CN106538535A - The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M - Google Patents
The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M Download PDFInfo
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- CN106538535A CN106538535A CN201510601218.7A CN201510601218A CN106538535A CN 106538535 A CN106538535 A CN 106538535A CN 201510601218 A CN201510601218 A CN 201510601218A CN 106538535 A CN106538535 A CN 106538535A
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- phenylancryic acetate
- bactericidal composition
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Abstract
The invention discloses the bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M.The bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M,, with 2-cyano-3-amino-3-phenylancryic acetate and Metalaxyl-M as main active, described 2-cyano-3-amino-3-phenylancryic acetate and the weight ratio of Metalaxyl-M are 1～70 for it：1～50.The invention also discloses application of the bactericidal composition on preventing and treating resistance plant fungal disease medicine is prepared, can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the Drug resistance of pathogenic bacteria, sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as wheat scab, bakanae disease of rice, tomato wilt, downy mildew, phytophthora root rot, effect is better than single dose use.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, the especially bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M
And its application.
Background technology
2-cyano-3-amino-3-phenylancryic acetate, outward appearance is white powder, molecular formula：C12H12N2O2, chemical name：2- cyano group -3- amino -3-
Ethyl phenylacrylate.
2-cyano-3-amino-3-phenylancryic acetate belongs to 2- cyanoacrylate antibacterial, is a kind of unique new type bactericide of model of action, to reaping hook mushroom
Effectively, the bakanae disease of rice that especially causes to the microbial head blight of reaping hook, fusarium moniliforme, fusarium oxysporum draw for the disease that causes
The tomato wilt for rising has good prevention effect.2-cyano-3-amino-3-phenylancryic acetate is absorbed by root, has translocatable upwards, face on blade
To blade bottom and interlobate translocatable poor.
Metalaxyl-M (Metalaxyl-M), molecular formula：C15H21NO4.Chemical name：N- (2,6- xylyls)-N-
(Methoxyacetyl)-D- alanine methyl ester.Structural formula：
Metalaxyl-M is the efficient systemic fungicide of Syngenta Co., Ltd's exploitation, with protection and therapeutical effect, can be by plant roots
Stem and leaf absorbs rapidly, and each position is run in plant body, thus resistance of rainwater washing against, to Pseudoperonospora cubensis, phytophthora pathogenic bacteria,
The crop pests such as the vegetable caused by rotten mildew fungus, fruit tree, Nicotiana tabacum L., oil plant, Cotton Gossypii, grain have efficient.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with Jing such as the change of pattern of farming, melon fruits and vegetables
Ji crops planting area progressively expands, and disease occurrence degree, generation quantity increase, and in preventing and treating, difficulty is increased；It is another
Aspect, the resistance of pathogen rise under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, phytopathy
Evil preventing and treating is faced with significant challenge.
The content of the invention
The purpose of the present invention is to provide a kind of applied widely, low cost, effect good 2-cyano-3-amino-3-phenylancryic acetate-containing for above-mentioned technical problem
With the plant bactericidal composition of Metalaxyl-M.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M, it with 2-cyano-3-amino-3-phenylancryic acetate and Metalaxyl-M as main active,
Described 2-cyano-3-amino-3-phenylancryic acetate is 1～70 with the weight ratio of Metalaxyl-M：1～50, wherein in bactericidal composition, active ingredient is with potentiation
Effective dose is present in compositionss.
In bactericidal composition of the present invention, the weight ratio preferably 5～50 of described 2-cyano-3-amino-3-phenylancryic acetate and Metalaxyl-M：10～
50, more preferably 5～40：10～30, much further preferably from 1：0.4～3.25, most preferably 1：04、1：2.5
Or 1：3.25.
In bactericidal composition of the present invention, both described 2-cyano-3-amino-3-phenylancryic acetate and Metalaxyl-M account for the weight percentage of compositionss and are
2～80%, preferably 5.5～70%.
Described bactericidal composition, it with 2-cyano-3-amino-3-phenylancryic acetate and Metalaxyl-M as main active and known auxiliary agent and excipient it is multiple
It is made into any one dosage form allow on pesticide.Known to these, auxiliary agent, excipient have dispersant, diffusant, defoamer, profit
Humectant, disintegrating agent etc., can be using to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium methylene bis-naphthalene sulfonate, detergent alkylate
Sulfoacid calcium, alkylphenol polyoxyethylene, alkylaryl polyoxyethylene polyoxypropylene ether again, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol
Polyoxyethylene ether, three phenethyl phenol polyoxyethylene ether phosphates, fatty alcohol-polyoxyethylene ether and its similar products, fatty amine polyoxy
Vinyl Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxypropylene block compound, castor oil polyoxyethylene ether, nonyl
Phenol polyethenoxy ether, TWEEN Series, Polyethylene Glycol series, Sulfonateses, carboxylate, sulfate, phosphate, phosphorous acid
One or more combinations in salt, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., figuration
Agent includes Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as Propylene Glycol), deionized water etc..Above auxiliary agent,
Excipient and other adjuvants can be with alone or be used in combination.
Described dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
It is a still further object of the present invention to provide the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M is true in preparation preventing and treating resistance plant
Application on fungus diseases medicine.Preferably, described bactericidal composition is preparing preventing and treating Cereal, fruit tree, vegetable crop resistance
Application in terms of fungal disease medicine.It is further preferred that the bactericidal composition of described 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M is in system
It is standby to prevent and treat wheat scab, bakanae disease of rice, the application on tomato wilt, downy mildew, phytophthora medicine.Most preferably,
Application of the bactericidal composition of described 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M on preventing and treating gibberella saubinetii medicine is prepared.Described kills
Bacteria composition is respectively provided with significant effect to above-mentioned resistance plant fungal disease, can produce higher synergistic function.
Compared with prior art, beneficial effects of the present invention：
(1), compared with single dose, the bactericidal composition scope of application of the present invention increases, and expands preventing and treating spectrum, it is adaptable to prevent and treat cereal
Class, fruit tree, the refractory fungal disease of vegetable, have to ascomycetess, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease good
Prevention effect, is particularly suitable for preventing and treating head blight, bakanae disease of rice, tomato wilt, downy mildew, phytophthora root rot, is respectively provided with
Significant effect, can produce higher synergistic function.
(2), compared with single dose, overcome and delayed Drug resistance, funguses can be suppressed to unitary agent (2-cyano-3-amino-3-phenylancryic acetate and smart first
White spirit is arbitrary) drug-fast generation, alternative routine and be also easy to produce the pesticide of resistance.
(3), the consumption of the amount ratio independent reactive compound of bactericidal composition of the present invention is substantially reduced, i.e. the activity of mixture is big
In the activity of independent component, compared with single dose, preventing and treating recruitment, drug cost are reduced.
Specific embodiment
With reference to embodiments technical scheme is described further, two kinds of reactive compounds can be processed into permission
Any one dosage form, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.The system of dosage form in embodiment
Preparation Method is conventional method.
" % " of the present invention is weight percentage.
Embodiment 1
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Metalaxyl-M 10g, detergent LS (to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g, expansion
Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin add to 100g, and mixture carries out comminution by gas stream,
Prepared effective ingredient weight percentage is 15% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M wettable powder.
Embodiment 2
2-cyano-3-amino-3-phenylancryic acetate 3g, Metalaxyl-M 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g are weighed, it is high
Ridge soil adds to 100g, and mixture carries out comminution by gas stream, and it is 15% 2-cyano-3-amino-3-phenylancryic acetate-essence first that effective ingredient weight percentage is obtained
White spirit wettable powder.
Embodiment 3
2-cyano-3-amino-3-phenylancryic acetate 2g, Metalaxyl-M 14g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g are weighed, it is high
Ridge soil adds to 100g, and mixture carries out comminution by gas stream, and it is 16% 2-cyano-3-amino-3-phenylancryic acetate-essence first that effective ingredient weight percentage is obtained
White spirit wettable powder.
Embodiment 4
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Metalaxyl-M 50g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33# (alkyl
Aryl polyoxyethylene polyoxypropylene ether) 2g, alkylphenol polyoxyethylene 1g, 100# solvent naphtha 13g, add water to 100g.Will
Above raw material routinely prepares the method input mixing kettle high speed mixing of aqueous emulsion, and making effective Ingredients Weight percentage composition is
55% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M aqueous emulsion.
Embodiment 5
Weigh 2-cyano-3-amino-3-phenylancryic acetate 2g, Metalaxyl-M 30g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, effective Ingredients Weight percentage composition is made for 32% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M
Microemulsion.
Embodiment 6
Weigh 2-cyano-3-amino-3-phenylancryic acetate 1g, Metalaxyl-M 5g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, 100# solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is thrown
Enter the mixing of mixing kettle high speed, effective Ingredients Weight percentage composition is made for 6% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M aqueous emulsion.
Embodiment 7
Weigh 2-cyano-3-amino-3-phenylancryic acetate 50g, Metalaxyl-M 20g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Oleum Sesami polyoxyethylene ether 2g, plus 100# solvent naphthas are to 100g.Above raw material is routinely prepared into the method input mixing kettle of cream
Middle mixing, makes effective Ingredients Weight percentage composition for 70% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M cream.
Embodiment 8
2-cyano-3-amino-3-phenylancryic acetate 2g, Metalaxyl-M 40g, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g are weighed, plus
100# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 42% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M cream.
Embodiment 9
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Metalaxyl-M 20g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material routinely
Mix in the method input mixing kettle for preparing microemulsion, effective Ingredients Weight percentage composition is made for 25% 2-cyano-3-amino-3-phenylancryic acetate-essence first frost
Clever microemulsion.
Embodiment 10
2-cyano-3-amino-3-phenylancryic acetate 5g, Metalaxyl-M 0.5g, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g are weighed, plus
100# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 5.5% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M cream.
Embodiment 11
2-cyano-3-amino-3-phenylancryic acetate 5g, Metalaxyl-M 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g are weighed,
100# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 35% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M cream.
Embodiment 12
Weigh 2-cyano-3-amino-3-phenylancryic acetate 10g, Metalaxyl-M 10g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 20% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M suspending agent into effective ingredient weight percentage.
Embodiment 13
Weigh 2-cyano-3-amino-3-phenylancryic acetate 30g, Metalaxyl-M 12g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 42% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M suspending agent into effective ingredient weight percentage.
Embodiment 14
Weigh 2-cyano-3-amino-3-phenylancryic acetate 2g, Metalaxyl-M 5g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and above raw material is pressed water dispersible granular agent method system
It is 7% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M water dispersion granule into effective ingredient weight percentage.
Embodiment 15
2-cyano-3-amino-3-phenylancryic acetate 4g, Metalaxyl-M 13g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g are weighed,
Polyvinyl alcohol 5g, Borax 2g, kieselguhr complement to 100g, and above raw material is formed with imitating into by water dispersible granular agent method
Weight percentage is divided to be 17% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M water dispersion granule.
Embodiment 16
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Metalaxyl-M 15g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 20% 2-cyano-3-amino-3-phenylancryic acetate-Metalaxyl-M suspending agent.
Embodiment 17
Indoor biometricses are tested：
Mycelial growth rate method is adopted indoors, determines different agents to wheat scab bacteria strain (FusaHum
Graminearum Sehw.) EC50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture,
Determine the building performance of mixture, circular is as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, and CTC exists for antagonism, CTC when being less than 80
It is summation action between 80-120.
Table 1：Indoor biometricses result of the 2-cyano-3-amino-3-phenylancryic acetate+Metalaxyl-M different ratio to wheat scab bacteria strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 2-cyano-3-amino-3-phenylancryic acetate (A) | Y=1.71X+3.62 | 6.3712 | - |
| Metalaxyl-M (B) | Y=2.05X+2.86 | 11.0456 | - |
| A:B=80:1 | Y=3.22X+1.81 | 9.7700 | 113.65 |
| A:B=1:0.4 | Y=1.94X+3.26 | 7.8523 | 178.42 |
| A:B=1:3.25 | Y=2.42X+2.66 | 9.3043 | 165.37 |
| A:B=1:2.5 | Y=1.82X+3.24 | 9.2184 | 181.15 |
| A:B=1:60 | Y=1.25X+3.43 | 17.8694 | 105.89 |
| A:B=1:70 | Y=1.63X+3.01 | 16.5606 | 114.45 |
1 indoor biometricses of table test result indicate that, 2-cyano-3-amino-3-phenylancryic acetate and Metalaxyl-M weight ratio are 1～70：1～50 compositionss are altogether
Malicious coefficient is both greater than 120, has obvious synergistic function to fusarium graminearum.
Field control effectiveness test：
Carried out preventing and treating wheat scab test with pesticidal preparations obtained in above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicament point respectively according to the difference of each composition
It is not pesticide single dose 25% 2-cyano-3-amino-3-phenylancryic acetate SC and 25% Metalaxyl-M EC and blank clean water experiment.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect method after investigating and prevent and treat before dispenser
For：5 points of randomization (takes 5m per in the test process area2), the state of an illness is carried out according to national field test relevant criterion
Classification, calculates preventive effect.
3rd, result of the test see the table below：
Field efficacy result of 2 2-cyano-3-amino-3-phenylancryic acetates of the table+Metalaxyl-M different ratio to wheat scab
2 field efficacy of table shows that 2-cyano-3-amino-3-phenylancryic acetate is better than 25% cyanogen alkene bacterium to wheat scab prevention effect with Metalaxyl-M compositionss
Ester suspending agent and 25% Metalaxyl-M cream, sterilization speed is fast, the lasting period is long, and prevention effect is better than single dose kind, in agricultural
There is using in using value.
Shown by indoor biometricses and field efficacy result, 2-cyano-3-amino-3-phenylancryic acetate there is obvious Synergistic to make with Metalaxyl-M compositionss
With the prevention effect of compositionss is excellent, and prevention effect is better than single dose kind, in agricultural application has using value.
Claims (10)
1. the bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M, it is characterised in that it with 2-cyano-3-amino-3-phenylancryic acetate and Metalaxyl-M is
Main active, described 2-cyano-3-amino-3-phenylancryic acetate and the weight ratio of Metalaxyl-M are 1～70：1～50.
2. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 1 and Metalaxyl-M, it is characterised in that described cyanogen
Alkene bacterium ester is 5～50 with the weight ratio of Metalaxyl-M：10～50.
3. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 2 and Metalaxyl-M, it is characterised in that described cyanogen
The weight ratio of alkene bacterium ester and Metalaxyl-M is 5～40：10～30.
4. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 3 and Metalaxyl-M, it is characterised in that described cyanogen
The weight ratio of alkene bacterium ester and Metalaxyl-M is 1：0.4～3.25.
5. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 1 and Metalaxyl-M, it is characterised in that described cyanogen
It is 2～80% that both alkene bacterium ester and Metalaxyl-M account for the weight percentage of compositionss.
6. the bactericidal composition of described 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 5 and Metalaxyl-M, it is characterised in that institute
It is 5.5～70% that both the 2-cyano-3-amino-3-phenylancryic acetate stated and Metalaxyl-M account for the weight percentage of compositionss.
7. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 1 and Metalaxyl-M, it is characterised in that it is with cyanogen alkene
Bacterium ester and Metalaxyl-M are that principle active component and insecticides adjuvant, excipient are configured to any one dosage form allow on pesticide.
8. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 7 and Metalaxyl-M, it is characterised in that described agent
Type is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the bactericidal composition of the 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M described in claim 1 is preparing preventing and treating resistance plant mycosises
Application on evil medicine.
10. the complex composition of the 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M described in claim 1 prevents and treats wheat scab, water in preparation
The Bakanae disease of rice, the application on tomato wilt, downy mildew, phytophthora root rot germ killing drugs, preferably prevents and treats wheat scab medicine in preparation
Application on thing.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107960414A (en) * | 2017-12-26 | 2018-04-27 | 江苏省农药研究所股份有限公司 | A kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and its application |
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| WO2002102148A2 (en) * | 2001-06-14 | 2002-12-27 | Syngenta Participations Ag | Composition and method for improving plant growth |
| CN103271031A (en) * | 2013-05-16 | 2013-09-04 | 青岛奥迪斯生物科技有限公司 | Sterilization composition containing cyanoacrylate bactericide and metalaxyl-M |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2002102148A2 (en) * | 2001-06-14 | 2002-12-27 | Syngenta Participations Ag | Composition and method for improving plant growth |
| CN103271031A (en) * | 2013-05-16 | 2013-09-04 | 青岛奥迪斯生物科技有限公司 | Sterilization composition containing cyanoacrylate bactericide and metalaxyl-M |
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| CN107960414A (en) * | 2017-12-26 | 2018-04-27 | 江苏省农药研究所股份有限公司 | A kind of bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and its application |
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Application publication date: 20170329 |