CN106973919A - A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid - Google Patents

A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid Download PDF

Info

Publication number
CN106973919A
CN106973919A CN201710130094.8A CN201710130094A CN106973919A CN 106973919 A CN106973919 A CN 106973919A CN 201710130094 A CN201710130094 A CN 201710130094A CN 106973919 A CN106973919 A CN 106973919A
Authority
CN
China
Prior art keywords
cyazofamid
fluoxastrobin
bactericidal composition
composition according
disease
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710130094.8A
Other languages
Chinese (zh)
Inventor
高瑞花
郭崇友
张宝俊
陈叶青
程清云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Huazhou Pharmaceutical Co Ltd
Original Assignee
Nanjing Huazhou Pharmaceutical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Huazhou Pharmaceutical Co Ltd filed Critical Nanjing Huazhou Pharmaceutical Co Ltd
Priority to CN201710130094.8A priority Critical patent/CN106973919A/en
Publication of CN106973919A publication Critical patent/CN106973919A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of bactericidal composition containing fluoxastrobin and cyazofamid and its application.The bactericidal composition is using fluoxastrobin and cyazofamid as principle active component, and wherein the mass ratio of fluoxastrobin and cyazofamid is 50:1~1:60.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, it is particularly useful for preventing and treating the fungal diseases such as powdery mildew, rust, clever blessing disease, net blotch, downy mildew, late blight, with higher synergistic function, overcome and delayed the resistance to the action of a drug of germ, sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and used.

Description

A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid
Technical field：
It is especially a kind of using fluoxastrobin and cyazofamid to be main living the present invention relates to a kind of bactericidal composition and application thereof The bactericidal composition of property composition and its application.
Background technology
Fluoxastrobin (Fluoxastrobin) is mitochondrial respiratory inhibitor, and its mechanism of action is by cytochrome b Electro transfer suppresses mitochondrial breathing between C1, and fluoxastrobin has quick-acting and lasting period long double grading, had to crop Good compatibility, appropriate processing formulation can further improve its osmosis for entering people's leaf portion by cuticula.Although it Absorbability by seed and root is poor, when being used as seed treatment, though have to seedling and kind biography and soil-borne disease Kill well and lasting effect.
Cyazofamid (Cyazofamid), molecular formula：C13H13ClN4O2S, chemical name：Chloro- 2- cyano group-N, the N- diformazans of 4- Base -5- p-methylphenyl imidazoles -1- sulfonamide.Structural formula：
Cyazofamid belongs to sulphaguanidine azoles fungicide.It is mould to Oomycete fungal such as phytophthora, downy mildew, Pseudo peronospara, corruption The plasmodiophora brassica bacteria of bacterium and Plasmodiophoromycetes has very high bioactivity.Mechanism of action is to block line grain in Oomycete germ body The electron transmission of cytochrome bc1 complexs carrys out the supply of interfering energy, and its binding site is Mei Q1 centers, with its homicide Microbial inoculum is without cross tolerance.There is high prevention effect to late blight and downy mildew.
The difficulty of prevention and cure of current phytopathogen is increasing, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc. Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity are increased, and difficulty is increased in preventing and treating；Separately On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality, plant Disease control is faced with significant challenge.
The content of the invention：
The purpose of the present invention be provide that a kind of applied widely, cost is low for above-mentioned technical problem, that effect is good is fluorine-containing The plant bactericidal composition of Fluoxastrobin and cyazofamid.
It is a still further object of the present invention to provide the bactericidal composition preventing and treating fungal diseases of plants on application, especially Purposes on the fungal diseases such as powdery mildew, rust, clever blessing disease, net blotch, downy mildew, late blight are prevented and treated.
The purpose of the present invention is to be achieved through the following technical solutions：
A kind of bactericidal composition containing fluoxastrobin and cyazofamid, the bactericidal composition is based on fluoxastrobin and cyazofamid Active ingredient is wanted, the wherein mass ratio of fluoxastrobin and cyazofamid is 50:1~1:60, wherein effective ingredient in bactericidal composition It is present in enhancing effective amount in composition.
The mass ratio of described bactericidal composition, wherein fluoxastrobin and cyazofamid is preferably 30：1~1：10, further Preferably 20：1~2.5:1、1:2~1:10.
In the compositions of the present invention, the weight/mass percentage composition that composition is accounted for both fluoxastrobin and cyazofamid is 2~80%. Preferably 5-70%, more preferably 10~40%.
Described bactericidal composition, wherein using fluoxastrobin and cyazofamid as principle active component and known auxiliary agent and tax Shape agent is re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, froth breaking Agent, wetting agent, disintegrant etc., can use calcium dodecyl benzene sulfonate, APES, benzyl phenol polyethenoxy Ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell Warm series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite, One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. are combined, and excipient includes Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other Auxiliary material can be with alone or be used in combination.
Described bactericidal composition, its formulation is missible oil, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
Application of the above-mentioned bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared.Especially in preventing and treating cereal Application in terms of class, fruit tree, vegetable crop disease has remarkable result.
Above-mentioned application, described fungal diseases of plants is powdery mildew, rust, clever blessing disease, net blotch, downy mildew, late blight At least one of disease.
The characteristics of bactericidal composition of the present invention：
1st, the fluoxastrobin and cyazofamid used in the present invention, the mechanism of action is different, mutual mixture will not produce it is low touch, can assist Same synergy, reduces dosage, reduces cost.
2nd, present composition scope of application increase, it is adaptable to prevent and treat Cereal, fruit tree, the refractory fungal disease of vegetables, Particularly preventing and treating powdery mildew, rust, clever blessing disease, net blotch, downy mildew, late blight etc. has significant effect.Present invention sterilization Composition has good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And suppress insect or true Drug-fast generation of the bacterium to unitary agent (fluoxastrobin and cyazofamid are any).Bactericidal composition of the present invention can produce higher Synergistic function, and the consumption of the amount ratio independent reactive compound of the mixture substantially reduces, the i.e. activity of mixture More than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as The fungal diseases such as powdery mildew, rust, clever blessing disease, net blotch, downy mildew, late blight have obvious synergistic function, overcome and prolong Delay the resistance to the action of a drug, expand preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) it is alternative normal Advise and be also easy to produce the agricultural chemicals of resistance；(4) compared with single dose, production and use cost reduction；(5) the drug-fast production of fungi is suppressed Raw, its effect is used apparently higher than its single dose.
Embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, determines EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows：
A certain single dose (generally selects EC as standard agent using in mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture × B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, and CTC exists when being less than 80 for antagonism, CTC It is summation action between 80-120.
According to active ingredient fluoxastrobin (A)：Cyazofamid (B) quality proportioning is：70：1、50：1、30：1、20：1、10：1、 5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50、1:60、1:70 are tested, and determine it to grape The co-toxicity coefficient of Pseudoperonospora cubensis (Plasmopara viticola (Berk.dt Curtis) Berl.Et de Toni.).
Table 1：Indoor biometricses result of the fluoxastrobin+cyazofamid different ratio to Plasmopara viticola
Field control effectiveness test：
Downy mildew of garpe experiment is prevented and treated with pesticidal preparations made from above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition Agent is the fluoxastrobin EC of agricultural chemicals single dose 10% and 10% cyazofamid SC and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser Method is：(every takes 5M for 5 points of grab sample in test process area2), carry out the state of an illness point according to national field test relevant criterion Level, calculates preventive effect.Result of the test is shown in Table 2：
The field test effect of table 2
Shown by indoor biometricses and field efficacy result, fluoxastrobin has with cyazofamid composition significantly cooperates with increasing Effect is acted on, and the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application value in agricultural application.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds below with specific embodiment The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% fluoxastrobin cyazofamid wettable powder (1:2)
By fluoxastrobin 5g, cyazofamid 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusant NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures carry out air-flow crushing, be made effectively into It is 15% fluoxastrobin cyazofamid wettable powder to divide mass percent.
Embodiment 2：15% fluoxastrobin cyazofamid wettable powder (1:4)
By fluoxastrobin 3g, cyazofamid 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin Add to 100g mixtures and carry out air-flow crushing, it is 15% fluoxastrobin cyazofamid wettable that active ingredient mass percent, which is made, Pulvis.
Embodiment 3：14% fluoxastrobin cyazofamid wettable powder (1:6)
By fluoxastrobin 2g, cyazofamid 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin Add to 100g mixtures and carry out air-flow crushing, it is 14% fluoxastrobin cyazofamid wettable that active ingredient mass percent, which is made, Pulvis.
Embodiment 4：20% fluoxastrobin cyazofamid suspending agent (1:1)
10g fluoxastrobins, 10g cyazofamids, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow Virgin rubber 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, 100g is complemented to water, is made in the presence of sand mill It is 20% fluoxastrobin cyazofamid suspending agent into active ingredient mass percent.
Embodiment 5：55% fluoxastrobin cyazofamid aqueous emulsion (1:10)
Weigh 5g fluoxastrobins, 50g cyazofamids, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol APEO 1g, 150# solvent naphtha 13g, adds water to 100g.The method input that above raw material is routinely prepared into aqueous emulsion is mixed The mixing of kettle high speed is closed, effective Ingredient percent is made for 55% fluoxastrobin cyazofamid aqueous emulsion.
Embodiment 6：42% fluoxastrobin cyazofamid missible oil (1:20)
Weigh 2g fluoxastrobins, 40g cyazofamids, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, 150# Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality is made Percentage is 42% fluoxastrobin cyazofamid missible oil.
Embodiment 7：70% fluoxastrobin cyazofamid missible oil (2.5:1)
Weigh 50g fluoxastrobins, 20g cyazofamids, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor Sesame oil APEO 2g, 150# solvent naphtha is to 100g.In the method input mixing kettle that above raw material is routinely prepared to missible oil Mixing, is made effective Ingredient percent for 70% fluoxastrobin cyazofamid missible oil.
Embodiment 8：18% fluoxastrobin cyazofamid water dispersion granule (5：1)
Weigh 15g fluoxastrobins, 3g cyazofamids, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second Enol 5g, borax 2g, diatomite complements to 100g, and above raw material is formed with by water dispersible granular agent method to imitate composition quality hundred Divide than being 18% fluoxastrobin cyazofamid water dispersion granule.
Embodiment 9：11% fluoxastrobin cyazofamid missible oil (10:1)
Weigh 10g fluoxastrobins, 1g cyazofamids, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, 150# Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality is made Percentage is 11% fluoxastrobin cyazofamid missible oil.
Embodiment 10：31.5% fluoxastrobin cyazofamid microemulsion (20:1)
Weigh 30g fluoxastrobins, 1.5g cyazofamids, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared micro- Mixed in the method input mixing kettle of emulsion, effective Ingredient percent is made for 31.5% fluoxastrobin cyazofamid micro emulsion Agent.
Embodiment 11：31% fluoxastrobin cyazofamid missible oil (30:1)
Weigh 30g fluoxastrobins, 1g cyazofamids, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150# Solvent naphtha is to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, effective composition quality is made Percentage is 31% fluoxastrobin cyazofamid missible oil.
Embodiment 12：51% fluoxastrobin cyazofamid suspending agent (50:1)
Weigh 50g fluoxastrobins, 1g cyazofamids, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan Glue 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, are made in the presence of sand mill Active ingredient mass percent is 51% fluoxastrobin cyazofamid suspending agent.
Embodiment 13：32% fluoxastrobin cyazofamid microemulsion (1:15)
Weigh 2g fluoxastrobins, 30g cyazofamids, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared into micro emulsion Mixed in the method input mixing kettle of agent, effective Ingredient percent is made for 32% fluoxastrobin cyazofamid microemulsion.
Embodiment 14：6% fluoxastrobin cyazofamid aqueous emulsion (1:5)
1g fluoxastrobins, 5g cyazofamids, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol is weighed to gather Oxygen vinethene 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared into aqueous emulsion puts into mixing Kettle high speed is mixed, and effective Ingredient percent is made for 6% fluoxastrobin cyazofamid aqueous emulsion.
Embodiment 15：62% fluoxastrobin cyazofamid microemulsion (1:30)
Weigh 2g fluoxastrobins, 60g cyazofamids, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared into micro emulsion Mixed in the method input mixing kettle of agent, effective Ingredient percent is made for 62% fluoxastrobin cyazofamid microemulsion.
Embodiment 16：51% fluoxastrobin cyazofamid suspending agent (1:50)
Weigh 1g fluoxastrobins, 50g cyazofamids, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan Glue 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, are made in the presence of sand mill Active ingredient mass percent is 51% fluoxastrobin cyazofamid suspending agent.
Embodiment 17：7% fluoxastrobin cyazofamid water dispersion granule (1：2.5)
Weigh 2g fluoxastrobins, 5g cyazofamids, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyethylene Alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with imitating into by water dispersible granular agent method It is 7% fluoxastrobin cyazofamid water dispersion granule to divide mass percent.

Claims (9)

1. a kind of bactericidal composition containing fluoxastrobin and cyazofamid, it is characterised in that the bactericidal composition is with fluoxastrobin and cyanogen White azoles is principle active component, and wherein the mass ratio of fluoxastrobin and cyazofamid is 50:1~1:60.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the fluoxastrobin and cyazofamid is 30：1~1：10.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the fluoxastrobin and cyazofamid is 20：1~2.5:1、1:2~1:10.
4. bactericidal composition according to claim 1, it is characterised in that both described fluoxastrobin and cyazofamid account for group The weight/mass percentage composition of compound is 2-80%.
5. bactericidal composition according to claim 5, it is characterised in that both described fluoxastrobin and cyazofamid account for group The weight/mass percentage composition of compound is 5-70%.
6. bactericidal composition according to claim 1, it is characterised in that using fluoxastrobin and cyazofamid as it is main effectively into Point and insecticides adjuvant, excipients be configured to any one formulation for allowing on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion, Wettable powder or water dispersion granule.
8. application of the bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared described in claim 1.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is powdery mildew, rust, clever blessing At least one of disease, net blotch, downy mildew, late blight.
CN201710130094.8A 2017-03-07 2017-03-07 A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid Pending CN106973919A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710130094.8A CN106973919A (en) 2017-03-07 2017-03-07 A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710130094.8A CN106973919A (en) 2017-03-07 2017-03-07 A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid

Publications (1)

Publication Number Publication Date
CN106973919A true CN106973919A (en) 2017-07-25

Family

ID=59338849

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710130094.8A Pending CN106973919A (en) 2017-03-07 2017-03-07 A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid

Country Status (1)

Country Link
CN (1) CN106973919A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101039578A (en) * 2004-10-12 2007-09-19 拜尔农作物科学股份公司 Fungicidal active ingredient combinations containing fluoxastrobin
EP2011396A1 (en) * 2007-07-03 2009-01-07 Bayer CropScience AG Active compound combinations

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101039578A (en) * 2004-10-12 2007-09-19 拜尔农作物科学股份公司 Fungicidal active ingredient combinations containing fluoxastrobin
CN102630683A (en) * 2004-10-12 2012-08-15 拜尔农作物科学股份公司 Fungicidal active ingredient combinations containing fluoxastrobin
EP2011396A1 (en) * 2007-07-03 2009-01-07 Bayer CropScience AG Active compound combinations

Similar Documents

Publication Publication Date Title
CN107027778A (en) A kind of bactericidal composition and its application containing fluoxastrobin and Tebuconazole
CN105941416A (en) Sterilizing composition containing bixafen and tebuconazole and application thereof
CN105794794A (en) Bactericidal composition containing isopyrazam and tiadinil and application of bactericidal composition
CN106508943A (en) Bactericidal composition containing benthiavalicarb-isopropyl and prochloraz, and applications thereof
CN106973919A (en) A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid
CN106889079A (en) A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine
CN106508931A (en) Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof
CN105766926A (en) Bactericidal composition containing bixafen and coumoxystrobin and application thereof
CN105379753B (en) A kind of bactericidal composition and its application containing mepanipyrim and different rice blast net
CN105746534A (en) Fungicidal composition containing isopyrazam and isotianil and application thereof
CN105360129B (en) A kind of bactericidal composition and its application containing mepanipyrim and cyazofamid
CN107047583A (en) A kind of bactericidal composition and its application containing fluoxastrobin and Mancozeb
CN105475342B (en) A kind of bactericidal composition and its application containing Silthiopham and fluazinam
CN105794792B (en) The bactericidal composition and its application of a kind of Fluxapyroxad-containsterilization and Wakil
CN106508932A (en) Bactericidal composition containing benthiavalicarb and cyproconazole and application thereof
CN105475340B (en) A kind of bactericidal composition and its application containing Silthiopham and metalaxyl
CN107047576A (en) A kind of bactericidal composition and its application containing fluoxastrobin and kresoxim-methyl
CN107333782A (en) A kind of bactericidal composition and its application of the pyrrole bacterium ketone of benzene containing amine and cyazofamid
CN106857565A (en) A kind of bactericidal composition and its application containing fluoxastrobin and SYP-3375
CN106973920A (en) A kind of bactericidal composition and its application containing fluoxastrobin and fenoxanil
CN107306958A (en) A kind of bactericidal composition and its application containing isopyrazam and azoles mepanipyrim
CN107467032A (en) A kind of bactericidal composition and its application containing isopyrazam and cyazofamid
CN107006492A (en) A kind of bactericidal composition and its application containing fluoxastrobin and metalaxyl
CN107771812A (en) A kind of bactericidal composition and its application containing Boscalid and cyazofamid
CN107027777A (en) A kind of bactericidal composition and its application containing fluoxastrobin and cyflufenamid

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination