide in the market serves Really, but still suffer from the defects such as bactericidal effect is poor, resistance increase, high residue.
Triazole bactericidal agent is organic heterocyclic compounds, and in chemical constitution, common feature is to contain on main chain There are hydroxyl (ketone group), substituted-phenyl and 1,2,4-triazole group compounds.Triazole bactericidal agent has height The features such as effect, wide spectrum, low-residual, lasting period length, interior absorption are strong, have protection concurrently, treat, root out And fumigation action.The antibacterial feature of triazole bactericidal agent be suppress in plant the appresorium of pathogenic bacteria, The normal development of haustorium, makes mycelial growth, the formation of spore is obstructed, and has Uptake and translocation, sprays Medicinal liquid, on crop, is the most i.e. absorbed, and typically through 2 hours, the dose of Crop can suppress The growth of Powdery Mildew.The root of plant can absorb triazolone, Triadimenol etc. and upwards be transmitted to overground part Point, utilize this feature, triazole type medicament to be commonly used for seed coat agent.After foliage-spray, can be from by medicine Position is to blade tip end transporting, and sheath, can be to the transporting of leaf portion by medicine.Triazole bactericidal agent kind is a lot, What Spread in China used has kind more than 20.
Mancozeb is a kind of wide spectrum, low toxicity, the protective fungicide of longevity of residure length.Former medicine is by for gloomy Manganese and zinc ion complexation form.The oxidation of acetone acid in its mechanism of action mainly suppression pathogenic bacteria body.It Mixed with other systemic fungicides, the generation of pathogenic bacteria resistance can be delayed, and to manganese, zinc deficiency There is therapeutical effect.To people, animal low toxicity, but skin and mucosa there is certain stimulation, to plant The safest.
Antibacterial kind containing single component often existing defects in crop disease control: make continuously With easily producing resistance, fungicidal spectrum is narrow, it is impossible to provide comprehensively protection, peasant's drug cost for crop High.Above-mentioned lacking can be overcome to a certain extent by the combination of two or more various active component Point.There is the combination mixture of two or more active component of potentiation, preventive effect can be improved, Reduce effective ingredient ground consumption, save peasant's drug cost, slow down Disease Resistance and occur, and can expand Preventing and treating spectrum.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of containing triazole bactericidal agent Bactericidal composition with Mancozeb.Two kinds of combination of active principles of described bactericidal composition use, and expand Fungicidal spectrum, slows down pathogenic bacteria resistance and occurs, and bactericidal effect is notable, it is possible to effectively prevent and treat crop disease Evil;And compared with triazole bactericidal agent and Mancozeb single dose, produce and use cost reduces, save Peasant's drug cost.
For reaching above-mentioned purpose, the technical scheme is that
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is triazole bactericidal agent and Mancozeb, described triazole bactericidal agent selected from tetraconazole, At least one in Tebuconazole, ring propanol azoles, enol azoles, powder alcohol azoles, hexanol azoles and glyoxalin, institute The weight ratio stating triazole bactericidal agent and Mancozeb is 50:1-1:100.
Further, the weight ratio of described triazole bactericidal agent and Mancozeb is 30:1-1:60.
Further, the weight ratio of described triazole bactericidal agent and Mancozeb is 1:20.
And have, described bactericidal composition is possibly together with dispersant, stabilizer, solvent, emulsifying agent, thickening One or more in agent.
Again, described triazole bactericidal agent and Mancozeb account for described bactericidal composition gross weight altogether 5%-70%.
Separately having, described triazole bactericidal agent and Mancozeb account for described bactericidal composition gross weight altogether 30%-50%.
Meanwhile, described bactericidal composition is prepared as wettable powder, suspending agent, dry powder doses, water-dispersible Any one in granule or cream.
The beneficial effects of the present invention is:
(1) what the present invention provided is a kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, and two Plant combination of active principles to use, expand fungicidal spectrum, slow down pathogenic bacteria resistance and occur, and bactericidal effect shows Write, it is possible to effectively prevent and treat corps diseases;
(2) what the present invention provided is a kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, with Triazole bactericidal agent is compared with Mancozeb single dose, produces and use cost reduces, save peasant's medication Cost.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with enforcement Example further describes.
Embodiment 1
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is hexanol azoles and Mancozeb, and the content of each composition is: hexanol azoles: 5%;Mancozeb: 0.1%.
Described bactericidal composition is possibly together with dispersant, solvent, emulsifying agent, thickening agent, described sterilization group Compound is prepared as wettable powder.
Embodiment 2
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is Tebuconazole and Mancozeb, and the content of each composition is: Tebuconazole: 10%;Maneb Zinc: 0.5%.
Described bactericidal composition is possibly together with dispersant, stabilizer, solvent, emulsifying agent, thickening agent, institute State bactericidal composition and be prepared as dry powder doses.
Embodiment 3
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is enol azoles and Mancozeb, and the content of each composition is: enol azoles: 20%;Maneb Zinc: 2%.
Described bactericidal composition is possibly together with dispersant, stabilizer, solvent, thickening agent, described sterilization group Compound is prepared as suspending agent.
Embodiment 4
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is ring propanol azoles and Mancozeb, and the content of each composition is: ring propanol azoles: 35%;Generation Gloomy MnZn: 35%.
Described bactericidal composition is possibly together with dispersant, stabilizer, solvent, emulsifying agent, thickening agent, institute State bactericidal composition and be prepared as water dispersible granules.
Embodiment 5
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is tetraconazole and Mancozeb, and the content of each composition is: tetraconazole: 1%;Dai Sen MnZn: 20%.
Described bactericidal composition is possibly together with dispersant, stabilizer, solvent, thickening agent, described sterilization group Compound is prepared as suspending agent.
Embodiment 6
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is glyoxalin and Mancozeb, and the content of each composition is: glyoxalin: 0.6%;Maneb Zinc: 30%.
Described bactericidal composition is possibly together with stabilizer, solvent, emulsifying agent, thickening agent, described sterilization group Compound is prepared as wettable powder.
Embodiment 7
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is hexanol azoles and Mancozeb, and the content of each composition is: hexanol azoles: 0.5%;Maneb Zinc: 40%.
Described bactericidal composition is possibly together with dispersant, stabilizer, solvent, emulsifying agent, thickening agent.Institute State bactericidal composition and be prepared as water dispersible granules.
Embodiment 8
A kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, in described bactericidal composition Active component is powder alcohol azoles and Mancozeb, and the content of each composition is: powder alcohol azoles: 0.5%;Maneb Zinc: 50%.
Described bactericidal composition is possibly together with dispersant, stabilizer, solvent, emulsifying agent, thickening agent, institute State bactericidal composition and be prepared as cream.
In order to the effect of bactericidal composition in embodiment 1-8 is tested, by above-mentioned bactericidal composition Even spraying after diluting 100 times, after medicine, 21 days rice sheath blight disease controlling results, are shown in Table 1.
The preventive effect of 21 days rice sheath blight diseases after bactericidal composition medicine in table 1 embodiment 1-8
Bactericidal composition Preventive effect (%)
Embodiment 1 90.7
Embodiment 2 90.2
Embodiment 3 86.8
Embodiment 4 90.5
Embodiment 5 87.6
Embodiment 6 90.2
Embodiment 7 88.9
Embodiment 8 89.1
As can be known from the above table, two kinds of combination of active principles of described bactericidal composition use, and bactericidal effect is notable, Slow down pathogenic bacteria resistance to occur;Additionally, compared with triazole bactericidal agent and Mancozeb single dose, produce and Use cost reduces, and saves peasant's drug cost.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted. Although being described in detail the present invention with reference to preferred embodiment, those of ordinary skill in the art should Work as understanding, the technical scheme of invention can be modified or equivalent, without deviating from the present invention The scope of technical scheme, it all should be contained in scope of the presently claimed invention.

Claims (7)

1. one kind contains triazole bactericidal agent and the bactericidal composition of Mancozeb, it is characterized in that, active component in described bactericidal composition is triazole bactericidal agent and Mancozeb, at least one in tetraconazole, Tebuconazole, ring propanol azoles, enol azoles, powder alcohol azoles, hexanol azoles and glyoxalin of described triazole bactericidal agent, the weight ratio of described triazole bactericidal agent and Mancozeb is 50:1-1:100.
The most according to claim 1 a kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, it is characterised in that the weight ratio of described triazole bactericidal agent and Mancozeb is 30:1-1:60.
The most according to claim 1 a kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, it is characterised in that the weight ratio of described triazole bactericidal agent and Mancozeb is 1:20.
The most according to claim 1 a kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, it is characterised in that described bactericidal composition is possibly together with one or more in dispersant, stabilizer, solvent, emulsifying agent, thickening agent.
The most according to claim 1 a kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, it is characterised in that described triazole bactericidal agent and Mancozeb account for the 5%-70% of described bactericidal composition gross weight altogether.
The most according to claim 1 a kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, it is characterised in that described triazole bactericidal agent and Mancozeb account for the 30%-50% of described bactericidal composition gross weight altogether.
The most according to claim 1 a kind of containing triazole bactericidal agent with the bactericidal composition of Mancozeb, it is characterised in that described bactericidal composition is prepared as any one in wettable powder, suspending agent, dry powder doses, water dispersible granules or cream.
CN201610194974.7A 2016-03-31 2016-03-31 Sterilization composition containing triazoles fungicide and mancozeb Pending CN105766957A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107736365A (en) * 2017-10-27 2018-02-27 王小艳 Bring up the incubation chamber sterilization liquid and preparation method thereof used of fry
CN107771835A (en) * 2017-10-27 2018-03-09 王小艳 Bring up bactericidal liquid used in the incubation chamber of fry
WO2024033949A1 (en) * 2022-08-12 2024-02-15 Indofil Industries Limited A synergistic fungicidal composition

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4584309A (en) * 1982-05-27 1986-04-22 Sumitomo Chemical Company, Limited Fungicidal compositions containing mixtures of a substituted triazole-1-penten-3-ol compound with other fungicides such as tetrachloroisophthalonitrile
CN1208560A (en) * 1998-07-01 1999-02-24 江苏省农药研究所 Olefine-contg. composite germicide wettability powder
CN1465249A (en) * 2002-06-30 2004-01-07 周耀德 Disinfectant for preventing and controlling apple ring spot and spot defoliation
WO2007128541A2 (en) * 2006-05-08 2007-11-15 Syngenta Participations Ag Pesticidal combinations comprising flutriafol
CN101700032A (en) * 2009-11-30 2010-05-05 青岛星牌作物科学有限公司 Bactericidal composition containing thiabendazole and application thereof
CN101779674A (en) * 2009-12-16 2010-07-21 陈章艳 Sterilization composition containing tetraconazole
CN101971839A (en) * 2010-11-21 2011-02-16 陕西美邦农药有限公司 Bactericidal composition containing cyproconazole
CN102057929A (en) * 2011-01-11 2011-05-18 陕西美邦农药有限公司 Bactericidal composition containing imibenconazole and thiocarbamate compound

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4584309A (en) * 1982-05-27 1986-04-22 Sumitomo Chemical Company, Limited Fungicidal compositions containing mixtures of a substituted triazole-1-penten-3-ol compound with other fungicides such as tetrachloroisophthalonitrile
CN1208560A (en) * 1998-07-01 1999-02-24 江苏省农药研究所 Olefine-contg. composite germicide wettability powder
CN1465249A (en) * 2002-06-30 2004-01-07 周耀德 Disinfectant for preventing and controlling apple ring spot and spot defoliation
WO2007128541A2 (en) * 2006-05-08 2007-11-15 Syngenta Participations Ag Pesticidal combinations comprising flutriafol
CN101700032A (en) * 2009-11-30 2010-05-05 青岛星牌作物科学有限公司 Bactericidal composition containing thiabendazole and application thereof
CN101779674A (en) * 2009-12-16 2010-07-21 陈章艳 Sterilization composition containing tetraconazole
CN101971839A (en) * 2010-11-21 2011-02-16 陕西美邦农药有限公司 Bactericidal composition containing cyproconazole
CN102057929A (en) * 2011-01-11 2011-05-18 陕西美邦农药有限公司 Bactericidal composition containing imibenconazole and thiocarbamate compound

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
WARNER, J.: "Field comparison of sterol-biosynthesis-inhibiting fungicides used alone and in combination with protectant fungicides for apple scab control.", 《PHYTOPROTECTION》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107736365A (en) * 2017-10-27 2018-02-27 王小艳 Bring up the incubation chamber sterilization liquid and preparation method thereof used of fry
CN107771835A (en) * 2017-10-27 2018-03-09 王小艳 Bring up bactericidal liquid used in the incubation chamber of fry
WO2024033949A1 (en) * 2022-08-12 2024-02-15 Indofil Industries Limited A synergistic fungicidal composition

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Application publication date: 20160720