CN101743973B - Bactericidal composition containing penconazole and chlorothalonil - Google Patents
Bactericidal composition containing penconazole and chlorothalonil Download PDFInfo
- Publication number
- CN101743973B CN101743973B CN 201010003088 CN201010003088A CN101743973B CN 101743973 B CN101743973 B CN 101743973B CN 201010003088 CN201010003088 CN 201010003088 CN 201010003088 A CN201010003088 A CN 201010003088A CN 101743973 B CN101743973 B CN 101743973B
- Authority
- CN
- China
- Prior art keywords
- penconazole
- tpn
- chlorothalonil
- bactericidal composition
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention relates to a bactericide composition with synergy. The composition contains penconazole and chlorothalonil serving as effective active components, wherein the weight ratio of penconazole to chlorothalonil is 1-40:80-1, and the effective active components is added with additives and excipient and prepared into wet powder, water dispersible granules or suspending agents. The composition is mainly used to prevent and control powdery mildew, downy mildew, anthracnose, ring spot and scab of vegetables and fruit trees.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition that contains penconazole and tpn.
Technical background
Penconazole (penconazole), molecular formula: C
13H
15Cl
2N
3, chemical name: 1-[2-(2,4-dichlorophenyl)-4-propyl group-DOX-2-methyl]-1-hydrogen-1,2, the 4-triazole.
Penconazole belongs to three nitrogen heterocycles bactericide, is sterol demethylation inhibitor, destroys and stop the biosynthesis of the cell membrane important composition composition ergosterol of germ, causes cell membrane not form, and is that germ is dead.Root, stem, leaf isoreactivity tissue by crop absorb, and can upwards conduct with body fluid in the plant body soon.
Tpn (chlorothalonil), molecular formula: C
8Cl
4N
2Chemical name: daconil M (2,4,5,6-tetrachloro-1,3-benzene dicarbonitrile).
Tpn can with the fungal cell in glyceraldehyde 3-phosphate dehydro-genase in the combined with protein of cysteine, destroy the metabolism of cell and loss of life power.Its Main Function is the prevention fungal infection, does not have interior suction conduction, but at plant surface good adhesivity is arranged, and is not subject to rain drop erosion, and the long drug effect phase is arranged.
No matter be penconazole, tpn or other efficient germicides, long-term separately use makes disease develop immunity to drugs easily, causes the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, and is unfavorable for environment sustainable development.The active ingredient of the different mechanisms of action is carried out composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is significantly filled a prescription, and can obviously improve preventive effect, greatly reduces the dosage of agricultural chemicals, also can enlarge fungicidal spectrum, improves germicidal efficiency.Penconazole is different from the tpn mechanism of action, and mutually composite have good synergistic effect within the specific limits.And composite about penconazole and tpn there is not yet relevant report at present at home and abroad.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition that contains penconazole and tpn.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains penconazole and tpn, wherein penconazole and tpn weight ratio are 1～40: 80～1.
The described bactericidal composition that contains penconazole and tpn, wherein the weight ratio of penconazole and tpn is 1～30: 70～10.
The described bactericidal composition that contains penconazole and tpn, wherein the weight ratio of penconazole and tpn is 1～20: 60～20.
The described bactericidal composition that contains penconazole and tpn, wherein the effective active component content accounts for 1～90% of gross weight, is preferably 10～80%.
The described bactericidal composition that contains penconazole and tpn is made wetting powder, water dispersible granules or suspending agent.
When making wetting powder, composition comprises following constituent content: penconazole 1～40%, tpn 1～80%, dispersant 5～10%, wetting agent 2～10%, filler 8～90%.
Penconazole, tpn, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, namely can be made into penconazole tpn wetting powder product.
When making water dispersible granules, composition comprises following constituent content: penconazole 1～40%, tpn 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, filler 10～90%.
Penconazole, tpn, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through air-flow crushing together, obtain the materials of granulating.With item quantitatively send in the fluidized bed granulation dryer through granulation and drying after, make penconazole chlorothalonil water dispersible granule product.
Comprise following constituent content when composition is made suspending agent: penconazole 1～30%, tpn 1～50%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in the above-mentioned formulation material are mixed through high speed shear, add penconazole, tpn, ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes penconazole tpn suspending agent product.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from: one or more in xanthan gum, polyvinyl alcohol, the polyethylene glycol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, the aluminium chloride.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), farming breast 1600
#In (phenethyl phenol polyoxy ethyl polypropylene-base ether), the ethylene oxide-propylene oxide block copolymer one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in preventing and treating powdery mildew, downy mildew, anthracnose, ring spot, the scab of vegetables and fruit tree.
Beneficial effect of the present invention: (1) present composition effective active composition penconazole and tpn belong to the bactericide of two kinds of different mechanisms of action, and both mutually are mixed and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single dose, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has special efficacy to powdery mildew, downy mildew, anthracnose, ring spot, the scab of vegetables and fruit tree.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Implementation of an application example one: penconazole and chlorothalonil compound are to the cucumber downy mildew Toxicity Determination
Test medicine provides by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation.
After each medicament establishment concentration range was determined in prerun, each medicament was established respectively 5 dosage by active constituent content and is processed, and established the clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt the mycelial growth rate method to measure medicament to the virulence of cucumber downy mildew.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates thus the EC of every kind of medicament
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively penconazole and tpn shared ratio in combination
A is penconazole
B is tpn
Result of the test is as shown in table 1:
Table 1 penconazole, tpn and composite toxicity test analysis of results table to cucumber downy mildew thereof
As shown in Table 1, penconazole, tpn are to the EC of powdery mildew of cucumber
50Be respectively 0.13mg/L and 55.24mg/L.The virulence of penconazole is higher than the virulence of tpn.1: 1,1: 10,1: 20,1: 30,1: 40 synergy ratio of penconazole and tpn proportioning is respectively 1.62,1.94,2.10,1.84,1.55, illustrating that penconazole and tpn were mixed in the scope at 1: 1～1: 40 all shows obvious synergistic effect, wherein synergy ratio SR is maximum when penconazole and tpn weight ratio are 1: 20, and synergistic effect is the most obvious.
Implementation of an application example two the implementation of Formulation Example
Embodiment 1 80% penconazole tpn wetting powder
Penconazole 20%, tpn 60%, lignosulfonates 5%, neopelex 3%, spaonin powder 2%, white carbon 10%, mixture carries out air-flow crushing, makes 80% penconazole tpn wetting powder.
Embodiment 2 65% penconazole tpn wetting powders
Penconazole 30%, tpn 35%, polycarboxylate 5%, soapberry powder 3%, white carbon 7%, diatomite 20%, mixture carries out air-flow crushing, makes 65% penconazole tpn wetting powder.
Embodiment 3 55% penconazole tpn wetting powders
Penconazole 10%, tpn 45%, alkylphenol-polyethenoxy are phonetic 5%, wetting and penetrating agent F3%, white carbon 17%, bentonite 20%, and mixture carries out air-flow crushing, makes 55% penconazole tpn wetting powder.
Embodiment 4 15% penconazole tpn wetting powders
Penconazole 5%, tpn 10%, lignosulfonates 5%, neopelex 3%, white carbon 17%, bentonite 60%, mixture carries out air-flow crushing, makes 15% penconazole tpn wetting powder.
Embodiment 5 80% penconazole chlorothalonil water dispersible granules
Penconazole 10%, tpn 70%, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, starch 10%, mix making 80% penconazole chlorothalonil water dispersible granule.
Embodiment 6 70% penconazole chlorothalonil water dispersible granules
Penconazole 15%, tpn 55%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 7%, kaolin 10% mix making 70% penconazole chlorothalonil water dispersible granule.
Embodiment 7 50% penconazole chlorothalonil water dispersible granules
Penconazole 4%, tpn 46%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 20%, bentonite 22%, mix making 50% penconazole chlorothalonil water dispersible granule.
Embodiment 8 43% penconazole chlorothalonil water dispersible granules
Penconazole 3%, tpn 40%, alkylphenol-polyethenoxy are phonetic 4%, DBSA 4%, starch 15%, diatomite 34%, mix making 43% penconazole chlorothalonil water dispersible granule.
Embodiment 9 48% penconazole tpn suspending agents
Penconazole 8%, tpn 40%, polycarboxylate 5%, Sodium Polyacrylate 2%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, phenyl phenol polyoxy ethyl ether 2%, deionized water adds to 100%, mixes to make 48% penconazole tpn suspending agent.
Embodiment 10 30% penconazole tpn suspending agents
Penconazole 6%, tpn 24%, alkyl benzene sulfonate calcium salt 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, alkyl benzene calcium sulfonate 2%, deionized water adds to 100%, mixes to make 30% penconazole tpn suspending agent.
Embodiment 11 22% penconazole tpn suspending agents
Penconazole 2%, tpn 20%, polycarboxylate 2%, neopelex 2%, silicone compound 0.1%, polyethylene glycol 0.5%, glycerine 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, mixes to make 22% penconazole tpn suspending agent.
Embodiment 12 10% penconazole tpn suspending agents
Penconazole 5%, tpn 5%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, mixes to make 10% penconazole tpn suspending agent.
Embodiment uses three penconazoles and tpn and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Luochuan County suburb, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 75% tpn wetting powder (commercial), 10% penconazole missible oil (commercial).
The investigation apple mildew state of an illness before the medicine, in for the first time dispenser of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 3 times.Investigated respectively apple mildew feelings index and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
Table 2 penconazole, tpn and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
| Treatment agent | Extension rate | 7 days preventive effects (%) behind the last medicine | 14 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 80% penconazole tpn wetting powder | 6000 times | 88.57 | 94.86 | 93.24 |
| 70% penconazole chlorothalonil water dispersible granule | 4000 times | 90.23 | 96.33 | 94.83 |
| 30% penconazole tpn suspending agent | 1500 times | 88.52 | 94.28 | 92.53 |
| 75% tpn wetting powder | 700 times | 63.13 | 65.48 | 62.35 |
| 10% penconazole missible oil | 2000 times | 74.51 | 80.64 | 78.58 |
As can be seen from Table 2, can effectively prevent and treat apple mildew behind penconazole and the chlorothalonil compound, control efficiency all is better than contrasting medicament, and the lasting period is long.In the test scope of medication target crop is had no adverse effects, and ring rot of apple is had good preventive effect, preventive effect reaches more than 91%.
Implementation of an application example four: penconazole and tpn and the composite pear scab test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is at Shaanxi Province's Weinan City Pucheng County, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 75% tpn wetting powder (commercial), 10% penconazole missible oil (commercial).
The investigation pear scab state of an illness before the medicine, in for the first time dispenser of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 3 times.Investigated respectively the pear scab disease index and calculated preventive effect in 7 days, 14 days, 30 days after for the second time dispenser.Experimental result is as follows:
Table 3 penconazole, tpn and the composite pear scab test of pesticide effectiveness of preventing and treating thereof
| Treatment agent | Extension rate | 7 days preventive effects (%) behind the last medicine | 14 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 65% penconazole tpn wetting powder | 6500 times | 89.24 | 95.55 | 95.40 |
| 50% penconazole chlorothalonil water dispersible granule | 1500 times | 89.57 | 96.52 | 95.13 |
| 22% penconazole tpn suspending agent | 500 times | 88.59 | 94.93 | 93.39 |
| 75% tpn wetting powder | 650 times | 63.28 | 67.29 | 65.38 |
| 10% penconazole missible oil | 2000 times | 75.35 | 82.42 | 81.32 |
As can be seen from Table 3, energy effectively preventing pear scab behind penconazole and the chlorothalonil compound, control efficiency all is better than contrasting medicament, and dosage is little, and the lasting period is long.The test scope of medication in to the target crop without harm.
Implementation of an application example five: penconazole, tpn and the composite control Chinese cabbage downy mildew test of pesticide effectiveness thereof
This experimental establishment is in the Lantian County, Xian City, Shanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 75% tpn wetting powder (commercial), 10% penconazole missible oil (commercial).
Investigation Chinese cabbage downy mildew state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates respectively disease index and calculates preventive effect in 7 days, 14 days after for the second time dispenser.Experimental result is as follows:
Table 4 penconazole, tpn and the composite control Chinese cabbage downy mildew test of pesticide effectiveness thereof
| Treatment agent | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 55% penconazole tpn wetting powder | 12 g/acres | 89.54 | 94.82 |
| 80% penconazole chlorothalonil water dispersible granule | 8 g/acres | 90.37 | 95.38 |
| 48% penconazole tpn suspending agent | 15 g/acres | 91.62 | 96.76 |
| 75% tpn wetting powder | 80 g/acres | 63.44 | 65.34 |
| 10% penconazole missible oil | 10 g/acres | 80.34 | 85.35 |
As can be seen from Table 4, can effectively prevent and treat Chinese cabbage downy mildew behind penconazole and the chlorothalonil compound and occur, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects.
Implementation of an application example six: penconazole, tpn and the composite control cucumber anthracnose test of pesticide effectiveness thereof
This experimental establishment is in the Gaoling County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 75% tpn wetting powder (commercial), 10% penconazole missible oil (commercial).
Investigation cucumber anthracnose state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates respectively disease index and calculates preventive effect in 7 days, 14 days after for the second time dispenser.Experimental result is as follows:
Table 5 penconazole, tpn and the composite control cucumber anthracnose test of pesticide effectiveness thereof
| Treatment agent | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 15% penconazole tpn wetting powder | 21 g/acres | 90.72 | 95.08 |
| 43% penconazole chlorothalonil water dispersible granule | 18 g/acres | 91.38 | 96.43 |
| 10% penconazole tpn suspending agent | 22 g/acres | 89.53 | 94.83 |
| 75% tpn wetting powder | 80 g/acres | 68.41 | 74.34 |
| 10% penconazole missible oil | 10 g/acres | 79.57 | 85.83 |
As can be seen from Table 5, can effectively prevent and treat cucumber anthracnose behind penconazole and the chlorothalonil compound and occur, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects, and cucumber had good preventive effect from the powder disease, preventive effect reaches more than 91%.
Claims (5)
1. bactericidal composition that contains penconazole and tpn, the weight ratio that it is characterized in that microbicide compositions effective active composition penconazole and tpn is 6: 7～1: 7 or 2: 23～1: 20.
2. the bactericidal composition that contains penconazole and tpn according to claim 1, it is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight.
3. the bactericidal composition that contains penconazole and tpn according to claim 2, it is characterized in that: wherein the effective active component content accounts for 10～80% of gross weight.
4. the bactericidal composition that contains penconazole and tpn according to claim 1, it is characterized in that: microbicide compositions is made wetting powder, water dispersible granules or suspending agent.
5. the bactericidal composition of penconazole and tpn that contains according to claim 1 is for the purposes of the powdery mildew of preventing and treating vegetables and fruit tree, downy mildew, anthracnose, ring spot, scab.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010003088 CN101743973B (en) | 2010-01-05 | 2010-01-05 | Bactericidal composition containing penconazole and chlorothalonil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010003088 CN101743973B (en) | 2010-01-05 | 2010-01-05 | Bactericidal composition containing penconazole and chlorothalonil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101743973A CN101743973A (en) | 2010-06-23 |
| CN101743973B true CN101743973B (en) | 2013-03-13 |
Family
ID=42472054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010003088 Expired - Fee Related CN101743973B (en) | 2010-01-05 | 2010-01-05 | Bactericidal composition containing penconazole and chlorothalonil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101743973B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101933514B (en) * | 2010-09-03 | 2013-03-13 | 江苏七洲绿色化工股份有限公司 | Bactericidal composite with triazole bactericide and chlorothalonil |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1993050A (en) * | 2004-08-03 | 2007-07-04 | 巴斯福股份公司 | Fungicidal synergistic mixtures made of triazolopyrimidine derivatives |
| CN101779677A (en) * | 2009-12-16 | 2010-07-21 | 陈章艳 | Sterilization composition containing penconazole |
-
2010
- 2010-01-05 CN CN 201010003088 patent/CN101743973B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1993050A (en) * | 2004-08-03 | 2007-07-04 | 巴斯福股份公司 | Fungicidal synergistic mixtures made of triazolopyrimidine derivatives |
| CN101779677A (en) * | 2009-12-16 | 2010-07-21 | 陈章艳 | Sterilization composition containing penconazole |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101743973A (en) | 2010-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101790986B (en) | Fungicide composite containing tricyclazole and hexaconazole | |
| CN102100233A (en) | Sterilization composition containing benziothiazolinone and hexaconazole | |
| CN101861871A (en) | Sterilization compound containing imazalil and prochloraz | |
| CN101971837A (en) | Antibacterial composition containing kasugamycin and mancozeb | |
| CN101731226B (en) | Bactericidal composition containing ethirimol and penconazole | |
| CN102017966B (en) | Kasugamycin and propineb-containing bactericidal composition | |
| CN101731248B (en) | Penconazole-containing and thioneb-containing sterilizing composition | |
| CN101731247B (en) | Penconazole-containing and thioneb-containing sterilizing composition | |
| CN101743973B (en) | Bactericidal composition containing penconazole and chlorothalonil | |
| CN101897336B (en) | Bactericidal composition containing imazalil and penconazole | |
| CN101999364A (en) | Hexaconazole-containing germicide composition | |
| CN101755823A (en) | Fungicidal composition containing flusilazole and pyrimethanil | |
| CN101720774B (en) | Bactericide composition containing penconazole and propineb | |
| CN101715767B (en) | Bactericidal composition containing kresoxim-methyl and penconazole | |
| CN101755781B (en) | Fungicidal composition containing penconazole and carbendazim | |
| CN101878762B (en) | Fungicide composition containing imazalil and hexaconazole | |
| CN101715772B (en) | Bactericidal composition containing carbendazim and ethirimol | |
| CN101874488B (en) | Bactericide composition containing imazalil and cyazofamid | |
| CN101779656B (en) | Bactericidal composite containing flusilazole and kresoxim-methyl | |
| CN101953343B (en) | Bactericidal composition containing imazalil and myclobutanil | |
| CN102017951B (en) | Germicide composition containing cyproconazole and chlorothalonil | |
| CN102017991A (en) | Bactericidal composition containing phosethyl-Al and triazole compound | |
| CN101755792A (en) | Fungicidal composition containing kresoxim methyl and thiophanate methyl | |
| CN101697720B (en) | Bactericide composition containing ethirimol and kresoxim | |
| CN101773126A (en) | Bactericidal composition containing azoxystrobin and penconazole |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130313 Termination date: 20170105 |