CN106538572A - The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb - Google Patents
The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb Download PDFInfo
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Abstract
The invention discloses the bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb.The bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb,, with 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb as main active, described 2-cyano-3-amino-3-phenylancryic acetate and the weight ratio of Mancozeb are 1～70 for it：1～50.The invention also discloses the application of bactericidal composition medicine on preventing and treating resistance plant fungal disease is prepared.Can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the Drug resistance of pathogenic bacteria, sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as wheat scab, bakanae disease of rice, tomato wilt, anthrax, early blight, downy mildew, capsicum epidemic disease, effect is better than single dose use.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, the especially bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb
And its application.
Background technology
2-cyano-3-amino-3-phenylancryic acetate, outward appearance is white powder, molecular formula：C12H12N2O2, chemical name：2- cyano group -3- amino -3-
Ethyl phenylacrylate.
2-cyano-3-amino-3-phenylancryic acetate belongs to 2- cyanoacrylate antibacterial, is a kind of unique new type bactericide of model of action, to reaping hook mushroom
Effectively, the bakanae disease of rice that especially causes to the microbial head blight of reaping hook, fusarium moniliforme, fusarium oxysporum draw for the disease that causes
The tomato wilt for rising has good prevention effect.2-cyano-3-amino-3-phenylancryic acetate is absorbed by root, has translocatable upwards, face on blade
To blade bottom and interlobate translocatable poor.
Mancozeb (Mancozeb), chemical name：The coordination network of ethylene bisdithiocarbamic manganese and zinc ion
The polycomponent coordination compound of compound or ethylidene dithiocarbamate manganese and zinc salt.Mancozeb is mainly used in preventing and treating
The multiple diseases that the Phytophthora of Phycomycetes, the Cercospora of Fungi Imperfecti, Ascochyta etc. cause.To on fruit tree, vegetable
Anthrax, the disease such as early blight it is effective.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with economy such as the change of pattern of farming, melon fruits and vegetables
Crops planting area progressively expands, and disease occurrence degree, generation quantity increase, and in preventing and treating, difficulty is increased；The opposing party
Face, the resistance of pathogen rise under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant disease
Preventing and treating is faced with significant challenge.
The content of the invention
The purpose of the present invention is to provide a kind of applied widely, low cost, effect good 2-cyano-3-amino-3-phenylancryic acetate-containing for above-mentioned technical problem
With the plant bactericidal composition of Mancozeb.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb, it with 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb as main active,
Described 2-cyano-3-amino-3-phenylancryic acetate is 1～70 with the weight ratio of Mancozeb：1～50, wherein in bactericidal composition, active ingredient is with potentiation
Effective dose is present in compositionss.
The weight ratio preferably 5～50 of described bactericidal composition, wherein 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb：10～50, further
Preferably 5～40：10～30, most preferably 1：1～5.
In bactericidal composition of the present invention, both described 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb account for the weight percent of compositionss and contain
Measure as 2～80%, preferably 5.5～70%.
Bactericidal composition of the present invention, it with 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb as main active, with known auxiliary agent and
Excipient is re-dubbed any one dosage form allow on pesticide.Auxiliary agent, excipient known to these have dispersant, diffusant, disappear
Infusion, wetting agent, disintegrating agent etc., can using to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium methylene bis-naphthalene sulfonate, ten
Dialkyl benzene sulfonic acids calcium, alkylphenol polyoxyethylene, alkylaryl polyoxyethylene polyoxypropylene ether again, Ben-zylphenol Polyoxyethyl Ether,
Phenethyl phenol polyethenoxy ether, three phenethyl phenol polyoxyethylene ether phosphates, fatty alcohol-polyoxyethylene ether and its similar products, fat
Fat amine polyoxyethylene ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxypropylene block compound, castor oil polyoxyethylene
Ether, NPE, TWEEN Series, Polyethylene Glycol series, Sulfonateses, carboxylate, sulfate, phosphate,
One or more groups in phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc.
Close, excipient includes Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as Propylene Glycol), deionized water etc..With
Upper auxiliary agent, excipient and other adjuvants can be with alone or be used in combination.
Described dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
It is a still further object of the present invention to provide the bactericidal composition of described 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb prevents and treats resistance in preparation
Application on fungal diseases of plants medicine.Preferably, described bactericidal composition is preparing preventing and treating Cereal, fruit tree, vegetable work
Application in terms of thing refractory fungal disease medicine, especially prevents and treats wheat scab in preparation, and bakanae disease of rice, Fructus Lycopersici esculenti are withered
Application on the fungal disease medicine such as disease, anthrax, early blight, downy mildew, capsicum epidemic disease, it is particularly peppery in preparation preventing and treating
Application in terms of green pepper epidemic disease medicine.Described bactericidal composition is respectively provided with significant effect, energy to above-mentioned resistance plant fungal disease
Produce higher synergistic function.
Compared with prior art, beneficial effects of the present invention：
(1), compared with single dose, the bactericidal composition scope of application of the present invention increases, and expands preventing and treating spectrum, it is adaptable to prevent and treat cereal
Class, fruit tree, the refractory fungal disease of vegetable, have to ascomycetess, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease good
Prevention effect, is particularly suitable for preventing and treating wheat scab, bakanae disease of rice, tomato wilt, anthrax, early blight, frost
Mildew, capsicum epidemic disease are respectively provided with significant effect, can produce higher synergistic function.
(2), compared with single dose, overcome and delayed Drug resistance, funguses can be suppressed to unitary agent (2-cyano-3-amino-3-phenylancryic acetate and Dai Sen
MnZn is arbitrary) drug-fast generation, alternative routine and be also easy to produce the pesticide of resistance.
(3), the consumption of the amount ratio independent reactive compound of bactericidal composition of the present invention is substantially reduced, i.e. the activity of mixture is big
In the activity of independent component, compared with single dose, preventing and treating recruitment, drug cost are reduced.
Specific embodiment
With reference to embodiments technical scheme is described further, two kinds of reactive compounds can be processed into permission
Any one dosage form, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.The system of dosage form in embodiment
Preparation Method is conventional method.
" % " of the present invention is weight percentage.
Embodiment 1
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Mancozeb 10g, detergent LS (to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g, expansion
Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin add to 100g, and mixture carries out comminution by gas stream,
Prepared effective ingredient weight percentage is 15% 2-cyano-3-amino-3-phenylancryic acetate-mancozeb wettable powder.
Embodiment 2
2-cyano-3-amino-3-phenylancryic acetate 3g, Mancozeb 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g are weighed, it is high
Ridge soil adds to 100g, and mixture carries out comminution by gas stream, and it is 15% 2-cyano-3-amino-3-phenylancryic acetate-Dai Sen that effective ingredient weight percentage is obtained
Mancozeb wettable powder.
Embodiment 3
2-cyano-3-amino-3-phenylancryic acetate 2g, Mancozeb 14g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g are weighed, it is high
Ridge soil adds to 100g, and mixture carries out comminution by gas stream, and it is 16% 2-cyano-3-amino-3-phenylancryic acetate-Dai Sen that effective ingredient weight percentage is obtained
Mancozeb wettable powder.
Embodiment 4
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Mancozeb 50g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33# (alkyl
Aryl polyoxyethylene polyoxypropylene ether) 2g, alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Will
Above raw material routinely prepares the method input mixing kettle high speed mixing of aqueous emulsion, and making effective Ingredients Weight percentage composition is
55% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb aqueous emulsion.
Embodiment 5
Weigh 2-cyano-3-amino-3-phenylancryic acetate 2g, Mancozeb 30g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, effective Ingredients Weight percentage composition is made for 32% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb
Microemulsion.
Embodiment 6
Weigh 2-cyano-3-amino-3-phenylancryic acetate 1g, Mancozeb 5g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material routinely prepares aqueous emulsion is thrown
Enter the mixing of mixing kettle high speed, effective Ingredients Weight percentage composition is made for 6% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb aqueous emulsion.
Embodiment 7
Weigh 2-cyano-3-amino-3-phenylancryic acetate 50g, Mancozeb 20g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Oleum Sesami polyoxyethylene ether 2g, plus 150# solvent naphthas are to 100g.Above raw material is routinely prepared into the method input mixing kettle of cream
Middle mixing, makes effective Ingredients Weight percentage composition for 70% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb cream.
Embodiment 8
2-cyano-3-amino-3-phenylancryic acetate 2g, Mancozeb 40g, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 42% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb cream.
Embodiment 9
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Mancozeb 20g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material routinely
Mix in the method input mixing kettle for preparing microemulsion, effective Ingredients Weight percentage composition is made for 25% 2-cyano-3-amino-3-phenylancryic acetate-maneb
Zinc microemulsion.
Embodiment 10
2-cyano-3-amino-3-phenylancryic acetate 5g, Mancozeb 0.5g, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 5.5% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb cream.
Embodiment 11
2-cyano-3-amino-3-phenylancryic acetate 5g, Mancozeb 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 35% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb cream.
Embodiment 12
Weigh 2-cyano-3-amino-3-phenylancryic acetate 10g, Mancozeb 10g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 20% 2-cyano-3-amino-3-phenylancryic acetate-mancozeb suspending agent into effective ingredient weight percentage.
Embodiment 13
Weigh 2-cyano-3-amino-3-phenylancryic acetate 30g, Mancozeb 12g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 42% 2-cyano-3-amino-3-phenylancryic acetate-mancozeb suspending agent into effective ingredient weight percentage.
Embodiment 14
Weigh 2-cyano-3-amino-3-phenylancryic acetate 2g, Mancozeb 5g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and above raw material is pressed water dispersible granular agent method system
It is 7% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb water dispersion granule into effective ingredient weight percentage.
Embodiment 15
2-cyano-3-amino-3-phenylancryic acetate 4g, Mancozeb 13g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g are weighed,
Polyvinyl alcohol 5g, Borax 2g, kieselguhr complement to 100g, and above raw material is formed with imitating into by water dispersible granular agent method
Weight percentage is divided to be 17% 2-cyano-3-amino-3-phenylancryic acetate-Mancozeb water dispersion granule.
Embodiment 16
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Mancozeb 15g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 20% 2-cyano-3-amino-3-phenylancryic acetate-mancozeb suspending agent.
Embodiment 17
(1) indoor biometricses test：
Mycelial growth rate method is adopted indoors, determines different agents to capsicum epidemic disease bacterial strain (Phytophthora capsici
Leonian EC)50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture, determines mixture
Building performance, circular is as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, and CTC exists for antagonism, CTC when being less than 80
It is summation action between 80-120.
Table 1：Indoor biometricses result of the 2-cyano-3-amino-3-phenylancryic acetate+Mancozeb different ratio to capsicum epidemic disease bacteria strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 2-cyano-3-amino-3-phenylancryic acetate (A) | Y=2.02X+5.53 | 0.549 | - |
| Mancozeb (B) | Y=2.56X+2.71 | 7.821 | - |
| A:B=80:1 | Y=1.42X+3.74 | 7.737 | 102.26 |
| A:B=1:1 | Y=1.54X+3.36 | 11.650 | 125.46 |
| A:B=1:3 | Y=1.70X+2.91 | 16.934 | 152.60 |
| A:B=1:5 | Y=2.67X+1.26 | 25.137 | 138.18 |
| A:B=1:60 | Y=1.58X+2.01 | 78.561 | 116.52 |
| A:B=1:70 | Y=2.50X+0.26 | 78.524 | 119.58 |
1 indoor biometricses of table test result indicate that, 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb weight ratio are 1～70：1～50 compositionss are altogether
Malicious coefficient is both greater than 120, has obvious synergistic function to phytophthora capsici.
(2) field control effectiveness test：
Carried out preventing and treating capsicum epidemic disease test with pesticidal preparations obtained in above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicament point respectively according to the difference of each composition
It is not pesticide single dose 25% 2-cyano-3-amino-3-phenylancryic acetate SC and 50% Mancozeb WP and blank clean water experiment.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect method after investigating and prevent and treat before dispenser
For：5 points of randomization (takes 5m per in the test process area2), the state of an illness is carried out according to national field test relevant criterion
Classification, calculates preventive effect.
3rd, result of the test see the table below：
Table 2：Field efficacy result of the 2-cyano-3-amino-3-phenylancryic acetate+Mancozeb different ratio to capsicum epidemic disease
As shown in Table 2：Compared with single dose, 2-cyano-3-amino-3-phenylancryic acetate has significant effect, energy with Mancozeb compositionss to capsicum epidemic disease
Produce higher synergistic function.The consumption of the amount ratio independent reactive compound of bactericidal composition is substantially reduced, i.e. mixture
Activity more than independent component activity, compared with single dose, reduce preventing and treating recruitment, drug cost.
Shown by indoor biometricses and field efficacy result, 2-cyano-3-amino-3-phenylancryic acetate there is obvious Synergistic to make with Mancozeb compositionss
With the prevention effect of compositionss is excellent, and prevention effect is better than single dose kind, in agricultural application has using value.
Claims (10)
1. the bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb, it is characterised in that, with 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb as main active, the weight ratio of described 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb is 1～70 for it：1～50.
2. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 1 and Mancozeb, it is characterised in that described 2-cyano-3-amino-3-phenylancryic acetate is 5～50 with the weight ratio of Mancozeb：10～50.
3. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 2 and Mancozeb, it is characterised in that the weight ratio of described 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb is 5～40：10～30.
4. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 3 and Mancozeb, it is characterised in that the weight ratio of described 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb is 1：1～5.
5. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 1 and Mancozeb, it is characterised in that it is 2～80% that both 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb account for the weight percentage of compositionss.
6. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 5 and Mancozeb, it is characterised in that it is 5.5～70% that both 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb account for the weight percentage of compositionss.
7. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 1 and Mancozeb, it is characterised in that it is with 2-cyano-3-amino-3-phenylancryic acetate and Mancozeb is as principle active component and insecticides adjuvant, excipient are configured to any one dosage form allow on pesticide.
8. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 7 and Mancozeb, it is characterised in that described dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the application of the bactericidal composition of the 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb described in claim 1 medicine on preventing and treating resistance plant fungal disease is prepared.
10. the bactericidal composition of the 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb described in claim 1 prevents and treats wheat scab in preparation, bakanae disease of rice, tomato wilt, anthrax, early blight, downy mildew, the preferably application on capsicum epidemic disease medicine, the application in terms of preventing and treating capsicum epidemic disease medicine is prepared.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101584329A (en) * | 2009-04-01 | 2009-11-25 | 陕西蒲城县美邦农药有限责任公司 | 2-cyano-3-amino-3-phenylancryic acetate and propineb-containing synergistic antiseptic composition |
| CN101642120A (en) * | 2009-07-09 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Pesticide composition containing dyson fungicides |
| WO2015049168A1 (en) * | 2013-10-03 | 2015-04-09 | Syngenta Participations Ag | Fungicidal compositions |
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2015
- 2015-09-18 CN CN201510598217.1A patent/CN106538572A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101584329A (en) * | 2009-04-01 | 2009-11-25 | 陕西蒲城县美邦农药有限责任公司 | 2-cyano-3-amino-3-phenylancryic acetate and propineb-containing synergistic antiseptic composition |
| CN101642120A (en) * | 2009-07-09 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Pesticide composition containing dyson fungicides |
| WO2015049168A1 (en) * | 2013-10-03 | 2015-04-09 | Syngenta Participations Ag | Fungicidal compositions |
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| Title |
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| 李恒奎 等: "禾谷镰孢菌对氰烯菌酯的敏感性基线及室内抗药性风险初步评估", 《植物病理学报》 * |
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