CN103891725A - Bactericidal composition containing isopyrazam and kresoxim-methyl and application thereof - Google Patents
Bactericidal composition containing isopyrazam and kresoxim-methyl and application thereof Download PDFInfo
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- CN103891725A CN103891725A CN201210591045.1A CN201210591045A CN103891725A CN 103891725 A CN103891725 A CN 103891725A CN 201210591045 A CN201210591045 A CN 201210591045A CN 103891725 A CN103891725 A CN 103891725A
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- naphthalene bacterium
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Abstract
The invention discloses a bactericidal composition containing isopyrazam and kresoxim-methyl and application thereof. The bactericidal composition is composed of main effect components isopyrazam and kresoxim-methyl in a weight ratio of (1-65):(1-70). The bactericidal composition is used for preventing and treating diseases of cereal crops, vegetables and fruit trees, has higher synergic action, overcomes and postpones the drug resistance of pathogenic bacteria, has the advantages of high bactericidal speed, long duration period and lower application cost, and has obviously better preventing and treating effects than a single agent. The bactericidal composition can be used for preventing and treating fungus diseases on crops, especially can be used for preventing and treating such fungus diseases as rust disease, powdery mildew, leaf spot, net blotch, glume blight, leaf blight, downy mildew, epidemic disease and the like, and has better effects than a single agent.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and uses thereof, especially a kind of bactericidal composition and application thereof take pyrazoles naphthalene bacterium amine and kresoxim-methyl as main active.
Background technology
Pyrazoles naphthalene bacterium amine (Isopyrazam), chemical name: 3-difluoromethyl-1-methyl-N-[1,2,3,4-tetrahydrochysene-9-(1-Methylethyl)-Isosorbide-5-Nitrae-methanonaphthalen-5-yl]-1H-pyrazole-4-carboxamide, molecular formula C
20h
23f
2n
3o, pyrazoles naphthalene bacterium amine (Isopyrazam) has following four kinds of isomer, the mixing that the present invention comprises any one or a few, chemical structural formula is as follows respectively:
The exploitation of pyrazoles naphthalene Jun Anshiyou Syngenta Co.,Ltd, this bactericide has broad spectrum of activity, multiple diseases in various crop is all had to the outstanding performance of preventing and treating, efficient to triazole type and methoxy acrylic resistant strain germ, especially very efficient to Septoria (Septoria) fungi, as the preventive effect of wheat rust and barley rust rot is all better than to epoxiconazole.This bactericide is take protective effect as main, but in field trial, also demonstrates certain therapeutic action, and its lasting period is long, and dispenser still shows positive effect after 7 weeks, and the protection period is longer about 2 weeks than triazole bactericidal agent.The market orientation of pyrazoles naphthalene bacterium amine comprises the disease on fruit tree, vegetables and cereal.
Kresoxim-methyl (Kresoxim-methyl), chemical name: (E)-2-methoxyimino-[2-(o-methyl-benzene oxygen ylmethyl) phenyl] methyl acetate, molecular formula is C
18h
19nO
4, structural formula:
The methoxy acrylic spectrum bactericide of kresoxim-methyl Shu Shi BASF Aktiengesellschaft exploitation, has protection, treats, roots out, infiltration, systemic activity, has good inhibition spore germination effect.Most of diseases that the pathomycetes such as Ascomycetes, Basidiomycetes, Fungi Imperfecti and oomycetes subclass are caused have good effect.
Methoxy acrylic bactericide is the class new type bactericide kind occurring in recent years, it is one of main pharmacy variety of preventing and treating in the market fungal disease, market share amount is very large, still action target is single for the active height of such medicament, this has also just caused the quick generation of germ resistance, such as such medicament of part is not equal to before in the control of powdery mildew, can not play due effect even if improve dosage, the composition research that therefore carries out such medicament and different mechanism medicaments is extremely urgent.
The difficulty of prevention and cure of phytopathogen is increasing at present, and on the one hand, along with the change of pattern of farming, the disease occurrence degree of melon and fruit, vegetables, cereal crop, generation quantity all increase, and are are objectively preventing and treating difficulty increasing; On the other hand, SM causes the resistance of pathogen to rise year by year under lasting medicament selection pressure, and the control efficiency of single dose is had a greatly reduced quality; The 3rd, the speed to introduce of new varieties of pesticides obviously declines at present, and lacks new action target medicament; The 4th, strict gradually due to environmental requirement, portioned product is limited to use, and causes medication selectivity to become less.In a word, how effectively plant disease being prevented and treated is the important topic that vast plant protection work person faces.
Summary of the invention:
The object of the invention is for above-mentioned technical problem provide a kind of applied widely, cost is low, the effective plant bactericidal composition containing pyrazoles naphthalene bacterium amine and kresoxim-methyl.
A further object of the invention is to provide this bactericidal composition and causes the application on fungal disease control sac fungi, basidiomycetes, imperfect fungus and Oomycete fungi, especially on the fungal diseases such as control rust, powdery mildew, leaf spot, net blotch, glume blight, leaf blight, downy mildew, epidemic disease purposes.
The object of the invention is to realize by following measures:
A kind of bactericidal composition, it contains pyrazoles naphthalene bacterium amine and kresoxim-methyl, and wherein pyrazoles naphthalene bacterium amine and kresoxim-methyl weight ratio are 1 ~ 65:1 ~ 70, and wherein in bactericidal composition, effective ingredient is present in composition with synergy effective dose.
Described bactericidal composition, wherein pyrazoles naphthalene bacterium amine and kresoxim-methyl weight ratio are preferably 3 ~ 30:10 ~ 60, more preferably 3 ~ 20:10 ~ 30, most preferably 1:0.5 ~ 8.
In the present composition, the two percentage by weight that accounts for composition of pyrazoles naphthalene bacterium amine and kresoxim-methyl is 2-80%.Be preferably 4-70%, most preferably 30-35%.
Described bactericidal composition, wherein pyrazoles naphthalene bacterium amine and kresoxim-methyl and known auxiliary agent and excipient are re-dubbed any one formulation allowing on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
These known auxiliary agents, excipients have emulsifier, wetting dispersing agent, suspending agent, defoamer, disintegrant, binding agent etc.
The aforementioned emulsifier can be applicable in insecticides adjuvant of the present invention comprises but is not limited to calcium dodecyl benzene sulfonate, the rare block compound of polyoxyethylene polyoxy third, castor oil polyoxyethylene ether, alkylphenol polyoxyethylene polyethenoxy ether, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether, phenethyl phenol polyethenoxy ether polyethenoxy ether, alkylphenol polyoxyethylene formaldehyde condensation products etc., and the phosphate of above-mentioned wherein part material and in and salt.Concrete kind is as serial in: agriculture breast 500# series, 600# series, 400# series, 1600# series, NP series, OP series, AEO series, By series, this dish series, tween etc.
The aforementioned wetting dispersing agent can be applicable in insecticides adjuvant of the present invention includes, but are not limited to one or more in sodium lignin sulfonate, calcium lignosulfonate, alkylnaphthalene sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products, Abietyl quaternary ammonium salt, alkylphenol polyoxyethylene phosphate, saponin, the withered powder of tea, fatty alcohol polyoxyethylene ether sulfate, lauryl sodium sulfate, neopelex, polycarboxylic acid salt and high molecular comb shape compound etc.
It is aforementioned that to can be applicable to excipient of the present invention be one or more in water, solvent or filler.
Described solvent includes, but are not limited to one or more of toluene, dimethylbenzene, solvent naphtha series, mixed methylnaphthalene, turpentine oil, vegetable oil, methyl oleate, carrene, chloroform, methyl alcohol, ethanol, isopropyl alcohol, n-butanol, cyclohexanone, isophorone, pyrrolidones, tetrahydrofurfuryl alcohol, acetic acid dimethyl ester, acetophenone, ethyl acetate, DMF, dimethyl sulfoxide (DMSO) etc.
Described filler is selected from one or more of white carbon, kaolin, precipitated calcium carbonate, diatomite, corn starch, quartz sand, talcum powder, ammonium sulfate, sodium sulphate, sodium chloride, potassium chloride etc.
As required, also can add the functional aids such as antifreezing agent, thickener, stabilizing agent, defoamer
Described antifreezing agent is selected from one or more of ethylene glycol, propane diols, urea, diethylene glycol (DEG), glycerine etc.
Described thickener is selected from one or more of xanthans, polyvinyl alcohol, bentonite, CMC, aluminium-magnesium silicate.
Described bactericidal composition, its formulation is missible oil, suspending agent, suspension emulsion, wetting powder, aqueous emulsion, microemulsion and water dispersion granule.
The application of described bactericidal composition aspect control cereal crop disease.
Beneficial effect of the present invention:
1, the present invention's pyrazoles naphthalene bacterium amine used is novel pyrazole acid amides bactericide, and kresoxim-methyl is wide spectrum methoxy acrylic bactericide, and mutually mixture can not produce low touching, can Synergistic, reduce dosage, and reduce costs.
2, the present composition scope of application increases, be applicable to prevent and treat the crop pest of Cereal, various melon and fruit, vegetables, particularly prevent and treat the crop pests such as paddy rice, wheat, barley, capsicum, banana, mango, pineapple, cucumber, tomato, as wheat rust, wheat powdery mildew, large wheat rust, wheat net blotch, capsicum epidemic disease, wheat leaf blight, beet powdery mildew etc.
Bactericidal composition of the present invention has good control efficiency to sac fungi, basidiomycetes, imperfect fungus and Oomycete fungal disease; Reduce because Synergistic causes consumption, can unitary agent (pyrazoles naphthalene bacterium amine and kresoxim-methyl are arbitrary) be developed immunity to drugs Antifungi.
Bactericidal composition of the present invention is prevented and treated the application on resistance fungi in preparation, especially all has significant effect in the application of control rust, powdery mildew, leaf spot, net blotch, glume blight, leaf blight, downy mildew, epidemic disease.Above-mentioned bactericidal composition can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture reduces greatly, and the activity of mixture is greater than the activity of independent component." % " of the present invention is mass percent.
Compared with prior art beneficial effect of the present invention: (1) is compared with single dose, said composition antagonism fungal disease has obvious synergistic function as fungal diseases such as rust, powdery mildew, leaf spot, net blotch, glume blight, leaf blight, downy mildew, epidemic diseases, overcome and delayed pesticide resistance, expanding prevention spectrum, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative routine and the easily agricultural chemicals of generation resistance; (4), compared with single dose, produce and use cost reduction; (5) the drug-fast generation of Antifungi, its successful uses higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of formulation is conventional laboratory's formulation method.
Two kinds of reactive compounds can be processed into any one formulation of permission, and below with two kinds of preparations that active ingredient is processed into of specific embodiment explanation, but the preparation that these two kinds of active components can be processed is not limited only to following listed.
Embodiment 1:
By pyrazoles naphthalene bacterium amine 3.3g, kresoxim-methyl 26.4g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 29.7% wetting powder.
Embodiment 2:
By pyrazoles naphthalene bacterium amine 5g, kresoxim-methyl 25g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 30% wetting powder.
Embodiment 3:
By pyrazoles naphthalene bacterium amine 10g, kresoxim-methyl 20g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 30% wetting powder.
Embodiment 4:
Take pyrazoles naphthalene bacterium amine 15g, kresoxim-methyl 15g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 30% wetting powder.
Embodiment 5:
Take pyrazoles naphthalene bacterium amine 20g, kresoxim-methyl 10g, sodium lignin sulfonate dispersant 6g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 30% wetting powder.
Embodiment 6:
Take 1g pyrazoles naphthalene bacterium amine, 5g kresoxim-methyl, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, DMF13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 6% pyrazoles naphthalene bacterium amine-kresoxim-methyl aqueous emulsion.
Embodiment 7:
Take 50g pyrazoles naphthalene bacterium amine, 20g kresoxim-methyl, sodium lignin sulfonate 8g, polycarboxylate salt dispersant 2g, lauryl sodium sulfate 1g, ammonium sulfate 5g, corn starch complement to 100g.The method that above raw material is prepared to water dispersion granule routinely first mixes, cross air-flow crushing afterwards, finally mediate granulation, and making main active ingredient weight percentage is 70% pyrazoles naphthalene bacterium amine-kresoxim-methyl water dispersion granule.
Embodiment 8:
Take 2g pyrazoles naphthalene bacterium amine, 40g kresoxim-methyl, sodium lignin sulfonate 8g, polycarboxylate salt dispersant 2g, lauryl sodium sulfate 1g, ammonium sulfate 5g, corn starch complement to 100g.The method that above raw material is prepared to water dispersion granule routinely first mixes, cross air-flow crushing afterwards, finally mediate granulation, and making main active ingredient weight percentage is 42% pyrazoles naphthalene bacterium amine-kresoxim-methyl water dispersion granule.
Embodiment 9:
Take 5g pyrazoles naphthalene bacterium amine, 20g kresoxim-methyl, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 25% pyrazoles naphthalene bacterium amine-kresoxim-methyl microemulsion.
Embodiment 10:
Take 5g pyrazoles naphthalene bacterium amine, 0.5g kresoxim-methyl, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, vegetable oil are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 5.5% pyrazoles naphthalene bacterium amine-kresoxim-methyl missible oil.
Embodiment 11:
Take 5g pyrazoles naphthalene bacterium amine, 30g kresoxim-methyl, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 35% pyrazoles naphthalene bacterium amine-kresoxim-methyl suspending agent.
Embodiment 12:
Take 10g pyrazoles naphthalene bacterium amine, 10g kresoxim-methyl, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 20% pyrazoles naphthalene bacterium amine-kresoxim-methyl suspending agent.
Embodiment 13:
Take 30g pyrazoles naphthalene bacterium amine, 12g kresoxim-methyl, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 42% pyrazoles naphthalene bacterium amine-kresoxim-methyl suspending agent.
Embodiment 13:
Take 2g pyrazoles naphthalene bacterium amine, 5g kresoxim-methyl, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and it is 7% pyrazoles naphthalene bacterium amine-kresoxim-methyl water dispersion granule that above raw material is made to main active ingredient weight percentage by water dispersible granular agent method.
Embodiment 14:
Take 4g pyrazoles naphthalene bacterium amine, 13g kresoxim-methyl, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and it is 17% pyrazoles naphthalene bacterium amine-kresoxim-methyl water dispersion granule that above raw material is made to main active ingredient weight percentage by water dispersible granular agent method.
Embodiment 15:
Take 5g pyrazoles naphthalene bacterium amine, 15g kresoxim-methyl, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 20% pyrazoles naphthalene bacterium amine-kresoxim-methyl suspending agent.
Embodiment 16:
Indoor biometrics test:
Take net blotch of barley (Pyrenophorateres (Sacc) Drechsler) as test strain, adopt mycelial growth rate method indoor, measure different medicaments to concentration EC in the inhibition of bacterial strain
50value, adopts the abundant co-toxicity coefficient computational methods of Sun Yun, calculates the co-toxicity coefficient (CTC) of mixture, determines the synergy of mixture, and computational methods are as follows:
1. (conventionally select EC take a certain single dose in mixture as standard medicament
50junior), calculate:
2. single dose toxicity index=standard medicament EC
50/ certain single dose EC in addition
50× 100
3. toxicity index × B single dose proportion in mixture of toxicity index × A single dose of theoretical toxicity index=A single dose proportion+B single dose in mixture.
4. the EC of actual measurement toxicity index=standard single dose
50the EC of value/mixture
50value × 100
5. co-toxicity coefficient CTC=actual measurement toxicity index/theoretical toxicity index × 100
Evaluate the value of mixture according to the numerical value of CTC, CTC is greater than at 120 o'clock and shows that mixture has synergetic, CTC is less than at 80 o'clock and shows that mixture has Antagonism, CTC shows that between 80-120 mixture has summation action, generally speaking, the CTC>120 of mixture is the basic demand of agriculture chemical compounding research and development.
Indoor biometrics result is as follows:
Table 1: the indoor biometrics result of the different proportionings of pyrazoles naphthalene bacterium amine+kresoxim-methyl to net blotch of barley
| Medicament | Virulence regression equation | EC 50（mg/L） | Co-toxicity coefficient |
| 10% pyrazoles naphthalene bacterium amine EC | Y=3.5709X+2.9714 | 3.6989 | --- |
| 30% kresoxim-methyl SC | Y=2.2061X+2.7607 | 10.3526 | --- |
| Embodiment 1(1:8) | Y=1.8501X+3.7693 | 4.6258 | 186.0 |
| Embodiment 2(1:5) | Y=2.1034X+3.7825 | 3.7915 | 212.1 |
| Embodiment 3(1:2) | Y=3.4063X+3.0784 | 3.6654 | 177.0 |
| Embodiment 4(1:1) | Y=1.771X+3.9832 | 3.7512 | 145.0 |
| Embodiment 5(2:1) | Y=3.4404X+3.1043 | 3.5564 | 131.7 |
Field control effectiveness test:
Indoor biometrics shows good Pesticidal composition, must carry out actual field medicine effect test, field medicine effect test is the important means that whether final evaluation Pesticidal composition has using value under the impact of field integrated environment, therefore the pesticide mixed preparation, making with embodiment on the basis of indoor biometrics has carried out preventing and treating the field medicine effect test of net blotch of barley.
1. test is processed: this test medicine consumption is established respectively three concentration for the treatment of according to the difference of each composition, and contrast medicament is respectively 30% kresoxim-methyl SC and 10% pyrazoles naphthalene bacterium amine EC and the test of blank clear water.
2. the each community of test method area is 66.7m
2, repeat 3 times; Inspection drug effect method before dispenser after Investigation and Prevention is: in test treatment region, adopt accidental sampling, sampling 5 points,, check net blotch of barley occurrence degree by 0.5 square metre every.
Table 2: the field control effectiveness test of the different pairing of pyrazoles naphthalene bacterium amine+kresoxim-methyl net blotch of barley:
Result by indoor biometrics and field medicine effect test shows, pyrazoles naphthalene bacterium amine and kresoxim-methyl composition have obvious synergistic function, the control efficiency of composition is good, and control efficiency is all better than single dose kind, in agricultural application, has good using value.
Claims (10)
1. a bactericidal composition, is characterized in that containing pyrazoles naphthalene bacterium amine and kresoxim-methyl, and wherein the weight ratio of pyrazoles naphthalene bacterium amine and kresoxim-methyl is 1 ~ 65:1 ~ 70.
2. bactericidal composition according to claim 1, the weight ratio that it is characterized in that pyrazoles naphthalene bacterium amine and kresoxim-methyl is 3 ~ 30:10 ~ 60.
3. bactericidal composition according to claim 2, is characterized in that described pyrazoles naphthalene bacterium amine and the weight ratio of kresoxim-methyl are 3 ~ 20:10 ~ 30, preferably 1:0.5 ~ 8.
4. the bactericidal composition that contains pyrazoles naphthalene bacterium amine and kresoxim-methyl according to claim 1, is characterized in that the two weight percentage that accounts for composition of pyrazoles naphthalene bacterium amine and kresoxim-methyl is 2-80%.
5. the bactericidal composition that contains pyrazoles naphthalene bacterium amine and kresoxim-methyl according to claim 4, is characterized in that the two weight percentage that accounts for composition of pyrazoles naphthalene bacterium amine and kresoxim-methyl is 4-70%.
6. the bactericidal composition that contains pyrazoles naphthalene bacterium amine and kresoxim-methyl according to claim 5, is characterized in that the two weight percentage that accounts for composition of pyrazoles naphthalene bacterium amine and kresoxim-methyl is 30-35%.
7. the Synergistic bactericidal composition containing pyrazoles naphthalene bacterium amine and kresoxim-methyl according to claim 1, is characterized in that take pyrazoles naphthalene bacterium amine and kresoxim-methyl as main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation allowing on agricultural chemicals.
8. the compound biocide composite containing pyrazoles naphthalene bacterium amine and kresoxim-methyl according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the application of the compound biocide composite containing pyrazoles naphthalene bacterium amine and kresoxim-methyl claimed in claim 1 on preparation control resistance plant fungal disease.
10. the compound biocide composite containing pyrazoles naphthalene bacterium amine and kresoxim-methyl according to claim 9 is in the application of preparing on the fungal disease germ killing drugs such as control rust, powdery mildew, leaf spot, net blotch, glume blight, leaf blight, downy mildew, epidemic disease.
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| CN104705304A (en) * | 2013-12-11 | 2015-06-17 | 上海中冠生物科技有限公司 | Compounded bactericide and preparation method thereof |
| CN108849947A (en) * | 2017-05-12 | 2018-11-23 | 广东广康生化科技股份有限公司 | A kind of bactericidal composition and its application containing folpet and isopyrazam |
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| CN101035432A (en) * | 2004-10-08 | 2007-09-12 | 辛根塔参与股份公司 | Fungicidal compositions |
| WO2007115765A1 (en) * | 2006-04-06 | 2007-10-18 | Syngenta Participations Ag | Fungicidal compositions |
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| WO2011082913A1 (en) * | 2010-01-08 | 2011-07-14 | Syngenta Participations Ag | Fungicidal compositions containing isopyrazam, azoxystrobin and cyproconazole |
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| CN101035432A (en) * | 2004-10-08 | 2007-09-12 | 辛根塔参与股份公司 | Fungicidal compositions |
| WO2007115765A1 (en) * | 2006-04-06 | 2007-10-18 | Syngenta Participations Ag | Fungicidal compositions |
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| CN104705304A (en) * | 2013-12-11 | 2015-06-17 | 上海中冠生物科技有限公司 | Compounded bactericide and preparation method thereof |
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