CN101731247A - Penconazole-containing and thioneb-containing sterilizing composition - Google Patents
Penconazole-containing and thioneb-containing sterilizing composition Download PDFInfo
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- CN101731247A CN101731247A CN201010003066A CN201010003066A CN101731247A CN 101731247 A CN101731247 A CN 101731247A CN 201010003066 A CN201010003066 A CN 201010003066A CN 201010003066 A CN201010003066 A CN 201010003066A CN 101731247 A CN101731247 A CN 101731247A
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- penconazole
- carbatene
- thioneb
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- bactericidal composition
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Abstract
The invention relates to a sterilizing composition having the synergy effect, which comprises the active ingredients of penconazole and thioneb in a weight ratio of 1-40 to 80-1. A wettable powder, a water dispersible granule and a suspending agent can be prepared by adding an auxiliary agent and an excipient into the active ingredients, and are mainly used for preventing and controlling powdery mildew, downy mildew, anthracnose, ring spot and scab of vegetables and fruit trees.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition that contains penconazole and Carbatene.
Technical background
Penconazole (penconazole), molecular formula: C
13H
15Cl
2N
3, chemical name: 1-[2-(2,4 dichloro benzene base)-4-propyl group-1,3-dioxolanes-2-methyl]-1-hydrogen-1,2, the 4-triazole.
Penconazole belongs to three nitrogen heterocycles bactericide, is sterol demethylation inhibitor, destroys and stop the biosynthesis of the cell membrane important composition composition ergosterol of germ, causes cell membrane not form, and is germ death.Root, stem, leaf isoreactivity tissue by crop absorb, and can upwards conduct with body fluid in the plant body soon.
Carbatene (metriam), molecular formula: (C
4H
6N
2S
4Zn) x chemical name: the co-ordination complex of two two sulphur deoxidation base formic acid manganese of ethylene and zinc ion.
Carbatene is a kind of good protective fungicide, belongs to low-toxin farm chemicals.Because wide, the difficult resistance that produces of its bactericidal range, control efficiency obviously is better than other same series bactericidal agents, so consumption is a large tonnage product in the world always.Be the substitute products of present other protective fungicides; domestic most composite bactericide is all formulated with mancozeb processing; but the MnZn preparation can cause the crop trace element accumulation and poison; by field application in recent years; remarkable to preventing and treating effects such as pear scab, alternaria leaf spot of apple, vegetable category eqpidemic disease, downy mildew, field crop rust; can effectively control disease fully without other any bactericide and take place, steady quality, reliable.
No matter be penconazole, Carbatene or other efficient germicides, long-term use separately makes disease develop immunity to drugs easily, causes the problem that dosage strengthens, preventive effect reduces, the lasting period shortens, and is unfavorable for environment sustainable development.The active ingredient of the different mechanisms of action is carried out composite, is to delay the disease method commonly used that develops immunity to drugs, and according to the effect in the production application, judge this composite be synergistic effect or antagonism.Complex role is more significantly filled a prescription, and can obviously improve preventive effect, reduces the dosage of agricultural chemicals greatly, also can enlarge fungicidal spectrum, improves germicidal efficiency.Penconazole is different with the Carbatene mechanism of action, and mutually composite have good synergistic effect within the specific limits.And composite about penconazole and Carbatene do not see relevant report at present at home and abroad as yet.
Summary of the invention
The objective of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition that contains penconazole and Carbatene.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains penconazole and Carbatene, wherein penconazole and Carbatene weight ratio are 1～40: 80～1.
The described bactericidal composition that contains penconazole and Carbatene, wherein the weight ratio of penconazole and Carbatene is 1～30: 70～10.
The described bactericidal composition that contains penconazole and Carbatene, wherein the weight ratio of penconazole and Carbatene is 1～20: 60～20.
The described bactericidal composition that contains penconazole and Carbatene, wherein the effective active component content accounts for 1～90% of gross weight, is preferably 10～80%.
The described bactericidal composition that contains penconazole and Carbatene is made wetting powder, water dispersible granules or suspending agent.
When making wetting powder, composition comprises following constituent content: penconazole 1～40%, Carbatene 1～80%, dispersant 5～10%, wetting agent 2～10%, filler 8～90%.
Penconazole, Carbatene, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into penconazole thioneb wettable powder product.
When making water dispersible granules, composition comprises following constituent content: penconazole 1～40%, Carbatene 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler 10～90%.
Penconazole, Carbatene, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes penconazole Carbatene water dispersible granules product.
Comprise following constituent content when composition is made suspending agent: penconazole 1～30%, Carbatene 1～50%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in the above-mentioned formulation material are mixed through high speed shear, add penconazole, Carbatene, ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes penconazole Carbatene suspending agent product.
Described dispersant is selected from polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, in phonetic one or more of polyoxyethylene carboxylate, ester polyoxyethylene.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from: one or more in xanthan gum, polyvinyl alcohol, the polyethylene glycol.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, the aluminium chloride.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), farming breast 1600
#In (phenethyl phenol polyoxy ethyl polypropylene-base ether), the ethylene oxide-propylene oxide block copolymer one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention is mainly used in powdery mildew, downy mildew, anthracnose, ring spot, the scab of control vegetables and fruit tree.
Beneficial effect of the present invention: (1) present composition effective active composition penconazole and Carbatene belong to the bactericide of two kinds of different mechanisms of action, and both are mixed mutually and can produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single agent, and dosage is little; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) present composition has special efficacy to powdery mildew, downy mildew, anthracnose, ring spot, the scab of vegetables and fruit tree.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Implementation of an application example one: penconazole and Carbatene are composite to the cucumber downy mildew Toxicity Determination
Test medicine provides by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation.
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament cucumber downy mildew.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively penconazole and Carbatene shared ratio in combination
A is a penconazole
B is a Carbatene
Result of the test is as shown in table 1:
Table 1 penconazole, Carbatene and composite toxicity test analysis of results table thereof to cucumber downy mildew
As shown in Table 1, penconazole, Carbatene are to the EC of cucumber downy mildew
50Be respectively 0.13mg/L and 36.28mg/L.The virulence of penconazole is higher than the virulence of Carbatene.1: 1,1: 5,1: 10,1: 15,1: 20 synergy ratio of penconazole and Carbatene proportioning is respectively 1.62,1.87,2.16,1.72,1.59, illustrating that penconazole and Carbatene were mixed in the scope at 1: 1～1: 20 all shows obvious synergistic effect, synergy ratio SR maximum when penconazole and Carbatene weight ratio are 1: 10 wherein, synergistic effect is the most obvious.
Implementation of an application example two the implementation of Formulation Example
Embodiment 1 80% penconazole thioneb wettable powder
Penconazole 20%, Carbatene 60%, lignosulfonates 5%, neopelex 3%, soapberry powder 2%, white carbon 10%, mixture carries out comminution by gas stream, makes 80% penconazole thioneb wettable powder.
Embodiment 2 65% penconazole thioneb wettable powders
Penconazole 30%, Carbatene 35%, polycarboxylate 5%, spaonin powder 3%, white carbon 7%, diatomite 20%, mixture carries out comminution by gas stream, makes 65% penconazole thioneb wettable powder.
Embodiment 3 55% penconazole thioneb wettable powders
Penconazole 10%, Carbatene 45%, alkylphenol-polyethenoxy are phonetic 5%, wetting and penetrating agent F3%, white carbon 17%, bentonite 20%, and mixture carries out comminution by gas stream, makes 55% penconazole thioneb wettable powder.
Embodiment 4 15% penconazole thioneb wettable powders
Penconazole 5%, Carbatene 10%, lignosulfonates 5%, neopelex 3%, white carbon 17%, bentonite 60%, mixture carries out comminution by gas stream, makes 15% penconazole thioneb wettable powder.
Embodiment 5 80% penconazole Carbatene water dispersible granules
Penconazole 10%, Carbatene 70%, alkylphenol-polyethenoxy are phonetic 3%, lignosulfonates 3%, lauryl sodium sulfate 4%, starch 10%, mixed 80% penconazole Carbatene water dispersible granules.
Embodiment 6 70% penconazole Carbatene water dispersible granules
Penconazole 20%, Carbatene 50%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, lauryl sodium sulfate 4%, sodium bicarbonate 3%, starch 7%, kaolin 10%, the mixed 70% penconazole Carbatene water dispersible granules that gets.
Embodiment 7 50% penconazole Carbatene water dispersible granules
Penconazole 4%, Carbatene 46%, alkylphenol-polyethenoxy are phonetic 5%, dodecyl benzene sulfonate 3%, starch 20%, bentonite 22%, mixed 50% penconazole Carbatene water dispersible granules.
Embodiment 8 43% penconazole Carbatene water dispersible granules
Penconazole 3%, Carbatene 40%, alkylphenol-polyethenoxy are phonetic 4%, DBSA 4%, starch 15%, diatomite 34%, mixed 43% penconazole Carbatene water dispersible granules.
Embodiment 9 48% penconazole Carbatene suspending agents
Penconazole 8%, Carbatene 40%, alkyl benzene sulfonate calcium salt 5%, Sodium Polyacrylate 2%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, phenyl phenol polyoxy ethyl ether 2%, deionized water adds to 100%, the mixed 48% penconazole Carbatene suspending agent that gets.
Embodiment 10 30% penconazole Carbatene suspending agents
Penconazole 6%, Carbatene 24%, polycarboxylate 4%, soapberry powder 5%, silicone compound 0.1%, hydroxyethylcellulose 0.1%, ethylene glycol 2%, alkyl benzene calcium sulfonate 2%, deionized water adds to 100%, the mixed 30% penconazole Carbatene suspending agent that gets.
Embodiment 11 22% penconazole Carbatene suspending agents
Penconazole 2%, Carbatene 20%, polycarboxylate 2%, neopelex 2%, silicone compound 0.1%, polyethylene glycol 0.5%, glycerine 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 22% penconazole Carbatene suspending agent that gets.
Embodiment 12 10% penconazole Carbatene suspending agents
Penconazole 5%, Carbatene 5%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fat acid compounds 0.1%, polyethylene glycol 0.5%, ethylene glycol 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 1%, deionized water adds to 100%, the mixed 10% penconazole Carbatene suspending agent that gets.
Embodiment uses three penconazoles and the Carbatene and the composite ring rot of apple test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Luochuan County suburb, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 70% thioneb wettable powder (commercial), 10% penconazole missible oil (commercial).
The investigation ring rot of apple state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 3 times.Investigated alternaria leaf spot of apple feelings index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
Table 2 penconazole, Carbatene and the composite ring rot of apple test of pesticide effectiveness of preventing and treating thereof
| Handle medicament | Extension rate | 7 days preventive effects (%) behind the last medicine | 14 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 80% penconazole thioneb wettable powder | 6000 times | ??89.93 | ??95.82 | ??93.43 |
| 70% penconazole Carbatene water dispersible granules | 5000 times | ??90.67 | ??96.76 | ??94.27 |
| 30% penconazole Carbatene suspending agent | 1500 times | ??88.22 | ??94.72 | ??92.39 |
| 70% thioneb wettable powder | 400 times | ??60.13 | ??65.81 | ??62.81 |
| 10% penconazole missible oil | 2000 times | ??74.51 | ??79.64 | ??78.18 |
As can be seen from Table 2, can effectively prevent and treat ring rot of apple after penconazole and Carbatene are composite, control efficiency all is better than contrasting medicament, and the lasting period is long.In the test scope of medication target crop is had no adverse effects, and apple mildew is had good preventive effect, preventive effect reaches more than 90%.
Implementation of an application example four: penconazole and Carbatene and the composite pear scab test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in suburb, Ningxia Province Yinchuan City, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 70% thioneb wettable powder (commercial), 10% penconazole missible oil (commercial).
The investigation pear scab state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated the pear scab disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 3 penconazole, Carbatene and the composite pear scab test of pesticide effectiveness of preventing and treating thereof
| Handle medicament | Extension rate | 7 days preventive effects (%) behind the last medicine | 14 days preventive effects (%) behind the last medicine | 30 days preventive effects (%) behind the last medicine |
| 65% penconazole thioneb wettable powder | 6500 times | ??88.96 | ??95.85 | ??95.46 |
| 50% penconazole Carbatene water dispersible granules | 1500 times | ??89.54 | ??96.16 | ??95.85 |
| 22% penconazole Carbatene suspending agent | 500 times | ??88.59 | ??94.91 | ??93.29 |
| 70% thioneb wettable powder | 450 times | ??63.28 | ??66.29 | ??65.38 |
| 10% penconazole missible oil | 2000 times | ??75.35 | ??82.42 | ??81.49 |
As can be seen from Table 3, energy effectively preventing pear scab after penconazole and Carbatene are composite, control efficiency all is better than contrasting medicament, and dosage is little, and the lasting period is long.In the test scope of medication, the target crop there is not harm.
Implementation of an application example five: penconazole, Carbatene and the composite control cucumber anthracnose test of pesticide effectiveness thereof
This experimental establishment is at the Xian City, Shanxi Province Changan District, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 70% thioneb wettable powder (commercial), 10% penconazole missible oil (commercial).
Investigation cucumber anthracnose state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively and calculates preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 4 penconazole, Carbatene and the composite control cucumber anthracnose test of pesticide effectiveness thereof
| Handle medicament | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 55% penconazole thioneb wettable powder | 12 gram/mus | ??89.54 | ??94.82 |
| 80% penconazole Carbatene water dispersible granules | 8 gram/mus | ??90.37 | ??95.38 |
| 48% penconazole Carbatene suspending agent | 15 gram/mus | ??91.62 | ??96.76 |
| Handle medicament | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 70% thioneb wettable powder | 70 gram/mus | ??63.44 | ??65.34 |
| 10% penconazole missible oil | 10 gram/mus | ??80.34 | ??85.35 |
As can be seen from Table 4, can effectively prevent and treat cucumber anthracnose after penconazole and Carbatene are composite and take place, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects, and powdery mildew of cucumber had good preventive effect, preventive effect reaches more than 91%.
Implementation of an application example six: penconazole, Carbatene and the composite control Chinese cabbage downy mildew test of pesticide effectiveness thereof
This experimental establishment is in the Gaoling County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi means of agricultural production trade Co., Ltd of U.S. nation, contrast medicament 70% thioneb wettable powder (commercial), 10% penconazole missible oil (commercial).
Investigation Chinese cabbage downy mildew state of an illness radix, total number of sheets, the sick number of sheets and sick leaf-size class number before the medicine, in the their early stage dispenser, dispenser in per 7 days once is total to dispenser 2 times, investigates disease index respectively and calculates preventive effect in 7 days, 14 days after the dispenser for the second time.Experimental result is as follows:
Table 5 penconazole, Carbatene and the composite control Chinese cabbage downy mildew test of pesticide effectiveness thereof
| Handle medicament | The preparation dosage | 7 days preventive effects (%) behind the medicine for the second time | 14 days preventive effects (%) behind the medicine for the second time |
| 15% penconazole thioneb wettable powder | 21 gram/mus | ??90.72 | ??95.08 |
| 43% penconazole Carbatene water dispersible granules | 18 gram/mus | ??91.38 | ??96.43 |
| 10% penconazole Carbatene suspending agent | 22 gram/mus | ??89.53 | ??94.83 |
| 70% thioneb wettable powder | 70 gram/mus | ??68.41 | ??74.34 |
| 10% penconazole missible oil | 10 gram/mus | ??79.57 | ??85.83 |
As can be seen from Table 5, can effectively prevent and treat Chinese cabbage downy mildew after penconazole and Carbatene are composite and take place, control efficiency all is better than contrasting medicament, in this test scope of medication the target crop is had no adverse effects.
Claims (6)
1. bactericidal composition that contains penconazole and Carbatene, the weight ratio that it is characterized in that microbicide compositions effective active composition penconazole and Carbatene is 1～40: 80～1.
2. the bactericidal composition that contains penconazole and Carbatene according to claim 1 is characterized in that: wherein the weight ratio of penconazole and Carbatene is 1～30: 70～10.
3. the bactericidal composition that contains penconazole and Carbatene according to claim 2 is characterized in that: wherein the weight ratio of penconazole and Carbatene is 1～20: 60～20.
4. the bactericidal composition that contains penconazole and Carbatene according to claim 1 is characterized in that: wherein the effective active component content accounts for 1～90% of gross weight.
5. the bactericidal composition that contains penconazole and Carbatene according to claim 4 is characterized in that: wherein the effective active component content accounts for 10～80% of gross weight.
6. the bactericidal composition that contains penconazole and Carbatene according to claim 1 is characterized in that: microbicide compositions is made wetting powder, water dispersible granules or suspending agent.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103583560A (en) * | 2012-08-13 | 2014-02-19 | 陕西美邦农药有限公司 | Sterilization composition containing simeconazole and thiocarbamates |
| CN104705322A (en) * | 2013-12-12 | 2015-06-17 | 南京华洲药业有限公司 | Sterilization composition containing penconazole and ambam and use thereof |
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| PL1819223T3 (en) * | 2004-11-26 | 2008-08-29 | Basf Se | Use of menadione for boosting the effectiveness of agrochemicals |
| CN101069511B (en) * | 2006-05-09 | 2012-12-05 | 陶氏农业科学公司 | Stabilized fungus-killing agent composition |
| KR20090117639A (en) * | 2008-05-09 | 2009-11-12 | 닛산 가가쿠 고교 가부시키 가이샤 | Pestcidal composition |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103583560A (en) * | 2012-08-13 | 2014-02-19 | 陕西美邦农药有限公司 | Sterilization composition containing simeconazole and thiocarbamates |
| CN103583560B (en) * | 2012-08-13 | 2015-09-09 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing simeconazoles and thiocarbamates |
| CN104705322A (en) * | 2013-12-12 | 2015-06-17 | 南京华洲药业有限公司 | Sterilization composition containing penconazole and ambam and use thereof |
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