CN102100233A - Sterilization composition containing benziothiazolinone and hexaconazole - Google Patents
Sterilization composition containing benziothiazolinone and hexaconazole Download PDFInfo
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- CN102100233A CN102100233A CN2011100484148A CN201110048414A CN102100233A CN 102100233 A CN102100233 A CN 102100233A CN 2011100484148 A CN2011100484148 A CN 2011100484148A CN 201110048414 A CN201110048414 A CN 201110048414A CN 102100233 A CN102100233 A CN 102100233A
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- thiophene
- azoles alcohol
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Abstract
The invention relates to a sterilization composition with a synergistic interaction, which comprises effective active components of benziothiazolinone and hexaconazole in a weight ratio of 1:40-80:5. Assistants and active preparations are added into the effective components so that the effective components are prepared into wettable powder, water dispersible granules and a suspending agent. The sterilization composition is mainly used for controlling powdery mildew, cladosporium cucumerinum and gray mold of vegetables and fruit trees.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition that contains mould ketone of thiophene and own azoles alcohol.
Technical background
The mould ketone of thiophene (Benziothiazolinone) is the heterocyclic nitrogen-group fungicide of Shaanxi Xida Huate Science ﹠ Technology Industrial Co., Ltd.'s exploitation.Molecular formula: C
7H
5NOS, chemical name: 1,2 benzisothiazole-3-ketone.
The mould ketone of thiophene is a kind of efficient, wide-spectrum bactericide, has the germ of destruction cell nucleus structure, disturbs the germ cell metabolism, makes its physiologic derangement, causes germ death.
Own azoles alcohol (Hexaconazole) is the triazole bactericidal agent of Syngenta Co.,Ltd's exploitation.Molecular formula: C
14H
17Cl
2X
3O, chemical name: (RS)-2-(2,4 dichloro benzene base)-1-(1H-1,2,4-triazol-1-yl)-oneself-2-alcohol.
Own azoles alcohol belongs to sterol demethylation inhibitor, destroys and stop the biosynthesis of the cell membrane important composition composition ergosterol of germ, causes cell membrane not form, and makes germ death.Suction, protectant therapeutic activity in the tool.
No matter be the mould ketone of thiophene, own azoles alcohol or other efficient germicides, long-term use separately makes disease develop immunity to drugs easily, causes the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, and is unfavorable for environment sustainable development.The active ingredient of the different mechanisms of action is mixed, and is to delay the disease method commonly used that develops immunity to drugs, and judges this be mixed synergistic effect or antagonism according to the effect in the production application.The effect of being mixed is prescription more significantly, can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.The mould ketone of thiophene destroys germ cell nucleus structure, and own azoles alcohol acts on the cell membrane of germ, mechanism of action difference, and being mixed mutually has good synergistic effect within the specific limits.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition that contains mould ketone of thiophene and own azoles alcohol.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains mould ketone of thiophene and own azoles alcohol, wherein mould ketone of thiophene and own azoles alcohol weight ratio is 1-40: 80-5.
The described bactericidal composition that contains mould ketone of thiophene and own azoles alcohol, wherein mould ketone of thiophene and own azoles alcohol weight ratio is 1-30: 70-10.
The described bactericidal composition that contains mould ketone of thiophene and own azoles alcohol, wherein mould ketone of thiophene and own azoles alcohol weight ratio is 1-20: 60-20.
The described bactericidal composition that contains mould ketone of thiophene and own azoles alcohol, wherein the effective active component content accounts for the 10-80% of gross weight.
Can be mixed with agricultural during the described bactericidal composition practical application that contains mould ketone of thiophene and own azoles alcohol and go up any formulation that allows, preparation formulation is made environment-friendly type formulations such as wetting powder, water dispersible granules or suspending agent.
When making wetting powder, constituent comprises following composition content: the mould ketone 1-40% of thiophene, own azoles alcohol 5-80%, dispersant 5-10%, wetting agent 2-10%, filler 8-90%.
The mould ketone of thiophene, own azoles alcohol, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the own azoles alcohol of the mould ketone of thiophene wetting powder product.
When making water dispersible granules, composition comprises following constituent content: the mould ketone 1-40% of thiophene, own azoles alcohol 5-80%, dispersant 3-12%, wetting agent 1-8%, disintegrant 1-10%, filler 10-90%.
The mould ketone of thiophene, own azoles alcohol, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes the mould ketone diniconazole water dispersible granule of thiophene product.
Comprise following constituent content when constituent is made suspending agent: the mould ketone 1-40% of thiophene, own azoles alcohol 5-80%, dispersant 2-10%, wetting agent 2-10%, defoamer 0.1-1%, thickener 0.1-2%, antifreeze 0.1-8%, deionized water add to 100%.
Tell shear-mixed even dispersant, wetting agent, defoamer, thickener, antifreeze process in the above-mentioned formulation material, add the mould ketone of thiophene, own azoles alcohol, ball milling machine ball milling 2-3 hour, make diameter of particle all once at 5 μ m, make the mould ketone hexaconazole suspending agent of thiophene product.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, moistening bleeding agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from: one or more in xanthan gum, polyvinyl alcohol, the polyethylene glycol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, the aluminium chloride.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in control vegetables and fruit tree powdery mildew, gray mold, scab.
Beneficial effect of the present invention: the mould ketone of (1) present composition effective active composition thiophene and own azoles alcohol belong to the bactericide of two kinds of different mechanisms of action, and both are mixed mutually and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has special efficacy to powdery mildew, gray mold, the scab of vegetables and fruit tree.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.
Implementation of an application example one
Mould ketone of thiophene and own azoles alcohol are mixed to the powdery mildew of cucumber Toxicity Determination.
Test medicine all has Shaanxi Xida Huate Science ﹠ Technology Industrial Co., Ltd. to provide.
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament powdery mildew of cucumber.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC50 value of every kind of medicament thus.The colleague calculates the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method, and SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively the mould ketone of the pure and mild thiophene of own azoles shared ratio in combination
A is own azoles alcohol
B is the mould ketone of thiophene
Result of the test is as shown in table 1:
The own azoles alcohol of table 1, the mould ketone of thiophene and be mixed to the toxicity test analysis of results table of powdery mildew of cucumber
As shown in Table 1, own azoles alcohol, the mould ketone of thiophene are respectively 0.18mg/L and 32.38mg/L to the EC50 of powdery mildew of cucumber.The virulence of own azoles alcohol is higher than the virulence of the mould ketone of thiophene.Own azoles alcohol is respectively 1.66,1.89,2.06,1.86,1.54 with 1: 1,1: 5,1: 10,1: 20,1: 30 synergy ratio of the mould ketone proportioning of thiophene, illustrate that own azoles alcohol and the mould ketone of thiophene are 1: 1-1: be mixed in 20 scopes and all show obvious synergistic effect, synergy ratio SR maximum when own azoles alcohol is 1: 10 with the mould ketone weight ratio of thiophene wherein, synergistic effect is the most obvious.
Implementation of an application example two
The implementation of Formulation Example
Embodiment 1
The own azoles alcohol of the mould ketone of 80% thiophene wetting powder
The mould ketone 30% of thiophene, own azoles alcohol 50%, polycarboxylate 5%, neopelex 3%, soapberry powder 2%, white carbon 10%, mixture carries out comminution by gas stream, makes the own azoles alcohol of the mould ketone of 80% thiophene wetting powder.
Embodiment 2
The own azoles alcohol of the mould ketone of 70% thiophene wetting powder
The mould ketone 20% of thiophene, own azoles alcohol 50%, lignosulfonates 5%, spaonin powder 3%, white carbon 7%, diatomite 15%, mixture carry out comminution by gas stream, make the own azoles alcohol of the mould ketone of 70% thiophene wetting powder.
Embodiment 3
The own azoles alcohol of the mould ketone of 60% thiophene wetting powder
The mould ketone 15% of thiophene, own azoles alcohol 45%, alkylphenol-polyethenoxy are phonetic 5%, neopelex 3%, white carbon 12%, bentonite 20%, mixture carry out gas and pulverize, and make the own azoles alcohol of the mould ketone of 60% thiophene wetting powder.
Embodiment 4
The own azoles alcohol of the mould ketone of 50% thiophene wetting powder
The mould ketone 8% of thiophene, own azoles alcohol 42%, lignosulfonates 5%, wetting and penetrating agent F 3%, white carbon 12%, bentonite 30%, mixture carry out comminution by gas stream, make the own azoles alcohol of the mould ketone of 50% thiophene wetting powder.
Embodiment 5
The mould ketone diniconazole water dispersible granule of 80% thiophene
The mould ketone 10% of thiophene, own azoles alcohol 70%, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, starch 10%, mixed the mould ketone diniconazole water dispersible granule of 80% thiophene.
Embodiment 6
The mould ketone diniconazole water dispersible granule of 65% thiophene
The mould ketone 5% of thiophene, own azoles alcohol 60%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 22%, the mixed mould ketone diniconazole water dispersible granule of 65% thiophene that gets.
Embodiment 7
The mould ketone diniconazole water dispersible granule of 50% thiophene
The mould ketone 4% of thiophene, own azoles alcohol 46%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 20%, bentonite 22%, mixed the mould ketone diniconazole water dispersible granule of 50% thiophene.
Embodiment 8
The mould ketone diniconazole water dispersible granule of 15% thiophene
The mould ketone 5% of thiophene, own azoles alcohol 10%, alkylphenol-polyethenoxy are phonetic 4%, DBSA 4%, ammonium sulfate 5%, starch 20%, diatomite 52%, mixed the mould ketone diniconazole water dispersible granule of 15% thiophene.
Embodiment 9
The mould ketone hexaconazole suspending agent of 50% thiophene
The mould ketone 10% of thiophene, own azoles alcohol 40%, alkyl benzene sulfonate calcium salt 5%, Sodium Polyacrylate 2%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%,, deionized water adds to 100%, is mixed and made into the mould ketone hexaconazole suspending agent of 50% thiophene.
Embodiment 10
The mould ketone hexaconazole suspending agent of 30% thiophene
The mould ketone 4% of thiophene, own azoles alcohol 26%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, deionized water add to 100%, the mixed mould ketone hexaconazole suspending agent of 30% thiophene that gets.
Embodiment 11
The mould ketone hexaconazole suspending agent of 21% thiophene
The mould ketone 1% of thiophene, own azoles alcohol 20%, polycarboxylate 2%, neopelex 2%, silicone compound 0.1%, polyethylene glycol 0.5%, glycerine 4%, deionized water add to 100%, the mixed mould ketone hexaconazole suspending agent of 21% thiophene that gets.
Embodiment 12
The mould ketone hexaconazole suspending agent of 10% thiophene
The mould ketone 5% of thiophene, own azoles alcohol 5%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, deionized water add to 100%, the mixed mould ketone hexaconazole suspending agent of 10% thiophene that gets.
Implementation of an application example three
The mould ketone of thiophene, own azoles alcohol and be mixed and prevent and treat the pear scab test of pesticide effectiveness
This experimental establishment is in Bin County suburb, Shaanxi Province, and the mould ketone wetting powder of medicament 40% thiophene, 10% hexaconazole suspending agent (commercial) are researched and developed, provided and contrast to test medicine by Shaanxi Xida Huate Science ﹠ Technology Industrial Co., Ltd..
The medicine " Invest, Then Investigate " pear scab state of an illness, in the dispenser for the first time of state of an illness initial stage, per 7 dispensers once are total to dispenser 3 times.Investigated the pear scab state of an illness respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
The mould ketone of table 2 thiophene, own azoles alcohol and be mixed and prevent and treat the pear scab test of pesticide effectiveness
As can be seen from Table 2, can effectively prevent pear scab after mould ketone of thiophene and own azoles alcohol are mixed, control efficiency all is better than contrasting medicament, and the lasting period is long.In the test scope of medication, the target crop is had no adverse effects.
Implementation of an application example four
The mould ketone of thiophene, own azoles alcohol and the control grape grey mould test of pesticide effectiveness that is mixed thereof
This experimental establishment is in suburb, Turpan, Xinjiang, and test medicine provides and contrast the mould ketone wetting powder of medicament 40% thiophene, 10% hexaconazole suspending agent (commercial) by Shaanxi Xida Huate Science ﹠ Technology Industrial Co., Ltd.'s research and development.
The medicine " Invest, Then Investigate " grape grey mould state of an illness, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated the grape grey mould disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
The mould ketone of table 3 thiophene, own azoles alcohol and the control grape grey mould test of pesticide effectiveness that is mixed thereof
As can be seen from Table 3, can prevent and treat downy mildew of garpe effectively after mould ketone of thiophene and own azoles alcohol are mixed, control efficiency all is better than contrasting medicament, and dosage is little, and the lasting period is long.In the test scope of medication, the target crop there is not harm.
Implementation of an application example five
The mould ketone of thiophene, own azoles alcohol and the control powdery mildew of strawberry test of pesticide effectiveness that is mixed thereof
This experimental establishment is in Hu County, Shaanxi Province, and the mould ketone wetting powder of medicament 40% thiophene, 10% hexaconazole suspending agent (commercial) are researched and developed, provided and contrast to test medicine by Shaanxi Xida Huate Science ﹠ Technology Industrial Co., Ltd..
Investigate powdery mildew of strawberry state of an illness radix, total number of sheets, the sick number of sheets before the medicine, reach sick leaf-size class number, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively and calculates preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
The mould ketone of table 4 thiophene, own azoles alcohol and the control powdery mildew of strawberry test of pesticide effectiveness that is mixed thereof
As can be seen from Table 4, can effectively prevent and treat powdery mildew of strawberry after mould ketone of thiophene and own azoles alcohol are mixed and take place, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects.
Implementation of an application example six
The mould ketone of thiophene, own azoles alcohol and be mixed and prevent and treat the powdery mildew of cucumber test of pesticide effectiveness
This experimental establishment is in the Jingyang County, Shaanxi Province, and the mould ketone wetting powder of medicament 40% thiophene, 10% hexaconazole suspending agent (commercial) are researched and developed, provided and contrast to test medicine by Shaanxi Xida Huate Science ﹠ Technology Industrial Co., Ltd..
Investigation powdery mildew of cucumber state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively and calculates preventive effect in 7 days, 15 days after the dispenser for the second time.Experimental result is as follows:
The mould ketone of table 5 thiophene, own azoles alcohol and be mixed and prevent and treat the powdery mildew of cucumber test of pesticide effectiveness
As can be seen from Table 5, can effectively prevent and treat powdery mildew of cucumber after mould ketone of thiophene and own azoles alcohol are mixed and take place, control efficiency all is better than contrasting medicament, and the target crop has no adverse effects in this test scope of medication.
Claims (8)
1. bactericidal composition that contains mould ketone of thiophene and own azoles alcohol, the weight ratio that it is characterized in that mould ketone of microbicide compositions effective active composition thiophene and own azoles alcohol is 1-40: 80-5.
2. the bactericidal composition that contains mould ketone of thiophene and own azoles alcohol according to claim 1 is characterized in that: wherein the weight ratio of mould ketone of thiophene and own azoles alcohol is 1-30: 70-10.
3. the bactericidal composition that contains mould ketone of thiophene and own azoles alcohol according to claim 2 is characterized in that: wherein the weight ratio of mould ketone of thiophene and own azoles alcohol is 1-20: 60-20.
4. the bactericidal composition that contains mould ketone of thiophene and own azoles alcohol according to claim 1 is characterized in that: wherein the weight ratio of mould ketone of thiophene and own azoles alcohol is 1-90%.
5. the bactericidal composition that contains mould ketone of thiophene and own azoles alcohol according to claim 4 is characterized in that: wherein the weight ratio of mould ketone of thiophene and own azoles alcohol is 10-80%.
6. the bactericidal composition that contains mould ketone of thiophene and own azoles alcohol according to claim 1 is characterized in that: described composition can be mixed with agricultural and go up any formulation that allows.
7. the bactericidal composition that contains mould ketone of thiophene and own azoles alcohol according to claim 6 is characterized in that: described combination dosage form is for making environment-friendly type formulations such as wetting powder, water dispersible granules or suspending agent.
8. the bactericidal composition that contains mould ketone of thiophene and own azoles alcohol according to claim 1 is used to prevent and treat powdery mildew, gray mold, the scab of vegetables and fruit tree.
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| AU2016413017C1 (en) * | 2016-06-26 | 2020-04-30 | Adama Huifeng (Jiangsu) Ltd. | Bactericide composition |
| US11219213B2 (en) | 2016-06-26 | 2022-01-11 | Adama Huifeng (Jiangsu), Ltd. | Fungicidal composition |
| CN106172437B (en) * | 2016-07-07 | 2018-06-19 | 江苏辉丰农化股份有限公司 | A kind of microbicide compositions |
| CN106172437A (en) * | 2016-07-07 | 2016-12-07 | 江苏辉丰农化股份有限公司 | A kind of microbicide compositions |
| CN107646857A (en) * | 2017-09-28 | 2018-02-02 | 陕西西大华特科技实业有限公司 | A kind of bactericidal composition containing cyflufenamid and benziothiazolinone and its application |
| CN111466392A (en) * | 2019-01-24 | 2020-07-31 | 陕西西大华特科技实业有限公司 | Bactericidal composition containing benziothiazolinone and tetraconazole and application thereof |
| CN111466392B (en) * | 2019-01-24 | 2021-08-27 | 陕西西大华特科技实业有限公司 | Bactericidal composition containing benziothiazolinone and tetraconazole and application thereof |
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| CN102100233B (en) | 2016-06-08 |
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