CN105475341A - Sterilization composition containing silthiopham and flusilazole and application thereof - Google Patents
Sterilization composition containing silthiopham and flusilazole and application thereof Download PDFInfo
- Publication number
- CN105475341A CN105475341A CN201511003182.9A CN201511003182A CN105475341A CN 105475341 A CN105475341 A CN 105475341A CN 201511003182 A CN201511003182 A CN 201511003182A CN 105475341 A CN105475341 A CN 105475341A
- Authority
- CN
- China
- Prior art keywords
- flusilazole
- silthiopham
- bactericidal composition
- composition according
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization composition containing silthiopham and flusilazole and application thereof. The sterilization composition takes silthiopham and flusilazole as main effective components, wherein the mass ratio of silthiopham to flusilazole is (1-70) to (1-50). The sterilization composition can be applied to prevention and treatment of diseases of cereals, fruit trees and vegetables, has a relatively high synergistic interaction effect and particularly can be applied to prevention and treatment of fungal diseases including take-all disease of wheat, pear scab, wheat glume blotch and the like; the drug resistance of pathogenic bacteria is overcome and delayed, the sterilization speed is high, the lasting period is long and the application cost is reduced; and the prevention and treatment effect is obviously better than that of a single dosage.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and uses thereof, especially a kind of be main active bactericidal composition and the application thereof of Silthiopham and Flusilazole.
Background technology
Silthiopham (Silthiopham), chemical name: N-pi-allyl-4,5-dimethyl-2-(TMS) thiophene-3-formamide.Silthiopham has good prolection, and the longevity of residure is long, all safer to crop, mammal and environment, has special efficacy to take-all.
Flusilazole (Flusilazole), molecular formula: C
16h
15f
2n
3si, chemical name: two (4-fluorophenyl)-(1H-1,2,4-triazol-1-yl methyl) monosilane.Structural formula:
Flusilazole is triazole bactericidal agent, and the mechanism of action destroys and stop the biosynthesis of ergosterol, causes cell membrane not formed, and makes germ dead.Effective to disease caused by sac fungi, basidiomycetes and imperfect fungus, invalid to oomycetes, there is special efficacy to pear scab.
The difficulty of prevention and cure of current phytopathogen is increasing, and on the one hand, along with the change of pattern of farming, the economic crops such as melon and fruit, vegetables cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in control, difficulty strengthens; On the other hand, the resistance of pathogen rises year by year under the medicament selection pressure continued, and the control efficiency of single dose is had a greatly reduced quality, and control of plant disease is faced with significant challenge.
Summary of the invention:
The object of the invention is the plant bactericidal composition containing Silthiopham and Flusilazole providing a kind of applied widely, cost low, effective for above-mentioned technical problem.
A further object of the invention is to provide this bactericidal composition and causes application on fungal disease at control plant epiphyte, is is especially preventing and treating the purposes on the fungal diseases such as take-all, pear scab, wheat glume blotch.
The object of the invention is to be achieved through the following technical solutions:
A kind of bactericidal composition containing Silthiopham and Flusilazole, this bactericidal composition with Silthiopham and Flusilazole for principle active component, wherein the mass ratio of Silthiopham and Flusilazole is 1 ~ 70:1 ~ 50, and wherein in bactericidal composition, effective ingredient is present in composition with enhancing effective amount.
Described bactericidal composition, wherein the mass ratio of Silthiopham and Flusilazole is preferably 1 ~ 50:1 ~ 50, more preferably 1 ~ 30:1 ~ 20, is further preferably 1 ~ 20:1 ~ 10.
Silthiopham and Flusilazole preferred mass proportioning also can be: 70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50
In the compositions of the present invention, the mass percentage accounting for composition both Silthiopham and Flusilazole is 2 ~ 80%.Preferably 5 ~ 70%.
Described bactericidal composition, wherein with Silthiopham and Flusilazole for principle active component and known auxiliary agent and excipient are re-dubbed any one formulation that agricultural chemicals allows.These known auxiliary agents, excipients has dispersant, diffusant, defoamer, wetting agent, disintegrant etc., calcium dodecyl benzene sulfonate can be adopted, alkylphenol polyoxyethylene, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products thereof, aliphatic amine polyoxyethylene ether, fatty acid ethylene oxide addition product, the rare block compound of polyoxyethylene polyoxy third, castor oil polyoxyethylene ether, polyoxyethylene nonylphenol ether, TWEEN Series, fatty alcohol-polyoxyethylene ether, polyethylene glycol series, Sulfonates, carboxylate, sulphate, phosphate, phosphite, lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, one or more combinations in quaternary etc., excipient comprises cyclohexanone, dimethylbenzene, various solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can be alone or and use.
Described bactericidal composition, its formulation is missible oil, wetting powder, suspending agent, aqueous emulsion or water dispersion granule.
The application of above-mentioned bactericidal composition on preparation control fungal diseases of plants medicine.Especially the application in control Cereal, fruit tree, vegetable crop disease has remarkable result.
Above-mentioned application, described fungal diseases of plants is at least one in take-all, pear scab, wheat glume blotch.
The feature of bactericidal composition of the present invention:
1, the Silthiopham that the present invention is used and Flusilazole, the mechanism of action is different, and mutual mixture can not produce low touching, can Synergistic, reduces dosage, reduces costs.
2, the present composition scope of application increases, and be applicable to the refractory fungal disease of preventing and treating Cereal, fruit tree, vegetables, particularly preventing and treating take-all, pear scab, wheat glume blotch etc. all has significant effect.Bactericidal composition of the present invention has good control efficiency to sac fungi, basidiomycetes, imperfect fungus and Oomycete fungal disease; And suppress insect or fungi to the drug-fast generation of unitary agent (Silthiopham and Flusilazole arbitrary).Bactericidal composition of the present invention can produce higher synergistic function, and the consumption of the independent reactive compound of the amount ratio of this mixture reduces greatly, and namely the activity of mixture is greater than the activity of independent component.
Compared with prior art beneficial effect of the present invention: (1) is compared with single dose, said composition antagonism fungal disease such as the fungal diseases such as take-all, pear scab, wheat glume blotch have obvious synergistic function, overcome and delayed pesticide resistance, expanding prevention is composed, and significantly improves control efficiency; (2) control recruitment, drug cost is reduced; (3) alternative routine and the easy agricultural chemicals producing resistance; (4) compared with single dose, produce and use cost reduction; (5) the drug-fast generation of Antifungi, its successful uses higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of formulation is conventional method, and " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure different agents to the EC of bacterial strain
50value, adopt co-toxicity coefficient computational methods, calculate the co-toxicity coefficient (CTC) of mixture, determine the building performance of mixture, circular is as follows:
With single dose a certain in mixture for standard agent (selects EC usually
50junior), calculate:
Single dose toxicity index=standard agent EC
50/ certain single dose EC
50× 100
Toxicity index × B single dose proportion in mixture of toxicity index × A single dose proportion+B single dose in mixture of theoretical toxicity index=A single dose
The EC of actual measurement toxicity index=standard single dose
50the EC of value/mixture
50value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
When co-toxicity coefficient classification: CTC is greater than 120, mixture has synergetic, and be antagonism when CTC is less than 80, CTC is summation action between 80-120.
According to active ingredient Silthiopham (A): Flusilazole (B) quality proportioning is: 80:1,70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50,1:60 test, measure its co-toxicity coefficient to take-all germ (GaeumannomycesgraminisSacc.Arx.olivcr).
Table 1: Silthiopham+Flusilazole different ratio is to the indoor biometrics result of gaeumannomyces graminis
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 12.5% Silthiopham SC | Y＝4.057+2.421X | 2.452 | - |
| 10% Flusilazole EW | Y＝4.064+1.025X | 8.197 | - |
| A:B＝80:1 | Y＝2.232+3.000X | 8.372 | 98.76 |
| A:B＝70:1 | Y＝1.661+4.157X | 6.356 | 130.26 |
| A:B＝50:1 | Y＝3.022+2.634X | 5.638 | 147.42 |
| A:B＝30:1 | Y＝4.139+1.048X | 6.628 | 126.53 |
| A:B＝20:1 | Y＝2.285+4.124X | 4.553 | 186.25 |
| A:B＝10:1 | Y＝3.160+2.589X | 5.138 | 170.41 |
| A:B＝5:1 | Y＝3.594+1.905X | 5.473 | 169.59 |
| A:B＝2.5:1 | Y＝0.494+5.497X | 6.604 | 155.20 |
| A:B＝1:1 | Y＝3.058+2.005X | 9.306 | 135.60 |
| A:B＝1:2 | Y＝2.848+2.354X | 8.206 | 187.49 |
| A:B＝1:4 | Y＝0.618+4.520X | 9.322 | 200.16 |
| A:B＝1:6 | Y＝0.842+3.632X | 13.961 | 147.06 |
| A:B＝1:10 | Y＝2.741+1.995X | 13.568 | 166.50 |
| A:B＝1:20 | Y＝0.972+3.201X | 18.129 | 135.98 |
| A:B＝1:30 | Y＝1.695+2.624X | 18.178 | 140.15 |
| A:B＝1:50 | Y＝1.344+3.068X | 15.553 | 168.45 |
| A:B＝1:60 | Y＝2.182+2.056X | 23.478 | 112.40 |
Field control effectiveness test:
Take-all test is prevented and treated with the pesticidal preparations that above-described embodiment is obtained.
1, test process: this test medicine consumption establishes three concentration for the treatment of respectively according to the difference of each composition, contrast medicament is agricultural chemicals single dose 12.5% Silthiopham SC and 10% Flusilazole EW and blank clean water experiment respectively.
2, each plot area of test method is 66.7m
2, repeat 3 times; Investigation drug effect method before dispenser after Investigation and Prevention is: random sampling 5 point in test treatment region, carries out severity Scaling, calculate preventive effect according to national field trial relevant criterion.Result of the test is in table 2:
Table 2 field test effect
Shown by indoor biometrics and field efficacy result, Silthiopham and Flusilazole composition have obvious synergistic function, and the control efficiency of composition is excellent, and control efficiency is all better than single dose kind, in agricultural application, have using value.
Two kinds of reactive compounds can be processed into any one formulation of permission, with specific embodiment, the preparation that two kinds of active ingredients are processed into are described below, but the preparation that these two kinds of active components can be processed be not limited only to following listed by.
Embodiment 1:15% Silthiopham Flusilazole wetting powder (1:2)
By Silthiopham 5g, Flusilazole 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and obtained active ingredient mass percent is 15% Silthiopham Flusilazole wetting powder.
Embodiment 2:15% Silthiopham Flusilazole wetting powder (1:4)
By Silthiopham 3g, Flusilazole 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and obtained active ingredient mass percent is 15% Silthiopham Flusilazole wetting powder.
Embodiment 3:14% Silthiopham Flusilazole wetting powder (1:6)
By Silthiopham 2g, Flusilazole 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and obtained active ingredient mass percent is 14% Silthiopham Flusilazole wetting powder.
Embodiment 4:20% Silthiopham Flusilazole suspending agent (1:1)
Take 10g Silthiopham, 10g Flusilazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill, make active ingredient mass percent is 20% Silthiopham Flusilazole suspending agent.
Embodiment 5:55% Silthiopham Flusilazole aqueous emulsion (1:10)
Take 5g Silthiopham, 50g Flusilazole, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, adds water to 100g.The method above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, and making active ingredient mass percent is 55% Silthiopham Flusilazole aqueous emulsion.
Embodiment 6:42% Silthiopham Flusilazole (1:20)
Take 2g Silthiopham, 40g Flusilazole, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and making active ingredient mass percent is 42% Silthiopham Flusilazole.
Embodiment 7:70% Silthiopham Flusilazole (2.5:1)
Take 50g Silthiopham, 20g Flusilazole, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor oil polyoxyethylene ether 2g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and making active ingredient mass percent is 70% Silthiopham Flusilazole.
Embodiment 8:18% Silthiopham Flusilazole water dispersion granule (5:1)
Take 15g Silthiopham, 3g Flusilazole, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and it is 17% Silthiopham Flusilazole water dispersion granule that above raw material is made active ingredient mass percent by water dispersible granular agent method.
Embodiment 9:11% Silthiopham Flusilazole (10:1)
Take 10g Silthiopham, 1g Flusilazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and making active ingredient mass percent is 11% Silthiopham Flusilazole.
Embodiment 10:31.5% Silthiopham oxazole fluosilicate micro emulsion (20:1)
Take 30g Silthiopham, 1.5g Flusilazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method above raw material being prepared routinely microemulsion drops in mixing kettle and mixes, and making active ingredient mass percent is 32% Silthiopham oxazole fluosilicate micro emulsion.
Embodiment 11:31% Silthiopham Flusilazole (30:1)
Take 30g Silthiopham, 1g Flusilazole, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and making active ingredient mass percent is 31% Silthiopham Flusilazole.
Embodiment 12:51% Silthiopham Flusilazole suspending agent (50:1)
Take 50g Silthiopham, 1g Flusilazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill, make active ingredient mass percent is 51% Silthiopham Flusilazole suspending agent.
Embodiment 13:32% Silthiopham oxazole fluosilicate micro emulsion (1:15)
Take 2g Silthiopham, 30g Flusilazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method above raw material being prepared routinely microemulsion drops in mixing kettle and mixes, and making active ingredient mass percent is 32% Silthiopham oxazole fluosilicate micro emulsion.
Embodiment 14:6% Silthiopham Flusilazole aqueous emulsion (1:5)
Take 1g Silthiopham, 5g Flusilazole, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, adds water to 100g.The method above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, and making active ingredient mass percent is 6% Silthiopham Flusilazole aqueous emulsion.
Embodiment 15:62% Silthiopham oxazole fluosilicate micro emulsion (1:30)
Take 2g Silthiopham, 60g Flusilazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method above raw material being prepared routinely microemulsion drops in mixing kettle and mixes, and making active ingredient mass percent is 62% Silthiopham oxazole fluosilicate micro emulsion.
Embodiment 16:51% Silthiopham Flusilazole suspending agent (1:50)
Take 1g Silthiopham, 50g Flusilazole, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill, make active ingredient mass percent is 51% Silthiopham Flusilazole suspending agent.
Embodiment 17:7% Silthiopham Flusilazole water dispersion granule (1:2.5)
Take 2g Silthiopham, 5g Flusilazole, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and it is 7% Silthiopham Flusilazole water dispersion granule that above raw material is made active ingredient mass percent by water dispersible granular agent method.
Claims (10)
1., containing a bactericidal composition for Silthiopham and Flusilazole, it is characterized in that this bactericidal composition with Silthiopham and Flusilazole for principle active component, wherein the mass ratio of Silthiopham and Flusilazole is 1 ~ 70:1 ~ 50.
2. bactericidal composition according to claim 1, is characterized in that the mass ratio of described Silthiopham and Flusilazole is 1 ~ 50:1 ~ 50.
3. bactericidal composition according to claim 2, is characterized in that the mass ratio of described Silthiopham and Flusilazole is 1 ~ 30:1 ~ 20.
4. bactericidal composition according to claim 3, is characterized in that the mass ratio of described Silthiopham and Flusilazole is 1 ~ 20:1 ~ 10.
5. bactericidal composition according to claim 1, is characterized in that the mass percentage that both described Silthiopham and Flusilazole account for composition is 2-80%.
6. bactericidal composition according to claim 5, is characterized in that the mass percentage that both described Silthiopham and Flusilazole account for composition is 10-40%.
7. bactericidal composition according to claim 1, is characterized in that with Silthiopham and Flusilazole for principle active component and insecticides adjuvant, excipients are mixed with any one formulation that agricultural chemicals allows.
8. bactericidal composition according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder or water dispersion granule.
9. the application of bactericidal composition according to claim 1 on preparation control fungal diseases of plants medicine.
10. application according to claim 9, is characterized in that described fungal diseases of plants is at least one in take-all, pear scab, wheat glume blotch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511003182.9A CN105475341A (en) | 2015-12-28 | 2015-12-28 | Sterilization composition containing silthiopham and flusilazole and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511003182.9A CN105475341A (en) | 2015-12-28 | 2015-12-28 | Sterilization composition containing silthiopham and flusilazole and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105475341A true CN105475341A (en) | 2016-04-13 |
Family
ID=55662922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511003182.9A Pending CN105475341A (en) | 2015-12-28 | 2015-12-28 | Sterilization composition containing silthiopham and flusilazole and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105475341A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106172474A (en) * | 2016-07-12 | 2016-12-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of containing metconazole with the bactericidal composition of Silthiopham |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2329713A1 (en) * | 2008-08-18 | 2011-06-08 | Mitsui Chemicals Agro, Inc. | Plant disease control agent comprising d-tagatose as active ingredient, and plant disease control method |
| CN103238621A (en) * | 2012-02-04 | 2013-08-14 | 陕西美邦农药有限公司 | Bactericidal composition containing silthiopham and triazole compound |
-
2015
- 2015-12-28 CN CN201511003182.9A patent/CN105475341A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2329713A1 (en) * | 2008-08-18 | 2011-06-08 | Mitsui Chemicals Agro, Inc. | Plant disease control agent comprising d-tagatose as active ingredient, and plant disease control method |
| CN103238621A (en) * | 2012-02-04 | 2013-08-14 | 陕西美邦农药有限公司 | Bactericidal composition containing silthiopham and triazole compound |
Non-Patent Citations (1)
| Title |
|---|
| 孙海燕 等: "不同杀菌剂拌种防治小麦全蚀病研究", 《植物保护》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106172474A (en) * | 2016-07-12 | 2016-12-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of containing metconazole with the bactericidal composition of Silthiopham |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105766952A (en) | Sterilization composition containing isopyrazam and folpet and application of sterilization composition | |
| CN104621130A (en) | Sterilization composition containing prothioconazole and azoxystrobin and application thereof | |
| CN104621125A (en) | Sterilization composition containing prothioconazole and trifloxystrobin and application thereof | |
| CN105475341A (en) | Sterilization composition containing silthiopham and flusilazole and application thereof | |
| CN104621127A (en) | Sterilization composition containing prothioconazole and fenoxanil and application thereof | |
| CN104621129A (en) | Sterilization composition containing prothioconazole and metalaxyl-M and application thereof | |
| CN104642335A (en) | Prothioconazole and bupirimate-containing sterilization composition and application thereof | |
| CN104642376A (en) | Bactericidal composition containing prothioconazole and flusilazole and application thereof | |
| CN105532721A (en) | Sterilization composition containing bixafen and ethirimol and application of sterilization composition | |
| CN105532670A (en) | Sterilization composition containing bixafen and diflumetorim and application of sterilization composition | |
| CN105746534A (en) | Fungicidal composition containing isopyrazam and isotianil and application thereof | |
| CN105746545A (en) | Fungicidal composition containing isopyrazam and thifluzamide and application thereof | |
| CN104705319A (en) | Sterilization composition containing penconazole and benthiavalicarb-isopropyl, and applications thereof | |
| CN104642328A (en) | Sterilization composition containing prothioconazole and isoprothiolane and use thereof | |
| CN104621154A (en) | Sterilization composition containing prothioconazole and benthiavalicarb-isopropyl and application thereof | |
| CN105475343A (en) | Bactericidal composition containing silthiopham and penthiopyrad and application thereof | |
| CN104642332A (en) | Bactericidal composition containing prothioconazole and diniconazole and application thereof | |
| CN105475340A (en) | Bactericidal composition containing silthiopham and metalaxyl and application thereof | |
| CN105379723A (en) | Sterilizing composition containing mepanioyrim and benalaxyl and application thereof | |
| CN105379722A (en) | Sterilizing composition containing mepanioyrim and ethirimol and application thereof | |
| CN105379724A (en) | Sterilizing composition containing mepanioyrim and metalaxyl-M and application thereof | |
| CN105475342A (en) | Bactericidal composition containing silthiopham and fluazinam and application thereof | |
| CN105557745A (en) | Bactericidal composition containing silthiopham and tiadinil and application thereof | |
| CN105394060A (en) | Sterilization composition containing mepanipyrim and propamocarb and application thereof | |
| CN105746527A (en) | Fungicidal composition containing isopyrazam and boscalid and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160413 |