CN106538570A - The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb - Google Patents
The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb Download PDFInfo
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- CN106538570A CN106538570A CN201510600590.6A CN201510600590A CN106538570A CN 106538570 A CN106538570 A CN 106538570A CN 201510600590 A CN201510600590 A CN 201510600590A CN 106538570 A CN106538570 A CN 106538570A
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Abstract
The invention discloses the bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb.The bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb,, with 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb as principle active component, described 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb weight ratio are 1～70 for it：1～50.The invention also discloses application of the bactericidal composition on preventing and treating resistance plant fungal disease medicine is prepared, can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the Drug resistance of pathogenic bacteria, sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as downy mildew, damping off, epidemic disease, late blight, balck shank, head blight, bakanae disease of rice, tomato wilt, effect is better than single dose use.
Description
Technical field
The present invention relates to the bactericidal composition of a kind of bactericidal composition and application thereof, especially a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb and
Its application.
Background technology
2-cyano-3-amino-3-phenylancryic acetate, outward appearance is white powder, molecular formula：C12H12N2O2, chemical name：2- cyano group -3- amino -3-
Ethyl phenylacrylate.
2-cyano-3-amino-3-phenylancryic acetate belongs to 2- cyanoacrylate antibacterial, is a kind of unique new type bactericide of model of action, to reaping hook mushroom
Effectively, the bakanae disease of rice that especially causes to the microbial head blight of reaping hook, fusarium moniliforme, fusarium oxysporum draw for the disease that causes
The tomato wilt for rising has good prevention effect.2-cyano-3-amino-3-phenylancryic acetate is absorbed by root, has translocatable upwards, face on blade
To blade bottom and interlobate translocatable poor.
Propamocarb (Propamocarb), chemical name is：3- (dimethylamino) propyl carbamic acid propyl ester, molecular formula：
C9H20N2O2.Structural formula：
Propamocarb belongs to carbamate fungicide, and low toxicity, safety, with preferable local systemic action, process energy after soil
By Root Absorption and it is delivered up to whole plant quickly；After stem and leaf spraying treatment, can be absorbed by blade rapidly and play protection work
With.Its mechanism of action is the synthesis of the phosphoric acid and fatty acid that suppress pathogenic bacteria cell membrane component, suppresses mycelial growth to spread and Sporangium
Formation and spore germination.Propamocarb is a kind of wide-spectrum bactericide, especially effective to Phycomycetes funguses, disk mould to tow stalk
Mould, downy mildew, phytophthora, the rotten funguses such as mould have good killing action.Suitable for Fructus Cucumidis sativi, Fructus Lycopersici esculenti, Fructus Capsici, Caulis et Folium Lactucae sativae, Ma Ling
The various crop such as the vegetables such as potato and Nicotiana tabacum L., Fructus Fragariae Ananssae, flowers, fruit tree.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with economy such as the change of pattern of farming, melon fruits and vegetables
Crops planting area progressively expands, and disease occurrence degree, generation quantity increase, and in preventing and treating, difficulty is increased；The opposing party
Face, the resistance of pathogen rise under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant disease
Preventing and treating is faced with significant challenge.
The content of the invention
The purpose of the present invention is to provide a kind of applied widely, low cost, effect good 2-cyano-3-amino-3-phenylancryic acetate-containing for above-mentioned technical problem
With the plant bactericidal composition of Propamocarb.
The purpose of the present invention is realized by following measures：
The bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb, it is with 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb as principle active component, described
2-cyano-3-amino-3-phenylancryic acetate and Propamocarb weight ratio be 1～70：1～50, wherein in bactericidal composition, active ingredient is with enhancing effective amount
It is present in compositionss.
Described bactericidal composition, wherein 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb weight ratio preferably 5～50：10～50, further preferably
For 5～40：10～30, most preferably 1：1～4.
In bactericidal composition of the present invention, both described 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb account for the weight percentage of compositionss
For 2～80%.It is preferred that 5.5～70%.
Described bactericidal composition, it is with 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb as principle active component and known insecticides adjuvant, excipient
It is configured to any one dosage form allow on pesticide.Auxiliary agent, excipient known to these have dispersant, diffusant, defoamer,
Wetting agent, disintegrating agent etc., can be using to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium methylene bis-naphthalene sulfonate, dodecyl
Benzenesulfonic acid calcium, alkylphenol polyoxyethylene, alkylaryl polyoxyethylene polyoxypropylene ether again, Ben-zylphenol Polyoxyethyl Ether, phenethyl
Phenol polyethenoxy ether, three phenethyl phenol polyoxyethylene ether phosphates, fatty alcohol-polyoxyethylene ether and its similar products, fatty amine gather
Oxygen vinyl Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxypropylene block compound, castor oil polyoxyethylene ether, nonyl
Base phenol polyethenoxy ether, TWEEN Series, Polyethylene Glycol series, Sulfonateses, carboxylate, sulfate, phosphate, phosphorous acid
One or more combinations in salt, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., figuration
Agent includes Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as Propylene Glycol), deionized water etc..Above auxiliary agent,
Excipient and other adjuvants can be with alone or be used in combination.
Described dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
It is a still further object of the present invention to provide the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb is preparing preventing and treating resistance plant funguses
Application on disease medicine.Preferably, described bactericidal composition is preparing preventing and treating Cereal, fruit tree, vegetable crop disease medicine
The application in object space face.It is further preferred that the bactericidal composition of described 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb is preparing preventing and treating downy mildew
Answering on disease, damping off, epidemic disease, late blight, balck shank, head blight, bakanae disease of rice, tomato wilt germ killing drugs
With.Most preferably, the bactericidal composition of described 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb is prevented and treated on tomato wilt germ killing drugs in preparation
Application.Described bactericidal composition is respectively provided with significant effect to above-mentioned resistance plant fungal disease, can produce higher collaboration
Potentiation.
Compared with prior art, beneficial effects of the present invention：
(1), compared with single dose, the bactericidal composition scope of application of the present invention increases, and expands preventing and treating spectrum, it is adaptable to prevent and treat cereal
Class, fruit tree, the refractory fungal disease of vegetable, have to ascomycetess, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease good
Prevention effect, is particularly suitable for preventing and treating downy mildew, damping off, epidemic disease, late blight, balck shank, head blight, rice bakanae disease
Disease, tomato wilt, are respectively provided with significant effect, can produce higher synergistic function.
(2), compared with single dose, overcome and delayed Drug resistance, funguses can be suppressed to unitary agent (2-cyano-3-amino-3-phenylancryic acetate and downy mildew
Prestige is arbitrary) drug-fast generation, alternative routine and be also easy to produce the pesticide of resistance.
(3), the consumption of the amount ratio independent reactive compound of bactericidal composition of the present invention is substantially reduced, i.e. the activity of mixture is big
In the activity of independent component, compared with single dose, preventing and treating recruitment, drug cost are reduced.
Specific embodiment
With reference to embodiments technical scheme is described further, two kinds of reactive compounds can be processed into permission
Any one dosage form, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.The system of dosage form in embodiment
Preparation Method is conventional method.
" % " of the present invention is weight percentage.
Embodiment 1
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Propamocarb 10g, detergent LS (to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin add to 100g, and mixture carries out comminution by gas stream, system
It is 15% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb wettable powder to obtain effective ingredient weight percentage.
Embodiment 2
Weigh 2-cyano-3-amino-3-phenylancryic acetate 3g, Propamocarb 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g, and mixture carries out comminution by gas stream, and effective ingredient weight percentage is obtained can for 15% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb
WP.
Embodiment 3
Weigh 2-cyano-3-amino-3-phenylancryic acetate 2g, Propamocarb 14g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g, and mixture carries out comminution by gas stream, and effective ingredient weight percentage is obtained can for 16% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb
WP.
Embodiment 4
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Propamocarb 50g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33# (alkyl virtue
Base polyoxyethylene polyoxypropylene ether) 2g, alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Will be with
Upper raw material routinely prepares the method input mixing kettle high speed mixing of aqueous emulsion, makes effective Ingredients Weight percentage composition for 55%
2-cyano-3-amino-3-phenylancryic acetate-Propamocarb aqueous emulsion.
Embodiment 5
Weigh 2-cyano-3-amino-3-phenylancryic acetate 2g, Propamocarb 30g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, it is that 32% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb is micro- to make effective Ingredients Weight percentage composition
Emulsion.
Embodiment 6
Weigh 2-cyano-3-amino-3-phenylancryic acetate 1g, Propamocarb 5g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, 150# solvent naphtha 13g, adds water to 100g.Above raw material is routinely prepared into the method input of aqueous emulsion
Mixing kettle high speed mixes, and makes effective Ingredients Weight percentage composition for 6% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb aqueous emulsion.
Embodiment 7
Weigh 2-cyano-3-amino-3-phenylancryic acetate 50g, Propamocarb 20g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, Semen Ricini
Oily polyoxyethylene ether 2g, plus 150# solvent naphthas are to 100g.Above raw material is routinely prepared in the method input mixing kettle of cream
Mixing, makes effective Ingredients Weight percentage composition for 70% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb cream.
Embodiment 8
2-cyano-3-amino-3-phenylancryic acetate 2g, Propamocarb 40g, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 42% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb cream.
Embodiment 9
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Propamocarb 20g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, it is that 25% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb is micro- to make effective Ingredients Weight percentage composition
Emulsion.
Embodiment 10
2-cyano-3-amino-3-phenylancryic acetate 5g, Propamocarb 0.5g, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 5.5% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb cream.
Embodiment 11
2-cyano-3-amino-3-phenylancryic acetate 5g, Propamocarb 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g are weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 35% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb cream.
Embodiment 12
Weigh 2-cyano-3-amino-3-phenylancryic acetate 10g, Propamocarb 10g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 20% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb suspending agent.
Embodiment 13
Weigh 2-cyano-3-amino-3-phenylancryic acetate 30g, Propamocarb 12g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 42% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb suspending agent.
Embodiment 14
Weigh 2-cyano-3-amino-3-phenylancryic acetate 2g, Propamocarb 5g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, poly-
Vinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and above raw material is made by water dispersible granular agent method
Effective ingredient weight percentage is 7% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb water dispersion granule.
Embodiment 15
Weigh 2-cyano-3-amino-3-phenylancryic acetate 4g, Propamocarb 13g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, poly-
Vinyl alcohol 5g, Borax 2g, kieselguhr complement to 100g, and above raw material is formed with imitating composition by water dispersible granular agent method
Weight percentage is 17% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb water dispersion granule.
Embodiment 16
Weigh 2-cyano-3-amino-3-phenylancryic acetate 5g, Propamocarb 15g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g, second
Glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, and effective ingredient is made in the presence of sand mill
Weight percentage is 20% 2-cyano-3-amino-3-phenylancryic acetate-Propamocarb suspending agent.
Embodiment 17
(1) indoor biometricses test：
Mycelial growth rate method is adopted indoors, determines different agents to tomato late blight pathogenic bacteria bacterial strain (Phytophthora
Infestans (Mont.) de Bary) EC50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient of mixture
(CTC), determine the building performance of mixture, circular is as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, and CTC exists for antagonism, CTC when being less than 80
It is summation action between 80-120.
Table 1：Indoor biometricses result of the 2-cyano-3-amino-3-phenylancryic acetate+Propamocarb different ratio to tomato late blight bacteria strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 2-cyano-3-amino-3-phenylancryic acetate (A) | Y=1.66X+4.66 | 1.598 | - |
| Propamocarb (B) | Y=2.18X+3.15 | 7.063 | - |
| A:B=80:1 | Y=4.22X+1.63 | 6.301 | 113.18 |
| A:B=1:1 | Y=1.25X+3.96 | 6.766 | 170.26 |
| A:B=1:2 | Y=2.41X+2.65 | 9.465 | 154.13 |
| A:B=1:4 | Y=1.73X+3.19 | 11.128 | 166.59 |
| A:B=1:60 | Y=1.60X+2.68 | 28.130 | 105.08 |
| A:B=1:70 | Y=2.50X+1.29 | 30.560 | 97.45 |
1 indoor biometricses of table test result indicate that, 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb weight ratio are 1～70：Poison is 1～50 compositionss altogether
Number both greater than 120, has obvious synergistic function to Phytophthora infestans pathogenic bacteria.
(2) field control effectiveness test：
Carried out preventing and treating tomato late blight test with pesticidal preparations obtained in above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicament point respectively according to the difference of each composition
It is not pesticide single dose 25% 2-cyano-3-amino-3-phenylancryic acetate SC and 15% Propamocarb WP and blank clean water experiment.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect method after investigating and prevent and treat before dispenser
For：5 points of (every 5m of randomization in the test process area2), the state of an illness point is carried out according to national field test relevant criterion
Level, calculates preventive effect.
3rd, result of the test see the table below：
Field efficacy result of 2 2-cyano-3-amino-3-phenylancryic acetates of the table+Propamocarb different ratio to tomato late blight
2 field efficacy of table shows that 2-cyano-3-amino-3-phenylancryic acetate is better than 25% 2-cyano-3-amino-3-phenylancryic acetate to tomato late blight prevention effect with Propamocarb compositionss
Suspending agent and 15% Propamocarb wettable powder, sterilization speed is fast, the lasting period is long, and prevention effect is better than single dose kind, in agriculture
There is in industry application using value.
Claims (10)
1. the bactericidal composition of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb, it is characterised in that, with 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb as principle active component, the weight ratio of described 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb is 1～70 for it：1～50.
2. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 1 and Propamocarb, it is characterised in that 2-cyano-3-amino-3-phenylancryic acetate is 5～50 with the weight ratio of Propamocarb：10～50.
3. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 2 and Propamocarb, it is characterised in that the weight ratio of described 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb is 5～40：10～30.
4. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 3 and Propamocarb, it is characterised in that the weight ratio of described 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb is 1：1～4.
5. the bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb according to claim 1, it is characterised in that it is 2～80% that both 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb account for the weight percentage of compositionss.
6. the bactericidal composition containing 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb according to claim 5, it is characterised in that it is 5.5～70% that both 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb account for the weight percentage of compositionss.
7. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 1 and Propamocarb, it is characterised in that it is with 2-cyano-3-amino-3-phenylancryic acetate and Propamocarb is as principle active component and insecticides adjuvant, excipient are configured to any one dosage form allow on pesticide.
8. the bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing according to claim 7 and Propamocarb, it is characterised in that described dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. application of the bactericidal composition of the 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb described in claim 1 on preventing and treating resistance plant fungal disease medicine is prepared.
10. the bactericidal composition of the 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb described in claim 1 is preparing the application prevented and treated on downy mildew, damping off, epidemic disease, late blight, balck shank, head blight, bakanae disease of rice, tomato wilt germ killing drugs, is preferably preparing the application prevented and treated on tomato wilt germ killing drugs.
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| CN201510600590.6A CN106538570A (en) | 2015-09-18 | 2015-09-18 | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb |
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| CN201510600590.6A CN106538570A (en) | 2015-09-18 | 2015-09-18 | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103493833A (en) * | 2013-09-29 | 2014-01-08 | 江苏省绿盾植保农药实验有限公司 | Bactericide composition containing JS399-19 and benthiavalicarb-isopropyl |
| WO2015049168A1 (en) * | 2013-10-03 | 2015-04-09 | Syngenta Participations Ag | Fungicidal compositions |
-
2015
- 2015-09-18 CN CN201510600590.6A patent/CN106538570A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103493833A (en) * | 2013-09-29 | 2014-01-08 | 江苏省绿盾植保农药实验有限公司 | Bactericide composition containing JS399-19 and benthiavalicarb-isopropyl |
| WO2015049168A1 (en) * | 2013-10-03 | 2015-04-09 | Syngenta Participations Ag | Fungicidal compositions |
Non-Patent Citations (1)
| Title |
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| 吴永刚 等: "农用杀菌剂的作用方式与分类", 《世界农药》 * |
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Application publication date: 20170329 |