CN101731248B - Penconazole-containing and thioneb-containing sterilizing composition - Google Patents
Penconazole-containing and thioneb-containing sterilizing composition Download PDFInfo
- Publication number
- CN101731248B CN101731248B CN 201010003069 CN201010003069A CN101731248B CN 101731248 B CN101731248 B CN 101731248B CN 201010003069 CN201010003069 CN 201010003069 CN 201010003069 A CN201010003069 A CN 201010003069A CN 101731248 B CN101731248 B CN 101731248B
- Authority
- CN
- China
- Prior art keywords
- penconazole
- zineb
- agent
- days
- bactericidal composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention relates to a sterilizing composition having the synergy effect, which comprises the active ingredients of penconazole and thioneb in a weight ratio of 1-40 to 80-1. A wettable powder, a water dispersible granule and a suspending agent can be prepared by adding an auxiliary agent and an excipient into the active ingredients, and are mainly used for preventing and controlling downy mildew, anthracnose, alternaria leaf spot of vegetables and fruit trees.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition that contains penconazole and zineb.
Technical background
Penconazole (penconazole) molecular formula: C13H15Cl2N3, chemical name: 1-[2-(2,4-dichlorophenyl)-4-propyl group-DOX-2-methyl]-1-hydrogen-1,2, the 4-triazole.
Penconazole belongs to three nitrogen heterocycles bactericide, is sterol demethylation inhibitor, destroys and stop the biosynthesis of the cell membrane important composition composition ergosterol of germ, causes cell membrane not form, and is that germ is dead.Root, stem, leaf isoreactivity tissue by crop absorb, and can upwards conduct with body fluid in the plant body soon.
Zineb (zineb), molecular formula are C
4H
6N
2S
4Zn, chemical name: zinc ethylenebisdithiocarbamate.
Zineb belongs to the benzene thiocarbamates; it is the protectant that a kind of foliage spray is used; to plant safety; the active ingredient chemical property is more active, easily is oxidized to different thiocyanation compound in water, to the cause of disease thalline contain-enzyme of SH base has strong inhibitory action; and the direct kill pathogens spore of energy; suppress the germination of spore, stop in the germ invaded plants body, but very little to the mycelial lethal effect of cause of disease in the invaded plants body.Therefore, use zineb to prevent and treat disease and should rest in the disease phase of beginning to see and carry out, just can obtain preferably effect.The drug effect phase of zineb is short, decomposes comparatively fast about 7 days of its longevity of residure behind the moisture in solar radiation and absorbing air.
No matter be penconazole, zineb or other efficient germicides, long-term separately use makes disease develop immunity to drugs easily, causes the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, and is unfavorable for environment sustainable development.The active ingredient of the different mechanisms of action is carried out composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is significantly filled a prescription, and can obviously improve preventive effect, greatly reduces the dosage of agricultural chemicals, also can enlarge fungicidal spectrum, improves germicidal efficiency.Penconazole is different from the zineb mechanism of action, and mutually composite have good synergistic effect within the specific limits.And composite about penconazole and zineb there is not yet relevant report at present at home and abroad.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition that contains penconazole and zineb.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains penconazole and zineb, wherein penconazole and zineb weight ratio are 1～40: 80～1.
The described bactericidal composition that contains penconazole and zineb, wherein the weight ratio of penconazole and zineb is 1～30: 70～10.
The described bactericidal composition that contains penconazole and zineb, wherein the weight ratio of penconazole and zineb is 1～20: 60～20.
The described bactericidal composition that contains penconazole and zineb, wherein the effective active component content accounts for 1～90% of gross weight, is preferably 10～80%.
The described bactericidal composition that contains penconazole and zineb is made wetting powder, water dispersible granules or suspending agent.
When making wetting powder, composition comprises following constituent content: penconazole 1～40%, zineb 1～80%, dispersant 5～10%, wetting agent 2～10%, filler 8～90%.
Penconazole, zineb, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, namely can be made into penconazole Zineb wettable powder product.
When making water dispersible granules, composition comprises following constituent content: penconazole 1～40%, zineb 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, filler 10～90%.
Penconazole, zineb, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through air-flow crushing together, obtain the materials of granulating.With item quantitatively send in the fluidized bed granulation dryer through granulation and drying after, make penconazole water dispersion granules agent of dithane product.
Comprise following constituent content when composition is made suspending agent: penconazole 1～40%, zineb 1～50%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in the above-mentioned formulation material are mixed through high speed shear, add penconazole, zineb, ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes penconazole zineb suspending agent product.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from: one or more in xanthan gum, polyvinyl alcohol, the polyethylene glycol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, the aluminium chloride.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), farming breast 1600
#In (phenethyl phenol polyoxy ethyl polypropylene-base ether), the ethylene oxide-propylene oxide block copolymer one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in preventing and treating downy mildew, anthracnose, the spot defoliation of vegetables and fruit tree.
Beneficial effect of the present invention: (1) present composition effective active composition penconazole and zineb belong to the bactericide of two kinds of different mechanisms of action, and both mutually are mixed and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single dose, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has special efficacy to downy mildew, anthracnose, the spot defoliation of vegetables and fruit tree.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.
Implementation of an application example one: penconazole and zineb are composite to the cucumber downy mildew Toxicity Determination
Test medicine provides by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation.
After each medicament establishment concentration range was determined in prerun, each medicament was established respectively 5 dosage by active constituent content and is processed, and established the clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt the mycelial growth rate method to measure medicament to the virulence of cucumber downy mildew.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates thus the EC of every kind of medicament
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively penconazole and zineb shared ratio in combination
A is penconazole
B is zineb
Result of the test is as shown in table 1:
Table 1 penconazole, zineb and composite toxicity test analysis of results table to cucumber downy mildew thereof
As shown in Table 1, penconazole, zineb are to the EC of cucumber downy mildew
50Be respectively 0.13mg/L and 56.28mg/L.The virulence of penconazole is higher than the virulence of zineb.1: 1,1: 5,1: 10,1: 15,1: 20 synergy ratio of penconazole and zineb proportioning is respectively 1.62,1.84,2.12,1.86,1.54, illustrating that penconazole and zineb were mixed in the scope at 1: 1～1: 20 all shows obvious synergistic effect, wherein synergy ratio SR is maximum when penconazole and zineb weight ratio are 1: 10, and synergistic effect is the most obvious.
Implementation of an application example two the implementation of Formulation Example
Embodiment 1 80% penconazole Zineb wettable powder
Penconazole 20%, zineb 60%, lignosulfonates 5%, neopelex 3%, soapberry powder 2%, white carbon 10%, mixture carries out air-flow crushing, makes 80% penconazole Zineb wettable powder.
Embodiment 2 65% penconazole Zineb wettable powders
Penconazole 30%, zineb 35%, polycarboxylate 5%, spaonin powder 3%, white carbon 7%, diatomite 20%, mixture carries out air-flow crushing, makes 65% penconazole Zineb wettable powder.
Embodiment 3 55% penconazole Zineb wettable powders
Penconazole 10%, zineb 45%, alkylphenol-polyethenoxy are phonetic 5%, wetting and penetrating agent F3%, white carbon 17%, bentonite 20%, and mixture carries out air-flow crushing, makes 55% penconazole Zineb wettable powder.
Embodiment 4 15% penconazole Zineb wettable powders
Penconazole 5%, zineb 10%, lignosulfonates 5%, neopelex 3%, white carbon 17%, bentonite 60%, mixture carries out air-flow crushing, makes 15% penconazole Zineb wettable powder.
Embodiment 5 80% penconazole water dispersion granules agent of dithane
Penconazole 10%, zineb 70%, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, starch 10%, mix making 80% penconazole water dispersion granules agent of dithane.
Embodiment 6 70% penconazole water dispersion granules agent of dithane
Penconazole 20%, zineb 50%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 7%, kaolin 10% mix making 70% penconazole water dispersion granules agent of dithane.
Embodiment 7 50% penconazole water dispersion granules agent of dithane
Penconazole 4%, zineb 46%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 20%, bentonite 22%, mix making 50% penconazole water dispersion granules agent of dithane.
Embodiment 8 43% penconazole water dispersion granules agent of dithane
Penconazole 3%, zineb 40%, alkylphenol-polyethenoxy are phonetic 4%, DBSA 4%, starch 15%, diatomite 34%, mix making 43% penconazole water dispersion granules agent of dithane.
Embodiment 9 48% penconazole zineb suspending agents
Penconazole 8%, zineb 40%, alkyl benzene sulfonate calcium salt 5%, Sodium Polyacrylate 2%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, phenyl phenol polyoxy ethyl ether 2%, deionized water adds to 100%, mixes to make 48% penconazole zineb suspending agent.
Embodiment 10 30% penconazole zineb suspending agents
Penconazole 6%, zineb 24%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, alkyl benzene calcium sulfonate 2%, deionized water adds to 100%, mixes to make 30% penconazole zineb suspending agent.
Embodiment 11 22% penconazole zineb suspending agents
Penconazole 2%, zineb 20%, polycarboxylate 2%, neopelex 2%, silicone compound 0.1%, polyethylene glycol 0.5%, glycerine 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, mixes to make 22% penconazole zineb suspending agent.
Embodiment 12 10% penconazole zineb suspending agents
Penconazole 5%, zineb 5%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, mixes to make 10% penconazole zineb suspending agent.
Embodiment uses three penconazoles and zineb and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
This experimental establishment is in Luochuan County suburb, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 80% Zineb wettable powder (commercial), 10% penconazole missible oil (commercial).
The investigation alternaria leaf spot of apple state of an illness before the medicine, in for the first time dispenser of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 3 times.Investigated respectively alternaria leaf spot of apple feelings index and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
Table 2 penconazole, zineb and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
| Treatment agent | Extension rate | 7 days preventive effects (%) behind the last medicine | 14 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 80% penconazole Zineb wettable powder | 6000 times | 89.16 | 95.62 | 93.17 |
| 70% penconazole water dispersion granules agent of dithane | 5000 times | 90.17 | 96.82 | 94.21 |
| 30% penconazole zineb suspending agent | 1500 times | 88.92 | 94.46 | 92.21 |
| 80% Zineb wettable powder | 400 times | 60.13 | 6.5.11 | 62.81 |
| 10% penconazole missible oil | 2000 times | 71.51 | 78.64 | 76.18 |
As can be seen from Table 2, can effectively prevent and treat alternaria leaf spot of apple after penconazole and zineb are composite, control efficiency all is better than contrasting medicament, and the lasting period is long.In the test scope of medication target crop is had no adverse effects, and the apple snow mildew is had good preventive effect, preventive effect reaches more than 91%.
Implementation of an application example four: penconazole and zineb and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in suburb, Ningxia Province Yinchuan City, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 80% Zineb wettable powder (commercial), 10% penconazole missible oil (commercial).
The investigation downy mildew of garpe state of an illness before the medicine, in for the first time dispenser of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated respectively the downy mildew of garpe disease index and calculated preventive effect in 7 days, 14 days, 30 days after for the second time dispenser.Experimental result is as follows:
Table 3 penconazole, zineb and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
| Treatment agent | Extension rate | 7 days preventive effects (%) behind the last medicine | 14 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 65% penconazole Zineb wettable powder | 6500 times | 88.36 | 95.05 | 95.06 |
| 50% penconazole water dispersion granules agent of dithane | 1500 times | 89.54 | 96.16 | 95.85 |
| 22% penconazole zineb suspending agent | 500 times | 88.55 | 94.91 | 93.27 |
| 80% Zineb wettable powder | 450 times | 63.28 | 66.30 | 65.38 |
| 10% penconazole missible oil | 2000 times | 75.36 | 82.42 | 81.42 |
As can be seen from Table 3, energy effectively preventing downy mildew of garpe after penconazole and zineb are composite, control efficiency all is better than contrasting medicament, and dosage is little, and the lasting period is long.The test scope of medication in to the target crop without harm.
Implementation of an application example five: penconazole, zineb and the composite control cucumber anthracnose test of pesticide effectiveness thereof
This experimental establishment is in area just outside a city gate town, Qian County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 80% Zineb wettable powder (commercial), 10% penconazole missible oil (commercial).
Investigation cucumber anthracnose state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates respectively disease index and calculates preventive effect in 7 days, 14 days after for the second time dispenser.Experimental result is as follows:
Table 4 penconazole, zineb and the composite control cucumber anthracnose test of pesticide effectiveness thereof
| Treatment agent | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 55% penconazole Zineb wettable powder | 12 g/acres | 89.75 | 94.35 |
| 80% penconazole water dispersion granules agent of dithane | 10 g/acres | 90.37 | 95.37 |
| 48% penconazole zineb suspending agent | 18 g/acres | 91.62 | 96.58 |
| 80% Zineb wettable powder | 70 g/acres | 63.44 | 65.34 |
| 10% penconazole missible oil | 12 g/acres | 80.34 | 85.35 |
As can be seen from Table 4, can effectively prevent and treat cucumber anthracnose after penconazole and zineb are composite and occur, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects, and cucumber downy mildew had good preventive effect, preventive effect reaches more than 91%.
Implementation of an application example six: penconazole, zineb and the composite control Chinese cabbage downy mildew test of pesticide effectiveness thereof
This experimental establishment is in the Gaoling County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 80% Zineb wettable powder (commercial), 10% penconazole missible oil (commercial).
Investigation Chinese cabbage downy mildew state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates respectively disease index and calculates preventive effect in 7 days, 14 days after for the second time dispenser.Experimental result is as follows:
Table 5 penconazole, zineb and the composite control Chinese cabbage downy mildew test of pesticide effectiveness thereof
| Treatment agent | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 15% penconazole Zineb wettable powder | 25 g/acres | 90.72 | 95.08 |
| 43% penconazole water dispersion granules agent of dithane | 22 g/acres | 91.38 | 96.43 |
| 10% penconazole zineb suspending agent | 25 g/acres | 89.53 | 94.83 |
| 80% Zineb wettable powder | 75 g/acres | 68.41 | 74.34 |
| 10% penconazole missible oil | 12 g/acres | 79.57 | 85.83 |
As can be seen from Table 5, can effectively prevent and treat Chinese cabbage downy mildew after penconazole and zineb are composite and occur, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects.
Claims (4)
1. bactericidal composition that contains penconazole and zineb, the weight ratio that it is characterized in that bactericidal composition effective active composition penconazole and zineb is 30: 35～1: 5 or 1: 7 or 4: 46～1: 15.
2. the bactericidal composition that contains penconazole and zineb according to claim 1, it is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight.
3. the bactericidal composition that contains penconazole and zineb according to claim 2, it is characterized in that: wherein the effective active component content accounts for 10～80% of gross weight.
4. the bactericidal composition that contains penconazole and zineb according to claim 1, it is characterized in that: bactericidal composition is made wetting powder, water dispersible granules or suspending agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010003069 CN101731248B (en) | 2010-01-05 | 2010-01-05 | Penconazole-containing and thioneb-containing sterilizing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010003069 CN101731248B (en) | 2010-01-05 | 2010-01-05 | Penconazole-containing and thioneb-containing sterilizing composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101731248A CN101731248A (en) | 2010-06-16 |
| CN101731248B true CN101731248B (en) | 2013-04-10 |
Family
ID=42455660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010003069 Expired - Fee Related CN101731248B (en) | 2010-01-05 | 2010-01-05 | Penconazole-containing and thioneb-containing sterilizing composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101731248B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104705322A (en) * | 2013-12-12 | 2015-06-17 | 南京华洲药业有限公司 | Sterilization composition containing penconazole and ambam and use thereof |
| CN106386828A (en) * | 2016-08-31 | 2017-02-15 | 柳州市惠农化工有限公司 | Pesticide composition containing C9H6Cl2N2O3S and zineb |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1325268A (en) * | 1998-11-06 | 2001-12-05 | 辛根塔参与股份公司 | Fungicidal combinations comprising thieno [2,3-d] pyrimidin-4-one |
| CN101087529A (en) * | 2004-12-23 | 2007-12-12 | 巴斯福股份公司 | Fungicidal mixtures |
| CN101779677A (en) * | 2009-12-16 | 2010-07-21 | 陈章艳 | Sterilization composition containing penconazole |
-
2010
- 2010-01-05 CN CN 201010003069 patent/CN101731248B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1325268A (en) * | 1998-11-06 | 2001-12-05 | 辛根塔参与股份公司 | Fungicidal combinations comprising thieno [2,3-d] pyrimidin-4-one |
| CN101087529A (en) * | 2004-12-23 | 2007-12-12 | 巴斯福股份公司 | Fungicidal mixtures |
| CN101779677A (en) * | 2009-12-16 | 2010-07-21 | 陈章艳 | Sterilization composition containing penconazole |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101731248A (en) | 2010-06-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101790986B (en) | Fungicide composite containing tricyclazole and hexaconazole | |
| CN101971837A (en) | Antibacterial composition containing kasugamycin and mancozeb | |
| CN101731226B (en) | Bactericidal composition containing ethirimol and penconazole | |
| CN101731248B (en) | Penconazole-containing and thioneb-containing sterilizing composition | |
| CN102017966B (en) | Kasugamycin and propineb-containing bactericidal composition | |
| CN101731247B (en) | Penconazole-containing and thioneb-containing sterilizing composition | |
| CN101999364A (en) | Hexaconazole-containing germicide composition | |
| CN101720774B (en) | Bactericide composition containing penconazole and propineb | |
| CN101897336B (en) | Bactericidal composition containing imazalil and penconazole | |
| CN101743973B (en) | Bactericidal composition containing penconazole and chlorothalonil | |
| CN101755792B (en) | Fungicidal composition containing kresoxim methyl and thiophanate methyl | |
| CN101715767B (en) | Bactericidal composition containing kresoxim-methyl and penconazole | |
| CN101755781B (en) | Fungicidal composition containing penconazole and carbendazim | |
| CN101715772B (en) | Bactericidal composition containing carbendazim and ethirimol | |
| CN101697720B (en) | Bactericide composition containing ethirimol and kresoxim | |
| CN101779632B (en) | Bactericidal composite containing phenol cycloheximide and ethirimol | |
| CN101953343B (en) | Bactericidal composition containing imazalil and myclobutanil | |
| CN101878762B (en) | Fungicide composition containing imazalil and hexaconazole | |
| CN102017951B (en) | Germicide composition containing cyproconazole and chlorothalonil | |
| CN101779649A (en) | Bactericidal composite containing phenol cycloheximide and thiophanate-methyl | |
| CN101874488B (en) | Bactericide composition containing imazalil and cyazofamid | |
| CN101779656B (en) | Bactericidal composite containing flusilazole and kresoxim-methyl | |
| CN101773125A (en) | Bactericidal composition containing dithianon and penconazole | |
| CN101773126A (en) | Bactericidal composition containing azoxystrobin and penconazole | |
| CN101971816B (en) | Sterilizing composition containing cyproconazole and dithianon |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130410 Termination date: 20170105 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |