CN103004822A - Bactericide composition containing pyraclostrobin and fluopicolide - Google Patents
Bactericide composition containing pyraclostrobin and fluopicolide Download PDFInfo
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- CN103004822A CN103004822A CN201310019607XA CN201310019607A CN103004822A CN 103004822 A CN103004822 A CN 103004822A CN 201310019607X A CN201310019607X A CN 201310019607XA CN 201310019607 A CN201310019607 A CN 201310019607A CN 103004822 A CN103004822 A CN 103004822A
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Abstract
The invention relates to the field of pesticides and bactericides, and particularly discloses a bactericide composition containing pyraclostrobin and fluopicolide. Effective ingredients of the bactericide composition are the pyraclostrobin and the fluopicolide respectively, and the weight ratio of the pyraclostrobin to the fluopicolide is 1-79:79-1. The bactericide composition containing the pyraclostrobin and the fluopicolide has the advantages that the pyraclostrobin and the fluopicolide are compounded, so that a control spectrum can be expanded, a good synergistic effect can be realized, an excellent killing effect can be realized for various pathogenic bacteria, a control effect is improved, resistance of the pathogenic bacteria to insecticides is reduced, high resistance to each insecticide due to the fact that the single insecticide is used for a long time is avoided, and the bactericide composition is low in toxicity and safe for environments, and is pollution-free.
Description
(1) technical field
The present invention relates to the agriculture chemicals fungicide field, particularly a kind of bactericidal composition that contains pyraclostrobin and fluopicolide.
(2) background technology
Pyraclostrobin (english common name: Pyraclostrobin has another name called pyraclostrobin), molecular formula is C
19H
18ClN
3O
4, molecular weight is 387.82, structural formula is:
Pyraclostrobin is line particle respiration inhibitor; it is a kind of broad-spectrum germicide; it can prevent and treat the disease that the fungal pathogens by types such as Ascomycetes, Basidiomycetes, Oomycete and deuteromycetes causes; have protection and therapeutic action, the diseases such as powdery mildew, downy mildew, scab, leaf spot, anthracnose, epidemic disease are all had preferably control efficiency.Although pyraclostrobin can be prevented and treated the plant disease that is caused by fungal pathogens such as ascus guiding principle, Basidiomycetes, Fungi Imperfecti and Oomycetes, but the action site of pyraclostrobin is single, if long-term single use, pathogene unavoidably can produce resistance, and this reagent cost is higher, and difficulty is larger in plant protection is promoted.
Fluopicolide, chemical name: 2,6-two chloro-N-(3-chloro-5-trifluoromethyl-2-picolyl) benzamide, its structural formula is:
Fluopicolide is the benzamide series bactericidal agent, has interior absorption, is a kind of high-efficiency broad spectrum bactericide, is mainly used in preventing and treating the microbial disease of Oomycete cause of disease such as downy mildew of garpe and potato late blight etc.Fluopicolide not only has unique mode of action; with other series bactericidal agent without cross resistance; and it is active to have good holding effect; disease on the various plants such as field crop, fruit tree, vegetables all had treatment and protective effect; but long-term use is more single to the effect of crop disease control; but the lasting period is short, and control efficiency is undesirable.
Along with the long-term use of above-mentioned two kinds of single doses, the pesticide resistance of pathogen increases gradually, and dosage also increases thereupon, has so just reduced control efficiency, causes cost accounting to increase.
(3) summary of the invention
The present invention is in order to remedy the deficiencies in the prior art, provides a kind of and can delay the pathogen resistance, the lasting period is long, control efficiency good, the bactericidal composition that contains pyraclostrobin and fluopicolide of environmental protection.
The present invention is achieved through the following technical solutions:
A kind of bactericidal composition that contains pyraclostrobin and fluopicolide, its active ingredient consists of pyraclostrobin and fluopicolide, and the weight ratio of described pyraclostrobin and fluopicolide is 1～79: 79～1.
Further the weight ratio of the described pyraclostrobin of screening and fluopicolide is 1～50: 50～1, and described active ingredient accounts for 10%～80% of bactericidal composition gross weight, is preferably 25%, and all the other are auxiliary element.
Bactericidal composition of the present invention can be processed into conventional formulation according to preparation production method conventional on the Pesticide Science, as: A missible oil (EC), B microemulsion (ME), C aqueous emulsion (EW), D wetting powder (WP), E water dispersible granules (WG), the preferred dosage form of the present invention is aqueous emulsion and wetting powder, and the weight ratio of each formulation constituent is respectively:
The weight ratio of A missible oil constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80% (gross weight of pyraclostrobin and fluopicolide is than between 10%～80%), emulsifier 5%～20%, all the other are solvent.
The weight ratio of B microemulsion constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80% (gross weight of pyraclostrobin and fluopicolide is than between 10%～80%), emulsifier 5%～20%, solvent 10%～30%, cosolvent 1%～30%, thickener 0.5%～5%, antifreezing agent 1%～5%, all the other are deionized water.
The weight ratio of C aqueous emulsion constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80% (gross weight of pyraclostrobin and fluopicolide is than between 10%～80%), emulsifier 5%～20%, solvent 10%～30%, cosolvent 1%～30%, thickener 0.5%～5%, antifreezing agent 1%～5%, pH value conditioning agent 0.1%～2%, all the other are deionized water.
The weight ratio of D wetting powder constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80% (gross weight of pyraclostrobin and fluopicolide is than between 10%～80%), wetting agent 1%～10%, dispersant 1%～15%, all the other are carrier.
The weight ratio of E water dispersible granules constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80% (gross weight of pyraclostrobin and fluopicolide is than between 10%～80%), wetting agent 1%～10%, dispersant 1%～15%, help disintegrant 1%～30%, adhesive 0.5%～5%, all the other are carrier.
Described emulsifier is one or more in alkyl benzene calcium sulfonate, alkylphenol polyoxyethylene, phenethyl phenol APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, alkylaryl polyoxyethylene polyoxypropylene ether, anhydrous sorbitol fatty acid ester APEO, the aliphatic alcohol polyoxyvinethene phosphate.
Described solvent comprises water or organic solvent, and organic solvent is one or more in dimethylbenzene, toluene, benzene, acetone, cyclohexanone, methyl alcohol, ethanol, pyrrolidones, diesel oil, the ethyl acetate.
Described cosolvent is one or more in methyl-sulfoxide, dimethyl formamide, methyl alcohol, ethanol, chloroform, acetone, isopropyl alcohol, the n-butanol.
Described thickener is one or more in xanthans, starch, gum Arabic, polyvinyl alcohol, the CMC.
Described antifreezing agent is one or more in urea, ethylene glycol, propane diols, the polyethylene glycol.
Described dispersant is one or more in alkylnaphthalene sulfonate, lignosulfonates, the alkylphenol polyoxyethylene.
Described wetting agent is one or more in lauryl sodium sulfate, calcium dodecyl benzene sulfonate, lignosulfonates, alkyl phenol formaldehyde resin polyoxyethylene ether, phenethyl phenol polyethenoxy ether, the polyoxyethylene nonylphenol ether.
Described pH value conditioning agent is one or more in glacial acetic acid, triethylamine, hydrochloric acid, the triethanolamine.
The described disintegrant that helps is in ammonium sulfate, calcium chloride, sodium chloride, magnesium chloride, aluminium chloride, the urea one or more.
Described adhesive is one or more in starch, gum Arabic, sodium silicate, gypsum, polyvinyl alcohol, paraffin, the pitch.
Described carrier is one or more in diatomite, attapulgite, calcium carbonate, kaolin, white carbon, talcum powder, potter's clay, the bentonite.
The beneficial effect that the present invention contains the bactericidal composition of pyraclostrobin and fluopicolide is: pyraclostrobin and fluopicolide are composite can expanding prevention compose and produce preferably synergistic function, multiple pathogen had stronger killing action, strengthened control efficiency, reduced the pesticide resistance of pathogen to medicament, avoid because the long-term high resistance to medicament of using single medicament and occurring, low toxicity, nuisanceless, safer to environment.
(4) embodiment
The invention will be further described below in conjunction with embodiment, but the present invention is not limited thereto, and the formulation preparation method among the embodiment is conventional preparation method, no longer describes in detail.
Embodiment 1:50% pyraclostrobin and fluopicolide missible oil comprise the following component of following weight:
20 kilograms of pyraclostrobins, 30 kilograms of fluopicolides, 4.5 kilograms of calcium dodecyl benzene sulfonates, 5.5 kilograms of anhydrous sorbitol fatty acid ester APEOs, 1 kilogram of dimethyl formamide, dimethylbenzene surplus.
Embodiment 2:10% pyraclostrobin and fluopicolide missible oil comprise the following component of following weight:
5 kilograms of pyraclostrobins, 5 kilograms of fluopicolides, 15 kilograms of phenethyl phenol APEOs, 20 kilograms of methyl alcohol, the ethanol surplus.
Embodiment 3:20% pyraclostrobin and fluopicolide microemulsion comprise the following component of following weight:
2 kilograms of pyraclostrobins, 18 kilograms of fluopicolides, 4 kilograms of alkyl phenol formaldehyde resin polyoxyethylene ethers, 14 kilograms in alkylaryl polyoxyethylene polyoxypropylene ether, 15 kilograms of toluene, 5 kilograms of cyclohexanone, 20 kilograms of isopropyl alcohols, 2 kilograms of polyvinyl alcohol, 2 kilograms of ethylene glycol, 3 kilograms of propane diols, deionized water surplus.
Embodiment 4:30% pyraclostrobin and fluopicolide microemulsion comprise the following component of following weight:
25 kilograms of pyraclostrobins, 5 kilograms of fluopicolides, 5 kilograms of alkylphenol polyoxyethylene, 13 kilograms of benzene, 4 kilograms in acetone, 3 kilograms of xanthans, 0.5 kilogram of starch, 2 kilograms of polyethylene glycol, deionized water surplus.
Embodiment 5:40% pyraclostrobin and fluopicolide aqueous emulsion comprise the following component of following weight:
37 kilograms of pyraclostrobins, 3 kilograms of fluopicolides, 12 kilograms of aliphatic alcohol polyoxyvinethene phosphates, 22 kilograms in ethyl acetate, 12 kilograms of n-butanols, 1.5 kilograms of gum Arabics, 1 kilogram in urea, 0.2 kilogram of glacial acetic acid, 0.3 kilogram in watery hydrochloric acid, the deionized water surplus.
Embodiment 6:51% pyraclostrobin and fluopicolide aqueous emulsion comprise the following component of following weight:
50 kilograms of pyraclostrobins, 1 kilogram of fluopicolide, 8 kilograms of calcium dodecyl benzene sulfonates, 17 kilograms in acetone, 3 kilograms of CMCs, 4 kilograms of ethylene glycol, 1 kilogram of triethanolamine, the deionized water surplus.
Embodiment 7:70% pyraclostrobin and fluopicolide wetting powder comprise the following component of following weight:
55 kilograms of pyraclostrobins, 15 kilograms of fluopicolides, 1.5 kilograms of lauryl sodium sulfate, 5 kilograms of calcium lignosulfonates, 7 kilograms of alkylnaphthalene sulfonates, 10 kilograms in potter's clay, the kaolin surplus.
Embodiment 8:51% pyraclostrobin and fluopicolide wetting powder comprise the following component of following weight:
1 kilogram of pyraclostrobin, 50 kilograms of fluopicolides, 5 kilograms of phenethyl phenol polyethenoxy ethers, 5 kilograms of polyoxyethylene nonylphenol ether, 8 kilograms of alkylphenol polyoxyethylene, the diatomite surplus.
Embodiment 9:80% pyraclostrobin and fluopicolide water dispersible granules comprise the following component of following weight:
1 kilogram of pyraclostrobin, 79 kilograms of fluopicolides, 3 kilograms of calcium dodecyl benzene sulfonates, 6 kilograms of lignosulfonates, 1 kilogram in calcium chloride, 1 kilogram in sodium chloride, 2 kilograms of gum Arabics, the bentonite surplus.
Embodiment 10:80% pyraclostrobin and fluopicolide water dispersible granules comprise the following component of following weight:
79 kilograms of pyraclostrobins, 1 kilogram of fluopicolide, 9 kilograms of lignosulfonates, 4 kilograms in urea, 0.5 kilogram of starch, 3 kilograms of sodium silicate, the kaolin surplus.
Test:
The mycelial growth rate method is adopted in test, and observed result behind the 5d is calculated the EC of each test medicine
50, the index such as co-toxicity coefficient, the co-toxicity of bactericidal composition adopts the abundant co-toxicity coefficient method representation of Sun Yun:
The theoretical toxicity index A=∑ of bactericidal composition (percentage of the toxicity index x of certain medicine this pharmaceutically active ingredient in composition)
CTC was synergistic effect greater than 120 o'clock, less than 80 o'clock be antagonism, be addition during 80-120.
Table 1 pyraclostrobin, fluopicolide and different proportioning thereof are to the result of the test of powdery mildew of cucumber
As can be seen from Table 1, synergistic effect is in various degree all arranged when pyraclostrobin and fluopicolide are composite, the co-toxicity coefficient of bactericidal composition (CTC) is all greater than 120, illustrate that pyraclostrobin and fluopicolide are composite, compare the pyraclostrobin single dose and the fluopicolide single dose has obvious synergistic effect.
For further verifying the practical effect of bactericidal composition, carry out demonstration test in multiple diseases such as pear scab, sigatokas, having chosen 20% pyraclostrobin+30% fluopicolide missible oil, 1% pyraclostrobin+50% fluopicolide wetting powder and 25% pyraclostrobin EC, 25% fluopicolide WP tests, bactericidal composition of the present invention has all been obtained good control efficiency, and control efficiency is all high than single dose.
The test effect of table 2 pyraclostrobin, fluopicolide and different proportionings thereof
As can be seen from Table 2, the field efficacy of 20% pyraclostrobin+30% fluopicolide missible oil, 1% pyraclostrobin+50% fluopicolide wetting powder is all apparently higher than the result of use of 25% pyraclostrobin EC and 25% fluopicolide WP single dose, the bactericidal composition that use contains pyraclostrobin and fluopicolide not only can improve drug effect, greatly reduce use cost, and can also improve the quality of crop.
Claims (10)
1. bactericidal composition that contains pyraclostrobin and fluopicolide, it is characterized in that: its active ingredient consists of pyraclostrobin and fluopicolide, and the weight ratio of described pyraclostrobin and fluopicolide is 1～79: 79～1.
2. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 1, it is characterized in that: the weight ratio of described pyraclostrobin and fluopicolide is 1～50: 50～1.
3. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 1 and 2, it is characterized in that: described active ingredient accounts for 10%～80% of bactericidal composition gross weight, and all the other are auxiliary 50 compositions.
4. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 3, it is characterized in that: the formulation of this bactericidal composition is A missible oil, B microemulsion, C aqueous emulsion, D wetting powder or E water dispersible granules, and the weight ratio of each formulation constituent is respectively:
The weight ratio of A missible oil constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80%, emulsifier 5%～20%, all the other are solvent.
The weight ratio of B microemulsion constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80%, emulsifier 5%～20%, solvent 10%～30%, cosolvent 1%～30%, thickener 0.5%～5%, antifreezing agent 1%～5%, all the other are deionized water.
The weight ratio of C aqueous emulsion constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80%, emulsifier 5%～20%, solvent 10%～30%, cosolvent 1%～30%, thickener 0.5%～5%, antifreezing agent 1%～5%, pH value conditioning agent 0.1%～2%, all the other are deionized water.
The weight ratio of D wetting powder constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80%, wetting agent 1%～10%, dispersant 1%～15%, all the other are carrier.
The weight ratio of E water dispersible granules constituent is: pyraclostrobin 1%～80%, fluopicolide 1%～80%, wetting agent 1%～10%, dispersant 1%～15%, help disintegrant 1%～30%, adhesive 0.5%～5%, all the other are carrier.
5. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 4, it is characterized in that: described emulsifier is one or more in alkyl benzene calcium sulfonate, alkylphenol polyoxyethylene, phenethyl phenol APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, alkylaryl polyoxyethylene polyoxypropylene ether, anhydrous sorbitol fatty acid ester APEO, the aliphatic alcohol polyoxyvinethene phosphate.
6. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 4, it is characterized in that: described solvent comprises water or organic solvent, and organic solvent is one or more in dimethylbenzene, toluene, benzene, acetone, cyclohexanone, methyl alcohol, ethanol, pyrrolidones, diesel oil, the ethyl acetate; Described cosolvent is one or more in methyl-sulfoxide, dimethyl formamide, methyl alcohol, ethanol, chloroform, acetone, isopropyl alcohol, the n-butanol.
7. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 4, it is characterized in that: described thickener is one or more in xanthans, starch, gum Arabic, polyvinyl alcohol, the CMC; Described antifreezing agent is one or more in urea, ethylene glycol, propane diols, the polyethylene glycol.
8. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 4, it is characterized in that: described dispersant is one or more in alkylnaphthalene sulfonate, lignosulfonates, the alkylphenol polyoxyethylene; Described wetting agent is one or more in lauryl sodium sulfate, calcium dodecyl benzene sulfonate, lignosulfonates, alkyl phenol formaldehyde resin polyoxyethylene ether, phenethyl phenol polyethenoxy ether, the polyoxyethylene nonylphenol ether.
9. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 4, it is characterized in that: described pH value conditioning agent is one or more in glacial acetic acid, triethylamine, hydrochloric acid, the triethanolamine; The described disintegrant that helps is in ammonium sulfate, calcium chloride, sodium chloride, magnesium chloride, aluminium chloride, the urea one or more.
10. a kind of bactericidal composition that contains pyraclostrobin and fluopicolide according to claim 4, it is characterized in that: described adhesive is one or more in starch, gum Arabic, sodium silicate, gypsum, polyvinyl alcohol, paraffin, the pitch; Described carrier is one or more in diatomite, attapulgite, calcium carbonate, kaolin, white carbon, talcum powder, potter's clay, the bentonite.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104430435A (en) * | 2014-12-29 | 2015-03-25 | 河北野田农用化学有限公司 | Water-dispersing granulated pesticide containing pyraclostrobin and boscalid, preparation method and application thereof |
| CN107125254A (en) * | 2017-05-30 | 2017-09-05 | 兴农药业（中国）有限公司 | A kind of composition pesticide of fluopicolide and pyraclostrobin |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102365956A (en) * | 2011-11-03 | 2012-03-07 | 陕西美邦农药有限公司 | Sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds |
| WO2012076634A1 (en) * | 2010-12-08 | 2012-06-14 | Basf Se | Fungicidal mixtures comprising pyraclostrobin |
| CN102919256A (en) * | 2012-11-28 | 2013-02-13 | 河北省农林科学院植物保护研究所 | Fluopicolide-containing compound bactericide and application thereof |
| CN103004819A (en) * | 2012-11-30 | 2013-04-03 | 王学权 | Fluopicolide-containing bactericide composition |
-
2013
- 2013-01-21 CN CN201310019607XA patent/CN103004822A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012076634A1 (en) * | 2010-12-08 | 2012-06-14 | Basf Se | Fungicidal mixtures comprising pyraclostrobin |
| CN102365956A (en) * | 2011-11-03 | 2012-03-07 | 陕西美邦农药有限公司 | Sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds |
| CN102919256A (en) * | 2012-11-28 | 2013-02-13 | 河北省农林科学院植物保护研究所 | Fluopicolide-containing compound bactericide and application thereof |
| CN103004819A (en) * | 2012-11-30 | 2013-04-03 | 王学权 | Fluopicolide-containing bactericide composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104430435A (en) * | 2014-12-29 | 2015-03-25 | 河北野田农用化学有限公司 | Water-dispersing granulated pesticide containing pyraclostrobin and boscalid, preparation method and application thereof |
| CN107125254A (en) * | 2017-05-30 | 2017-09-05 | 兴农药业（中国）有限公司 | A kind of composition pesticide of fluopicolide and pyraclostrobin |
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Application publication date: 20130403 |