CN106508931A - Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof - Google Patents
Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof Download PDFInfo
- Publication number
- CN106508931A CN106508931A CN201510587341.8A CN201510587341A CN106508931A CN 106508931 A CN106508931 A CN 106508931A CN 201510587341 A CN201510587341 A CN 201510587341A CN 106508931 A CN106508931 A CN 106508931A
- Authority
- CN
- China
- Prior art keywords
- thifluzamide
- metsulfovax
- composition containing
- benzene metsulfovax
- bactericidal composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof. The fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide adopts benthiavalicarb-isopropyl and thifluzamide as the main active components, and the benthiavalicarb-isopropyl and thifluzamide are in a weigth ratio of 1-70:1-50. The invention also discloses application of the fungicidal composition in preparation of drugs for controlling fungal diseases in resistant plants, can be applied to control of cereal, fruit tree and vegetable diseases, has high synergistic effect, can overcome and delay drug resistance of pathogens, has fast fungicidal speed and long duration, lowers the application cost, and has a control effect obviously superior to that of a single agent. The fungicidal composition provided by the invention can be used for controlling fungal diseases in crops, is especially suitable for control of Phytophthora root rot, late blight, downy mildew, damping-off, sheath blight and other fungal diseases, and has a effect better than that of a single agent.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, especially a kind of bactericidal composition containing benzene metsulfovax and thifluzamide
And its application.
Background technology
Benzene metsulfovax (benthiavalicarb-isopropyl), molecular formula：C18H24FN3O3S, chemical name：[[(6- fluorobenzene is simultaneously
Thiazol-2-yl)-ethylaminocarbonyl] -2- methyl-propyls] carbamic acid isopropyl ester.
Benzene metsulfovax have good bactericidal activity to phytophthora root rot, to its sporangial formation, sporangial sprouting at low concentrations
There is good inhibiting effect, but the release to zoospore and the movement of zoospore are not acted on.In field test, benzene thiophene bacterium
Amine is with relatively low dosage (25～75g a.i./hm2) can effectively control late blight, grape and other crops of potato and tomato
Downy mildew.
Thifluzamide (Thifluzamide), molecular formula：C13H6Br2F6N2O2S, chemical name：Bis- bromo- 2- methyl -4'- three of 2', 6'-
Fluorine methoxyl group -4- Trifluoromethyl-1s, 3- thiadiazoles -5- hydroxyl anilides, chemical structural formula：
Thifluzamide belongs to thiazole amide bactericide, with strong Uptake and translocation and long lasting effect.To Rhizoctonia, handle rest fungus
The pathomycetes such as category, Ustilago, Tilletia, corticium, nuclear cavity Pseudomonas are active, especially true to Basidiomycetes
Microbial disease such as banded sclerotial blight, damping-off etc. have special efficacy.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with economy such as the change of pattern of farming, melon fruits and vegetables
Crops planting area progressively expands, and disease occurrence degree, generation quantity increase, and in preventing and treating, difficulty is increased；The opposing party
Face, the resistance of pathogen rise under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant disease
Preventing and treating is faced with significant challenge.
The content of the invention
The purpose of the present invention be for above-mentioned technical problem provide a kind of applied widely, low cost, effect it is good containing benzene metsulfovax
With the plant bactericidal composition of thifluzamide.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing benzene metsulfovax and thifluzamide, it with benzene metsulfovax and thifluzamide as main active,
Described benzene metsulfovax are 1～70 with thifluzamide weight ratio：1～50, wherein in bactericidal composition, effective ingredient has with synergy
Effect amount is present in composition.
In bactericidal composition of the present invention, the weight ratio preferably 5～50 of described benzene metsulfovax and thifluzamide：10～
50, more preferably 5～40：10～50, most preferably 1：2～10.
In bactericidal composition of the present invention, both described benzene metsulfovax and thifluzamide account for the weight percentage of composition
For 2～80%, preferably 5.5～70%.
Bactericidal composition of the present invention, it is with benzene metsulfovax and thifluzamide as principle active component and known auxiliary agent and tax
Shape agent is re-dubbed any one formulation allow on agricultural chemicals.Known to these, auxiliary agent, excipients have dispersant, diffusant, froth breaking
Agent, wetting agent, disintegrant etc., can using to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium methylene bis-naphthalene sulfonate, 12
Alkyl benzene calcium sulfonate, APES, alkylaryl polyoxyethylene polyoxypropylene ether again, Ben-zylphenol Polyoxyethyl Ether, benzene
Ethyl phenol polyethenoxy ether, three phenethyl phenol polyoxyethylene ether phosphates, AEO and its similar products, fat
Amine APEO, fatty acid ethylene oxide addition product, polyoxyethylene polyoxypropylene block compound, castor oil polyoxyethylene
Ether, NPE, TWEEN Series, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate,
One or more groups in phosphite, lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc.
Close, excipient includes cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water etc..With
Upper auxiliary agent, excipient and other auxiliary materials can be with alone or be used in combination.
Described formulation is missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
It is a still further object of the present invention to provide the bactericidal composition causes on fungal disease medicine in preparation preventing and treating resistance plant fungi
Application.Preferably, described bactericidal composition is preparing preventing and treating Cereal, fruit tree, vegetable crop refractory fungal disease medicine
The application of aspect, is especially preparing the fungal disease medicines such as preventing and treating phytophthora root rot, late blight, downy mildew, damping-off, banded sclerotial blight
On application, most preferably prevent and treat application on downy mildew of garpe medicine preparing.Described bactericidal composition is to above-mentioned resistance plant
Fungal disease is respectively provided with significant effect, can produce higher synergistic function.
Compared with prior art, beneficial effects of the present invention：
(1), compared with single dose, the bactericidal composition scope of application of the present invention increases, and expands preventing and treating spectrum, it is adaptable to prevent and treat cereal
Class, fruit tree, the refractory fungal disease of vegetables, have preventing and treating effect well to sac fungus, basidiomycetes, Fungi Imperfecti fungal disease
Really, it is particularly suitable for preventing and treating phytophthora root rot, late blight, downy mildew, damping-off, banded sclerotial blight, is respectively provided with significant effect, energy
Produce higher synergistic function.
(2), compared with single dose, overcome and delayed the resistance to the action of a drug, fungi can be suppressed to unitary agent (benzene metsulfovax and thiophene furan
Acid amides is arbitrary) drug-fast generation, alternative routine and be also easy to produce the agricultural chemicals of resistance.
(3), the consumption of the amount ratio independent reactive compound of bactericidal composition of the present invention is substantially reduced, i.e. the activity of mixture is big
In the activity of independent component, compared with single dose, preventing and treating recruitment, drug cost is reduced.
Specific embodiment
With reference to embodiments technical scheme is described further, two kinds of reactive compounds can be processed into permission
Any one formulation, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.The system of formulation in embodiment
Preparation Method is conventional method.
" % " of the present invention is weight percentage.
Embodiment 1
Weigh benzene metsulfovax 5g, thifluzamide 10g, detergent LS (to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g, expansion
Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g, and mixture carries out air-flow crushing,
Prepared active ingredient weight percentage is 15% benzene metsulfovax-thifluzamide wettable powder.
Embodiment 2
Benzene metsulfovax 3g, thifluzamide 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g is weighed, it is high
Ridge soil adds to 100g, and mixture carries out air-flow crushing, and it is 15% benzene metsulfovax-thiophene furan that active ingredient weight percentage is obtained
Acid amides wettable powder.
Embodiment 3
Benzene metsulfovax 2g, thifluzamide 14g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g is weighed, it is high
Ridge soil adds to 100g, and mixture carries out air-flow crushing, and it is 16% benzene metsulfovax-thiophene furan that active ingredient weight percentage is obtained
Acid amides wettable powder.
Embodiment 4
Weigh benzene metsulfovax 5g, thifluzamide 50g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33# (alkyl
Aryl polyoxyethylene polyoxypropylene ether) 2g, APES 1g, 150# solvent naphtha 13g, add water to 100g.Will
Above raw material routinely prepares the method input mixing kettle high speed mixing of aqueous emulsion, and making effective Ingredients Weight percentage composition is
55% benzene metsulfovax-thifluzamide aqueous emulsion.
Embodiment 5
Weigh benzene metsulfovax 2g, thifluzamide 30g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, effective Ingredients Weight percentage composition is made for 32% benzene metsulfovax-thifluzamide
Microemulsion.
Embodiment 6
Weigh benzene metsulfovax 1g, thifluzamide 5g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is thrown
Enter the mixing of mixing kettle high speed, effective Ingredients Weight percentage composition is made for 6% benzene metsulfovax-thifluzamide aqueous emulsion.
Embodiment 7
Weigh benzene metsulfovax 50g, thifluzamide 20g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Sesame oil APEO 2g, plus 150# solvent naphthas are to 100g.Above raw material is routinely prepared into the method input mixing kettle of missible oil
Middle mixing, makes effective Ingredients Weight percentage composition for 70% benzene metsulfovax-thifluzamide missible oil.
Embodiment 8
Benzene metsulfovax 2g, thifluzamide 40g, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g is weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, make active ingredient
Weight percentage is 42% benzene metsulfovax-thifluzamide missible oil.
Embodiment 9
Weigh benzene metsulfovax 5g, thifluzamide 20g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.By above raw material routinely
Mix in the method input mixing kettle for preparing microemulsion, effective Ingredients Weight percentage composition is made for 25% benzene metsulfovax-thiophene furan acyl
Amine microemulsion.
Embodiment 10
Benzene metsulfovax 5g, thifluzamide 0.5g, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g is weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, make active ingredient
Weight percentage is 5.5% benzene metsulfovax-thifluzamide missible oil.
Embodiment 11
Benzene metsulfovax 5g, thifluzamide 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g is weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, make active ingredient
Weight percentage is 35% benzene metsulfovax-thifluzamide missible oil.
Embodiment 12
Weigh benzene metsulfovax 10g, thifluzamide 10g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 20% benzene metsulfovax-thifluzamide suspending agent into active ingredient weight percentage.
Embodiment 13
Weigh benzene metsulfovax 30g, thifluzamide 12g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 42% benzene metsulfovax-thifluzamide suspending agent into active ingredient weight percentage.
Embodiment 14
Weigh benzene metsulfovax 2g, thifluzamide 5g, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is pressed water dispersible granular agent method system
It is 7% benzene metsulfovax-thifluzamide water dispersion granule into active ingredient weight percentage.
Embodiment 15
Weigh benzene metsulfovax 4g, thifluzamide 13g, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, borax 2g, diatomite complement to 100g, and above raw material is formed with imitating into by water dispersible granular agent method
Weight percentage is divided to be 17% benzene metsulfovax-thifluzamide water dispersion granule.
Embodiment 16
Weigh benzene metsulfovax 5g, thifluzamide 15g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 20% benzene metsulfovax-thifluzamide suspending agent.
Embodiment 17
Indoor biometricses are tested：
Mycelial growth rate method is adopted indoors, determines different agents to downy mildew of garpe bacterial strain (Plasmopara viticola)
EC50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, has
Body computational methods are as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, and CTC exists for antagonism, CTC when being less than 80
It is summation action between 80-120.
Table 1：Indoor biometricses result of the benzene metsulfovax+thifluzamide different ratio to downy mildew of garpe bacterial strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| Benzene metsulfovax (A) | Y=2.50X+3.46 | 4.1255 | - |
| Thifluzamide (B) | Y=1.94X+3.26 | 7.8620 | - |
| A:B=80:1 | Y=2.30X+2.93 | 7.906 | 100.23 |
| A:B=1:2 | Y=1.82X+3.53 | 6.392 | 180.04 |
| A:B=1:4 | Y=2.47X+2.81 | 7.728 | 164.15 |
| A:B=1:6 | Y=1.11X+4.03 | 7.442 | 178.25 |
| A:B=1:10 | Y=2.06X+3.32 | 6.572 | 210.63 |
| A:B=1:60 | Y=1.25X+3.61 | 12.894 | 114.50 |
| A:B=1:70 | Y=4.12X+0.15 | 15.010 | 98.56 |
1 indoor biometricses of table test result indicate that, benzene metsulfovax and thifluzamide weight ratio are 1～70：1～50 composition is altogether
Malicious coefficient is both greater than 120, has obvious synergistic function to Plasmopara viticola.
Field control effectiveness test：
Carried out preventing and treating downy mildew of garpe test with pesticidal preparations obtained in above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicament point respectively according to the difference of each composition
It is not 10% benzene metsulfovax EW of agricultural chemicals single dose and 24% thifluzamide SC and blank clean water experiment.
2nd, test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is：5 points of the grab sample in the test process area (takes 5m per2), the state of an illness is carried out according to national field test relevant criterion
Classification, calculates preventive effect.
3rd, result of the test see the table below：
Table 2：Field efficacy result of the benzene metsulfovax+thifluzamide different ratio to downy mildew of garpe
As shown in Table 2：Compared with single dose, benzene metsulfovax and thifluzamide composition have significant effect to downy mildew of garpe,
Higher synergistic function can be produced.The consumption of the amount ratio independent reactive compound of bactericidal composition is substantially reduced, that is, mix
Activity of the activity of thing more than independent component, compared with single dose, reduces preventing and treating recruitment, drug cost.
Shown by indoor biometricses and field efficacy result, benzene metsulfovax there is obvious Synergistic to make with thifluzamide composition
With the prevention effect of composition is excellent, and prevention effect is better than single dose kind, in agricultural application has using value.
Claims (10)
1. a kind of bactericidal composition containing benzene metsulfovax and thifluzamide, it is characterised in that it with benzene metsulfovax and thifluzamide is
Main active, described benzene metsulfovax are 1～70 with thifluzamide weight ratio：1～50.
2. the bactericidal composition containing benzene metsulfovax and thifluzamide according to claim 1, it is characterised in that benzene metsulfovax
Weight ratio with thifluzamide is 5～50：10～50.
3. the bactericidal composition containing benzene metsulfovax and thifluzamide according to claim 2, it is characterised in that described benzene
The weight ratio of metsulfovax and thifluzamide is 5～40：10～50.
4. the bactericidal composition containing benzene metsulfovax and thifluzamide according to claim 3, it is characterised in that described benzene
The weight ratio of metsulfovax and thifluzamide is 1：2～10.
5. the bactericidal composition containing benzene metsulfovax and thifluzamide according to claim 1, it is characterised in that described benzene
It is 2～80% that both metsulfovax and thifluzamide account for the weight percentage of composition.
6. the bactericidal composition containing benzene metsulfovax and thifluzamide according to claim 5, it is characterised in that described benzene
It is 5.5～70% that both metsulfovax and thifluzamide account for the weight percentage of composition.
7. the bactericidal composition containing benzene metsulfovax and thifluzamide according to claim 1, it is characterised in that it is with benzene thiophene
Bacterium amine and thifluzamide are that principle active component and insecticides adjuvant, excipients are configured to any one formulation allow on agricultural chemicals.
8. the bactericidal composition containing benzene metsulfovax and thifluzamide according to claim 7, it is characterised in that described agent
Type is missible oil, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the bactericidal composition containing benzene metsulfovax and thifluzamide described in claim 1 is preparing preventing and treating resistance plant nosomycosis
Application on evil medicine.
10. the bactericidal composition containing benzene metsulfovax and thifluzamide described in claim 1 is preparing preventing and treating phytophthora root rot, late blight
Application on disease, downy mildew, damping-off, banded sclerotial blight medicine, is preferably preparing the application prevented and treated on downy mildew of garpe medicine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510587341.8A CN106508931A (en) | 2015-09-15 | 2015-09-15 | Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510587341.8A CN106508931A (en) | 2015-09-15 | 2015-09-15 | Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106508931A true CN106508931A (en) | 2017-03-22 |
Family
ID=58348660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510587341.8A Pending CN106508931A (en) | 2015-09-15 | 2015-09-15 | Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106508931A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107581194A (en) * | 2017-10-11 | 2018-01-16 | 安徽省农业科学院作物研究所 | A kind of bactericidal composition and its prevention and controls for preventing and treating wheat scab |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1409596A (en) * | 1999-12-13 | 2003-04-09 | 拜尔公司 | Fungicidal combinations of active substances |
| WO2010072634A2 (en) * | 2008-12-22 | 2010-07-01 | Basf Se | Post-harvest treatment method |
| CN103478153A (en) * | 2013-10-12 | 2014-01-01 | 京博农化科技股份有限公司 | Sterile composition containing boscalid and benthiavalicarb isopropyl |
-
2015
- 2015-09-15 CN CN201510587341.8A patent/CN106508931A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1409596A (en) * | 1999-12-13 | 2003-04-09 | 拜尔公司 | Fungicidal combinations of active substances |
| WO2010072634A2 (en) * | 2008-12-22 | 2010-07-01 | Basf Se | Post-harvest treatment method |
| CN103478153A (en) * | 2013-10-12 | 2014-01-01 | 京博农化科技股份有限公司 | Sterile composition containing boscalid and benthiavalicarb isopropyl |
Non-Patent Citations (1)
| Title |
|---|
| 仇是胜 等: "琥珀酸脱氢酶抑制剂类杀菌剂的研究进展(I)", 《现代农药》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107581194A (en) * | 2017-10-11 | 2018-01-16 | 安徽省农业科学院作物研究所 | A kind of bactericidal composition and its prevention and controls for preventing and treating wheat scab |
| CN107581194B (en) * | 2017-10-11 | 2020-05-29 | 安徽省农业科学院作物研究所 | Bactericidal composition for preventing and treating wheat scab and prevention and treatment method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106508943A (en) | Bactericidal composition containing benthiavalicarb-isopropyl and prochloraz, and applications thereof | |
| CN106889079B (en) | A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine | |
| CN106508931A (en) | Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof | |
| CN106508932A (en) | Bactericidal composition containing benthiavalicarb and cyproconazole and application thereof | |
| CN107296047A (en) | A kind of bactericidal composition and its application containing isopyrazam and jinggangmeisu | |
| CN106538565A (en) | The bactericidal composition and its application of a kind of containing fluopyram and thifluzamide | |
| CN106508936A (en) | Bactericidal composition containing benthiavalicarb-isopropyl and carbendazim, and applications thereof | |
| CN105379753B (en) | A kind of bactericidal composition and its application containing mepanipyrim and different rice blast net | |
| CN105746534A (en) | Fungicidal composition containing isopyrazam and isotianil and application thereof | |
| CN106538543A (en) | The bactericidal composition and its application of a kind of containing fluopyram and Bravo | |
| CN105941425B (en) | A kind of bactericidal composition and its application of fluorine-containing ether bacterium acid amides and Wakil | |
| CN105360129B (en) | A kind of bactericidal composition and its application containing mepanipyrim and cyazofamid | |
| CN105360128B (en) | A kind of bactericidal composition and its application containing mepanipyrim and Boscalid | |
| CN105379731B (en) | It is a kind of containing mepanipyrim He the bactericidal composition of famoxadone and its application | |
| CN107047583A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and Mancozeb | |
| CN106508934A (en) | Fungicidal composition containing benthiavalicarb-isopropyl and amobam and application thereof | |
| CN106973919A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid | |
| CN106508930A (en) | Sterilization composition containing benthiavalicarb-isopropyl and fludioxonil | |
| CN107333782A (en) | A kind of bactericidal composition and its application of the pyrrole bacterium ketone of benzene containing amine and cyazofamid | |
| CN106508933A (en) | Sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim | |
| CN106973920A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and fenoxanil | |
| CN106538569A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and benzene metsulfovax | |
| CN107306990A (en) | A kind of bactericidal composition and its application containing isopyrazam and Flusilazole | |
| CN106857565A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and SYP-3375 | |
| CN105831127A (en) | Desflurane bacteria amide and metconazole-containing sterilization composition and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170322 |