CN102823603A - Sterilization compound containing chloroisobromine cyanuric acid - Google Patents
Sterilization compound containing chloroisobromine cyanuric acid Download PDFInfo
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- CN102823603A CN102823603A CN2012103456286A CN201210345628A CN102823603A CN 102823603 A CN102823603 A CN 102823603A CN 2012103456286 A CN2012103456286 A CN 2012103456286A CN 201210345628 A CN201210345628 A CN 201210345628A CN 102823603 A CN102823603 A CN 102823603A
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Abstract
The invention discloses a sterilization compound containing chloroisobromine cyanuric acid, comprising a raw medicine formed by compounding a sterilizing agent A and a sterilizing agent B, wherein the proportion of the sterilizing agent A to the sterilizing agent B is (1-80):(1-80); the sterilizing agent A is the chloroisobromine cyanuric acid; and the sterilizing agent B is any one of the following types of the sterilizing agents: copper preparations, methoxy acrylic esters, triazoles, amides, benzimidazoles, thiocarbamates, substituted benzenes, dicarboximides, phthalimides, imidazoles, morpholines, carbamates, oxazoles and the like. The sterilization compound is formed by compounding the sterilizing agent A and the sterilizing agent B so that not only a sterilization spectrum is enlarged, but also the drug resistance of bacteria is slowed; and the sterilization compound has an obvious lasting synergistic effect.
Description
Technical field
The present invention relates to technical field of pesticide, specifically, relate to a kind of bactericidal composition that contains chlorobromide isocyanuric acid.
Background technology
Bactericide is the one type of agricultural chemicals that is used to prevent and treat the plant disease that is caused by various pathogenic microorganisms, refers generally to fungicide.But in the world, normally as the general name of medicament of all kinds of pathogenic microorganisms of control.Along with the development of bactericide, distinguish subclass such as bactericide, virucide, algicide again.According to investigations, the whole world pathogenic microorganism (fungi, strong bacterium, rickettsia, mycoplasma, virus, algae etc.) harmful to plant has more than 80,000 kinds.Using bactericide is a kind of cost-effective method of controlling plant diseases.
Early stage bactericide all is an inorganic compound, is wherein still using so far like Cosan and copper agent (like bordeaux mixture).Twentieth century four the fifties, developed the organosulfureous fungicides that three main series are arranged: beautiful type of good fortune, generation gloomy type of (like zineb) and trichloro-methylthio diformazan carboxylic acid imide, organochlorine, organic mercury, organoarsenic fungicide also have development in addition.These bactericide are protectant mostly, and limitation is arranged in the application.Since the sixties, more the bactericide of polyvoltine type constantly occurs, and wherein most important progress is the appearance of systemic fungicide.Meanwhile, farm antibiotics also has development faster.Organic mercury, organo-arsenic and some organochlorine bactericide are because of toxicity or problem of environmental pollution gradually are eliminated.The systemics bactericide of a new generation further enlarges the market of bactericide owing to control efficiency improves.To the eighties, the kind of bactericide is above 200 kinds.
Chlorobromide isocyanuric acid, english common name: chloroisobromine cyanuric acid, spray in crop surface and can discharge hypobromous acid (HOBr) and hypochlorous acid (HOCL) at leisure, the ability of strong kill bacteria, fungi and virus is arranged.In addition, because of initiation material is rich in sylvite and trace element crowd, therefore, chlorobromide isocyanuric acid not only has the ability of strong prevention and kill bacteria, fungi and virus, and effect such as promotion crop alimentary growth is arranged.
Yet in the real process of agricultural production, preventing and treating the problem that disease is easy to generate most is the drug-fast generation of germ.The different cultivars composition carries out composite, is to prevent and treat the very common method of resistance germ.
Copper agent, all effective to fungi, bacterium, and do not have resistance, there is not volatility.Its sterilizing mechanisms is: moisture copper is the copper of biologically active; Moisture copper copper ion releasing; Act on a plurality of sites after copper ion is absorbed, cause nonspecific protein denaturation, and then cause three results: 1, suppress the sprouting of the brood body of fungi and bacterium; 2, suppress the growth of bacterium; 3, stop the growth of mycelia.This series bactericidal agent mainly comprises: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
Methoxy acrylic bactericide (claiming Strobilurin abroad) is a kind of bionical bactericide, is a landmark disinfectant use in agriculture after benzimidazole and triazole type, at present, has become one type of very important bactericide.It has fungicidal spectrum very widely, almost all known fungies are all had control efficiency, and using dosage is low.Its mechanism of action all is to suppress mitochondrial respiration through the electronics transmission of blocking between cytochrome b and the c1, can effectively prevent and treat the pathogen series that other bactericide is produced resistance.This series bactericidal agent mainly comprises: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, ZJ0712, Fluoxastrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Triazole bactericidal agent, common feature is on its chemical constitution, contains hydroxyl (ketone group), substituted-phenyl and 1,2 on the main chain, 4-triazole group compound.Triazole bactericidal agent is except that to Mastigomycotina, the middle oomycetes non-activity, and the pathogen of Ascomycotina, Basidiomycotina and Deuteromycotina is all had activity, and its mechanism of action is damaged somatic cells film function for to influence the sterols biosynthesis.This series bactericidal agent mainly comprises: penta ring bacterium, bromuconazole, cyproconazole, ether azoles, alkene azoles alcohol, smart alkene azoles alcohol, oxole bacterium, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, own azoles alcohol, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, nitrile bacterium azoles, imidazoles, paclobutrazol, penconazole, Difenoconazole, propiconazole, prothioconazoles, simeconazoles, Tebuconazole, fluorine ether azoles, triazolone, triadimenol, triticonazole, uniconazole P.
Acid amide fungicides is the organic compound that contains amide structure in the chemical constitution.Rust pathogen Uromyces, Puccinia and black rust pathogen Ustilago, Tilletia to the wheat class; And the soil fungis such as Rhizoctonia that on crops such as tomato, eggplant, cucumber, cause root rot, fusarium wilt are effectively, and are effective especially to Basidiomycetes.This series bactericidal agent mainly comprises: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, different metsulfovax, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
Benzimidazole germicide is one type of organic bactericide of parent with the benzimidazole ring that bactericidal activity is arranged, and inhales bactericidal activity in nearly all this compounds all shows.This series bactericidal agent mainly comprises carbendazim, thiophanate methyl etc.
The thiocarbamates bactericide, its main mechanism: COASH is destroyed in (1), thereby influences oxidation of fatty acids; (2) suppressing with copper, iron etc. is the activity of the enzyme of prothetic group.This series bactericidal agent mainly comprises: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
Substituted beneze-group fungicides contain the organic bactericide of phenyl ring in the chemical constitution, its most of kind has efficiently, the characteristics of low toxicity, wide spectrum.This series bactericidal agent mainly comprises pcnb, tpn, fenaminosulf etc.
Dicarboximide fungicide is one type of broad-spectrum germicide, and spore germination, the mycelial growth of fungi all had inhibitory action, causes thalli morphology to change, and the mycelia top has produced abnormal branch and swelling.This series bactericidal agent mainly comprises iprodione, dimethachlon, procymidone etc.
The imidazoles bactericide is one type of broad-spectrum germicide, and this series bactericidal agent mainly comprises Prochloraz, cyanogen frost azoles, presses down mould azoles, efficiently presses down mould azoles, prochloraz-manganese chloride complex complex compound, fluorine bacterium azoles, pefurazoate etc.
Summary of the invention
The objective of the invention is to overcome the defective of prior art, a kind of bactericidal composition that contains chlorobromide isocyanuric acid is provided.
For addressing the above problem, the technical scheme that the present invention adopted is:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Said bactericide A is a chlorobromide isocyanuric acid;
Optional one of which in the bactericide that said bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates He oxazole class, and other types.
Say further:
Said copper agent bactericide is an optional one of which in the following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
Said methoxy acrylic bactericide is an optional one of which in the following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, ZJ0712, Fluoxastrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Said triazole bactericidal agent is an optional one of which in the following bactericide: penta ring bacterium; Bromuconazole; Cyproconazole; The ether azoles; Alkene azoles alcohol; Smart alkene azoles alcohol; Oxole bacterium; RH-7592; Fluquinconazole; Flusilazole; Flutriafol; Tricyclazole; Own azoles alcohol; The acid amides azoles; Cycltebuconazole; Encircle penta azoles bacterium; Nitrile bacterium azoles; Imidazoles; Paclobutrazol; Bitertanol; Penconazole; Difenoconazole; Propiconazole; Prothioconazoles; Tetraconazole; Simeconazoles; Tebuconazole; Fluorine ether azoles; Triazolone; Triadimenol; Triticonazole; Uniconazole P.
Said acid amide fungicides is an optional one of which in the following bactericide: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, different metsulfovax, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
Said benzimidazole germicide is carbendazim or thiophanate methyl.
Said thiocarbamates bactericide is an optional one of which in the following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
Said substituted beneze-group fungicides are tpn; Said pyroles bactericide is fludioxonil or fenpiclonil; Said dicarboximide fungicide is iprodione, dimethachlon or procymidone; Said phthalimide series bactericidal agent is captan or folpet; Said carbamate fungicide is Propamocarb or the mould prestige of second.
Said imidazoles bactericide is an optional one of which in the following bactericide: Prochloraz, cyanogen frost azoles, press down mould azoles, efficiently press down mould azoles, prochloraz-manganese chloride complex complex compound, fluorine bacterium azoles, pefurazoate;
Said morpholine series bactericidal agent is an optional one of which in the following bactericide: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine;
Suo Shu oxazole series bactericidal agent is optional one of which: oxazole bacterium ketone, SYP-Z048 、 hymexazo, a Wakil in the following bactericide.
Said other series bactericidal agents are Rabcide, Yekuzuo, bromothalonil.
Furtherly, the proportioning of said bactericide A and bactericide B is: 2: 1.
Again furtherly, said bactericide be missible oil, micro emulsion, water and milk, suspending agent (comprising: do outstanding, water is outstanding and oil outstanding), all formulations such as pulvis, soluble liquid, wetting powder, granula, soluble powder, water dispersible granules or suspension emulsion.
Owing to adopted technique scheme, compared with prior art, the present invention adopts bactericide A and forms with bactericide B is composite, has not only enlarged fungicidal spectrum, has also slowed down the pesticide resistance of germ, has significantly lasting synergistic effect.
Below in conjunction with embodiment the present invention is further specified.
Embodiment
A kind of bactericidal composition that contains chlorobromide isocyanuric acid comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Said bactericide A is a chlorobromide isocyanuric acid;
Optional one of which in the bactericide that said bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates He oxazole class, and other types.
Said copper agent bactericide is an optional one of which in the following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
Said methoxy acrylic bactericide is an optional one of which in the following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, ZJ0712, Fluoxastrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Said triazole bactericidal agent is an optional one of which in the following bactericide: penta ring bacterium; Bromuconazole; Cyproconazole; The ether azoles; Alkene azoles alcohol; Smart alkene azoles alcohol; Oxole bacterium; RH-7592; Fluquinconazole; Flusilazole; Flutriafol; Tricyclazole; Own azoles alcohol; The acid amides azoles; Cycltebuconazole; Encircle penta azoles bacterium; Nitrile bacterium azoles; Imidazoles; Paclobutrazol; Bitertanol; Penconazole; Difenoconazole; Propiconazole; Prothioconazoles; Tetraconazole; Simeconazoles; Tebuconazole; Fluorine ether azoles; Triazolone; Triadimenol; Triticonazole; Uniconazole P.
Said acid amide fungicides is an optional one of which in the following bactericide: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, different metsulfovax, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
Said benzimidazole germicide is carbendazim or thiophanate methyl.
Said thiocarbamates bactericide is an optional one of which in the following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
Said substituted beneze-group fungicides are tpn; Said pyroles bactericide is fludioxonil or fenpiclonil; Said dicarboximide fungicide is iprodione, dimethachlon or procymidone; Said phthalimide series bactericidal agent is captan or folpet; Said carbamate fungicide is Propamocarb or the mould prestige of second.
Said imidazoles bactericide is an optional one of which in the following bactericide: Prochloraz, cyanogen frost azoles, press down mould azoles, efficiently press down mould azoles, prochloraz-manganese chloride complex complex compound, fluorine bacterium azoles, pefurazoate;
Said morpholine series bactericidal agent is an optional one of which in the following bactericide: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine;
Suo Shu oxazole series bactericidal agent is optional one of which: oxazole bacterium ketone, SYP-Z048 、 hymexazo, a Wakil in the following bactericide.
Said other series bactericidal agents are Rabcide, Yekuzuo, bromothalonil.
One of preferred as technique scheme, the proportioning of said bactericide A and bactericide B is: 2: 1.
Embodiment 1:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 2:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 3:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 4:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 5:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 6:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 7:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 8:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 9:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 10:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 11:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 12:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 13:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 14:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 15:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 16:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Claims (10)
1. bactericidal composition that contains chlorobromide isocyanuric acid, it is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Said bactericide A is a chlorobromide isocyanuric acid;
Optional one of which in the bactericide that said bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates He oxazole class, and other types.
2. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said copper agent bactericide is an optional one of which in the following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
3. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said methoxy acrylic bactericide is an optional one of which in the following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, ZJ0712, Fluoxastrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
4. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said triazole bactericidal agent is an optional one of which in the following bactericide: penta ring bacterium, bromuconazole, cyproconazole, ether azoles, alkene azoles alcohol, smart alkene azoles alcohol, oxole bacterium, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, tricyclazole, own azoles alcohol, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, nitrile bacterium azoles, imidazoles, paclobutrazol, bitertanol, penconazole, Difenoconazole, propiconazole, prothioconazoles, tetraconazole, simeconazoles, Tebuconazole, fluorine ether azoles, triazolone, triadimenol, triticonazole, uniconazole P.
5. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said acid amide fungicides is an optional one of which in the following bactericide: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, different metsulfovax, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
6. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said benzimidazole germicide is carbendazim or thiophanate methyl.
7. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said thiocarbamates bactericide is an optional one of which in the following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
8. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said substituted beneze-group fungicides are tpn; Said pyroles bactericide is fludioxonil or fenpiclonil; Said dicarboximide fungicide is iprodione, dimethachlon or procymidone; Said phthalimide series bactericidal agent is captan or folpet; Said carbamate fungicide is Propamocarb or the mould prestige of second.
9. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that:
Said imidazoles bactericide is an optional one of which in the following bactericide: Prochloraz, cyanogen frost azoles, press down mould azoles, efficiently press down mould azoles, prochloraz-manganese chloride complex complex compound, fluorine bacterium azoles, pefurazoate;
Said morpholine series bactericidal agent is an optional one of which in the following bactericide: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine;
Suo Shu oxazole series bactericidal agent is optional one of which: oxazole bacterium ketone, SYP-Z048 、 hymexazo, a Wakil in the following bactericide.
10. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said other series bactericidal agents are Rabcide, Yekuzuo, bromothalonil.
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| CN110741869A (en) * | 2019-11-29 | 2020-02-04 | 贵州黎源上品农业科技开发有限公司 | Method for improving fruit setting rate and yield of Bufna |
| CN111213659A (en) * | 2020-03-29 | 2020-06-02 | 邢宇俊 | Bactericidal composition containing metconazole and chlorobromoisocyanuric acid |
| CN112369325A (en) * | 2020-10-21 | 2021-02-19 | 甘肃亚盛农业研究院有限公司 | Safe, low-toxicity and high-efficiency sterilization method for plant explants |
| CN112715562A (en) * | 2021-01-08 | 2021-04-30 | 黑龙江巨卓作物科学有限公司 | Bactericidal composition containing chlorobromoisocyanuric acid and tricyclazole |
| CN116035012A (en) * | 2023-01-09 | 2023-05-02 | 河南科技学院 | Sterilization composition containing bromoisocyanuric acid and fluxapyroxad hydroxylamine |
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