CN106342834A - Bactericidal composition containing fluoxastrobin and allyl cyanide azoxystrobin and application of bactericidal composition - Google Patents

Bactericidal composition containing fluoxastrobin and allyl cyanide azoxystrobin and application of bactericidal composition Download PDF

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Publication number
CN106342834A
CN106342834A CN201610766117.XA CN201610766117A CN106342834A CN 106342834 A CN106342834 A CN 106342834A CN 201610766117 A CN201610766117 A CN 201610766117A CN 106342834 A CN106342834 A CN 106342834A
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China
Prior art keywords
fluoxastrobin
bactericidal composition
cyano
amino
phenylancryic acetate
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Pending
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CN201610766117.XA
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Chinese (zh)
Inventor
孙会杰
万维肖
陈叶青
杨琴
邢刚
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN201610766117.XA priority Critical patent/CN106342834A/en
Publication of CN106342834A publication Critical patent/CN106342834A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms

Abstract

The invention discloses a bactericidal composition containing fluoxastrobin and allyl cyanide azoxystrobin and application of the bactericidal composition. The bactericidal composition takes fluoxastrobin and allyl cyanide azoxystrobin as main active ingredients, wherein the weight ratio of the fluoxastrobin to allyl cyanide azoxystrobin is (1-70):(1-50). The bactericidal composition can be applied to controlling of cereal, fruit tree and vegetable diseases, has high synergetic effects, capacities of overcoming and delaying drug resistance of bacteria, high sterilization speed and long lasting period, the application cost is reduced, and the control effect is obviously superior to that of a single dosage. The bactericidal composition disclosed by the invention can be used for controlling fungal diseases on crops, particularly can be used for controlling the fungal diseases such as rust disease, glume blight, net blotch, powdery mildew, downy mildew, tomato wilt, rice bakanae disease and the like, and the effect is better than that of a single dosage.

Description

A kind of bactericidal composition containing fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate and its application
Technical field
The present invention relates to a kind of bactericidal composition and application thereof, especially one kind are main with fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate The bactericidal composition of active component and its application.
Background technology
Fluoxastrobin (fluoxastrobin), molecular formula: c21h16clfn4o5, chemical name: { 2- [6- (2- chlorobenzene oxygen Base) -5-FU -4- base oxygen] phenyl } (5,6- dihydros-Isosorbide-5-Nitrae, 2- diazine -3- base) ketone o- methyloxime, structural formula:
Fluoxastrobin has the bactericidal activity of wide spectrum, to nearly all Mycophytes (Ascomycetes, Basidiomycetess, Oomycete And Fungi Imperfecti) disease such as tens of kinds of diseases such as rust, glume blight, net blotch, powdery mildew, downy mildew all have good activity.
2-cyano-3-amino-3-phenylancryic acetate, outward appearance is white powder, molecular formula: c12h12n2o2, chemical name: 2- cyano group -3- amino -3- amino Ethyl acrylate.
2-cyano-3-amino-3-phenylancryic acetate is a kind of unique new type bactericide of model of action, and the disease that reaping hook mushroom is caused is effective, especially The tomato wilt that microbial head blight, fusarium moniliforme cause to reaping hook bakanae disease of rice, fusarium oxysporum cause has very Good preventing and treating.Absorbed by root, blade had translocatable upwards, towards blade bottom and interlobate translocatable relatively Difference.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc. Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty increases;Separately On the one hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant Disease control is faced with significant challenge.
Content of the invention
The purpose of the present invention is to provide a kind of applied widely, low cost, effect good fluorine-containing for above-mentioned technical problem Fluoxastrobin and the plant bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate.
It is a still further object of the present invention to provide this bactericidal composition causes answering on fungal disease in preventing and treating plant epiphyte With especially in control rust, glume blight, net blotch, powdery mildew, downy mildew, head blight, tomato wilt, bakanae disease of rice Deng on fungal disease purposes.
The purpose of the present invention is realized by following measures:
A kind of bactericidal composition containing fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate, said composition is based on fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate Want effective ingredient, wherein fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate weight are than for 1~70:1~50.In bactericidal composition, active ingredient is to increase Effect effective dose is present in compositionss.
In the present invention, the fluoxastrobin in bactericidal composition and 2-cyano-3-amino-3-phenylancryic acetate can be in weight than 1~70:1~50 scopes Interior any adjustment, the such as weight of the two than for 5~50:10~50,5~40:10~30,1~5:1~20,1~2:0.5~ 15th, 1:1~10,1:1~9 etc..In another kind of scheme, fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate can select following weight than in appoint Meaning one or more: 1:50,1:49,1:48,1:47,1:46,1:45,1:44,1:43,1:42,1:41,1:40,1:39,1: 38、1:37、1:36、1:35、1:34、1:33、1:32、1:31、1:30、1:29、1:28、1:27、1:26、1:25、1:24、1: 23、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、 1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、 13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、 28:1、29:1、30:1、31:1、32:1、33:1、34:1、35:1、36:1、37:1、38:1、39:1、40:1、41:1、42:1、 43:1、44:1、45:1、46:1、47:1、48:1、49:1、50:1、51:1、52:1、53:1、54:1、55:1、56:1、57:1、 58:1、59:1、60:1、61:1、62:1、63:1、64:1、65:1、66:1、67:1、68:1、69:1、70:1、2:3、2:5、3:4、 3:5,3:2,4:3,5:2,5:3 etc..
In the compositions of the present invention, the percentage by weight accounting for compositionss both fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate is 1~95%, Preferably 2~80%, further preferred 10~40%.
Described bactericidal composition, wherein with fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate as principle active component, with known pesticide Auxiliary agent and/or excipient are configured to any one dosage form allow on pesticide.Auxiliary agent known to these, excipient include but do not limit In dispersant, diffusant, defoamer, wetting agent, disintegrating agent etc., calcium dodecyl benzene sulfonate, alkyl phenol polyoxy second can be adopted Alkene ether, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and its similar products, fatty amine Polyoxyethylene ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonateses, carboxylate, sulphuric acid One of salt, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc. or Multiple combinations, excipient includes Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent (as propylene glycol), deionized water etc..With Upper auxiliary agent, excipient and other adjuvant can be alone or be used in combination.
Described bactericidal composition, its dosage form is that cream, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate Granule.
This bactericidal composition can apply to prevent and treat resistance plant fungal disease aspect, particularly in preventing and treating Cereal, really Tree, the application of vegetable crop disease aspect.
The present composition scope of application increases it is adaptable to preventing and treating Cereal, fruit tree, the disease of vegetable, particularly prevents and treats Rust, glume blight, net blotch, powdery mildew, downy mildew, head blight, tomato wilt, bakanae disease of rice.Bactericidal composite of the present invention Thing has good prevention effect to ascomycetess, basidiomycetes, Fungi Imperfecti fungal disease;And suppress insect or funguses to unitary agent The drug-fast generation of (fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate are arbitrary).
Application on preparation preventing and treating refractory fungal for the bactericidal composition of the present invention, especially in control rust, glume blight, net Pinta, powdery mildew, downy mildew, head blight, tomato wilt, the application of bakanae disease of rice class fungal disease all have significant effect Really.Above-mentioned bactericidal composition can produce higher synergistic function, and the amount ratio independent reactive compound of this mixture Consumption substantially reduce, that is, the activity of mixture be more than independent component activity.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism fungal disease has Substantially synergistic function, overcomes and has delayed Drug resistance, and expanding prevention is composed hence it is evident that improve prevention effect;(2) reduce preventing and treating Recruitment, drug cost;(3) pesticide that is alternative conventional and being also easy to produce resistance;(4) compared with single dose, produce and use cost fall Low;(5) suppress the drug-fast generation of funguses, its effect uses apparently higher than its single dose.
Specific embodiment
The invention will be further described with reference to embodiments, and in embodiment, the preparation method of dosage form is routine side Method, " % " of the present invention is mass percent.
Indoor biometricses are tested:
Adopt mycelial growth rate method indoors, measure different agents to downy mildew of garpe bacterial strain (plasmopara Viticola ec)50Value, using co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (ctc) of mixture, determines the increasing of mixture Effect property, circular is as follows:
With in mixture, a certain single dose (generally selects ec as standard agent50Junior), calculated:
Single dose toxicity index=standard agent ec50/ certain single dose ec50×100
The toxicity index of the toxicity index of theoretical toxicity index=a single dose × a single dose proportion+b single dose in mixture × b single dose proportion in mixture
The ec of actual measurement toxicity index=standard single dose50The ec of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified: when ctc is more than 120, mixture has synergetic, and it is antagonism that ctc is less than when 80, and ctc exists It is summation action between 80-120.
Table 1: the indoor biometricses result to downy mildew of garpe bacterial strain for the fluoxastrobin+2-cyano-3-amino-3-phenylancryic acetate different ratio
Medicament Virulence regression equation ec50(mg/l) Co-toxicity coefficient
Fluoxastrobin (a) Y=2.65x+10.06 0.0123 -
2-cyano-3-amino-3-phenylancryic acetate (b) Y=1.76x+3.76 5.0709 -
A:b=70:1 Y=2.05x+3.55 5.1135 100.58
A:b=10:1 Y=2.69x+3.66 3.1368 177.78
A:b=1:1 Y=2.30x+3.38 5.043 200.63
A:b=1:3 Y=2.02x+3.18 7.940 253.62
A:b=1:6 Y=2.16x+2.49 14.514 241.05
A:b=1:9 Y=1.15x+3.57 17.612 198.65
A:b=1:20 Y=1.23x+2.93 48.2594 210.45
A:b=1:70 Y=1.95x+0.23 279.2125 110.23
Field control effectiveness test:
Prevent and treat downy mildew of garpe test with the pesticidal preparations that following embodiments are obtained.
1st, test process: this test medicine consumption sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition Agent is pesticide single dose 10% fluoxastrobin ec and 25% 2-cyano-3-amino-3-phenylancryic acetate se and blank clean water experiment respectively.
2nd, test method: each plot area is 66.7m2, it is repeated 3 times;Investigation drug effect after investigating before dispenser and preventing and treating Method is: in test process area, (every takes 5m to 5 points of randomization2), carry out disease according to national field test relevant criterion Mutual affection level, calculates preventive effect.
3rd, result of the test see table:
Shown by indoor biometricses and field efficacy result, fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate compositionss have significantly collaborative Potentiation, the prevention effect of compositionss is excellent, and prevention effect is all better than single dose kind, has application valency in agricultural application Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates two kinds with specific embodiment below The preparation that effective ingredient is processed into, but the preparation that can process of this two kinds of active components be not limited only to set forth below.
Embodiment 1:
By fluoxastrobin 5g, 2-cyano-3-amino-3-phenylancryic acetate 10g, detergent ls (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, diffusion Agent nno (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, is obtained effectively Ingredients Weight percentage composition is 15% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate wettable powder.
Embodiment 2:
By fluoxastrobin 3g, 2-cyano-3-amino-3-phenylancryic acetate 12g, sodium lauryl sulphate 3g, diffusant nno4g, white carbon 5g, Kaolin Add to 100g mixture and carry out comminution by gas stream, prepared effective ingredient weight percentage can for 15% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate WP.
Embodiment 3:
By fluoxastrobin 2g, 2-cyano-3-amino-3-phenylancryic acetate 14g, sodium lauryl sulphate 3g, diffusant nno4g, white carbon 5g, Kaolin Add to 100g mixture and carry out comminution by gas stream, prepared effective ingredient weight percentage can for 16% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate WP.
Embodiment 4:
Weigh 5g fluoxastrobin, 50g 2-cyano-3-amino-3-phenylancryic acetate, phenethyl phenol polyethenoxy ether phosphate ester 3g, agriculture breast 33#2g, alkyl Phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared aqueous emulsion puts into Mixing kettle high speed mixes, and making effective Ingredients Weight percentage composition is 55% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate aqueous emulsion.
Embodiment 5:
Weigh 2g fluoxastrobin, 30g 2-cyano-3-amino-3-phenylancryic acetate, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared micro- The method of Emulsion puts in mixing kettle and mixes, and making effective Ingredients Weight percentage composition is that 32% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate is micro- Emulsion.
Embodiment 6:
Weigh 1g fluoxastrobin, 5g 2-cyano-3-amino-3-phenylancryic acetate, phenethyl phenol polyethenoxy ether phosphate ester 3g, agriculture breast 33#2g, alkyl phenol Polyoxyethylene ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared aqueous emulsion puts into mixed Close the mixing of kettle high speed, making effective Ingredients Weight percentage composition is 6% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate aqueous emulsion.
Embodiment 7:
Weigh 50g fluoxastrobin, 20g 2-cyano-3-amino-3-phenylancryic acetate, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, Castor oil polyoxyethylene ether 2g, 150# solvent naphtha is to 100g.The method that above raw material is routinely prepared cream puts into mixing kettle Middle mixing, making effective Ingredients Weight percentage composition is 70% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate cream.
Embodiment 8:
Weigh 2g fluoxastrobin, 40g 2-cyano-3-amino-3-phenylancryic acetate, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, 150# solvent naphtha is to 100g.The method that above raw material is routinely prepared cream puts in mixing kettle and mixes, and makes effective ingredient Weight percentage is 42% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate cream.
Embodiment 9:
Weigh 5g fluoxastrobin, 20g 2-cyano-3-amino-3-phenylancryic acetate, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid Ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared micro- The method of Emulsion puts in mixing kettle and mixes, and making effective Ingredients Weight percentage composition is that 25% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate is micro- Emulsion.
Embodiment 10:
Weigh 5g fluoxastrobin, 0.5g 2-cyano-3-amino-3-phenylancryic acetate, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, 150# solvent naphtha is to 100g.The method that above raw material is routinely prepared cream puts in mixing kettle and mixes, and makes effective ingredient Weight percentage is 5.5% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate cream.
Embodiment 11:
Weigh 5g fluoxastrobin, 30g 2-cyano-3-amino-3-phenylancryic acetate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150# solvent naphtha is to 100g.The method that above raw material is routinely prepared cream puts in mixing kettle and mixes, and makes effective ingredient Weight percentage is 35% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate cream.
Embodiment 12:
Weigh 10g fluoxastrobin, 10g 2-cyano-3-amino-3-phenylancryic acetate, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, Xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, in the effect of sand mill Under make effective Ingredients Weight percentage composition be 20% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate suspending agent.
Embodiment 13:
Weigh 30g fluoxastrobin, 12g 2-cyano-3-amino-3-phenylancryic acetate, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, Xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, in the effect of sand mill Under make effective Ingredients Weight percentage composition be 42% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate suspending agent.
Embodiment 14:
Weigh 2g fluoxastrobin, 5g 2-cyano-3-amino-3-phenylancryic acetate, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, poly- second Enol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and above raw material is formed with imitating by water dispersible granular agent method Ingredients Weight percentage composition is 7% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate water dispersion granule.
Embodiment 15:
Weigh 4g fluoxastrobin, 13g 2-cyano-3-amino-3-phenylancryic acetate, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, gather Vinyl alcohol 5g, Borax 2g, kieselguhr 28g complements to 100g, and above raw material is formed with imitating composition by water dispersible granular agent method Weight percentage is 17% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate water dispersion granule.
Embodiment 16:
Weigh 5g fluoxastrobin, 15g 2-cyano-3-amino-3-phenylancryic acetate, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, yellow Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, in the presence of sand mill Making effective Ingredients Weight percentage composition is 20% fluoxastrobin -2-cyano-3-amino-3-phenylancryic acetate suspending agent.

Claims (10)

1. a kind of bactericidal composition containing fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate is it is characterised in that said composition is with fluoxastrobin and cyanogen alkene Bacterium ester is principle active component, and the wherein weight of fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate ratio is for 1~70:1~50.
2. bactericidal composition according to claim 1 is it is characterised in that the weight ratio of described fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate For 1~5:1~20.
3. bactericidal composition according to claim 1 is it is characterised in that the weight ratio of described fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate For 1~2:0.5~15.
4. the bactericidal composition according to claim 1 or 3 is it is characterised in that the weight of described fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate Than for 1:1~10.
5. bactericidal composition according to claim 1 is it is characterised in that both described fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate account for group The percentage by weight of compound is 2~80%.
6. bactericidal composition according to claim 5 is it is characterised in that both described fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate account for group The percentage by weight of compound is 10~40%.
7. bactericidal composition according to claim 1 is it is characterised in that said composition with fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate is Principle active component, is configured to any one dosage form of permission on pesticide with insecticides adjuvant and/or excipient.
8. bactericidal composition according to claim 7 it is characterised in that described dosage form be cream, suspending agent, aqueous emulsion, can WP, microemulsion or water dispersion granule.
9. the bactericidal composition containing fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate described in claim 1 is on preventing and treating resistance plant fungal disease Application.
10. the bactericidal composition containing fluoxastrobin and 2-cyano-3-amino-3-phenylancryic acetate described in claim 1 is in control rust, glume blight, filigree Application on disease, powdery mildew, downy mildew, head blight, tomato wilt or bakanae disease of rice class fungal disease.
CN201610766117.XA 2016-08-29 2016-08-29 Bactericidal composition containing fluoxastrobin and allyl cyanide azoxystrobin and application of bactericidal composition Pending CN106342834A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102302004A (en) * 2011-07-05 2012-01-04 青岛奥迪斯生物科技有限公司 Suspension seed coating agent containing JS399-19 (2-cyano-3-amino-3-ethyl phenylacrylate)
CN102715156A (en) * 2012-06-29 2012-10-10 陕西上格之路生物科学有限公司 Sterilization composition containing js399-19
CN104094943A (en) * 2014-06-13 2014-10-15 广东中迅农科股份有限公司 Bactericidal composition containing fluoxastrobin and triflumizole

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102302004A (en) * 2011-07-05 2012-01-04 青岛奥迪斯生物科技有限公司 Suspension seed coating agent containing JS399-19 (2-cyano-3-amino-3-ethyl phenylacrylate)
CN102715156A (en) * 2012-06-29 2012-10-10 陕西上格之路生物科学有限公司 Sterilization composition containing js399-19
CN104094943A (en) * 2014-06-13 2014-10-15 广东中迅农科股份有限公司 Bactericidal composition containing fluoxastrobin and triflumizole

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Application publication date: 20170125