CN106508933A - Sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim - Google Patents
Sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim Download PDFInfo
- Publication number
- CN106508933A CN106508933A CN201510587468.XA CN201510587468A CN106508933A CN 106508933 A CN106508933 A CN 106508933A CN 201510587468 A CN201510587468 A CN 201510587468A CN 106508933 A CN106508933 A CN 106508933A
- Authority
- CN
- China
- Prior art keywords
- mepanipyrim
- composition containing
- benzene metsulfovax
- bactericidal composition
- metsulfovax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim. The sterilization composition uses benthiavalicarb-isopropyl and mepanipyrim as main active components, wherein a weight ratio of benthiavalicarb-isopropyl to mepanipyrim is (1-70): (1-50). The invention also discloses application of the sterilization composition to preparation of drugs used for preventing and treating fungal diseases of resistant plants; and the sterilization composition is applicable to prevention and treatment of diseases attacking cereals, fruit trees and vegetable, has high synergistic interaction, overcomes and delays the resistance of pathogens and has the advantages of fast sterilization speed, long action period, reduced application cost and obviously better prevention and treatment effect compared with individual usage of benthiavalicarb-isopropyl and mepanipyrim. The sterilization composition is applicable to prevention and treatment of fungal diseases attacking crops, especially to prevention and treatment of fungal diseases like late blight, downy mildew, powdery mildew and gray mold; and the effect of the sterilization composition is better than the effect of individual benthiavalicarb-isopropyl or mepanipyrim.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, especially a kind of bactericidal composition containing benzene metsulfovax and mepanipyrim and
Its application.
Background technology
Benzene metsulfovax (benthiavalicarb-isopropyl), molecular formula：C18H24FN3O3S, chemical name：[[(6- fluorobenzene is simultaneously
Thiazol-2-yl)-ethylaminocarbonyl] -2- methyl-propyls] carbamic acid isopropyl ester.
Benzene metsulfovax have good bactericidal activity to phytophthora root rot, to its sporangial formation, sporangial sprouting at low concentrations
There is good inhibiting effect, but the release to zoospore and the movement of zoospore are not acted on.In field test, benzene thiophene bacterium
Amine is with relatively low dosage (25～75g a.i./hm2) can effectively control late blight, Fructus Vitis viniferae and other crops of Rhizoma Solani tuber osi and Fructus Lycopersici esculenti
Downy mildew.
Mepanipyrim (Mepanipyrim), molecular formula：C14H13N3, chemical name：N- (4- methyl -6- propyl- acetylenic -2- bases) benzene
Amine, chemical structural formula：
There is mepanipyrim unique mechanism of action to suppress pathogen protein secreting, including reducing some hydrolysis enzyme levels, according to pushing away
Survey these enzymes to enter people host plant with pathogen and cause the necrosis of host tissue relevant, the gray mold of various vegetable crops can be prevented and treated
And powdery mildew.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with economy such as the change of pattern of farming, melon fruits and vegetables
Crops planting area progressively expands, and disease occurrence degree, generation quantity increase, and in preventing and treating, difficulty is increased；The opposing party
Face, the resistance of pathogen rise under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant disease
Preventing and treating is faced with significant challenge.
The content of the invention
The purpose of the present invention be for above-mentioned technical problem provide a kind of applied widely, low cost, effect it is good containing benzene metsulfovax
With the plant bactericidal composition of mepanipyrim.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition containing benzene metsulfovax and mepanipyrim, it is with benzene metsulfovax and mepanipyrim as main active, described
Benzene metsulfovax and mepanipyrim weight ratio be 1～70：1～50, wherein in bactericidal composition, active ingredient is deposited with enhancing effective amount
In being compositionss.
In bactericidal composition of the present invention, the weight ratio preferably 5～50 of described benzene metsulfovax and mepanipyrim：10～50,
More preferably 5～40：10～50, most preferably 1：2～10.
In bactericidal composition of the present invention, both benzene metsulfovax and mepanipyrim account for compositionss weight percentage be 2～
80%, preferably 5.5～70%.
Bactericidal composition of the present invention with benzene metsulfovax and mepanipyrim as principle active component and known auxiliary agent and excipient it is multiple
It is made into any one dosage form allow on pesticide.Known to these, auxiliary agent, excipient have dispersant, diffusant, defoamer, profit
Humectant, disintegrating agent etc., can be using to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium methylene bis-naphthalene sulfonate, detergent alkylate
Sulfoacid calcium, alkylphenol polyoxyethylene, alkylaryl polyoxyethylene polyoxypropylene ether again, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol
Polyoxyethylene ether, three phenethyl phenol polyoxyethylene ether phosphates, fatty alcohol-polyoxyethylene ether and its similar products, fatty amine polyoxy
Vinyl Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxypropylene block compound, castor oil polyoxyethylene ether, nonyl
Phenol polyethenoxy ether, TWEEN Series, Polyethylene Glycol series, Sulfonateses, carboxylate, sulfate, phosphate, phosphorous acid
One or more combinations in salt, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., figuration
Agent includes Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as Propylene Glycol), deionized water etc..Above auxiliary agent,
Excipient and other adjuvants can be with alone or be used in combination.
Described dosage form is cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
It is a still further object of the present invention to provide the bactericidal composition causes on fungal disease medicine in preparation preventing and treating resistance plant funguses
Application.Preferably, described bactericidal composition answering in terms of preventing and treating Cereal, fruit tree, vegetable crop disease medicine is prepared
With especially preventing and treating application on the fungal disease medicine such as late blight, downy mildew, powdery mildew, gray mold preparing, particularly
Application on preventing and treating Phytophthora infestans medicine is prepared.Described bactericidal composition is respectively provided with aobvious to above-mentioned resistance plant fungal disease
The effect of work, can produce higher synergistic function.
Compared with prior art, beneficial effects of the present invention：
(1), compared with single dose, the bactericidal composition scope of application of the present invention increases, and expands preventing and treating spectrum, it is adaptable to prevent and treat cereal
Class, fruit tree, the refractory fungal disease of vegetable, have preventing and treating effect well to ascomycetess, basidiomycetes, Fungi Imperfecti fungal disease
Really, it is particularly suitable for preventing and treating late blight, downy mildew, powdery mildew, gray mold, is respectively provided with significant effect, can produces higher
Synergistic function.
(2), compared with single dose, overcome and delayed Drug resistance, funguses can be suppressed to unitary agent (benzene metsulfovax and phonetic bacterium
Amine is arbitrary) drug-fast generation, alternative routine and be also easy to produce the pesticide of resistance.
(3), the consumption of the amount ratio independent reactive compound of bactericidal composition of the present invention is substantially reduced, i.e. the activity of mixture is big
In the activity of independent component, compared with single dose, preventing and treating recruitment, drug cost is reduced.
Specific embodiment
With reference to embodiments technical scheme is described further, two kinds of reactive compounds can be processed into permission
Any one dosage form, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.The system of dosage form in embodiment
Preparation Method is conventional method.
" % " of the present invention is weight percentage.
Embodiment 1
Weigh benzene metsulfovax 5g, mepanipyrim 10g, detergent LS (to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g, diffusion
Agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin add to 100g, and mixture carries out comminution by gas stream, system
It is 15% benzene metsulfovax-mepanipyrim wettable powder to obtain effective ingredient weight percentage.
Embodiment 2
Weigh benzene metsulfovax 3g, mepanipyrim 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g, and mixture carries out comminution by gas stream, and it is 15% benzene metsulfovax-mepanipyrim that effective ingredient weight percentage is obtained
Wettable powder.
Embodiment 3
Weigh benzene metsulfovax 2g, mepanipyrim 14g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, kaolinite
Soil adds to 100g, and mixture carries out comminution by gas stream, and it is 16% benzene metsulfovax-mepanipyrim that effective ingredient weight percentage is obtained
Wettable powder.
Embodiment 4
Weigh benzene metsulfovax 5g, mepanipyrim 50g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33# (alkyl virtue
Base polyoxyethylene polyoxypropylene ether) 2g, alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Will be with
Upper raw material routinely prepares the method input mixing kettle high speed mixing of aqueous emulsion, makes effective Ingredients Weight percentage composition for 55%
Benzene metsulfovax-mepanipyrim aqueous emulsion.
Embodiment 5
Weigh benzene metsulfovax 2g, mepanipyrim 30g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, it is that 32% benzene metsulfovax-mepanipyrim is micro- to make effective Ingredients Weight percentage composition
Emulsion.
Embodiment 6
Weigh benzene metsulfovax 1g, mepanipyrim 5g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
Polyoxyethylene ether 1g, 150# solvent naphtha 13g, add water to 100g.Above raw material is routinely prepared into the method input of aqueous emulsion
Mixing kettle high speed mixes, and makes effective Ingredients Weight percentage composition for 6% benzene metsulfovax-mepanipyrim aqueous emulsion.
Embodiment 7
Weigh benzene metsulfovax 50g, mepanipyrim 20g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, Semen Ricini
Oily polyoxyethylene ether 2g, plus 150# solvent naphthas are to 100g.Above raw material is routinely prepared in the method input mixing kettle of cream
Mixing, makes effective Ingredients Weight percentage composition for 70% benzene metsulfovax-mepanipyrim cream.
Embodiment 8
Benzene metsulfovax 2g, mepanipyrim 40g, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g is weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 42% benzene metsulfovax-mepanipyrim cream.
Embodiment 9
Weigh benzene metsulfovax 5g, mepanipyrim 20g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyoxyethylene ether phosphates
3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely matched somebody with somebody
Mix in the method input mixing kettle of microemulsion processed, it is that 25% benzene metsulfovax-mepanipyrim is micro- to make effective Ingredients Weight percentage composition
Emulsion.
Embodiment 10
Benzene metsulfovax 5g, mepanipyrim 0.5g, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g is weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 5.5% benzene metsulfovax-mepanipyrim cream.
Embodiment 11
Benzene metsulfovax 5g, mepanipyrim 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g is weighed, plus
150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared cream, make effective ingredient
Weight percentage is 35% benzene metsulfovax-mepanipyrim cream.
Embodiment 12
Weigh benzene metsulfovax 10g, mepanipyrim 10g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 20% benzene metsulfovax-mepanipyrim suspending agent.
Embodiment 13
Weigh benzene metsulfovax 30g, mepanipyrim 12g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g,
Ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill effectively into
Weight percentage is divided to be 42% benzene metsulfovax-mepanipyrim suspending agent.
Embodiment 14
Benzene metsulfovax 2g, mepanipyrim 5g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g is weighed, is gathered
Vinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and above raw material is made by water dispersible granular agent method
Effective ingredient weight percentage is 7% benzene metsulfovax-mepanipyrim water dispersion granule.
Embodiment 15
Weigh benzene metsulfovax 4g, mepanipyrim 13g, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, poly-
Vinyl alcohol 5g, Borax 2g, kieselguhr complement to 100g, and above raw material is formed with imitating composition by water dispersible granular agent method
Weight percentage is 17% benzene metsulfovax-mepanipyrim water dispersion granule.
Embodiment 16
Weigh benzene metsulfovax 5g, mepanipyrim 15g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthan gum 0.15g, second
Glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make effective ingredient in the presence of sand mill
Weight percentage is 20% benzene metsulfovax-mepanipyrim suspending agent.
Embodiment 17
Indoor biometricses are tested：
Mycelial growth rate method is adopted indoors, determines different agents to tomato late blight bacterial strain (Phytophthora infestans
(Mont.) de Bary) EC50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient of mixture
(CTC), determine the building performance of mixture, circular is as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, and CTC exists for antagonism, CTC when being less than 80
It is summation action between 80-120.
Table 1：Indoor biometricses result of the benzene metsulfovax+mepanipyrim different ratio to tomato late blight bacterial strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| Benzene metsulfovax (A) | Y=2.12X+5.68 | 0.478 | - |
| Mepanipyrim (B) | Y=2.35X+3.42 | 4.685 | - |
| A:B=80:1 | Y=3.65X+2.48 | 4.891 | 96.86 |
| A:B=1:2 | Y=1.45X+3.93 | 5.441 | 214.52 |
| A:B=1:4 | Y=2.01X+3.09 | 8.931 | 186.26 |
| A:B=1:6 | Y=1.94X+2.93 | 11.679 | 174.18 |
| A:B=1:10 | Y=1.33X+3.53 | 12.764 | 199.85 |
| A:B=160 | Y=2.36X+1.20 | 40.948 | 98.00 |
| A:B=170 | Y=1.99X+1.95 | 34.151 | 119.63 |
1 indoor biometricses of table test result indicate that, benzene metsulfovax and mepanipyrim weight ratio are 1～70：1～50 compositionss are malicious altogether
Coefficient is both greater than 120, has obvious synergistic function to Phytophthora infestans pathogenic bacteria.
Field control effectiveness test：
Carried out preventing and treating tomato late blight test with pesticidal preparations obtained in above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicament point respectively according to the difference of each composition
It is not 15% benzene metsulfovax WP of pesticide single dose and 25% mepanipyrim SC and blank clean water experiment.
2nd, test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is：5 points of randomization (takes 5m per in the test process area2), the state of an illness is carried out according to national field test relevant criterion
Classification, calculates preventive effect.
3rd, result of the test see the table below：
Table 2：Field efficacy result of the benzene metsulfovax+mepanipyrim different ratio to tomato late blight
As shown in Table 2：Compared with single dose, benzene metsulfovax and mepanipyrim compositionss have significant effect, energy to tomato late blight
Produce higher synergistic function.The consumption of the amount ratio independent reactive compound of bactericidal composition is substantially reduced, i.e. mixture
Activity more than independent component activity, compared with single dose, reduce preventing and treating recruitment, drug cost.
Shown by indoor biometricses and field efficacy result, benzene metsulfovax there is obvious Synergistic to make with mepanipyrim compositionss
With the prevention effect of compositionss is excellent, and prevention effect is better than single dose kind, in agricultural application has using value.
Claims (10)
1. a kind of bactericidal composition containing benzene metsulfovax and mepanipyrim, it is characterised in that it is main with benzene metsulfovax and mepanipyrim
Active component, described benzene metsulfovax and mepanipyrim weight ratio are 1～70：1～50.
2. the bactericidal composition containing benzene metsulfovax and mepanipyrim according to claim 1, it is characterised in that described benzene thiophene
Bacterium amine is 5～50 with the weight ratio of mepanipyrim：10～50.
3. the bactericidal composition containing benzene metsulfovax and mepanipyrim according to claim 2, it is characterised in that described benzene thiophene
The weight ratio of bacterium amine and mepanipyrim is 5～40：10～30.
4. the bactericidal composition containing benzene metsulfovax and mepanipyrim according to claim 3, it is characterised in that described benzene thiophene
The weight ratio of bacterium amine and mepanipyrim is 1：2～10.
5. the bactericidal composition containing benzene metsulfovax and mepanipyrim according to claim 1, it is characterised in that described benzene thiophene
It is 2～80% that both bacterium amine and mepanipyrim account for the weight percentage of compositionss.
6. the bactericidal composition containing benzene metsulfovax and mepanipyrim according to claim 5, it is characterised in that described benzene thiophene
It is 5.5～70% that both bacterium amine and mepanipyrim account for the weight percentage of compositionss.
7. the bactericidal composition containing benzene metsulfovax and mepanipyrim according to claim 1, it is characterised in that it is with benzene thiophene bacterium
Amine and mepanipyrim are that principle active component and insecticides adjuvant, excipient are configured to any one dosage form allow on pesticide.
8. the bactericidal composition containing benzene metsulfovax and mepanipyrim according to claim 7, it is characterised in that described dosage form
It is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the bactericidal composition containing benzene metsulfovax and mepanipyrim described in claim 1 is preparing preventing and treating resistance plant fungal disease
Application on medicine.
10. the bactericidal composition containing benzene metsulfovax and mepanipyrim described in claim 1 preparation prevent and treat late blight, downy mildew,
Application on powdery mildew, grey mold medicine, the preferably application on preventing and treating Phytophthora infestans medicine is prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510587468.XA CN106508933A (en) | 2015-09-15 | 2015-09-15 | Sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510587468.XA CN106508933A (en) | 2015-09-15 | 2015-09-15 | Sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106508933A true CN106508933A (en) | 2017-03-22 |
Family
ID=58349192
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510587468.XA Pending CN106508933A (en) | 2015-09-15 | 2015-09-15 | Sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106508933A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0224339A2 (en) * | 1985-10-30 | 1987-06-03 | Kumiai Chemical Industry Co., Ltd. | Pyrimidine derivative, process for preparing same and agricultural or horticultural fungicidal composition containing same |
| CN1409596A (en) * | 1999-12-13 | 2003-04-09 | 拜尔公司 | Fungicidal combinations of active substances |
| CN104012541A (en) * | 2013-02-28 | 2014-09-03 | 陕西美邦农药有限公司 | Fungicidal composition containing diflumetorim and triazole |
-
2015
- 2015-09-15 CN CN201510587468.XA patent/CN106508933A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0224339A2 (en) * | 1985-10-30 | 1987-06-03 | Kumiai Chemical Industry Co., Ltd. | Pyrimidine derivative, process for preparing same and agricultural or horticultural fungicidal composition containing same |
| CN1409596A (en) * | 1999-12-13 | 2003-04-09 | 拜尔公司 | Fungicidal combinations of active substances |
| CN104012541A (en) * | 2013-02-28 | 2014-09-03 | 陕西美邦农药有限公司 | Fungicidal composition containing diflumetorim and triazole |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106508943A (en) | Bactericidal composition containing benthiavalicarb-isopropyl and prochloraz, and applications thereof | |
| CN106508936A (en) | Bactericidal composition containing benthiavalicarb-isopropyl and carbendazim, and applications thereof | |
| CN106508931A (en) | Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof | |
| CN106508933A (en) | Sterilization composition containing benthiavalicarb-isopropyl and mepanipyrim | |
| CN105941427A (en) | Bactericidal composition containing spiroxamine and zinc thiazole and application of bactericidal composition | |
| CN106538543A (en) | The bactericidal composition and its application of a kind of containing fluopyram and Bravo | |
| CN107296047A (en) | A kind of bactericidal composition and its application containing isopyrazam and jinggangmeisu | |
| CN106889079A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine | |
| CN106538568A (en) | The bactericidal composition and its application of a kind of containing fluopyram and Propamocarb | |
| CN105746525A (en) | Fungicidal composition containing isopyrazam and mepanipyrim and application thereof | |
| CN106508932A (en) | Bactericidal composition containing benthiavalicarb and cyproconazole and application thereof | |
| CN106538535A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M | |
| CN106508934A (en) | Fungicidal composition containing benthiavalicarb-isopropyl and amobam and application thereof | |
| CN105379753B (en) | A kind of bactericidal composition and its application containing mepanipyrim and different rice blast net | |
| CN106538536A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and metalaxyl | |
| CN106508928A (en) | Sterilization composition containing benthiavalicarb-isopropyl and isoprothiolane and application thereof | |
| CN106538565A (en) | The bactericidal composition and its application of a kind of containing fluopyram and thifluzamide | |
| CN106508929A (en) | Sterilization composition containing benthiavalicarb-isopropyl and cyprodinil as well as application thereof | |
| CN106538570A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Propamocarb | |
| CN106538569A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and benzene metsulfovax | |
| CN106538545A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and cyazofamid | |
| CN106538567A (en) | The bactericidal composition and its application of a kind of containing fluopyram and polyoxin | |
| CN105941402A (en) | Bactericidal composition containing spiroxamine and cyflufenamid and application of bactericidal composition | |
| CN106508930A (en) | Sterilization composition containing benthiavalicarb-isopropyl and fludioxonil | |
| CN106538572A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Mancozeb |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170322 |
|
| RJ01 | Rejection of invention patent application after publication |