CN106538565A - The bactericidal composition and its application of a kind of containing fluopyram and thifluzamide - Google Patents
The bactericidal composition and its application of a kind of containing fluopyram and thifluzamide Download PDFInfo
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- CN106538565A CN106538565A CN201510595983.2A CN201510595983A CN106538565A CN 106538565 A CN106538565 A CN 106538565A CN 201510595983 A CN201510595983 A CN 201510595983A CN 106538565 A CN106538565 A CN 106538565A
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- thifluzamide
- fluopyram
- bactericidal composition
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Abstract
The invention discloses the bactericidal composition and its application of a kind of containing fluopyram and thifluzamide.The bactericidal composition of a kind of containing fluopyram and thifluzamide,, with fluopyram and thifluzamide as main active, described fluopyram and the weight ratio of thifluzamide are 1～70 for it：1～50.The invention also discloses application of the bactericidal composition on preventing and treating resistance plant fungal disease medicine is prepared, can be applicable to prevent and treat Cereal, fruit tree, vegetable disease, with higher synergistic function, overcome and delayed the resistance to the action of a drug of germ, sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and uses.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as gray mold, downy mildew, powdery mildew, banded sclerotial blight, damping-off, effect is better than single dose use.
Description
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, the especially Bactericidal composite of a kind of containing fluopyram and thifluzamide
Thing and its application.
Background technology
Fluopyram (Fluopyram), molecular formula：C16H11ClF6N2O, chemical name：N- [2- [chloro- 5- (the fluoroforms of 3-
Base) -2- pyridines] ethyl] -2- (trifluoromethyl) benzamide, structural formula：
Fluopyram is a kind of new pyridine ethyl benzamide series bactericidal agent, by hindering succinate dehydrogenase in respiratory chain
Electro transfer and suppress mitochondrial respiratory.It is mainly used on broad leaf crop, preventing and treating the microbial disease of capsule, to cucumber, cucurbita pepo etc.
Downy mildew, powdery mildew on vegetables, downy mildew of fruit tree etc. cause multiple diseases to have favorable effect by germ.
Thifluzamide (Thifluzamide), molecular formula：C13H6Br2F6N2O2S.Chemical name：Bis- bromo- 2- methyl -4'- trifluoros of 2', 6'-
Methoxyl group -4- Trifluoromethyl-1s, 3- thiadiazoles -5- hydroxyl anilides, chemical structural formula：
Thifluzamide is called thiophene fluorine bacterium amine, belongs to thifluzamide succinic acid ester dehydrogenase inhibitor, makees for paddy rice, Cereal
Thing and lawn, it is to the pathomycete such as Rhizoctonia, Puccinia, raw meat black point of Pseudomonas, corticium, Ustilago effectively, right
The fungus-caused disease of Basidiomycetes, such as damping-off etc. have special efficacy.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with economy such as the change of pattern of farming, melon fruits and vegetables
Crops planting area progressively expands, and disease occurrence degree, generation quantity increase, and in preventing and treating, difficulty is increased；The opposing party
Face, the resistance of pathogen rise under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant disease
Preventing and treating is faced with significant challenge.
The content of the invention
The purpose of the present invention is to provide a kind of applied widely, low cost, effect good fluorine-containing pyrrole bacterium acyl for above-mentioned technical problem
The plant bactericidal composition of amine and thifluzamide.
The purpose of the present invention is realized by following measures：
A kind of bactericidal composition of containing fluopyram and thifluzamide, it with fluopyram and thifluzamide as chief active into
Point, the weight ratio of described fluopyram and thifluzamide is 1～70：1～50, wherein effective ingredient in bactericidal composition
It is present in composition with enhancing effective amount.
In described bactericidal composition, the weight ratio preferably 5～50 of described fluopyram and thifluzamide：10～50,
More preferably 5～40：10～40, most preferably 1：1～8.
In bactericidal composition of the present invention, both described fluopyram and thifluzamide account for the weight percentage of composition and are
2～80%, preferably 5.5～70%.
Bactericidal composition of the present invention is with fluopyram and thifluzamide as principle active component and known auxiliary agent and figuration
Agent is re-dubbed any one formulation allow on agricultural chemicals.Known to these, auxiliary agent, excipients have dispersant, diffusant, froth breaking
Agent, wetting agent, disintegrant etc., can using to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium methylene bis-naphthalene sulfonate, 12
Alkyl benzene calcium sulfonate, APES, alkylaryl polyoxyethylene polyoxypropylene ether again, Ben-zylphenol Polyoxyethyl Ether, benzene
Ethyl phenol polyethenoxy ether, three phenethyl phenol polyoxyethylene ether phosphates, AEO and its similar products, fat
Amine APEO, fatty acid ethylene oxide addition product, polyoxyethylene polyoxypropylene block compound, castor oil polyoxyethylene
Ether, NPE, TWEEN Series, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate,
One or more groups in phosphite, lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc.
Close, excipient includes cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water etc..With
Upper auxiliary agent, excipient and other auxiliary materials can be with alone or be used in combination.
Described formulation is missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
It is a still further object of the present invention to provide the bactericidal composition is preparing the fungus-caused fungal disease medicine of preventing and treating resistance plant
On application.Preferably, described bactericidal composition is preparing preventing and treating Cereal, fruit tree, vegetable crop refractory fungal disease medicine
The application in object space face, especially prevents and treats the fungal disease medicine such as gray mold, downy mildew, powdery mildew, banded sclerotial blight, damping-off in preparation
Application on thing, the most preferably application on preventing and treating wheat sharp eyespot medicine is prepared.Described bactericidal composition is planted to above-mentioned resistance
Thing fungal disease is respectively provided with significant effect, can produce higher synergistic function.
Compared with prior art, beneficial effects of the present invention：
(1), compared with single dose, the bactericidal composition scope of application of the present invention increases, and expands preventing and treating spectrum, it is adaptable to prevent and treat cereal
Class, fruit tree, the refractory fungal disease of vegetables, have preventing and treating effect well to sac fungus, basidiomycetes, Fungi Imperfecti fungal disease
Really, it is particularly suitable for preventing and treating gray mold, downy mildew, powdery mildew, banded sclerotial blight, damping-off, is respectively provided with significant effect, energy
Produce higher synergistic function.
(2), compared with single dose, overcome and delayed the resistance to the action of a drug, fungi can be suppressed to unitary agent (fluopyram and thiophene
Ofurace is arbitrary) drug-fast generation, alternative routine and be also easy to produce the agricultural chemicals of resistance.
(3), the consumption of the amount ratio independent reactive compound of bactericidal composition of the present invention is substantially reduced, i.e. the activity of mixture is big
In the activity of independent component, compared with single dose, preventing and treating recruitment, drug cost are reduced.
Specific embodiment
With reference to embodiments technical scheme is described further, two kinds of reactive compounds can be processed into permission
Any one formulation, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.The system of formulation in embodiment
Preparation Method is conventional method.
" % " of the present invention is weight percentage.
Embodiment 1
Weigh fluopyram 5g, thifluzamide 10g, detergent LS (to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g,
Dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g, and mixture carries out air-flow powder
Broken, it is 15% fluopyram-thifluzamide wettable powder that active ingredient weight percentage is obtained.
Embodiment 2
Fluopyram 3g, thifluzamide 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g are weighed,
Kaolin adds to 100g, and mixture carries out air-flow crushing, be obtained active ingredient weight percentage be 15% fluopyram-
Thifluzamide wettable powder.
Embodiment 3
Fluopyram 2g, thifluzamide 16g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g are weighed,
Kaolin adds to 100g, and mixture carries out air-flow crushing, be obtained active ingredient weight percentage be 18% fluopyram-
Thifluzamide wettable powder.
Embodiment 4
Weigh fluopyram 5g, thifluzamide 50g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33# (alkane
Base aryl polyoxyethylene polyoxypropylene ether) 2g, APES 1g, 150# solvent naphtha 13g, add water to 100g.
Above raw material is routinely prepared into the method input mixing kettle high speed mixing of aqueous emulsion, making effective Ingredients Weight percentage composition is
55% fluopyram-thifluzamide aqueous emulsion.
Embodiment 5
Weigh fluopyram 2g, thifluzamide 30g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.By above raw material routinely
Mix in the method input mixing kettle for preparing microemulsion, effective Ingredients Weight percentage composition is made for 32% fluopyram-thiophene furan
Acid amides microemulsion.
Embodiment 6
Weigh fluopyram 1g, thifluzamide 5g, three phenethyl phenol polyoxyethylene ether phosphate 3g, agriculture breast 33#2g, alkane
Base phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared into aqueous emulsion
The high speed mixing of input mixing kettle, makes effective Ingredients Weight percentage composition for 6% fluopyram-thifluzamide aqueous emulsion.
Embodiment 7
Weigh fluopyram 50g, thifluzamide 20g, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, plus 150# solvent naphthas are to 100g.Above raw material is routinely prepared into the method input mixing of missible oil
Mix in kettle, effective Ingredients Weight percentage composition is made for 70% fluopyram-thifluzamide missible oil.
Embodiment 8
Fluopyram 2g, thifluzamide 40g, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g are weighed,
Plus 150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, make effectively into
Weight percentage is divided to be 42% fluopyram-thifluzamide missible oil.
Embodiment 9
Weigh fluopyram 5g, thifluzamide 20g, calcium dodecyl benzene sulfonate 6g, three phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.By above raw material by normal
Rule prepare microemulsion method input mixing kettle in mix, make effective Ingredients Weight percentage composition for 25% fluopyram-
Thifluzamide microemulsion.
Embodiment 10
Fluopyram 5g, thifluzamide 0.5g, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g are weighed,
Plus 150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, make effectively into
Weight percentage is divided to be 5.5% fluopyram-thifluzamide missible oil.
Embodiment 11
Fluopyram 5g, thifluzamide 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g are weighed,
Plus 150# solvent naphthas are to 100g.Mix in the method input mixing kettle that above raw material is routinely prepared missible oil, make effectively into
Weight percentage is divided to be 35% fluopyram-thifluzamide missible oil.
Embodiment 12
Weigh fluopyram 10g, thifluzamide 10g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 20% fluopyram-thifluzamide suspending agent into active ingredient weight percentage.
Embodiment 13
Weigh fluopyram 30g, thifluzamide 12g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 42% fluopyram-thifluzamide suspending agent into active ingredient weight percentage.
Embodiment 14
Weigh fluopyram 2g, thifluzamide 5g, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is pressed water dispersion granule side
Method makes active ingredient weight percentage for 7% fluopyram-thifluzamide water dispersion granule.
Embodiment 15
Weigh fluopyram 4g, thifluzamide 13g, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, borax 2g, diatomite complement to 100g, and above raw material is formed with by water dispersible granular agent method
Effect Ingredients Weight percentage composition is 17% fluopyram-thifluzamide water dispersion granule.
Embodiment 16
Weigh fluopyram 5g, thifluzamide 15g, lignin 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans
0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, make in the presence of sand mill
It is 20% fluopyram-thifluzamide suspending agent into active ingredient weight percentage.
Embodiment 17
Indoor biometricses are tested：
Mycelial growth rate method is adopted indoors, determines different agents to wheat sharp eyespot bacteria strain (Rhizotonia cerealis
Van der Hoeven apud.Boerema＆Verhoeven) EC50Value, using co-toxicity coefficient computational methods, calculates mixed
The co-toxicity coefficient (CTC) of agent, determines the building performance of mixture, and circular is as follows：
With in mixture, a certain single dose (generally selects EC as standard agent50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：When CTC is more than 120, mixture has synergetic, and CTC exists for antagonism, CTC when being less than 80
It is summation action between 80-120.
Table 1：Indoor biometricses result of the fluopyram+thifluzamide different ratio to wheat sharp eyespot bacterial strain
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| Fluopyram (A) | Y=2.53X+3.88 | 2.761 | - |
| Thifluzamide (B) | Y=1.16X+5.20 | 0.668 | - |
| A:B=80:1 | Y=4.12X+3.87 | 2.632 | 101.01 |
| A:B=1:1 | Y=1.87X+5.56 | 0.501 | 214.51 |
| A:B=1:2 | Y=2.42X+5.63 | 0.548 | 163.18 |
| A:B=1:4 | Y=1.41X+5.53 | 0.419 | 187.96 |
| A:B=1:8 | Y=2.59X+5.81 | 0.487 | 149.80 |
| A:B=1:60 | Y=3.33X+5.73 | 0.603 | 112.23 |
| A:B=1:70 | Y=2.95X+5.61 | 0.620 | 108.96 |
1 indoor biometricses of table test result indicate that, fluopyram and thifluzamide weight ratio are 1～70：1～50 composition
Co-toxicity coefficient is both greater than 120, has obvious synergistic function to rhizoctonia cerealis.
Field control effectiveness test：
Carried out preventing and treating wheat sharp eyespot test with pesticidal preparations obtained in above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicament point respectively according to the difference of each composition
It is not 41.7% fluopyram SC of agricultural chemicals single dose and 24% thifluzamide SC and blank clean water experiment.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect method after investigating and prevent and treat before dispenser
For：5 points of the grab sample in the test process area (takes 5m per2), the state of an illness point is carried out according to national field test relevant criterion
Level, calculates preventive effect.
3rd, result of the test see the table below：
Table 2：Field efficacy result of the fluopyram+thifluzamide different ratio to wheat sharp eyespot
As shown in Table 2：Compared with single dose, fluopyram and thifluzamide composition have significant effect to wheat sharp eyespot
Really, higher synergistic function can be produced.The consumption of the amount ratio independent reactive compound of bactericidal composition is substantially reduced, i.e.,
Activity of the activity of mixture more than independent component, compared with single dose, reduces preventing and treating recruitment, drug cost.
Shown by indoor biometricses and field efficacy result, fluopyram has obvious Synergistic with thifluzamide composition
Effect, the prevention effect of composition are excellent, and prevention effect is better than single dose kind, in agricultural application have using value.
Claims (10)
1. the bactericidal composition of a kind of containing fluopyram and thifluzamide, it is characterised in that it is with fluopyram and thiophene furan acyl
Amine is main active, and described fluopyram and the weight ratio of thifluzamide are 1～70：1～50.
2. the bactericidal composition of containing fluopyram according to claim 1 and thifluzamide, it is characterised in that described
Fluopyram is 5～50 with the weight ratio of thifluzamide：10～50.
3. the bactericidal composition of containing fluopyram according to claim 2 and thifluzamide, it is characterised in that described
Fluopyram is 5～40 with the weight ratio of thifluzamide：10～40.
4. the bactericidal composition of containing fluopyram according to claim 3 and thifluzamide, it is characterised in that described
Fluopyram is 1 with the weight ratio of thifluzamide：1～8.
5. the bactericidal composition of containing fluopyram according to claim 1 and thifluzamide, it is characterised in that described
It is 2～80% that both fluopyram and thifluzamide account for the weight percentage of composition.
6. the bactericidal composition of containing fluopyram according to claim 5 and thifluzamide, it is characterised in that described
It is 5.5～70% that both fluopyram and thifluzamide account for the weight percentage of composition.
7. the bactericidal composition of containing fluopyram according to claim 1 and thifluzamide, it is characterised in that it is with fluorine
Pyrrole bacterium acid amides and thifluzamide are that principle active component and insecticides adjuvant, excipients are configured to any one agent allow on agricultural chemicals
Type.
8. the bactericidal composition of containing fluopyram according to claim 7 and thifluzamide, it is characterised in that described
Formulation is missible oil, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the bactericidal composition of the containing fluopyram and thifluzamide described in claim 1 is preparing preventing and treating resistance plant fungi
Application on disease medicine.
10. the bactericidal composition of the containing fluopyram and thifluzamide described in claim 1 prevents and treats gray mold, downy mildew in preparation
Application on disease, powdery mildew, banded sclerotial blight, damping-off medicine, the preferably application on preventing and treating wheat sharp eyespot medicine is prepared.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108294026A (en) * | 2018-02-28 | 2018-07-20 | 佛山市海力盈生物科技有限公司 | A kind of composition pesticide containing Pyriofenone and thifluzamide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005077180A1 (en) * | 2004-02-12 | 2005-08-25 | Bayer Cropscience Sa | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting mitosis and cell division |
| CN1918125A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the transport of electrons of the respiratory chain in phytopathogenic fungal organisms |
| CN1917762A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
-
2015
- 2015-09-17 CN CN201510595983.2A patent/CN106538565A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005077180A1 (en) * | 2004-02-12 | 2005-08-25 | Bayer Cropscience Sa | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting mitosis and cell division |
| CN1918125A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the transport of electrons of the respiratory chain in phytopathogenic fungal organisms |
| CN1917762A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108294026A (en) * | 2018-02-28 | 2018-07-20 | 佛山市海力盈生物科技有限公司 | A kind of composition pesticide containing Pyriofenone and thifluzamide |
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Application publication date: 20170329 |