CN103918691A - Imazalil-containing sterilization composition - Google Patents
Imazalil-containing sterilization composition Download PDFInfo
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- CN103918691A CN103918691A CN201310036277.5A CN201310036277A CN103918691A CN 103918691 A CN103918691 A CN 103918691A CN 201310036277 A CN201310036277 A CN 201310036277A CN 103918691 A CN103918691 A CN 103918691A
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Abstract
The invention discloses an imazalil-containing sterilization composition, and belongs to the technical field of pesticides. The sterilization composition comprises a raw pesticide prepared by compounding a bactericide A and a bactericide B with a ratio of 1-80:1-80; the bactericide A is imazalil or efficient imazalil; and the bactericide B is any one of the following bactericides: a copper preparation, methoxy acrylates, triazoles, amides, benzimidazoles, thiocarbamates, substituted benzenes, pyrroles, dicarboximides, phthalimides, imidazoles, morpholines, carbamates, oxazoles, antibiotics, and the like. The sterilization composition comprises the raw pesticide prepared by compounding imazalil or efficient imazalil and a bactericide B, the sterilization spectrum is expanded, the pesticide resistance of pathogens is alleviated, and the sterilization composition has obvious continuous synergic effect.
Description
Technical field
The present invention relates to technical field of pesticide, specifically, relate to a kind of bactericidal composition that contains imazalil.
Background technology
Bactericide is the class agricultural chemicals for preventing and treating the plant disease being caused by various pathogenic microorganisms, refers generally to fungicide.But the general name that in the world, normally conduct prevents and treats the medicament of all kinds of pathogenic microorganisms.Along with the development of bactericide, distinguish again the subclass such as bactericide, virucide, algicide.According to investigations, the whole world pathogenic microorganism (fungi, strong bacterium, rickettsia, mycoplasma, virus, algae etc.) harmful to plant has more than 80,000 kinds.Using bactericide is the cost-effective method of one of controlling plant diseases.
Early stage bactericide is all inorganic compound, wherein as Cosan and copper agent (as bordeaux mixture) are still using so far.Twentieth century four the fifties, developed the organosulfureous fungicides that have three main series: the U.S. class of good fortune, generation gloomy class (as zineb) and trichloro-methylthio diformazan carboxylic acid imide, organochlorine, organic mercury, organoarsenic fungicide also have development in addition.These bactericide are protectant mostly, have limitation in application.Since the sixties, the bactericide of more chemical types constantly occurs, wherein most important progress is the appearance of systemic fungicide.Meanwhile, farm antibiotics also has development faster.Organic mercury, organo-arsenic and some organochlorine bactericide, because toxicity or problem of environmental pollution are gradually eliminated.The systemics bactericide of a new generation further expands the market of bactericide because control efficiency improves.To the eighties, the kind of bactericide has exceeded 200 kinds.
But in the real process of agricultural production, preventing and treating the problem that disease the most easily produces is the drug-fast generation of germ.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistance germ.
Summary of the invention
The object of the invention is to overcome the defect of prior art, a kind of bactericidal composition that contains imazalil is provided.
For addressing the above problem, the technical solution adopted in the present invention is:
A bactericidal composition that contains imazalil, is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine forming of bactericide B;
Described bactericide A is imazalil or efficient imazalil;
Any one in the bactericide that described bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates, oxazole class and antibiotics, and other classes.
Say further:
Described copper agent bactericide is any one in following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
Described methoxy acrylic bactericide is any one in following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, ZJ0712, fluoxastrobin, nitrile Fluoxastrobin, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Described triazole bactericidal agent is any one in following bactericide: penta ring bacterium, bromuconazole, ether azoles, alkene azoles alcohol, smart alkene azoles alcohol, oxole bacterium, Fluquinconazole, Flutriafol, tricyclazole, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, imidazoles, paclobutrazol, prothioconazoles, fluosilicic bitertanol azoles, Tebuconazole, triazolone, triadimenol, triticonazole, uniconazole P.
Described acid amide fungicides is any one in following bactericide: M 9834, smart M 9834, benodanil,, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, isotianil, the third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
Described thiocarbamates bactericide is any one in following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
Described benzimidazole germicide is thiophanate methyl;
Described substituted beneze-group fungicides are tpn;
Described pyroles bactericide is fludioxonil or fenpiclonil;
Described dicarboximide fungicide be iprodione,
Dimethachlon or procymidone;
Described phthalimide series bactericidal agent is captan or folpet;
Described carbamate fungicide is Propamocarb or the mould prestige of second.
Described imidazoles bactericide is any one in following bactericide: prochloraz-manganese chloride complex complex compound, pefurazoate;
Described morpholine series bactericidal agent is any one in following bactericide: dimethomorph, flumorph, bacterium quinoline, butadiene morpholine;
Described oxazole series bactericidal agent is any one in following bactericide: Famoxate, SYP-Zo48, the mould spirit of evil, Wakil;
Described antibiotics bactericide is any one in following bactericide: jinggangmeisu, kasugarnycin, pesticide corrosion 120, agricultural streptomycin, blasticidin-S, Polyoxin.
Described other series bactericidal agents are Rabcide, Yekuzuo or bromothalonil.
Furtherly, the proportioning of described bactericide A and bactericide B is: 2: 1.
Again furtherly, described bactericide be missible oil, micro emulsion, water and milk, suspending agent (comprising: dry outstanding, water is outstanding and oil outstanding), all formulations such as fumicants, pulvis, soluble liquid, wetting powder, granula, soluble powder, water dispersible granules or suspension emulsion.
Owing to having adopted technique scheme, compared with prior art, in the present invention, include by imazalil or efficient imazalil and the composite former medicine forming of bactericide B, not only expanded fungicidal spectrum, also slow down the pesticide resistance of germ, had and significantly continue synergistic effect.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
The bactericidal composition that contains imazalil of the present invention, comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine forming of bactericide B;
Described bactericide A is imazalil or efficient imazalil;
Any one in the bactericide that described bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates, oxazole class and antibiotics, and other classes.
One of preferred as technique scheme, the proportioning of described bactericide A and bactericide B is: 2: 1.
Imazalil, is a kind of systemic fungicide, and many fungal diseases of invasion and attack fruit, vegetables and ornamental plants are had to preventive effect.Citrus, banana and other fruit are sprayed to formula dipping, and the water that can prevent and treat after results rots.
Copper agent, all effective to fungi, bacterium, and there is no resistance, there is no volatility.Its sterilizing mechanisms is: moisture copper is to have bioactive copper, moisture copper discharges copper ion, after copper ion is absorbed, act on multiple sites, cause nonspecific protein denaturation, and then cause three results: 1, the sprouting of the brood body of Antifungi and bacterium; 2, the growth of anti-bacteria; 3, stop the growth of mycelia.In the present invention, any one that what this series bactericidal agent adopted is in following bactericide: described copper agent bactericide is any one in following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
Methoxy acrylic bactericide (claiming Strobilurin abroad), is a kind of bionic fungicide, is a landmark disinfectant use in agriculture after benzimidazole and triazole type, at present, has become the very important bactericide of a class.It has fungicidal spectrum very widely, almost all known fungies are had to control efficiency, and using dosage is low.Its mechanism of action is all that the electronics transmission by blocking between cytochrome b and c1 suppresses mitochondrial respiration, can effectively prevent and treat the pathogen series that other bactericide is produced to resistance.In the present invention, any one that what this series bactericidal agent adopted is in following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, ZJ0712, fluoxastrobin, nitrile Fluoxastrobin, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Triazole bactericidal agent, in its chemical constitution, common feature is, contains hydroxyl (ketone group), substituted-phenyl and 1,2,4-triazole group compound on main chain.Triazole bactericidal agent, except to Mastigomycotina, middle oomycetes non-activity, all has activity to the pathogen of Ascomycotina, Basidiomycotina and Deuteromycotina, and its mechanism of action, for to affect sterols biosynthesis, is damaged somatic cells film function.In the present invention, any one that what this series bactericidal agent adopted is in following bactericide: penta ring bacterium, bromuconazole, ether azoles, alkene azoles alcohol, smart alkene azoles alcohol, oxole bacterium, Fluquinconazole, Flutriafol, tricyclazole, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, imidazoles, paclobutrazol, prothioconazoles, fluosilicic bitertanol azoles, Tebuconazole, triazolone, triadimenol, triticonazole, uniconazole P.
Acid amide fungicides is the organic compound that contains amide structure in chemical constitution.Rust pathogen Uromyces, Puccinia and black rust pathogen Ustilago to wheat class, Tilletia, and the soil fungi such as Rhizoctonia that causes root rot, fusarium wilt on the crops such as tomato, eggplant, cucumber is effectively, effective especially to Basidiomycetes.In the present invention, any one that what this series bactericidal agent adopted is in following bactericide: M 9834, smart M 9834, benodanil,, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, isotianil, the third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
Thiocarbamates bactericide, its main mechanism: (1) destroys COASH, thus affect the oxidation of fatty acid; (2) activity of the enzyme of inhibition taking copper, iron etc. as prothetic group.In the present invention, any one that what this series bactericidal agent adopted is in following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
Benzimidazole germicide, to have the benzimidazole ring of bactericidal activity as a class organic bactericide of parent, nearly all this compounds all shows interior suction bactericidal activity.In the present invention, what this series bactericidal agent adopted is thiophanate methyl.
Substituted beneze-group fungicides, contain the organic bactericide of phenyl ring in chemical constitution, its most of kind has efficiently, the feature of low toxicity, wide spectrum.In the present invention, what this series bactericidal agent adopted is tpn.
Pyroles bactericide, the wide-spectrum bactericide of genus non-internal-absorting, by suppressing the relevant transfer of glucose phosphorylated, and the mycelial growth of Antifungi, finally cause germ death.Mechanism of action uniqueness, with existing biocide agent without cross resistance.In the present invention, what this series bactericidal agent adopted is fludioxonil or fenpiclonil.
Dicarboximide fungicide, is a class broad-spectrum germicide, and spore germination, mycelial growth to fungi all have inhibitory action, causes thalli morphology to change, and mycelia top has produced abnormal branch and swelling.In the present invention, what this series bactericidal agent adopted is iprodione, dimethachlon or procymidone.
Phthalimide series bactericidal agent, broad spectrum activity low toxicity bactericide, taking protective effect as main, has certain therapeutic action concurrently.In the present invention, what this series bactericidal agent adopted is captan or folpet.
Carbamate fungicide, belongs to low toxicity bactericide, medicament enter after somatic cells with somatic cells in tubulin binding, thereby affect the division of cell.In the present invention, what this series bactericidal agent adopted is the mould prestige of Propamocarb or second.
Imidazoles bactericide is a class broad-spectrum germicide.In the present invention, what this series bactericidal agent adopted is prochloraz-manganese chloride complex complex compound or pefurazoate.
Morpholine series bactericidal agent, is a series bactericidal agent that contains morpholine ring structure, is the broad spectrum activity systemic fungicide with protection and therapeutic action.In the present invention, any one that what this series bactericidal agent adopted is in following bactericide: dimethomorph, flumorph, bacterium quinoline, butadiene morpholine.
Oxazole series bactericidal agent, in the present invention, any one that what this series bactericidal agent adopted is in following bactericide: Famoxate, SYP-Zo48, the mould spirit of evil, Wakil.
Antibiotics bactericide, deriving from the secondary metabolite of microorganisms and the bioactivator of generation is model, manually synthesizes or structure of modification, becomes artificial semisynthetic product.This series bactericidal agent have interior absorption energy, efficient, selectivity by force, effectively treatment and protective effect, and biological degradation is fast, nuisanceless, to advantages such as person poultry safeties.In the present invention, any one that what this series bactericidal agent adopted is in following bactericide: jinggangmeisu, kasugarnycin, pesticide corrosion 120, agricultural streptomycin, blasticidin-S, Polyoxin.
In addition, in the present invention, also adopted the one in Rabcide, Yekuzuo or bromothalonil.
Embodiment 1:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of imazalil;
The former medicine 10% of Thiodiazole-copper;
Wetting agent 4%;
Dispersant 6%;
White carbon 4%;
Kaolin 56%.
Embodiment 2:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 50% of imazalil;
The former medicine 3% of azoles bacterium ester;
Wetting agent 4%;
Dispersant 4%;
White carbon 5%;
Kaolin 34%.
Embodiment 3:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 30% of imazalil;
Mensurating Tricyclazole Technical 10%;
Wetting agent 5%;
Dispersant 5%;
White carbon 5%;
Kaolin 45%.
Embodiment 4:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of imazalil;
The former medicine 20% of dimethomorph;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 40%.
Embodiment 5:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of imazalil;
The former medicine 40% of thiophanate methyl;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 20%.
Embodiment 6:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of imazalil;
The former medicine 38% of zineb;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 22%.
Embodiment 7:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The efficient former medicine 20% of imazalil;
The former medicine 42% of pefurazoate;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 18%.
Embodiment 8:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The efficient former medicine 20% of imazalil;
The former medicine 45% of tpn;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 15%.
Embodiment 9:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The efficient former medicine 20% of imazalil;
The former medicine 15% of fludioxonil;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 45%.
Embodiment 10:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of imazalil;
The former medicine 20% of iprodione;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 40%.
Embodiment 11:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The former medicine 20% of imazalil;
The former medicine 10% of the mould prestige of second;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 50%.
Embodiment 12:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The efficient former medicine 22% of imazalil;
The former medicine 20% of bromothalonil;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 38%.
Embodiment 13:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The efficient former medicine 32% of imazalil;
The former medicine 20% of flumorph;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 28%.
Embodiment 14:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The efficient former medicine 32% of imazalil;
The former medicine 20% of Wakil;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 28%.
Embodiment 15:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The efficient former medicine 32% of imazalil;
The former medicine 10% of Polyoxin;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 38%.
Embodiment 16:
A bactericidal composition that contains imazalil, each raw material components and consumption are as follows:
Raw material consumption (weight portion)
The efficient former medicine 32% of imazalil;
The former medicine 10% of captan;
Wetting agent 7%;
Dispersant 8%;
White carbon 5%;
Kaolin 38%.
Claims (9)
1. a bactericidal composition that contains imazalil, is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine forming of bactericide B;
Described bactericide A is imazalil or efficient imazalil;
Any one in the bactericide that described bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates, oxazole class and antibiotics, and other classes.
2. the bactericidal composition that contains imazalil according to claim 1, is characterized in that: described copper agent bactericide is any one in following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
3. the bactericidal composition that contains imazalil according to claim 1, is characterized in that: described methoxy acrylic bactericide is any one in following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, ZJ0712, fluoxastrobin, nitrile Fluoxastrobin, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
4. the bactericidal composition that contains imazalil according to claim 1, is characterized in that: described triazole bactericidal agent is any one in following bactericide: penta ring bacterium, bromuconazole, ether azoles, alkene azoles alcohol, smart alkene azoles alcohol, oxole bacterium, Fluquinconazole, Flutriafol, tricyclazole, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, imidazoles, paclobutrazol, prothioconazoles, fluosilicic bitertanol azoles, Tebuconazole, triazolone, triadimenol, triticonazole, uniconazole P.
5. the bactericidal composition that contains imazalil according to claim 1, is characterized in that: described acid amide fungicides is any one in following bactericide: M 9834, smart M 9834, benodanil,, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, isotianil, the third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
6. the bactericidal composition that contains imazalil according to claim 1, is characterized in that: described thiocarbamates bactericide is any one in following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
7. the bactericidal composition that contains imazalil according to claim 1, is characterized in that: described benzimidazole germicide is thiophanate methyl; Described substituted beneze-group fungicides are tpn; Described pyroles bactericide is fludioxonil or fenpiclonil; Described dicarboximide fungicide is iprodione, dimethachlon or procymidone; Described phthalimide series bactericidal agent is captan or folpet; Described carbamate fungicide is Propamocarb or the mould prestige of second.
8. the bactericidal composition that contains imazalil according to claim 1, is characterized in that:
Described imidazoles bactericide is any one in following bactericide: prochloraz-manganese chloride complex complex compound, pefurazoate;
Described morpholine series bactericidal agent is any one in following bactericide: dimethomorph, flumorph, bacterium quinoline, butadiene morpholine;
Described oxazole series bactericidal agent is any one in following bactericide: Famoxate, SYP-Zo48, the mould spirit of evil, Wakil;
Described antibiotics bactericide is any one in following bactericide: jinggangmeisu, kasugarnycin, pesticide corrosion 120, agricultural streptomycin, blasticidin-S, Polyoxin.
9. the bactericidal composition that contains imazalil according to claim 1, is characterized in that: described other series bactericidal agents are Rabcide, Yekuzuo or bromothalonil.
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