CN106538543A - The bactericidal composition and its application of a kind of containing fluopyram and Bravo - Google Patents
The bactericidal composition and its application of a kind of containing fluopyram and Bravo Download PDFInfo
- Publication number
- CN106538543A CN106538543A CN201510593847.XA CN201510593847A CN106538543A CN 106538543 A CN106538543 A CN 106538543A CN 201510593847 A CN201510593847 A CN 201510593847A CN 106538543 A CN106538543 A CN 106538543A
- Authority
- CN
- China
- Prior art keywords
- bravo
- fluopyram
- bactericidal composition
- containing fluopyram
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses the bactericidal composition and its application of a kind of containing fluopyram and Bravo.The bactericidal composition of a kind of containing fluopyram and Bravo,, with fluopyram and Bravo as main active, described fluopyram and Bravo weight ratio are 1～70 for it：1～50.The invention also discloses application of the bactericidal composition on preventing and treating resistance plant fungal disease disease is prepared, can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the Drug resistance of pathogenic bacteria, sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to for fungal diseases such as control rust, anthrax, powdery mildew, downy mildew, gray molds, and effect is better than single dose use.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, the especially bactericidal composition of a kind of containing fluopyram and Bravo
And its application.
Background technology
Fluopyram (Fluopyram), molecular formula：C16H11ClF6N2O, chemical name：N- [2- [chloro- 5- (the fluoroforms of 3-
Base) -2- pyridines] ethyl] -2- (trifluoromethyl) Benzoylamide, structural formula：
Fluopyram is a kind of new pyridine ethyl benzamide series bactericidal agent, by hindering succinate dehydrogenase in respiratory chain
Electron transfer and suppress mitochondrial respiratory.It is mainly used on broad leaf crop, preventing and treating the microbial disease of capsule, to Fructus Cucumidis sativi, Cucurbita pepo L. etc.
Downy mildew, powdery mildew on vegetable, downy mildew of fruit tree etc. cause multiple diseases to have favorable effect by pathogenic bacteria.
Bravo (Chlorothalonil), chemical name is：2,4,5,6- tetra- chloro- 1,3- dicyanobenzenes, daconil M,
Molecular formula：C8Cl4N2.Structural formula：
Bravo is wide spectrum, protective fungicide, and the mechanism of action is that can occur with the glyceraldehyde 3-phosphate dehydrogenase in fungal cell
Effect, is combined with the protein containing cysteine in the enzyme, so as to destroy the enzymatic activity, makes the metabolism of fungal cell
It is damaged and loses vitality, Bravo does not have Uptake and translocation effect, but after being sprayed onto on plant, can has good on body surface
Cohesiveness, be difficult to be fallen by rain drop erosion, thus the drug effect phase be longer.Be mainly used in rust on fruit tree, vegetable, anthrax,
The preventing and treating of powdery mildew, downy mildew.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with economy such as the change of pattern of farming, melon fruits and vegetables
Crops planting area progressively expands, and disease occurrence degree, generation quantity increase, and in preventing and treating, difficulty is increased；The opposing party
Face, the resistance of pathogen rise under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant disease
Preventing and treating is faced with significant challenge.
The content of the invention
The purpose of the present invention is to provide a kind of applied widely, low cost, effect good fluorine-containing pyrrole bacterium acyl for above-mentioned technical problem
The plant bactericidal composition of amine and Bravo.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition of containing fluopyram and Bravo, it with fluopyram and Bravo as main active,
The weight ratio of described fluopyram and Bravo is 1～70：1～50, wherein in bactericidal composition, active ingredient is with potentiation
Effective dose is present in compositionss.
In bactericidal composition of the present invention, the weight ratio preferably 5～50 of described fluopyram and Bravo：10～
50, more preferably 5～40：10～45, most preferably 1：1～9.
In bactericidal composition of the present invention, both described fluopyram and Bravo account for the weight percent of compositionss and contain
Measure as 2～80%, preferably 5.5～70%.
Bactericidal composition of the present invention is with fluopyram and Bravo as principle active component and known auxiliary agent and excipient
It is re-dubbed any one dosage form allow on pesticide.Auxiliary agent, excipient known to these have dispersant, diffusant, defoamer,
Wetting agent, disintegrating agent etc., can be using to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium methylene bis-naphthalene sulfonate, dodecyl
Benzenesulfonic acid calcium, alkylphenol polyoxyethylene, alkylaryl polyoxyethylene polyoxypropylene ether again, Ben-zylphenol Polyoxyethyl Ether, phenethyl
Phenol polyethenoxy ether, three phenethyl phenol polyoxyethylene ether phosphates, fatty alcohol-polyoxyethylene ether and its similar products, fatty amine gather
Oxygen vinyl Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxypropylene block compound, castor oil polyoxyethylene ether, nonyl
Base phenol polyethenoxy ether, TWEEN Series, Polyethylene Glycol series, Sulfonateses, carboxylate, sulfate, phosphate, phosphorous acid
One or more combinations in salt, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., figuration
Agent includes Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as Propylene Glycol), deionized water etc..Above auxiliary agent,
Excipient and other adjuvants can be with alone or be used in combination.
Described dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule etc..
It is a still further object of the present invention to provide the bactericidal composition causes the application on fungal disease in preventing and treating plant epiphyte, especially
It is the purposes on the fungal diseases such as control rust, anthrax, powdery mildew, downy mildew, gray mold.
It is a still further object of the present invention to provide the bactericidal composition is preparing the fungus-caused fungal disease medicine of preventing and treating resistance plant
On application.Preferably, described bactericidal composition is preparing preventing and treating Cereal, fruit tree, vegetable crop refractory fungal disease medicine
The application in object space face, is especially preparing the fungal disease medicine such as control rust, anthrax, powdery mildew, downy mildew, gray mold
On application, most preferably prevent and treat application on downy mildew of garpe medicine preparing.Described bactericidal composition is to above-mentioned resistance plant
Fungal disease is respectively provided with significant effect, can produce higher synergistic function.
Compared with prior art, beneficial effects of the present invention：
(1), compared with single dose, the bactericidal composition scope of application of the present invention increases, and expands preventing and treating spectrum, it is adaptable to prevent and treat cereal
Class, fruit tree, the refractory fungal disease of vegetable, have preventing and treating effect well to ascomycetess, basidiomycetes, Fungi Imperfecti fungal disease
Really, control rust, anthrax, powdery mildew, downy mildew, gray mold are particularly suitable for, significant effect is respectively provided with, can be produced
The higher synergistic function of life.
(2), compared with single dose, overcome and delayed Drug resistance, funguses can be suppressed to unitary agent (fluopyram and hundred
Bacterium is arbitrary clearly) drug-fast generation, alternative routine and be also easy to produce the pesticide of resistance.
(3), the consumption of the amount ratio independent reactive compound of bactericidal composition of the present invention is substantially reduced, i.e. the activity of mixture is big
In the activity of independent component, compared with single dose, preventing and treating recruitment, drug cost are reduced.
Specific embodiment
With reference to embodiments technical scheme is described further, two kinds of reactive compounds can be processed into permission
Any one dosage form, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.The system of dosage form in embodiment
Preparation Method is conventional method.
" % " of the present invention is weight percentage.
Embodiment 1
Weigh fluopyram 5g, Bravo 10g, detergent LS (to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g, expansion
Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin add to 100g, and mixture carries out comminution by gas stream,
Prepared effective ingredient weight percentage is 15% fluopyram-Bravo wettable powder.
Embodiment 2
Fluopyram 3g, Bravo 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g are weighed, it is high
Ridge soil adds to 100g, and mixture carries out comminution by gas stream, and it is 15% fluopyram-hundred that effective ingredient weight percentage is obtained
The clear wettable powder of bacterium.
Embodiment 3
Fluopyram 2g, Bravo 18g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g are weighed, it is high
Ridge soil adds to 100g, and mixture carries out comminution by gas stream, and it is 20% fluopyram-hundred that effective ingredient weight percentage is obtained
The clear wettable powder of bacterium.
Embodiment 4
Weigh fluopyram 5g, Bravo 50g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33# (alkyl
Aryl polyoxyethylene polyoxypropylene ether) 2g, alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Will
Above raw material routinely prepares the method input mixing kettle high speed mixing of aqueous emulsion, and making effective Ingredients Weight percentage composition is
55% fluopyram-Bravo aqueous emulsion.
Embodiment 5
Weigh fluopyram 2g, Bravo 30g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, effective Ingredients Weight percentage composition is made for 32% fluopyram-Bravo
Microemulsion.
Embodiment 6
Weigh fluopyram 1g, Bravo 5g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is thrown
Enter the mixing of mixing kettle high speed, effective Ingredients Weight percentage composition is made for 6% fluopyram-Bravo aqueous emulsion.
Embodiment 7
Weigh fluopyram 50g, Bravo 20g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Oleum Sesami polyoxyethylene ether 2g, plus 150# solvent naphthas are to 100g.Above raw material is routinely prepared into the method input mixing kettle of cream
Middle mixing, makes effective Ingredients Weight percentage composition for 70% fluopyram-Bravo cream.
Embodiment 8
Fluopyram 2g, Bravo 40g, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 42% fluopyram-Bravo cream.
Embodiment 9
Weigh fluopyram 5g, Bravo 20g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material routinely
Mix in the method input mixing kettle for preparing microemulsion, effective Ingredients Weight percentage composition is made for-hundred bacterium of 25% fluopyram
Clear microemulsion.
Embodiment 10
Fluopyram 5g, Bravo 0.5g, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 5.5% fluopyram-Bravo cream.
Embodiment 11
Fluopyram 5g, Bravo 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 35% fluopyram-Bravo cream.
Embodiment 12
Weigh fluopyram 10g, Bravo 10g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 20% fluopyram-Bravo suspending agent into effective ingredient weight percentage.
Embodiment 13
Weigh fluopyram 30g, Bravo 12g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 42% fluopyram-Bravo suspending agent into effective ingredient weight percentage.
Embodiment 14
Weigh fluopyram 2g, Bravo 5g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and above raw material is pressed water dispersible granular agent method system
It is 7% fluopyram-Bravo water dispersion granule into effective ingredient weight percentage.
Embodiment 15
Weigh fluopyram 4g, Bravo 13g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, kieselguhr complement to 100g, and above raw material is formed with imitating composition by water dispersible granular agent method
Weight percentage is 17% fluopyram-Bravo water dispersion granule.
Embodiment 16
Weigh fluopyram 5g, Bravo 15g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 20% fluopyram-Bravo suspending agent.
Embodiment 17
Indoor biometricses are tested：
Mycelial growth rate method is adopted indoors, determines different agents to downy mildew of garpe bacterial strain (Plasmopara viticola)
EC50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, has
Body computational methods are as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, and CTC exists for antagonism, CTC when being less than 80
It is summation action between 80-120.
Table 1：Indoor biometricses result of the fluopyram+Bravo different ratio to downy mildew of garpe bacterial strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| Fluopyram (A) | Y=2.25X+3.05 | 7.332 | - |
| Bravo (B) | Y=1.48X+3.41 | 11.956 | - |
| A:B=80:1 | Y=1.52X+3.37 | 11.740 | 102.33 |
| A:B=1:1 | Y=1.26X+3.87 | 7.864 | 188.48 |
| A:B=1:3 | Y=2.94X+2.02 | 10.315 | 156.18 |
| A:B=1:6 | Y=2.15X+3.03 | 8.232 | 210.30 |
| A:B=1:9 | Y=1.75X+3.24 | 10.198 | 178.65 |
| A:B=1:60 | Y=2.63X+1.77 | 16.850 | 114.52 |
| A:B=1:70 | Y=2.54X+1.92 | 16.286 | 118.66 |
1 indoor biometricses of table test result indicate that, fluopyram and Bravo weight ratio are 1～70：1～50 compositionss are altogether
Malicious coefficient is both greater than 120, has obvious synergistic function to Plasmopara viticola.
Field control effectiveness test：
Downy mildew of garpe test is prevented and treated with pesticidal preparations obtained in above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicament point respectively according to the difference of each composition
It is not 41.7% fluopyram SC of pesticide single dose and 75% Chlorothalonil WP against cucumber mildew and blank clean water experiment.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect method after investigating and prevent and treat before dispenser
For：5 points of randomization (takes 5M per in the test process area2), the state of an illness point is carried out according to national field test relevant criterion
Level, calculates preventive effect.
3rd, result of the test see the table below：
Table 2：Field efficacy result of the fluopyram+Bravo different ratio to downy mildew of garpe
As shown in Table 2：Compared with single dose, fluopyram and Bravo compositionss have significant effect to downy mildew of garpe,
Higher synergistic function can be produced.The consumption of the amount ratio independent reactive compound of bactericidal composition is substantially reduced, that is, mix
Activity of the activity of thing more than independent component, compared with single dose, reduces preventing and treating recruitment, drug cost.
Shown by indoor biometricses and field efficacy result, fluopyram there is obvious Synergistic to make with Bravo compositionss
With the prevention effect of compositionss is excellent, and prevention effect is better than single dose kind, in agricultural application has using value.
Claims (10)
1. the bactericidal composition of a kind of containing fluopyram and Bravo, it is characterised in that it with fluopyram and Bravo is
The weight ratio of main active, described fluopyram and Bravo is 1～70：1～50.
2. the bactericidal composition of containing fluopyram according to claim 1 and Bravo, it is characterised in that described fluorine
The weight ratio of pyrrole bacterium amide and Bravo is 5～50：10～50.
3. the bactericidal composition of containing fluopyram according to claim 2 and Bravo, it is characterised in that described fluorine
The weight ratio of pyrrole bacterium amide and Bravo is 5～40：10～45.
4. the bactericidal composition of containing fluopyram according to claim 3 and Bravo, it is characterised in that described fluorine
The weight ratio of pyrrole bacterium amide and Bravo is 1：1～9.
5. the bactericidal composition of containing fluopyram according to claim 1 and Bravo, it is characterised in that described fluorine
It is 2～80% that both pyrrole bacterium amide and Bravo account for the weight percentage of compositionss.
6. the bactericidal composition containing fluopyram and Bravo according to claim 5, it is characterised in that described
It is 5.5～70% that both fluopyram and Bravo account for the weight percentage of compositionss.
7. the bactericidal composition of containing fluopyram according to claim 1 and Bravo, it is characterised in that it is with fluorine pyrrole
Bacterium amide and Bravo are that principle active component and insecticides adjuvant, excipient are configured to any one dosage form allow on pesticide.
8. the bactericidal composition of containing fluopyram according to claim 7 and Bravo, it is characterised in that described agent
Type is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the bactericidal composition of the containing fluopyram and Bravo described in claim 1 is preparing preventing and treating resistance plant mycosises
The application fallen ill on medicine.
10. the bactericidal composition of the containing fluopyram and Bravo described in claim 1 prepare control rust, anthrax,
Application on powdery mildew, downy mildew, grey mold medicine, is preferably preparing the application prevented and treated on downy mildew of garpe medicine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510593847.XA CN106538543A (en) | 2015-09-17 | 2015-09-17 | The bactericidal composition and its application of a kind of containing fluopyram and Bravo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510593847.XA CN106538543A (en) | 2015-09-17 | 2015-09-17 | The bactericidal composition and its application of a kind of containing fluopyram and Bravo |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106538543A true CN106538543A (en) | 2017-03-29 |
Family
ID=58362942
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510593847.XA Pending CN106538543A (en) | 2015-09-17 | 2015-09-17 | The bactericidal composition and its application of a kind of containing fluopyram and Bravo |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106538543A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108459000A (en) * | 2018-03-16 | 2018-08-28 | 北方工业大学 | Time-resolved fluorescence test strip for detecting fluopyram and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005077180A1 (en) * | 2004-02-12 | 2005-08-25 | Bayer Cropscience Sa | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting mitosis and cell division |
| CN1917762A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
| EP2039772A2 (en) * | 2009-01-06 | 2009-03-25 | Bayer CropScience AG | Method for improved utilization of the production potential of transgenic plants introduction |
| CN103535354A (en) * | 2012-07-13 | 2014-01-29 | 陕西美邦农药有限公司 | Efficient bactericidal composition |
-
2015
- 2015-09-17 CN CN201510593847.XA patent/CN106538543A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005077180A1 (en) * | 2004-02-12 | 2005-08-25 | Bayer Cropscience Sa | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting mitosis and cell division |
| CN1917762A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
| EP2039772A2 (en) * | 2009-01-06 | 2009-03-25 | Bayer CropScience AG | Method for improved utilization of the production potential of transgenic plants introduction |
| CN103535354A (en) * | 2012-07-13 | 2014-01-29 | 陕西美邦农药有限公司 | Efficient bactericidal composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108459000A (en) * | 2018-03-16 | 2018-08-28 | 北方工业大学 | Time-resolved fluorescence test strip for detecting fluopyram and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106538543A (en) | The bactericidal composition and its application of a kind of containing fluopyram and Bravo | |
| CN106508943A (en) | Bactericidal composition containing benthiavalicarb-isopropyl and prochloraz, and applications thereof | |
| CN106538568A (en) | The bactericidal composition and its application of a kind of containing fluopyram and Propamocarb | |
| CN106538565A (en) | The bactericidal composition and its application of a kind of containing fluopyram and thifluzamide | |
| CN106508931A (en) | Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof | |
| CN105831131A (en) | Bactericidal composition containing fluxapyroxad and thiabendazole and application thereof | |
| CN105746525A (en) | Fungicidal composition containing isopyrazam and mepanipyrim and application thereof | |
| CN106508936A (en) | Bactericidal composition containing benthiavalicarb-isopropyl and carbendazim, and applications thereof | |
| CN105766926A (en) | Bactericidal composition containing bixafen and coumoxystrobin and application thereof | |
| CN106538575A (en) | The bactericidal composition and its application of a kind of containing fluopyram and thiram | |
| CN105941427A (en) | Bactericidal composition containing spiroxamine and zinc thiazole and application of bactericidal composition | |
| CN105360129B (en) | A kind of bactericidal composition and its application containing mepanipyrim and cyazofamid | |
| CN105746534A (en) | Fungicidal composition containing isopyrazam and isotianil and application thereof | |
| CN106538536A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and metalaxyl | |
| CN106538535A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M | |
| CN105831124A (en) | Bactericidal composition containing fluxapyroxad and ethirimol and application thereof | |
| CN106508932A (en) | Bactericidal composition containing benthiavalicarb and cyproconazole and application thereof | |
| CN105475341A (en) | Sterilization composition containing silthiopham and flusilazole and application thereof | |
| CN106538571A (en) | The bactericidal composition and its application of a kind of containing fluopyram and zineb | |
| CN106538567A (en) | The bactericidal composition and its application of a kind of containing fluopyram and polyoxin | |
| CN106508928A (en) | Sterilization composition containing benthiavalicarb-isopropyl and isoprothiolane and application thereof | |
| CN106538541A (en) | The bactericidal composition and its application of a kind of containing fluopyram and carboxin | |
| CN106508929A (en) | Sterilization composition containing benthiavalicarb-isopropyl and cyprodinil as well as application thereof | |
| CN106508933A (en) | Sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim | |
| CN105746527A (en) | Fungicidal composition containing isopyrazam and boscalid and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170329 |
|
| RJ01 | Rejection of invention patent application after publication |