CN103004819A - Fluopicolide-containing bactericide composition - Google Patents

Fluopicolide-containing bactericide composition Download PDF

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CN103004819A
CN103004819A CN2012105236632A CN201210523663A CN103004819A CN 103004819 A CN103004819 A CN 103004819A CN 2012105236632 A CN2012105236632 A CN 2012105236632A CN 201210523663 A CN201210523663 A CN 201210523663A CN 103004819 A CN103004819 A CN 103004819A
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bactericide
fluopicolide
fluoxastrobin
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combination
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王学权
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Abstract

Belonging to the technical field of pesticides, the invention discloses a Fluopicolide-containing bactericide composition, which includes a primary drug compounded from bactericide A and bactericide B. Specifically, bactericide A and bactericide B are in a ratio of 1-80:1-80. The bactericide A is Fluopicolide, and the bactericide B is any one of: Iprovalicarb, flumorph, cymoxanil, phosethyl-Al, propamocarb, Metalaxyl-M, oxadixyl, hymexazol, enestroburin, SYP-1620, pyraoxystrobin, pyrametostrobin, pyraclostrobin, fluoxastrobin, azoxystrobin and picoxystrobin. Compared with the prior art, the composition provided in the invention is compounded from bactericide A and bactericide B which are used in combination, slows down the generation of Fluopicolide resistance in pathogenic bacteria, prolongs the efficacy duration, and has a very strong synergistic effect.

Description

A kind of bactericide combination that contains fluopicolide
Technical field
The present invention relates to technical field of pesticide, specifically, relate to a kind of bactericide combination that contains fluopicolide.
Background technology
Bactericide is for a class agricultural chemicals of preventing and treating the plant disease that is caused by various pathogenic microorganisms, refers generally to fungicide.But in the world, normally as the general name of medicament of all kinds of pathogenic microorganisms of control.Along with the development of bactericide, distinguish again the subclass such as bactericide, virucide, algicide.According to investigations, the whole world pathogenic microorganism (fungi, strong bacterium, rickettsia, mycoplasma, virus, algae etc.) harmful to plant has more than 80,000 kinds.Using bactericide is a kind of cost-effective method of controlling plant diseases.
Early stage bactericide all is inorganic compound, is wherein still using so far such as Cosan and copper agent (such as bordeaux mixture).Twentieth century four the fifties, developed the organosulfureous fungicides that three main series are arranged: the U.S. class of good fortune, generation gloomy class (such as zineb) and trichloro-methylthio diformazan carboxylic acid imide, organochlorine, organic mercury, organoarsenic fungicide also have development in addition.These bactericide are protectant mostly, and limitation is arranged in the application.Since the sixties, more the bactericide of polyvoltine type constantly occurs, and wherein most important progress is the appearance of systemic fungicide.Meanwhile, farm antibiotics also has faster development.Organic mercury, organo-arsenic and some organochlorine bactericide are because toxicity or problem of environmental pollution gradually are eliminated.The systemics bactericide of a new generation further enlarges the market of bactericide owing to control efficiency improves.To the eighties, the kind of bactericide is above 200 kinds.
At present; bactericide various in style; wherein; fluopicolide is a kind of Oomycete vegetable disease of preventing and treating; insecticide with efficient protection and result for the treatment of; this product has good system's conductivity and stronger thin layer penetration power, and each Main Morphology of pathogen is all had preferably inhibitory action, can provide comprehensively and lasting protection for young leaves, stem, stem tuber, young fruit.Although it is relatively good that fluopicolide is prevented and treated the effect of disease,, through long abuse, germ has produced slight pesticide resistance to it.
Iprovalicarb is the amino-acid ester analog derivative, has unique brand-new biomimetic features, makes its mechanism of action be different from the bactericide that other prevent and treat Oomycete.Its mechanism of action is: act on the synthetic of fungal cell wall and protein, can suppress infecting and sprouting of spore, can suppress mycelial growth simultaneously, cause its distortion, death.Have good treatment and eradicant action for Peronosporaceae and the fungus-caused disease of Phytophthora.
Flumorph belongs to morpholine class disinfectant use in agriculture, and is effective especially to Peronospora, epidemic disease mycin germ.To the Oomycete on grape, potato and the tomato, especially Peronosporaceae and Phytophthora bacterium have fungicidal effectiveness, can use with tagging property bactericide.
Frost urea cyanogen is a kind of efficient, low toxicity bactericide, to the Peronosporales fungi, belongs to effectively such as epidemic disease frost genus, Peronospora, single shaft frost.Frost urea cyanogen and other protective fungicides are used with extensively, are used in the brassicaceous vegetable such as cucumber, grape, tomato, lichee, huge dish and tobacco etc.
Three second aluminium phosphates are a kind of organic phosphates systemic fungicides, have protection and therapeutic action, and the microbial disease of the algaes such as Peronospora, Phytophthora is had good preventive effect.
Propamocarb belongs to the aliphatic category bactericide, and low toxicity, safety have preferably local systemic action.After processing soil, can also upwards be delivered to whole strain plant by Root Absorption very soon; After the cauline leaf spraying is processed, can be played a protective role by rapid absorption of blade.Propamocarb is a kind of wide-spectrum bactericide, effective especially to algae Gammaproteobacteria fungi,, the fungies such as dish stalk mould, downy mildew, epidemic disease mould, corruption mould mould to tow have good control efficiency, its mechanism of action is to suppress the phosphoric acid of germ cell membrane component and synthesizing of fatty acid, suppresses mycelial growth and spreads and sporangial formation and spore germination.
Essence-metalaxyl belongs to the anilide bactericide, to the vegetables due to Pseudoperonospora cubensis, phytophthora root rot bacterium, the rotten mildew fungus, and fruit tree, tobacco, oil plant, cotton, the crop pests such as grain have efficiently.
Wakil has very high preventive effect to Peronosporales pathogeny bacterium, and protection and therapeutic action are arranged, and the lasting period is long.
Dislike mould spirit, it is a kind of broad-spectrum germicide, the plant disease that the Various Diseases fungal pathogens is caused has prevents and treats the result preferably, the rotten bacterium of pythium spp, seedling, sickle-like bacteria, rhizoctonia, photovoltaicing leather bacteria, root shell bacterium, snow mould to mastigomycetes, sac fungi, basidiomycetes, Deuteromycotina have good result for the treatment of, being a kind of efficient, low toxicity, the bactericide of environmental protection, soil disinfectant, is again a plant growth regulators simultaneously.Dislike mould spirit and have interior absorption and conductivity, can directly be absorbed by plant root, and rapidly mobile in plant corpus; In soil, can improve drug effect, and the lasting period is long, uses in two weeks and still have bactericidal activity.It is unique to dislike the mould clever mechanism of action, can the mycelial normal growth of establishment disease fungus or direct killing pathogenic bacteria, and have promote that crop root grows, the effect of strong plantlets and rootage and raising survival rate.
Enestroburin belongs to methoxy acrylic bactericide, and fungicidal spectrum is wide, active high, has prevention and therapeutic action, to by mastigomycetes, the plurality of plant diseases that causes in conjunction with bacterium, sac fungi, basidiomycetes and imperfect fungus good control efficiency being arranged.The mechanism of action of Enestroburin be by with the combination of cytochrome b c1 complex, suppress mitochondrial electronics transmission, thereby it is synthetic to destroy the germ energy, plays bactericidal action, and cucumber, downy mildew of garpe, wheat powdery mildew etc. are had good control efficiency.
Alkene oxime amine, belong to methoxy acrylic bactericide, fungicidal spectrum is wide, active high, has preventive and therapeutic action, with environment, biology good compatibility is arranged, the plurality of plant diseases that is caused by mastigomycetes, zygomycete, sac fungi, basidiomycetes and imperfect fungus there is good control efficiency, to powdery mildew, rust control efficiency brilliance.Simultaneously, plant growth proterties and quality are improved significantly, and can improve output.The mechanism of action of alkene oxime amine is: the mitochondrial respiratory that acts on fungi, medicament by with the mitochondria electron transport chain in the combination of Complex II I (Cyt bc1 compound), the blocking-up electronics by Cyt bc1 complex logistics to Cytc, the ATP that destroys fungi is synthetic, thereby plays the effect of inhibition or kill fungi.
Azoles bacterium ester; bactericidal activity with wide spectrum; have simultaneously protection and therapeutic action, downy mildew, powdery mildew, gray mold, anthracnose, rice blast, brown spot and the early blight of vegetables and crop, late blight etc. are all had good preventive effect, have simultaneously obvious desinsection, acaricidal activity.
Azoles amine bacterium ester belongs to the bactericide of methoxy acrylic, and fungicidal spectrum is wide, has good protection and therapeutic activity.
Pyraclostrobin belongs to the bactericide of methoxy acrylic.Its mechanism of action is the mitochondrial respiratory inhibitor, makes mitochondria can not produce and provide cell eubolism institute energy requirement, finally causes cell death.It can control most of diseases such as Ascomycetes, Basidiomycetes, deuteromycetes, Oomycete.Growth to spore germination and leaf intramatrical mycelium has very strong inhibitory action, has protection and therapeutic activity.Have permeability and local systemic activity, the lasting period is long, resistance of rainwater washing against.Be widely used in preventing and treating the disease on wheat, paddy rice, peanut, grape, vegetables, potato, banana, lemon, coffee, fruit tree, walnut, tea tree, tobacco and ornamental plants, lawn and other field crops.
Fluoxastrobin belongs to methoxy acrylic bactericide, and its mechanism of action also is the mitochondrial respiratory inhibitor, namely shifts by electronics between cytochrome b and C1 and suppresses mitochondrial breathing.The fluoxastrobin application period is wide, no matter grows such as spore germination, germ tube in early days and intrusion leaf section at fungal infection, or can both provide extraordinary protection and therapeutic action at growth period of hypha, but infects the most effective to spore germination and initial stage.The systemic activity of the excellence that cause has, it can be rapidly absorbed, and can transmit to the top equably in leaf section, so have good resistance of rainwater washing against ability.
Fluoxastrobin, belong to methoxy acrylic bactericide, efficiently, wide spectrum, nearly all mycota disease such as powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast etc. all there is good activity, can be used for cauline leaf spraying, seed treatment, also soil treatment be can carry out, cereal, paddy rice, peanut, grape, potato, fruit tree, vegetables, coffee, lawn etc. are mainly used in.
ZEN 90160 is controlling object wide spectrum, systemic fungicide.The mechanism of action and characteristics: the mitochondrial respiratory inhibitor, namely shift by electronics between cytochrome b and C1 and suppress mitochondrial breathing.Control is effective to the bacterial strain that 14-demethylation enzyme inhibitor, benzamides, three carboxyl acylamides and benzimidazole produce resistance.Be mainly used in preventing and treating the foliage disease of wheat class such as leaf blight, leaf rust, glume blight, brown spot, powdery mildew etc.
Summary of the invention
The objective of the invention is to overcome the defective of prior art, a kind of bactericide combination that contains fluopicolide is provided.
For addressing the above problem, the technical solution adopted in the present invention is:
A kind of bactericide combination that contains fluopicolide, it is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Described bactericide A is fluopicolide;
Described bactericide B is optional one in the following bactericide: iprovalicarb, flumorph, white urea cyanogen, three second aluminium phosphates, Propamocarb, Metalaxyl-M, Wakil, the mould spirit of evil, Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, fluoxastrobin, Fluoxastrobin, ZEN 90160.
Say that further the proportioning of described bactericide A and bactericide B is: 2: 1.
Furtherly, described bactericide be missible oil, micro emulsion, water and milk, suspending agent (comprising: do outstanding, water is outstanding and oil outstanding), all formulations such as pulvis, soluble liquid, wetting powder, granula, soluble powder, water dispersible granules or suspension emulsion.
Owing to adopted technique scheme, compared with prior art, the present invention adopts bactericide A and forms with bactericide B is composite, and composite use has slowed down germ to the drug-fast generation of fluopicolide, the prolongation lasting period, and very strong synergistic effect is arranged.
Embodiment
The present invention will be further described below in conjunction with embodiment.
A kind of bactericide combination that contains fluopicolide comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Described bactericide A is fluopicolide;
Described bactericide B is the optional one in the following bactericide: iprovalicarb, flumorph, white urea cyanogen, three second aluminium phosphates, Propamocarb, Metalaxyl-M, Wakil, the mould spirit of evil, Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, fluoxastrobin, Fluoxastrobin, ZEN 90160.
One of preferred as technique scheme, the proportioning of described bactericide A and bactericide B is: 2: 1.
Embodiment 1:
A kind of bactericide combination that contains fluopicolide, each raw material components and consumption are as follows:
Figure BSA00000819949600051
Embodiment 2:
A kind of bactericide combination that contains fluopicolide, each raw material components and consumption are as follows:
Figure BSA00000819949600052
Embodiment 3:
A kind of bactericide combination that contains fluopicolide, each raw material components and consumption are as follows:
Figure BSA00000819949600061
Embodiment 4:
A kind of bactericide combination that contains fluopicolide, each raw material components and consumption are as follows:
Figure BSA00000819949600062

Claims (1)

1. bactericide combination that contains fluopicolide, it is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Described bactericide A is fluopicolide;
Described bactericide B is optional one in the following bactericide: iprovalicarb, flumorph, white urea cyanogen, three second aluminium phosphates, Propamocarb, essence-metalaxyl, Wakil, the mould spirit of evil, Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, fluoxastrobin, Fluoxastrobin, ZEN 90160.
CN2012105236632A 2012-11-30 2012-11-30 Fluopicolide-containing bactericide composition Pending CN103004819A (en)

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Cited By (10)

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CN103004822A (en) * 2013-01-21 2013-04-03 山东滨农科技有限公司 Bactericide composition containing pyraclostrobin and fluopicolide
CN103814907A (en) * 2014-01-26 2014-05-28 上海艳紫化工科技有限公司 Pesticide suspending agent compounded from flumorph and pyraoxystrobin
CN104115853A (en) * 2013-04-23 2014-10-29 陕西美邦农药有限公司 Pesticide composition containing carbamate bactericide
CN104663675A (en) * 2015-02-04 2015-06-03 河南科技学院 Sterilization composition containing hymexazol and fluopyram and application of sterilization composition
CN106035379A (en) * 2016-06-27 2016-10-26 中国烟草总公司郑州烟草研究院 Bactericide composition containing phenylamide and benzamide bactericides and biocontrol bacterium, preparation and applications
CN107027763A (en) * 2017-06-15 2017-08-11 陕西先农生物科技有限公司 Containing fluopicolide and the composition pesticide of cymoxanil and preparation method thereof
CN107125254A (en) * 2017-05-30 2017-09-05 兴农药业(中国)有限公司 A kind of composition pesticide of fluopicolide and pyraclostrobin
CN107771808A (en) * 2016-08-29 2018-03-09 南京华洲药业有限公司 A kind of bactericidal composition and its application containing ZEN 90160 and fluopicolide
CN108432765A (en) * 2018-03-12 2018-08-24 佛山市盈辉作物科学有限公司 A kind of bactericidal composition of bacterium containing figured silk fabrics amine and ZEN 90160
CN112970760A (en) * 2021-02-24 2021-06-18 安徽科技学院 Ternary compound bactericide and application thereof in prevention and treatment of wheat stem basal rot

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Cited By (12)

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Publication number Priority date Publication date Assignee Title
CN103004822A (en) * 2013-01-21 2013-04-03 山东滨农科技有限公司 Bactericide composition containing pyraclostrobin and fluopicolide
CN104115853A (en) * 2013-04-23 2014-10-29 陕西美邦农药有限公司 Pesticide composition containing carbamate bactericide
CN103814907A (en) * 2014-01-26 2014-05-28 上海艳紫化工科技有限公司 Pesticide suspending agent compounded from flumorph and pyraoxystrobin
CN103814907B (en) * 2014-01-26 2016-03-02 上海艳紫化工科技有限公司 Flumorph and the composite agricultural chemicals suspension agent of azoles bacterium ester
CN104663675A (en) * 2015-02-04 2015-06-03 河南科技学院 Sterilization composition containing hymexazol and fluopyram and application of sterilization composition
CN106035379A (en) * 2016-06-27 2016-10-26 中国烟草总公司郑州烟草研究院 Bactericide composition containing phenylamide and benzamide bactericides and biocontrol bacterium, preparation and applications
CN107771808A (en) * 2016-08-29 2018-03-09 南京华洲药业有限公司 A kind of bactericidal composition and its application containing ZEN 90160 and fluopicolide
CN107125254A (en) * 2017-05-30 2017-09-05 兴农药业(中国)有限公司 A kind of composition pesticide of fluopicolide and pyraclostrobin
CN107027763A (en) * 2017-06-15 2017-08-11 陕西先农生物科技有限公司 Containing fluopicolide and the composition pesticide of cymoxanil and preparation method thereof
CN108432765A (en) * 2018-03-12 2018-08-24 佛山市盈辉作物科学有限公司 A kind of bactericidal composition of bacterium containing figured silk fabrics amine and ZEN 90160
CN108432765B (en) * 2018-03-12 2020-04-07 佛山市盈辉作物科学有限公司 Sterilization composition containing valienamine and picoxystrobin
CN112970760A (en) * 2021-02-24 2021-06-18 安徽科技学院 Ternary compound bactericide and application thereof in prevention and treatment of wheat stem basal rot

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